This standard specifies the requirements, sampling, test methods, inspection rules, and marking, labeling, packaging, transportation and storage of fluorescent brightener 013-1 (CI fluorescent brightener 393). This product is mainly used for whitening thermoplastics, polyester chips and polyester fibers. HG/T 3703-2002 Fluorescent Brightener OB-1 HG/T3703-2002 Standard download decompression password: www.bzxz.net

ICS 71.100.01;87.060.10
Chemical Industry Standard of the People's Republic of China
(2002)
Published on 2002-09-28
Implemented on 2003-06-01
Registration No. of the State Economic and Trade Commission of the People's Republic of China: 10975-2002
HG/T3703-2002
This standard is a newly formulated recommended chemical industry standard. This standard is proposed by the oil and chemical industry enterprises. This standard is the National Chemical Standardization Technical Requirements for Imported Materials, and was drafted by Feng Misheng, Shenyang Chemical Research Institute, and Shenzhen Huayang Chemical Company. The main authors of this standard are: Dong Shisheng, Jiu, Rong Jianming, and Zhu Baijun! This standard is released for the first time.
This standard is the responsibility of the National Dye Standardization Committee of the People's Republic of China. 1 Jiang Wei
Chemical Industry Standard of the People's Republic of China
Fluuresent wlitening agrnt aB-1C/T3703—2002
The standard specifies the requirements for the properties of light-sensitive agents (1<(.1, light-sensitive agents 393), sampling, cold test methods, inspection period and marking, signature, and packaging.
This product is used for the heat-resistant plastics, cut and red-core polyester. Format:
Type: tHNO
Quality list: 415:7 International Relative Quality Standards 2 Reference Standards
The following standards contain clauses that shall be cited in this standard and constitute the clauses of this standard. This standard is valid from the latest version: All standards will be revised. The use of this standard is not allowed! The latest version of the standard is G3/T125
GR/T 2372
GB/I ​​23&j
GH:T S87A
G:T5332
Indication and determination of acceptable values
Determination of dyestuff staining conditions
Determination of dyestuff intermediate water
1 General rules for product collection
Specifications and test methods for water in absorption chambers S396:?) 1. Determination of product composition
Quality requirements of fluorescent agent 1: Table 1 Requirements for the amount of fluorescent agent-fluorescent agent
Tag name
"Light-emitting diode: for product)Www.bzxZ.net
4. Price 4 Standard products
Contents
7 pieces, 55
Approved by the Ministry of Economic Affairs of the People's Republic of China on September 28, 2002 Purpose
Product price average powder technology
10u±3
2003-06-01 implementation
4 Sampling
HG/T3703-2002
The sampling is carried out in batches, and the products mixed and divided in batches are considered as one batch. The number of sampling barrels for each batch shall comply with the provisions of 3. subsection of Taiwan F5678-19F. The packaging of the sampled products must be intact, and the sampling time must be such that the outside world is close to the product. The sampling is carried out from the upper, middle and lower parts with a probe. The total amount of the sampled products should be less than 233. The sampled products should be fully scalded and divided into containers that are clean, dry, light-resistant and well-sealed. The containers shall be marked with the product name, batch number, sampling date and place, and the samples shall be kept for inspection.
5 Test method
Unless otherwise noted, the reagents in this standard and the analytically pure test water shall conform to the optical properties of the test water specified in GSS32 (B/T120-1s15.2 Specification for the image comparison test results). 5.1 Appearance evaluation
The evaluation shall be conducted once a month.
5.2 Determination of light intensity
5.2.1 Total reagents in the instrument
UV-visible For the light treatment, the sensitivity is m1, c) colorimetric cell: 10n-25ml, d) colorimetric cell: distillation cell, ccam: isobutylene glycol, NN-methoxyethylamide (IMF) 5.2.2 Analysis of the sample Take the inflammatory reagent (0.011g each and the test piece, and dilute to 0.cc3 16, put L. in water, add dichloromethane to dissolve, and then add 10% brown solution to the sample, then dilute to the mark, and mix in ultrasonic light, and absorb the solution, and measure the concentration of 1% 25% by volume. Use 1MF to measure the concentration. Take DF as the reference, and use 1emm colorimetric cell to measure the extinction position at m. In the process of determination, from solution to extinction, do not control the effect, and do not place the sample for too long, so as to avoid the sample being affected by light. 2. Measure the preparation and timing of the sample, and avoid light exposure. 5.2.3 Analysis of the results of the test The degree of transparency is calculated according to the formula (E×1
wherein. · The extinction value of the sample is:
The mass of the sample is:
The amount of the sample,
The two methods are measured in parallel. The remaining difference is 2 points: 5.3 Whitening and color light determination
5.3.1 Formula and financial agent
a) Standard salt test material: 10g/1
Dyeing agent MF: 10/L.
d) Sulfur acid: 98%.
E Oxidation agent: 100F:L.
Cleaning agent
5. 3.2 Fabric pretreatment
HG/T3703—2002
The fabric is treated under the following conditions.
3/. Detergent JTT, bath ratio is 1:100, 70~X0 treatment 1(1min), take out, wash with water, remove the water, and prepare. 5.3.3 Preparation
Take fluorescent whitening system 8: standard sample and test sample (accurate to 0.0001g), add 3ml of acid to each beaker and dissolve it as much as possible, add this liquid to the mixture and stir rapidly Next, add 5L of dispersant MF, add the total volume of the liquid in water not exceeding 4mL, and transfer all the liquid to a large beaker with a small beaker of water. Then add 1000mL of brown concentrate to the beaker, dilute with water to the mark, and take about 50mL of the brown concentrate with water. Prepare according to Table 2. The color depth is 0.5W (UWl> East color with 2g of pure polyester cloth, the latent ratio is 11. Table? Preparation of dyeing film: 0.005% mixed dyeing: 0.001/mL dyeing solution: 1 4/L about dyeing solution: 5. 3. 4 Dyeing machine: use acetic acid 7 brand sales belt to adjust to .. ~ 5 times the pressure: heat to 400℃ in a dyeing machine, heat to 130℃ in 4℃, dye at 50℃, cool down, take out and wash with water, dry for ten minutes. 5.3.5 Evaluation of chromatic intensity and color
According to the specification of CB/23749, the first edition
5.4 Determination of content
5.4.1 Summary of the method
Use the sensitive phase chromatographic method, and use the standard method to quantify to obtain the content of B1 on the carrier. 5.4.2 Instrument and stationary phase
The liquid cabinet chromatograph meets the operating requirements,
Relatively speaking: the flow rate is 1.~5mT./m; in this case, the internal temperature is 1.0~1.0mT./m; ... ]--5mV recorder or universal chromatographic latent count machine. Excitation: flat radiator, wall sonicator. Analytical flat (point, 5.4.3 Test and material preparation a) Alcohol, HG/I3703-2002, optical enhancement 17 (with the chromatographic conditions specified in 5.4.2) 5.4.4 Chromatographic separation conditions a) Flow rate: medium alcohol, bi wavelength sram c flow rate t. mL/in, density: 10 Sichuan ultra-high extraction, gas condensation conditions are different, choose the best separation conditions, the mobile phase composition is degassed by an ultrasonic generator. 5.4.5 Fat model diameter
5.4.5.1 Preparation of external standard solution
Take 111% pure product of fluorescent brand 1 and add 1% chloroform to 0.02% beaker, add 1% brown liquid, add 1% trichloroethane to dissolve, and fully dissolve in ultraviolet radiation. This external standard solution is as follows: Assume that the product should be protected from light. 5.4.5.2 Preparation of sample solution
Sample 11mg (accurate 0.00u2g) of fluorescent brightener (B-1) is placed in a 0.1% beaker. Transfer the sample to 1% chloroform and bring it to the scale in a colorimetric container. Use three bottles of methane to degrade the sample. After the whole is fully dissolved by sonication, this is the sample solution. It should be stored away from sunlight. 5.4 .6 Analytical step
Preheat the machine for 10i-20i. After the instrument is tested, add 10.0% of the external standard liquid and the test liquid into the new sample and use the gasket to treat it. 5.4.7 The new sample is calculated based on the mass fraction of 9% or less or the content of the optical enhancement agent 2) in the north: Ame
In the formula: the composition fraction of bisulfite 1 in the pure product, the composition fraction of external standard optical enhancement agent B in the test solution; the quality of the test product shall be no more than 8%. The value of the result of the second determination should not be greater than 1/2. Take the non-determination system 5.4.8 Color consumption
Flame light network (1 liquid busy color No. Attached with example Figure 1.
5.5 Determination of volatile matter content
IC/T3703·2002
1 state 24 know things: 3 Micron increase mouth 11114 a know thing 1 Micron mountain Qi - liquid and color medicine
6H/238% dry method: let 1 out of the step (300 5): 5.6 points determination
according to ([3/7531 provisions, calcination temperature is 55) 1351. 6 inspection classification
6.1 inspection classification
2 standard coordinate table 1 12, 67 teachers for the first 5, small 5 items for the fixed age items: in the continuous effect of the normal production once a year.
6.2 ! The quality inspection department of the production department shall conduct inspections according to the requirements of the standard. The production department shall ensure that all the products out of the "fluorescent whitening agent" meet the requirements of the standard. 6. 3 If any quality index in the inspection result does not meet the requirements of this standard, the sample can be taken from the package for inspection within two months. If only one quality index meets the requirements of this standard, the whole batch of products cannot be accepted. 7 Marking, labeling, packaging, transportation and storage 7.1 European markings, etc. For fluorescent whitening, each package shall be painted with a firm and clear label, starting with the product name, specification, and label, and the standard number and batch number shall be printed on it. It is also called the standard number and batch number. In the standard product quality inspection certificate, the packaging plastic value, 7.2 bags
capital increase judgment - H type iron drum packaging, add seal and to, 4 kg or 5 kg net fruit content: other positions negotiated with the user.
age group Kaiya measurement limit, small light change hospital fire, anti-rate, the river do not damage the packaging. .5
HG/T:37032002
7.4 care
strict storage of products in cold, dry and windy warehouse: storage for one cow.
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