Some standard content:
GB 4838--2000
This standard is a revised version based on GB4838-1984 "Emulsion Pesticide Packaging" in combination with the current development status of pesticide packaging in my country. The main points of the revision are as follows.
In Chapter 5 "Technical Requirements for Packaging":
Added requirements for the packaging environment, the packaging process must not pollute the surrounding environment, the preparation before packaging, and the packaged products must be inspected and qualified;
In terms of packaging, added high-density polyethylene fluorinated bottles and their quality requirements; stipulated that small packaging must add medium packaging; supplemented the requirements for packaging measurement deviation and the reserved amount of packaging bottles (barrels). In Chapter 6: "Packaging Marking":
In terms of outer packaging marking, added requirements for the "three certificates" number and warranty period;-label content, added provisions for E-ISO common name, factory address, toxicity mark and product warranty period. In the chapters "Test Methods" and "Packaging Acceptance": - The difficult-to-operate road transport test is cancelled, and the pressure bearing test is changed to a more practical stacking test; - The air tightness and hydraulic pressure tests of large barrels in the package are added. This standard replaces GB4838-1984 from the date of implementation. This standard was first issued in December 1984. This standard was proposed by the former Ministry of Chemical Industry.
This standard is under the jurisdiction of Shenyang Chemical Research Institute. This standard was drafted by Shenyang Chemical Research Institute. Participating drafting units of this standard: Jiangsu Longdeng Boshimo Packaging Materials Co., Ltd., Shandong Huayang Pesticide Chemical Group Co., Ltd., Shandong Pesticide Industry Co., Ltd.
The main drafters of this standard: Lou Shaowei, Hou Yukai, Chen Jinchun, Gao Dejun, Teng Jun. 315
1 Scope
National Standard of the People's Republic of China
Packaging for emulsifiable concentrates of pesticides
GB 4838—2000
Replaces GB4838-1984
This standard specifies the packaging technical requirements, packaging markings, and the transportation, storage, test methods and packaging acceptance of emulsifiable concentrates of pesticides.
This standard is applicable to packaging of emulsifiable concentrates of pesticides.
2 Cited Standards
The provisions contained in the following standards constitute the provisions of this standard through reference in this standard. When this standard is published, the versions shown are valid. All standards are subject to revision, and parties using this standard should explore the possibility of using the latest versions of the following standards. GB190-1990 Dangerous Goods Packaging Marking
GB191—1990 Pictorial Marking of Packaging Storage and Transportation
GB/T325—1991 Steel Drum
GB/T2637—1995 Safety
GB2638—1981 Glass Medicine Bottle
9 General Rules for Pesticide Packaging
GB 3796--1999
GB/T 4122. 1--1996
GB/T 4857.1—1992
GB/T 4857.3--1992
Basics of packaging terminology
: Method of marking various parts during testing
Transport packages
Static load stacking test method
Transport packages
Packaging of transport packages
GB/T 4857.5—1992
GB/T6543-1986Corrugated paper boxes
GB/T 69801995
Calcium plastic corrugated boxes
Drop test method
GB12463--1990General technical conditions for dangerous goods transport packaging GB/T 17344--1998
Airtightness test method
、Packaging container
3 Terminology
The packaging terms used in this standard shall comply with the provisions of GB/T4122.1. 4 Packaging classification
4.1 Pesticide emulsifiable concentrate packaging is divided into two categories: one is large barrel packaging, which should use steel drums or plastic drums with a capacity of 250L (kg), 200L (kg), 100L (kg), 50L (kg); the other is bottle (bag) packaging, which should use glass bottles, high-density polyethylene fluoride bottles and other equivalent bottles (bags), etc. The net content of each bottle is 1000mL (g), 500mL (g), 250mL (g), 100mL (g), etc. 4.2 The packaging form of pesticide emulsifiable concentrate shall comply with the requirements for storage, transportation, sales and use. It is permitted to use equivalent packaging other than this standard or more advanced packaging approved by the State Administration of Quality and Technical Supervision on July 31, 2000 316
2001-03-01 implementation
GB 4838-2000
, but it must meet the test requirements specified in this standard. 5 Packaging technical requirements
5.1 Packaging environment and packaging preparation
5.1.1 The packaging environment of pesticide emulsifiable concentrates should be kept clean, dry, well ventilated, and well lit, with detoxification and fire prevention facilities. The packaging process must not pollute the surrounding environment.
5.1.2 Packaging barrels and packaging bottles must be clean and dry, not undergo any physical or chemical reactions with the contents, and be able to protect the product from the adverse effects of external environmental conditions; and the specific requirements for packaging containers should be specified in the product standards or ordering agreements. 5.1.3 Pesticide emulsions that are easily decomposed by light should be packaged in opaque bottles, such as high-density polyethylene fluoride bottles and brown glass bottles. 5.1.4 Pesticide emulsions that are easily decomposed by water should not be packaged in ordinary plastic bottles and polyester bottles. 5.1.5 When packaging pesticide emulsions, it is necessary to prevent confusion between different varieties. For example, when packaging insecticides and fungicides, herbicides must not be mixed in to avoid serious pesticide damage.
5.2 Product Packaging
Before packaging, pesticide emulsion products should be inspected by the quality inspection department to meet the corresponding product standards and issue a quality certificate before packaging.
5.3 Packaging Materials
Pesticide emulsions generally use the following packaging materials. 5.3.1 Glass bottles
5.3.1.1 Appearance: The bottle body is smooth, the color is pure, the bottle mouth is round and straight, the thickness is uniform, there are no cracks, and there are few bubbles. 5.3.1.2 No bursting after rapid cooling with a temperature difference of 35°C. Test according to Chapter 9 of Part 4 of GB2638--1981. 5.3.1.3 Chemical stability: Keep the glass bottle containing methyl red acid solution in a water bath at 85°C for 30 minutes, and the light red color should not disappear. Test according to Chapter 10 of Part 4 of GB2638--1981. 5.3.2 High-density polyethylene fluoride bottle
5.3.2.1 Should not undergo any physical and chemical reaction with the contents. 5.3.2.2 Should be able to effectively prevent moisture (water) in the air from penetrating into the bottle. 5.3.2.3 Should have sufficient mechanical strength and meet the requirements of Class 3.2I plastic bottles in GB3796. 5.3.2.4 Fluorination performance: After the inner wall is painted with Sudan red dye, it is placed at (50 ± 2) ℃ for 15 minutes. After cleaning with X-100 fatty acid salt solution or other feasible detergents, there should be no red residue on the inner wall of the bottle. 5.3.3 An
shall comply with the provisions of GB/T2637.
5.3.4 Steel drums and plastic drums
Steel drums shall comply with the provisions of GB/T325 and the test quantitative value requirements of 3.2 of GB3796-1999 for Class I steel drums; plastic drums shall comply with the test quantitative value requirements of 3.2 of GB3796-1999 for Class I plastic drums. 5.3.5 Corrugated paper boxes
shall comply with the provisions of GB/T6543.
5.3.6 Calcium plastic corrugated boxes
shall comply with the provisions of GB/T6980.
5.3.7 Shockproof materials
Common shockproof materials include straw covers, corrugated paper covers, pads, partitions, bubble plastic films and expanded polystyrene molding films. 5.4 Product packaging requirements
5.4.1 Inner packaging
5.4.1.1 Glass bottles and high-density polyethylene fluorinated bottles or equivalent bottles should be used for the inner packaging of pesticide emulsions. Glass bottles and fluorinated bottles should have suitable inner plugs and screw caps or outer caps with gaskets. The packaged bottles should not leak when inverted. 317
GB 4838—2000
5.4.1.2 The inner packaging units of pesticide emulsions are generally 100mL (g), 200mL (g), 250mL (g), 500mL (g), 1000mL (g) (different packaging units can also be used according to user requirements). The packaging measurement deviation shall comply with the "Regulations on the Supervision of Measurement of Quantitatively Packaged Commodities" (Order No. 43 of the former State Administration of Technical Supervision).
5-4.1.3 Plant growth regulators and some other high-efficiency pesticide emulsions can be packaged in 4-10 packs and sealed with hot melt. The packaging volume per 4-10 pack is generally 2 ml (g), 5 mL (g), and 10 mL (g). Usually, every 10 packs are placed in a corrugated paper box (or other material box) as the middle packaging. 5.4.1.4 Pesticide emulsions used for subpackaging are generally packaged in large barrels (steel barrels, plastic barrels), with a net content of 50 kg (L), 100 kg (1), 200 kg (L), and 250 kg (L) per barrel. The barrel cover should have a gasket, and after tightening, it should be inverted and there should be no leakage. 5.4.1.5 The packaging bottles (barrels, bags) containing pesticide emulsions should have an appropriate reserve to ensure safety. 5.4.2 Outer packaging
5.4.2.1 The outer packaging of pesticide emulsions mainly adopts corrugated paper boxes and calcium plastic corrugated boxes for pesticides. The net weight of each box should not exceed 15 kg. 5.4.2.2, Assembly quantity of outer packaging
The assembly quantity of outer packaging is determined according to the packaging unit and net content. The recommended assembly quantity is shown in Table 1. Table 1, Assembly quantity of outer packaging
Packaging unit (g or mL)
The above packaging unit and assembly quantity can also be adjusted appropriately according to user requirements. 5.4.3 Packing and sealing
Assembly quantity
Net content (kg or L)
6~～8
5.4.3.1Put the qualified pesticide emulsifiable concentrate into the specified packaging bottle, cover the inner plug and outer cover, and seal it. 5.4.3.2 Attach a conspicuous and firm label to the bottle. For glass bottles, cover them with shockproof materials such as corrugated paper or bubble plastic. 5.4.3.3 After placing a cushion at the bottom of the corrugated paper box (calcium plastic box), arrange the bottles in order in the box according to the assembly quantity specified in 5.4.2.2, and cover it with a piece of corrugated paper board or foam plastic board or other shockproof materials. 5.4.3.4 For corrugated paper boxes and calcium plastic boxes, the bottom and cover of the box are sealed with tape or nails. Then, according to the total mass of the packaging box, use polypropylene strapping tape to tie two horizontal strips, three horizontal strips, two vertical strips and one horizontal strip, or two vertical and horizontal strips to form a "well" shape. The tied outer packaging should not be loose under normal storage and transportation conditions. For light packaging boxes below 5kg, no strapping is required, but it must meet the test requirements of this standard. 6 Packaging Marking
6.1 Identification of packaging box parts
According to 2.1 of GB/T4857.1-1992, the provisions of each side of the parallelepiped packaging box are shown in Figure 1. Figure 1 Identification of various parts of the packaging box
6.2 Inner packaging (middle packaging) label
A firm and eye-catching label should be affixed to the inner packaging bottle and the middle packaging box. The label content should include: 318
GB 4838—2000
1) Product name (active ingredient content + Chinese common name + dosage form); 2) E-ISO common name;
3) Active ingredient and its content (single active ingredient preparation can be omitted); 4) Pesticide registration certificate number;
5) Production license (pesticide production approval certificate) number; 6) Product standard number;
7) Net content (by mass, g or by volume, mI); 8) Trademark;
9) Production date or (and) batch number;
10) Manufacturer (company) name;
11) Manufacturer (company) address, telephone, fax and zip code can also be marked; 12) Toxicity mark (according to the actual measured data of the product's acute oral toxicity, it can be divided into highly toxic, 13) Product instructions for use;
14) Precautions (especially safety precautions and scope of use); 15) Warranty period;
16) Approved product name and product barcode may be added according to conditions. In addition, the label shall also comply with the national "Product Identification and Labeling Regulations" (Technical Supervision Bureau Supervision [1997172]). 6.3 For the marking of large barrels for repackaging, refer to 6.2, but the product instructions and other content may be omitted. 6.4 External packaging marking
6.4.1 On the 5th and 6th sides of the box (see Figure 1), the trademark is marked in the upper left corner, and the product name (active ingredient content) is marked in the upper middle part. Volume + Chinese common name + dosage form); the pesticide registration number, production license (pesticide production approval certificate) number and product standard number are marked from left to right above the product name. The manufacturer (company) name is marked at the bottom of sides 5 and 6, and the manufacturer (company) address, telephone, fax and zip code, etc. are marked below the name (the specific arrangement of the above marking content can also be adjusted appropriately). 6.4.2 Toxicity and other hazard signs are marked on the upper part of sides 2 and 4 of the box, and the packaging unit and assembly quantity, net content, box specifications [length × width × height (mm)], production date or (and) batch number and warranty period are marked in the middle and lower part. The color bar markings are divided into different colors according to the different biological activities of the pesticides.
Herbicides - green, insecticides - red, fungicides - black, rodenticides - blue, plant Plant growth regulators - the dark yellow label and the color bar mark at the bottom of the front of the packaging box should be consistent with the provisions of GB3796. 7 Package transportation and storage
7.1 Transportation
7.1.1 During the transportation process, the drug should be handled in accordance with the requirements for drug loading and unloading, pay attention to safety protection, handle with care, and not drop, roll or invert. 7.1.2 Automobile transportation should be covered with rainproof tarpaulin and tied with ropes to prevent slipping. 7.1.3 Railway transportation should use boxcars and be shipped in accordance with the regulations for railway drug transportation. 7.1.4 During transportation, it should not be mixed with food, seeds, and feed, avoid contact with skin and eyes, and prevent inhalation through the mouth and nose. 7.2 Storage
7.2.1 Pesticide emulsion packages and barrels should be stored in a ventilated and dry warehouse, and the warehouse should be away from fire sources. 7.2.2 Corrugated paper packaging boxes and calcium plastic boxes should be stacked at a height of more than 100mm from the ground, and the stacking height should not exceed 3.0m. 7.2.3 As pesticide emulsifiable concentrate products are toxic and flammable, there should be anti-toxic, fire-proof and moisture-proof facilities in the warehouse. 7.2.4 When pesticide emulsifiable concentrate packages are stored in cargo yards and docks, they must be covered with felt cloth, kept away from fire sources, and warning signs must be hung. 7.2.5 When stored, they must not be mixed with food, seeds, or feed to prevent children from contacting them. 319Www.bzxZ.net
8 Test methods
8.1 The stacking test shall be carried out in accordance with GB/T4857.3. 8.2 The drop test shall be carried out in accordance with GB/T4857.5. 8.3 The airtight test shall be carried out in accordance with GB/T17344. GB 4838—2000
8.4 The hydraulic test shall be carried out in accordance with Appendix C of GB/T325—1991. 9 Packaging acceptance
9.1 Packaging quality inspection
9.1.1 Sampling: For each batch less than 10,000 pieces, 0.5% sampling (at least 3 pieces) shall be taken; for each batch greater than 10,000 pieces, 0.3% sampling shall be taken. 9.1.2 Appearance inspection: The package is intact, without loose or falling straps, with clear markings, complete contents and correct positions. 9.1.3 Unpacking inspection: The label of the packaging bottle is firm, the contents are clear and complete, and no wrong, crooked or missing labels shall be allowed. The packaging quantity is correct, and the certificate and instruction manual are placed in the box. The batch number of the certificate and the batch number of the bottle body shall be consistent. 9.1.4 Leakage inspection: Turn the packaging box upside down for 3 minutes, unpack and inspect, and there should be no leakage at the bottle mouth. 9.1.5 Net content inspection: Deduct the mass of the empty bottle and accept according to the national measurement regulations for quantitatively packaged commodities. 9.1.6 Stacking test of packaging: It shall meet the requirements of Table 1 in 4.1 of GB12463-1990. 9.1.7 Package drop test: It shall meet the ear level requirements of Table 2, 4.1, GB12463-1990. 9.1.8 Package airtightness test: It shall meet the requirements of Level 1, Table 3, 4.1, GB12463-1990. 9.1.9 Package hydraulic test: It shall meet the requirements of Table 4, 4.1, GB12463-1990. 9.2 Package quality acceptance
When the user and the manufacturer have a dispute over the quality of the package, the user has the right to re-test it according to the provisions of this standard. If the re-test results do not meet the requirements of this standard, the user has the right to reject it. 3202. Assembly quantity of outer packaging
The assembly quantity of outer packaging is determined according to the packaging unit and net content. The recommended assembly quantity is shown in Table 1. Table 1, Assembly quantity of outer packaging
Packaging unit (g or mL)
The above packaging unit and assembly quantity can also be adjusted appropriately according to user requirements. 5.4.3 Packing and sealing
Assembly quantity
Net content (kg or L)
6~～8
5.4.3.1Put the qualified pesticide emulsifiable concentrate into the specified packaging bottle, cover the inner plug and outer cover, and seal it. 5.4.3.2 Attach a conspicuous and firm label to the bottle. For glass bottles, cover them with shockproof materials such as corrugated paper or bubble plastic. 5.4.3.3 After placing a cushion at the bottom of the corrugated paper box (calcium plastic box), arrange the bottles in order in the box according to the assembly quantity specified in 5.4.2.2, and cover it with a piece of corrugated paper board or foam plastic board or other shockproof materials. 5.4.3.4 For corrugated paper boxes and calcium plastic boxes, the bottom and cover of the box are sealed with tape or nails. Then, according to the total mass of the packaging box, use polypropylene strapping tape to tie two horizontal strips, three horizontal strips, two vertical strips and one horizontal strip, or two vertical and horizontal strips to form a "well" shape. The tied outer packaging should not be loose under normal storage and transportation conditions. For light packaging boxes below 5kg, no strapping is required, but it must meet the test requirements of this standard. 6 Packaging Marking
6.1 Identification of packaging box parts
According to 2.1 of GB/T4857.1-1992, the provisions of each side of the parallelepiped packaging box are shown in Figure 1. Figure 1 Identification of various parts of the packaging box
6.2 Inner packaging (middle packaging) label
A firm and eye-catching label should be affixed to the inner packaging bottle and the middle packaging box. The label content should include: 318
GB 4838—2000
1) Product name (active ingredient content + Chinese common name + dosage form); 2) E-ISO common name;
3) Active ingredient and its content (single active ingredient preparation can be omitted); 4) Pesticide registration certificate number;
5) Production license (pesticide production approval certificate) number; 6) Product standard number;
7) Net content (by mass, g or by volume, mI); 8) Trademark;
9) Production date or (and) batch number;
10) Manufacturer (company) name;
11) Manufacturer (company) address, telephone, fax and zip code can also be marked; 12) Toxicity mark (according to the actual measured data of the product's acute oral toxicity, it can be divided into highly toxic, 13) Product instructions for use;
14) Precautions (especially safety precautions and scope of use); 15) Warranty period;
16) Approved product name and product barcode may be added according to conditions. In addition, the label shall also comply with the national "Product Identification and Labeling Regulations" (Technical Supervision Bureau Supervision [1997172]). 6.3 For the marking of large barrels for repackaging, refer to 6.2, but the product instructions and other content may be omitted. 6.4 External packaging marking
6.4.1 On the 5th and 6th sides of the box (see Figure 1), the trademark is marked in the upper left corner, and the product name (active ingredient content) is marked in the upper middle part. Volume + Chinese common name + dosage form); the pesticide registration number, production license (pesticide production approval certificate) number and product standard number are marked from left to right above the product name. The manufacturer (company) name is marked at the bottom of sides 5 and 6, and the manufacturer (company) address, telephone, fax and zip code, etc. are marked below the name (the specific arrangement of the above marking content can also be adjusted appropriately). 6.4.2 Toxicity and other hazard signs are marked on the upper part of sides 2 and 4 of the box, and the packaging unit and assembly quantity, net content, box specifications [length × width × height (mm)], production date or (and) batch number and warranty period are marked in the middle and lower part. The color bar markings are divided into different colors according to the different biological activities of the pesticides.
Herbicides - green, insecticides - red, fungicides - black, rodenticides - blue, plant Plant growth regulators - the dark yellow label and the color bar mark at the bottom of the front of the packaging box should be consistent with the provisions of GB3796. 7 Package transportation and storage
7.1 Transportation
7.1.1 During the transportation process, the drug should be handled in accordance with the requirements for drug loading and unloading, pay attention to safety protection, handle with care, and not drop, roll or invert. 7.1.2 Automobile transportation should be covered with rainproof tarpaulin and tied with ropes to prevent slipping. 7.1.3 Railway transportation should use boxcars and be shipped in accordance with the regulations for railway drug transportation. 7.1.4 During transportation, it should not be mixed with food, seeds, and feed, avoid contact with skin and eyes, and prevent inhalation through the mouth and nose. 7.2 Storage
7.2.1 Pesticide emulsion packages and barrels should be stored in a ventilated and dry warehouse, and the warehouse should be away from fire sources. 7.2.2 Corrugated paper packaging boxes and calcium plastic boxes should be stacked at a height of more than 100mm from the ground, and the stacking height should not exceed 3.0m. 7.2.3 As pesticide emulsifiable concentrate products are toxic and flammable, there should be anti-toxic, fire-proof and moisture-proof facilities in the warehouse. 7.2.4 When pesticide emulsifiable concentrate packages are stored in cargo yards and docks, they must be covered with felt cloth, kept away from fire sources, and warning signs must be hung. 7.2.5 When stored, they must not be mixed with food, seeds, or feed to prevent children from contacting them. 319
8 Test methods
8.1 The stacking test shall be carried out in accordance with GB/T4857.3. 8.2 The drop test shall be carried out in accordance with GB/T4857.5. 8.3 The airtight test shall be carried out in accordance with GB/T17344. GB 4838—2000
8.4 The hydraulic test shall be carried out in accordance with Appendix C of GB/T325—1991. 9 Packaging acceptance
9.1 Packaging quality inspection
9.1.1 Sampling: For each batch less than 10,000 pieces, 0.5% sampling (at least 3 pieces) shall be taken; for each batch greater than 10,000 pieces, 0.3% sampling shall be taken. 9.1.2 Appearance inspection: The package is intact, without loose or falling straps, with clear markings, complete contents and correct positions. 9.1.3 Unpacking inspection: The label of the packaging bottle is firm, the contents are clear and complete, and no wrong, crooked or missing labels shall be allowed. The packaging quantity is correct, and the certificate and instruction manual are placed in the box. The batch number of the certificate and the batch number of the bottle body shall be consistent. 9.1.4 Leakage inspection: Turn the packaging box upside down for 3 minutes, unpack and inspect, and there should be no leakage at the bottle mouth. 9.1.5 Net content inspection: Deduct the mass of the empty bottle and accept according to the national measurement regulations for quantitatively packaged commodities. 9.1.6 Stacking test of packaging: It shall meet the requirements of Table 1 in 4.1 of GB12463-1990. 9.1.7 Package drop test: It shall meet the ear level requirements of Table 2, 4.1, GB12463-1990. 9.1.8 Package airtightness test: It shall meet the requirements of Level 1, Table 3, 4.1, GB12463-1990. 9.1.9 Package hydraulic test: It shall meet the requirements of Table 4, 4.1, GB12463-1990. 9.2 Package quality acceptance
When the user and the manufacturer have a dispute over the quality of the package, the user has the right to re-test it according to the provisions of this standard. If the re-test results do not meet the requirements of this standard, the user has the right to reject it. 3202. Assembly quantity of outer packaging
The assembly quantity of outer packaging is determined according to the packaging unit and net content. The recommended assembly quantity is shown in Table 1. Table 1, Assembly quantity of outer packaging
Packaging unit (g or mL)
The above packaging unit and assembly quantity can also be adjusted appropriately according to user requirements. 5.4.3 Packing and sealing
Assembly quantity
Net content (kg or L)
6~～8
5.4.3.1Put the qualified pesticide emulsifiable concentrate into the specified packaging bottle, cover the inner plug and outer cover, and seal it. 5.4.3.2 Attach a conspicuous and firm label to the bottle. For glass bottles, cover them with shockproof materials such as corrugated paper or bubble plastic. 5.4.3.3 After placing a cushion at the bottom of the corrugated paper box (calcium plastic box), arrange the bottles in order in the box according to the assembly quantity specified in 5.4.2.2, and cover it with a piece of corrugated paper board or foam plastic board or other shockproof materials. 5.4.3.4 For corrugated paper boxes and calcium plastic boxes, the bottom and cover of the box are sealed with tape or nails. Then, according to the total mass of the packaging box, use polypropylene strapping tape to tie two horizontal strips, three horizontal strips, two vertical strips and one horizontal strip, or two vertical and horizontal strips to form a "well" shape. The tied outer packaging should not be loose under normal storage and transportation conditions. For light packaging boxes below 5kg, no strapping is required, but it must meet the test requirements of this standard. 6 Packaging Marking
6.1 Identification of packaging box parts
According to 2.1 of GB/T4857.1-1992, the provisions of each side of the parallelepiped packaging box are shown in Figure 1. Figure 1 Identification of various parts of the packaging box
6.2 Inner packaging (middle packaging) label
A firm and eye-catching label should be affixed to the inner packaging bottle and the middle packaging box. The label content should include: 318
GB 4838—2000
1) Product name (active ingredient content + Chinese common name + dosage form); 2) E-ISO common name;
3) Active ingredient and its content (single active ingredient preparation can be omitted); 4) Pesticide registration certificate number;
5) Production license (pesticide production approval certificate) number; 6) Product standard number;
7) Net content (by mass, g or by volume, mI); 8) Trademark;
9) Production date or (and) batch number;
10) Manufacturer (company) name;
11) Manufacturer (company) address, telephone, fax and zip code can also be marked; 12) Toxicity mark (according to the actual measured data of the product's acute oral toxicity, it can be divided into highly toxic, 13) Product instructions for use;
14) Precautions (especially safety precautions and scope of use); 15) Warranty period;
16) Approved product name and product barcode may be added according to conditions. In addition, the label shall also comply with the national "Product Identification and Labeling Regulations" (Technical Supervision Bureau Supervision [1997172]). 6.3 For the marking of large barrels for repackaging, refer to 6.2, but the product instructions and other content may be omitted. 6.4 External packaging marking
6.4.1 On the 5th and 6th sides of the box (see Figure 1), the trademark is marked in the upper left corner, and the product name (active ingredient content) is marked in the upper middle part. Volume + Chinese common name + dosage form); the pesticide registration number, production license (pesticide production approval certificate) number and product standard number are marked from left to right above the product name. The manufacturer (company) name is marked at the bottom of sides 5 and 6, and the manufacturer (company) address, telephone, fax and zip code, etc. are marked below the name (the specific arrangement of the above marking content can also be adjusted appropriately). 6.4.2 Toxicity and other hazard signs are marked on the upper part of sides 2 and 4 of the box, and the packaging unit and assembly quantity, net content, box specifications [length × width × height (mm)], production date or (and) batch number and warranty period are marked in the middle and lower part. The color bar markings are divided into different colors according to the different biological activities of the pesticides.
Herbicides - green, insecticides - red, fungicides - black, rodenticides - blue, plant Plant growth regulators - the dark yellow label and the color bar mark at the bottom of the front of the packaging box should be consistent with the provisions of GB3796. 7 Package transportation and storage
7.1 Transportation
7.1.1 During the transportation process, the drug should be handled in accordance with the requirements for drug loading and unloading, pay attention to safety protection, handle with care, and not drop, roll or invert. 7.1.2 Automobile transportation should be covered with rainproof tarpaulin and tied with ropes to prevent slipping. 7.1.3 Railway transportation should use boxcars and be shipped in accordance with the regulations for railway drug transportation. 7.1.4 During transportation, it should not be mixed with food, seeds, and feed, avoid contact with skin and eyes, and prevent inhalation through the mouth and nose. 7.2 Storage
7.2.1 Pesticide emulsion packages and barrels should be stored in a ventilated and dry warehouse, and the warehouse should be away from fire sources. 7.2.2 Corrugated paper packaging boxes and calcium plastic boxes should be stacked at a height of more than 100mm from the ground, and the stacking height should not exceed 3.0m. 7.2.3 As pesticide emulsifiable concentrate products are toxic and flammable, there should be anti-toxic, fire-proof and moisture-proof facilities in the warehouse. 7.2.4 When pesticide emulsifiable concentrate packages are stored in cargo yards and docks, they must be covered with felt cloth, kept away from fire sources, and warning signs must be hung. 7.2.5 When stored, they must not be mixed with food, seeds, or feed to prevent children from contacting them. 319
8 Test methods
8.1 The stacking test shall be carried out in accordance with GB/T4857.3. 8.2 The drop test shall be carried out in accordance with GB/T4857.5. 8.3 The airtight test shall be carried out in accordance with GB/T17344. GB 4838—2000
8.4 The hydraulic test shall be carried out in accordance with Appendix C of GB/T325—1991. 9 Packaging acceptance
9.1 Packaging quality inspection
9.1.1 Sampling: For each batch less than 10,000 pieces, 0.5% sampling (at least 3 pieces) shall be taken; for each batch greater than 10,000 pieces, 0.3% sampling shall be taken. 9.1.2 Appearance inspection: The package is intact, without loose or falling straps, with clear markings, complete contents and correct positions. 9.1.3 Unpacking inspection: The label of the packaging bottle is firm, the contents are clear and complete, and no wrong, crooked or missing labels shall be allowed. The packaging quantity is correct, and the certificate and instruction manual are placed in the box. The batch number of the certificate and the batch number of the bottle body shall be consistent. 9.1.4 Leakage inspection: Turn the packaging box upside down for 3 minutes, unpack and inspect, and there should be no leakage at the bottle mouth. 9.1.5 Net content inspection: Deduct the mass of the empty bottle and accept according to the national measurement regulations for quantitatively packaged commodities. 9.1.6 Stacking test of packaging: It shall meet the requirements of Table 1 in 4.1 of GB12463-1990. 9.1.7 Package drop test: It shall meet the ear level requirements of Table 2, 4.1, GB12463-1990. 9.1.8 Package airtightness test: It shall meet the requirements of Level 1, Table 3, 4.1, GB12463-1990. 9.1.9 Package hydraulic test: It shall meet the requirements of Table 4, 4.1, GB12463-1990. 9.2 Package quality acceptance
When the user and the manufacturer have a dispute over the quality of the package, the user has the right to re-test it according to the provisions of this standard. If the re-test results do not meet the requirements of this standard, the user has the right to reject it. 3202 Inner packaging (middle packaging) label
A firm and eye-catching label should be affixed to the inner packaging bottle and the middle packaging box. The label content should include: 318
GB 4838—2000
1) Product name (active ingredient content + Chinese common name + dosage form); 2) E-ISO common name;
3) Active ingredient and its content (single active ingredient preparation can be omitted); 4) Pesticide registration certificate number;
5) Production license (pesticide production approval certificate) number; 6) Product standard number;
7) Net content (by mass, g or by volume, mI); 8) Trademark;
9) Production date or (and) batch number;
10) Manufacturer (company) name;
11) Manufacturer (company) address, telephone, fax and zip code can also be marked; 12) Toxicity mark (according to the actual measured data of the product's acute oral toxicity, it can be divided into highly toxic, 13) Product instructions for use;
14) Precautions (especially safety precautions and scope of use); 15) Warranty period;
16) Approved product name and product barcode may be added according to conditions. In addition, the label shall also comply with the national "Product Identification and Labeling Regulations" (Technical Supervision Bureau Supervision [1997172]). 6.3 For the marking of large barrels for repackaging, refer to 6.2, but the product instructions and other content may be omitted. 6.4 External packaging marking
6.4.1 On the 5th and 6th sides of the box (see Figure 1), the trademark is marked in the upper left corner, and the product name (active ingredient content) is marked in the upper middle part. Volume + Chinese common name + dosage form); the pesticide registration number, production license (pesticide production approval certificate) number and product standard number are marked from left to right above the product name. The manufacturer (company) name is marked at the bottom of sides 5 and 6, and the manufacturer (company) address, telephone, fax and zip code, etc. are marked below the name (the specific arrangement of the above marking content can also be adjusted appropriately). 6.4.2 Toxicity and other hazard signs are marked on the upper part of sides 2 and 4 of the box, and the packaging unit and assembly quantity, net content, box specifications [length × width × height (mm)], production date or (and) batch number and warranty period are marked in the middle and lower part. The color bar markings are divided into different colors according to the different biological activities of the pesticides.
Herbicides - green, insecticides - red, fungicides - black, rodenticides - blue, plant Plant growth regulators - the dark yellow label and the color bar mark at the bottom of the front of the packaging box should be consistent with the provisions of GB3796. 7 Package transportation and storage
7.1 Transportation
7.1.1 During the transportation process, the drug should be handled in accordance with the requirements for drug loading and unloading, pay attention to safety protection, handle with care, and not drop, roll or invert. 7.1.2 Automobile transportation should be covered with rainproof tarpaulin and tied with ropes to prevent slipping. 7.1.3 Railway transportation should use boxcars and be shipped in accordance with the regulations for railway drug transportation. 7.1.4 During transportation, it should not be mixed with food, seeds, and feed, avoid contact with skin and eyes, and prevent inhalation through the mouth and nose. 7.2 Storage
7.2.1 Pesticide emulsion packages and barrels should be stored in a ventilated and dry warehouse, and the warehouse should be away from fire sources. 7.2.2 Corrugated paper packaging boxes and calcium plastic boxes should be stacked at a height of more than 100mm from the ground, and the stacking height should not exceed 3.0m. 7.2.3 As pesticide emulsifiable concentrate products are toxic and flammable, there should be anti-toxic, fire-proof and moisture-proof facilities in the warehouse. 7.2.4 When pesticide emulsifiable concentrate packages are stored in cargo yards and docks, they must be covered with felt cloth, kept away from fire sources, and warning signs must be hung. 7.2.5 When stored, they must not be mixed with food, seeds, or feed to prevent children from contacting them. 319
8 Test methods
8.1 The stacking test shall be carried out in accordance with GB/T4857.3. 8.2 The drop test shall be carried out in accordance with GB/T4857.5. 8.3 The airtight test shall be carried out in accordance with GB/T17344. GB 4838—2000
8.4 The hydraulic test shall be carried out in accordance with Appendix C of GB/T325—1991. 9 Packaging acceptance
9.1 Packaging quality inspection
9.1.1 Sampling: For each batch less than 10,000 pieces, 0.5% sampling (at least 3 pieces) shall be taken; for each batch greater than 10,000 pieces, 0.3% sampling shall be taken. 9.1.2 Appearance inspection: The package is intact, without loose or falling straps, with clear markings, complete contents and correct positions. 9.1.3 Unpacking inspection: The label of the packaging bottle is firm, the contents are clear and complete, and no wrong, crooked or missing labels shall be allowed. The packaging quantity is correct, and the certificate and instruction manual are placed in the box. The batch number of the certificate and the batch number of the bottle body shall be consistent. 9.1.4 Leakage inspection: Turn the packaging box upside down for 3 minutes, unpack and inspect, and there should be no leakage at the bottle mouth. 9.1.5 Net content inspection: Deduct the mass of the empty bottle and accept according to the national measurement regulations for quantitatively packaged commodities. 9.1.6 Stacking test of packaging: It shall meet the requirements of Table 1 in 4.1 of GB12463-1990. 9.1.7 Package drop test: It shall meet the ear level requirements of Table 2, 4.1, GB12463-1990. 9.1.8 Package airtightness test: It shall meet the requirements of Level 1, Table 3, 4.1, GB12463-1990. 9.1.9 Package hydraulic test: It shall meet the requirements of Table 4, 4.1, GB12463-1990. 9.2 Package quality acceptance
When the user and the manufacturer have a dispute over the quality of the package, the user has the right to re-test it according to the provisions of this standard. If the re-test results do not meet the requirements of this standard, the user has the right to reject it. 3202 Inner packaging (middle packaging) label
A firm and eye-catching label should be affixed to the inner packaging bottle and the middle packaging box. The label content should include: 318
GB 4838—2000
1) Product name (active ingredient content + Chinese common name + dosage form); 2) E-ISO common name;
3) Active ingredient and its content (single active ingredient preparation can be omitted); 4) Pesticide registration certificate number;
5) Production license (pesticide production approval certificate) number; 6) Product standard number;
7) Net content (by mass, g or by volume, mI); 8) Trademark;
9) Production date or (and) batch number;
10) Manufacturer (company) name;
11) Manufacturer (company) address, telephone, fax and zip code can also be marked; 12) Toxicity mark (according to the actual measured data of the product's acute oral toxicity, it can be divided into highly toxic, 13) Product instructions for use;
14) Precautions (especially safety precautions and scope of use); 15) Warranty period;
16) Approved product name and product barcode may be added according to conditions. In addition, the label shall also comply with the national "Product Identification and Labeling Regulations" (Technical Supervision Bureau Supervision [1997172]). 6.3 For the marking of large barrels for repackaging, refer to 6.2, but the product instructions and other content may be omitted. 6.4 External packaging marking
6.4.1 On the 5th and 6th sides of the box (see Figure 1), the trademark is marked in the upper left corner, and the product name (active ingredient content) is marked in the upper middle part. Volume + Chinese common name + dosage form); the pesticide registration number, production license (pesticide production approval certificate) number and product standard number are marked from left to right above the product name. The manufacturer (company) name is marked at the bottom of sides 5 and 6, and the manufacturer (company) address, telephone, fax and zip code, etc. are marked below the name (the specific arrangement of the above marking content can also be adjusted appropriately). 6.4.2 Toxicity and other hazard signs are marked on the upper part of sides 2 and 4 of the box, and the packaging unit and assembly quantity, net content, box specifications [length × width × height (mm)], production date or (and) batch number and warranty period are marked in the middle and lower part. The color bar markings are divided into different colors according to the different biological activities of the pesticides.
Herbicides - green, insecticides - red, fungicides - black, rodenticides - blue, plant Plant growth regulators - the dark yellow label and the color bar mark at the bottom of the front of the packaging box should be consistent with the provisions of GB3796. 7 Package transportation and storage
7.1 Transportation
7.1.1 During the transportation process, the drug should be handled in accordance with the requirements for drug loading and unloading, pay attention to safety protection, handle with care, and not drop, roll or invert. 7.1.2 Automobile transportation should be covered with rainproof tarpaulin and tied with ropes to prevent slipping. 7.1.3 Railway transportation should use boxcars and be shipped in accordance with the regulations for railway drug transportation. 7.1.4 During transportation, it should not be mixed with food, seeds, and feed, avoid contact with skin and eyes, and prevent inhalation through the mouth and nose. 7.2 Storage
7.2.1 Pesticide emulsion packages and barrels should be stored in a ventilated and dry warehouse, and the warehouse should be away from fire sources. 7.2.2 Corrugated paper packaging boxes and calcium plastic boxes should be stacked at a height of more than 100mm from the ground, and the stacking height should not exceed 3.0m. 7.2.3 As pesticide emulsifiable concentrate products are toxic and flammable, there should be anti-toxic, fire-proof and moisture-proof facilities in the warehouse. 7.2.4 When pesticide emulsifiable concentrate packages are stored in cargo yards and docks, they must be covered with felt cloth, kept away from fire sources, and warning signs must be hung. 7.2.5 When stored, they must not be mixed with food, seeds, or feed to prevent children from contacting them. 319
8 Test methods
8.1 The stacking test shall be carried out in accordance with GB/T4857.3. 8.2 The drop test shall be carried out in accordance with GB/T4857.5. 8.3 The airtight test shall be carried out in accordance with GB/T17344. GB 4838—2000
8.4 The hydraulic test shall be carried out in accordance with Appendix C of GB/T325—1991. 9 Packaging acceptance
9.1 Packaging quality inspection
9.1.1 Sampling: For each batch less than 10,000 pieces, 0.5% sampling (at least 3 pieces) shall be taken; for each batch greater than 10,000 pieces, 0.3% sampling shall be taken. 9.1.2 Appearance inspection: The package is intact, without loose or falling straps, with clear markings, complete contents and correct positions. 9.1.3 Unpacking inspection: The label of the packaging bottle is firm, the contents are clear and complete, and no wrong, crooked or missing labels shall be allowed. The packaging quantity is correct, and the certificate and instruction manual are placed in the box. The batch number of the certificate and the batch number of the bottle body shall be consistent. 9.1.4 Leakage inspection: Turn the packaging box upside down for 3 minutes, unpack and inspect, and there should be no leakage at the bottle mouth. 9.1.5 Net content inspection: Deduct the mass of the empty bottle and accept according to the national measurement regulations for quantitatively packaged commodities. 9.1.6 Stacking test of packaging: It shall meet the requirements of Table 1 in 4.1 of GB12463-1990. 9.1.7 Package drop test: It shall meet the ear level requirements of Table 2, 4.1, GB12463-1990. 9.1.8 Package airtightness test: It shall meet the requirements of Level 1, Table 3, 4.1, GB12463-1990. 9.1.9 Package hydraulic test: It shall meet the requirements of Table 4, 4.1, GB12463-1990. 9.2 Package quality acceptance
When the user and the manufacturer have a dispute over the quality of the package, the user has the right to re-test it according to the provisions of this standard. If the re-test results do not meet the requirements of this standard, the user has the right to reject it. 3203 The airtight test shall be carried out in accordance with GB/T17344. GB 4838—2000
8.4 The hydraulic test shall be carried out in accordance with Appendix C of GB/T325—1991. 9 Packaging acceptance
9.1 Packaging quality inspection
9.1.1 Sampling: For each batch less than 10,000 pieces, 0.5% sampling (at least 3 pieces) shall be taken; for each batch greater than 10,000 pieces, 0.3% sampling shall be taken. 9.1.2 Appearance inspection: The package is intact, without loose or falling straps, with clear markings, complete contents and correct positions. 9.1.3 Unpacking inspection: The label of the packaging bottle is firm, the contents are clear and complete, and it shall not be wrongly pasted, crookedly pasted or omitted. The packaging quantity is correct, and the certificate of conformity and instruction manual are placed in the box. The batch number of the certificate of conformity and the batch number of the bottle body shall be consistent. 9.1.4 Leakage inspection: Turn the packaging box upside down for 3 minutes, unpack and inspect, and there should be no leakage at the bottle mouth. 9.1.5 Net content inspection: deduct the weight of the empty bottle and accept in accordance with the national metrology regulations for quantitatively packaged goods. 9.1.6 Stacking test of packages: shall meet the requirements of Table 1 in 4.1 of GB12463-1990. 9.1.7 Drop test of packages: shall meet the ear level requirements of Table 2 in 4.1 of GB12463-1990. 9.1.8 Airtightness test of packages: shall meet the requirements of Level 1 in Table 3 in 4.1 of GB12463-1990. 9.1.9 Hydraulic test of packages: shall meet the requirements of Table 4 in 4.1 of GB12463-1990. 9.2 Acceptance of packaging quality
When the user and the manufacturer have a dispute over the quality of the packaging, the user has the right to re-inspect it in accordance with the provisions of this standard. If the re-inspection results do not meet the requirements of this standard, the user has the right to reject it. 3203 The airtight test shall be carried out in accordance with GB/T17344. GB 4838—2000
8.4 The hydraulic test shall be carried out in accordance with Appendix C of GB/T325—1991. 9 Packaging acceptance
9.1 Packaging quality inspection
9.1.1 Sampling: For each batch less than 10,000 pieces, 0.5% sampling (at least 3 pieces) shall be taken; for each batch greater than 10,000 pieces, 0.3% sampling shall be taken. 9.1.2 Appearance inspection: The package is intact, without loose or falling straps, with clear markings, complete contents and correct positions. 9.1.3 Unpacking inspection: The label of the packaging bottle is firm, the contents are clear and complete, and it shall not be wrongly pasted, crookedly pasted or omitted. The packaging quantity is correct, and the certificate of conformity and instruction manual are placed in the box. The batch number of the certificate of conformity and the batch number of the bottle body shall be consistent. 9.1.4 Leakage inspection: Turn the packaging box upside down for 3 minutes, unpack and inspect, and there should be no leakage at the bottle mouth. 9.1.5 Net content inspection: deduct the weight of the empty bottle and accept in accordance with the national metrology regulations for quantitatively packaged goods. 9.1.6 Stacking test of packages: shall meet the requirements of Table 1 in 4.1 of GB12463-1990. 9.1.7 Drop test of packages: shall meet the ear level requirements of Table 2 in 4.1 of GB12463-1990. 9.1.8 Airtightness test of packages: shall meet the requirements of Level 1 in Table 3 in 4.1 of GB12463-1990. 9.1.9 Hydraulic test of packages: shall meet the requirements of Table 4 in 4.1 of GB12463-1990. 9.2 Acceptance of packaging quality
When the user and the manufacturer have a dispute over the quality of the packaging, the user has the right to re-inspect it in accordance with the provisions of this standard. If the re-inspection results do not meet the requirements of this standard, the user has the right to reject it. 320
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