Safety rules for classification、precautionary labelling and precautionary statements of chemicals - Flammable solids
Some standard content:
1CS 13.300
National Standard of the People's Republic of China
GB20582-2006
Safety rules for classification, prccautionary labelling and precautionary statements of chemicals--Flammablesolids2006-10-24Promulgated
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China
Standardization Administration of China
2008-01-01Implementation
Chapter 4, Chapter 6, Chapter 7, Chapter 8 of this standard Chapter 1 is mandatory, and the rest are recommended. GB20582-2006
This standard is not equivalent to the United Nations "Globally Harmonized System of Classification and Labeling of Chemicals" (IIS). Its relevant technical content is consistent with iHS. The text format of the standard is in accordance with GB/T1200C. This standard was proposed by the National Technical Committee for the Management of Hazardous Chemicals (5AC/T25I) and is under the responsibility of the drafting unit: Small Chemical Standardization Institute. This standard was drafted by Jiangsu Export and Import Bureau. Inspection and Quarantine Bureau, Sichuan Provincial Dangerous Chemicals Quality Supervision and Inspection Institute, Shandong Exit-Entry Inspection and Quarantine Bureau, Jiangxi Exit-Entry Inspection and Quarantine Bureau The main contributors of this standard are: Shi Wanbing, Song Zhenqian, Jiang Rong, Xu Yan, Qian Xinyou, Zheng Wei. This standard will be implemented in the small production field from January 1, 2008; in the circulation field from December 31, 2008; and in the transition period from November 1, 2008 to December 31, 2008. Scope
Chemical classification, warning labels and warning statements Safety specifications Flammable solids
CB 205822006
This standard specifies the technical description and definition, classification, demarcation and guidance, category and hazard warning labels, configuration of category safety labels and warning instructions for flammable substances.
This standard applies to the hazard classification, warning labels and other warning instructions of combustion-supporting substances in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals.
2 Normative References
The provisions of the following documents are used or applied to this standard through reference. The terms of this standard. For undated references, all subsequent amendments (not including errata) or revisions are not applicable to this standard. However, parties to this standard are encouraged to study whether to use the latest version of these documents. For undated references, the latest version applies. 6169.142005 Classification and name of dangerous goods (United Nations Chemical Classification and Standards) United Nations Recommendations on the Transport of Dangerous Goods (United Nations Recommendations on the Transport of Dangerous Goods) 3. Terms and definitions
Flammable solids
refer to substances that are easily ignited and can cause or promote ignition through friction. Flammable solids refer to substances that are dangerous and can be easily ignited and ignite quickly if they come into short contact with an ignition source (such as a lit match). 4. Classification || tt||4.1 When powdered, granular or mixed materials or mixtures are tested one or more times in accordance with the United Nations Recommendations on the Transport of Dangerous Goods, Part III, Section 33.2, the burning point is less than 15 or the burning rate is greater than 2.2 mm, they are classified as flammable solids. 4.2 When weak or alloyed powders can be ignited and extend to the entire length of the sample in 10 minutes or less, they are classified as flammable bodies.
4,3 Before the point of the award (striking a match) is reached, the solid can be classified as flammable solids:
4.4 According to Table 1 of the United Nations Recommendations on the Transport of Dangerous Goods, the test and standards are in the register, 2.! Classification of flammable solids: For materials or mixtures other than metal powders: a) the humid zone can block flames for at least 4 m and b) the burning time is less than 22 ms or the burning rate is greater than 22 ms, for metal powders, the burning time is not less than 10 m: Burning rate test: For materials or mixtures other than metal powders: a) the humid zone can block flames for at least 4 m and h) the burning time is less than 4 s or the burning rate is greater than 2.2 mm/s, the qualified final
burning area is greater than
or equal to
Method: For the classification test of fixed substances or mixtures, the test should be carried out according to the mixture provided. For example: if a chemical substance is submitted in a form different from the form in the test for the purpose of transport, and it is considered that the performance is actually the same as that in the classification test, then the substance must also be tested in the new form. 5 Decision process
The decision process for delisting is not part of the coordinated classification system, but is an additional indicator The guidance proposes that the personnel responsible for the classification of flammable phases should conduct a study before and during the use of the judgment process. The classification of flammable phases should be carried out according to the N.1 test method specified in Section 33.2.1 of the United Nations Recommendations on the Transport of Dangerous Goods Tests and Criteria. The procedure consists of two tests: a screening test and a burning rate test. Classification is carried out according to the judgment process in Figure 1. Mass transfer of materials/wetted compounds
Screening test
Burning rate test
Materials or intermediates other than metals have a combustion time of less than 4b5 or a burning rate of 2.2 m:e Metal content:
Burning time less than 10-in
Materials or intermediates other than powders: Does the wetted area prevent the flame?
All metal powders:
Burning time 5:nin Code?
Flammable solid determination process
Not classified
Non-flammable
Category 1
6Categories and warning labels
Flammable solid categories and warning labels are shown in Table 2.
Table 2 Flammable solid categories and warning labels
Hazard categories
Burning rate test:
Non-metallic powder materials
The wet zone does not stop burning, the combustion distance is less than 455 or the combustion speed is less than 2.2mm/s
Metallic powder:
The burning time is not more than 5 min
Burning rate test:
Non-enterprise powder materials
The wet zone does not stop burning, the combustion distance is less than 4 mi, and the combustion distance is less than s or the combustion speed is greater than 2, 2 mm/s.
Metal powder:
Burning time is greater than 5 min and less than or equal to 10 uint7 Configuration of categories and labels
GB 20582—2006
Warning label elements
Graphic symbol
Hazard statements
Graphic symbol
Hazard statements
Flammable solids
For chemical products, each category of the hazard type is listed in the order of designated graphic symbols, names and hazard statements. The United Nations Recommendations on the Transport of Dangerous Goods Model Regulations involve dangerous types. According to the requirements of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GIIS), the corresponding graphic signs for each category are listed below. The configuration of flammable solid categories and label elements is shown in Table 3.
Category 1
Flammable solids
Category 2
Flammable solids
Configuration of flammable solid categories and label elements Remarks
In the "Recommendations on the Transport of Dangerous Goods Model Regulations":
) The color of the rectangular sign
Graphic code, numbers
Black:
Background: white band
with seven drooping
stripes.
The number 4 in the figure is
GK 69442005
.
The general minimum size of the cargo delivery graphic mark
is
100 nm×:100 mml
GB 20582—2006
8 Precautionary statements
The standard provides some general precautionary statements, which are intended to provide instructions for labels of specific substances. The instructions provided for labels of specific substances should use the precautionary statements that are most suitable for the specific situation. When using the words in brackets in the precautionary statements, any words in the brackets can be used to supplement the core content contained in the sentence or replace the content. 8.1 Statement of physical hazards
Precautionary statements
Avoid sources of fire:
Keep away from open flames (no inhalation)
Keep away from heat sources, sparks) and flames (no inhalation). Keep away from heat and fire sources (no inhalation).
Stay away from the sun, avoid smoking
Avoid heat sources, ignition sources, oxidants. Do not smoke. Do not shout at fire, avoid sparks and inhale oxidants. Do not use tools that may produce ignition.
Avoid direct sunlight,
Keep away from open flames, fire and hot surfaces.
Avoid near heat sources or places where the product is stored. b) Container instructions:
Keep the container closed,
Keep the container closed
Keep the container closed when not in use,
Store in a sealed container.
! Can be stored in the original container
Storage of container packaging:
and in a cool place:
Keep the temperature change not more than (
Below the boiling point" (
Below the melting point) Decompose at (
)
Also decompose when
Keep the container/package in a well-ventilated place
Keep the container/package in a well-ventilated place, and store it in the original container, and in a well-ventilated place. Keep the container/package tightly closed and in a well-ventilated place, and store it in a cool/low temperature, well-ventilated (100 degrees Celsius) place (away from heat and fire sources)), and store and transport it within the explosion limit range according to the dangerous chemical packaging-list.
Exposed to a temperature higher than 4.4℃130F) may cause a small fire) Separate it from incompatible substances and store it:
It is forbidden to be transported together with oxidants, etc. During transportation and purchase, oxidants, oxygen, explosives, [hazardous elements, compressed air, [acids] and alkalis] and food chemicals should be isolated from each other: Oxidants, acids and explosives should not be stored and transported. 4 c) Firefighting: Use carbon dioxide, deionized water or foaming socks. In case of fire hazard, use [8.2 Instructions for preventing possible misuse and exposure to health effects 8.2.1 Ventilation control Use in well-ventilated areas. Use only under proper ventilation conditions [or close the system ventilation device]. Do not enter the use area and storage area without proper ventilation. 20582—2006
It can only be used under the condition of adequate ventilation (or closed system ventilation) to keep the harmful substances (dust, smoke, gas, etc. in the air) low. The recommended contact limit is 100%.
Use appropriate ventilation to remove vapors (smoke, dust, etc.). Use proper ventilation and control in high temperature operations to avoid exposure to vapors. During use and use, avoid vapor accumulation by providing appropriate ventilation. "When using, there is a ventilation device" and local exhaust ventilation must be used. Respiratory protection is prohibited. Use in an area with appropriate ventilation. Do not inhale (powder vapor or spray).
8.2.2 Hygiene measures
It is prohibited to smoke, eat or drink during use.
It is prohibited to eat, drink or inhale during work.
Wash before eating and drinking.
|Wash thoroughly after handling
Avoid all contact and maintain good hygiene.
Prevent contact with skin and eyes:
Prevent contact with shoes.
Prevent splashing in eyes
Wash thoroughly with soap and water after handling and before eating, drinking or smoking.
Prevent contact with skin, eyes and clothing.
Prevent splashing in eyes, eyes and clothing.
Prevent contact with skin (eyes or clothing)
Prevent splashing in eyes, eyes and clothing
8.2.3 Personal protective equipment
Wear appropriate protective clothing (goggles/mask). Wear protective clothing and gloves (regular protective equipment): Wear eye protection (goggles, mask or safety glasses). Wear appropriate personal protective equipment. Avoid contact with eyes. 8.3 Instructions for appropriate measures in the event of an accident 8.3. 1 Leakage
Be sure to stay away from the danger zone.
In case of leakage, consult an expert,
The manufacturer is the only material! Clean the area and all objects contaminated by this substance. Cover with an absorbent or put into containers. Collect and dispose of. Cover the spill with a scourer
Soak up the remaining material in sand or an inert absorbent and store in a safe place. GB 20582--2006
Wash the remaining liquid at the door
with plenty of water. Do not flush the leak directly into the sewer.
Avoid it from flowing into drains and sewers.
Clean up the leak immediately:
Sweep it up and remove it immediately.
Handle flammable leaks with non-sparking equipment and remove all sources of ignition. Ensure that the fan is properly ventilated to remove steam and fumes. Collect the leak and spillage into a sealable (metal, plastic) container as much as possible. Do not return the leak to the original container.
Clean up the leak with a vacuum cleaner
Sweep the leak into
Sweep the leak into a second group to collect the remaining.
Remove the remaining material and put it in the hand
8. 3.2 Fire fighting
Container.
Container; if necessary, wet it first to avoid dust. Dust 1 Move to a safe place
If avoiding fire, use (specify the exact type of fire fighting equipment) If water will increase the danger, do not use water. Use sulfamonium sulfate, dry powder or foam,
Water can be used to cool or protect the exposed material. If the gas flow cannot be cut off, allow the gas to burn. Cut off the source, such as firewood. No harm to the surroundings. Let the fire burn out by itself: Otherwise, use If the surroundings are on fire: All extinguishing agents can be used. If the surroundings are on fire: (Use appropriate extinguishing agents). Firefighters should wear complete protective clothing, including portable breathing apparatus. 8.4 First aid
8.4.1 General
In case of accident or physical discomfort, seek medical help immediately (post medical labels where possible). When calling a poison control center, emergency station or doctor for treatment, you should carry the product cover or label with you. 8.4.
Accidents caused by inhalation
In case of inhalation, take the victim to fresh air and keep quiet. If inhaled, give medical treatment immediately.
Move the victim to fresh air and rest!bzxz.net
Immediately move the victim to fresh air: give medical treatment immediately. If symptoms or signs continue to appear, seek medical attention immediately. If breathing stops, give artificial respiration. If breathing is difficult: give oxygen.
Adopt a semi-supine position.
Use artificial respiration if necessary.
Do not use mouth-to-mouth respiration.
If inhaled, give oxygen or human respiration, seek medical attention. If inhaled, amyl nitrite, get medical treatment. Take the patient to fresh air, call 120 emergency or call for ambulance, then perform artificial respiration, preferably mouth-to-mouth respiration if possible. Call the poison control center or doctor for further treatment. 8.4.3 Accidents caused by ingestion. If the person should get skin treatment immediately: If swallowed, induce vomiting, seek medical treatment immediately and show the container or label. If swallowed, seek medical treatment immediately and show the container or label. If swallowed: flush the mouth with water (only applicable to the case of conscious injured person) If swallowed, and the patient is conscious and awake, induce vomiting immediately according to the doctor's instructions. (Do not induce vomiting). (If conscious, give two glasses of water and get medical treatment immediately). Drink (one glass of two) water. Call a doctor (or call the poison control center immediately). Give activated carbon slurry.
Inhalation (only for patients who are conscious) Do not inhale.
Do not give anything to drink.
Drink plenty of water.
Breathe,
Inhalation wears protective cover.
If inhaled, drink lukewarm water, induce vomiting, call a doctor. If inhaled, drink slightly moist (water) to vomit, clear the stomach and call a doctor. If inhaled, drink plant matter, inhalation, call a doctor. If inhaled, rinse the mouth with water, drink milk or milk. If inhaled, use sodium thiosulfate aqueous solution to wash the stomach. If inhaled, induce vomiting, use sodium thiosulfate aqueous solution to wash the stomach. If inhaled, inhalation, enema and gastric lavage can be used with vegetable oil. If inhaled, use copper sulfate aqueous solution to wash the stomach. If inhaled, use sodium thiosulfate aqueous solution to wash the stomach and clear the stomach. If inhaled, induce vomiting,Wash with potassium permanganate solution. If ingested, drink milk or live food, wash the stomach, call a doctor, if ingested, call the poisoning center or doctor immediately for treatment advice. If the injured can, let him take a sip of water. Do not vomit. Wash the mouth with water. If ingested, there are no corrosion symptoms, wash the mouth. If ingested, vomit, wash the stomach with 60mL potassium iodide solution, call a specialist or doctor: Do not feed anything to unconscious people. 8. 4.4 Accidents caused by skin contact GB 20582—2006 After contact with the skin, take off all contaminated clothes immediately and wash with water (the product specified by the manufacturer): (If irritation develops or persists, seek medical treatment immediately): If irritation develops and persists, seek medical treatment immediately, wash with a soft detergent immediately. Then wash with water for 15 minutes]. Rinse with plenty of water. (If irritation develops and continues, seek medical treatment immediately).
Immediately rinse the skin with plenty of water and remove contaminated clothing. If irritation (redness, rash, pools) deepens, seek medical treatment immediately. GB 20582—2006
Before reuse, wash contaminated clothing. Remove contaminated clothing only after thorough washing. Wash contaminated body parts with plenty of water. Wash contaminated body parts with soap and fresh water: If in direct contact with the body, seek medical treatment immediately. If in contact with skin or eyes, wash with water. If injured,
If in contact with skin, immediately apply 2 ml of silver nitrate aqueous solution, remove contaminated clothing
Immediately rinse the skin with plenty of water for 1 mn-29 rin. 8.4.5 Accidents caused by eye contact
In case of contact, flush the eye immediately with a solution specified by the manufacturer for at least 15 minutes. Immediately seek medical attention. If the eyelids are open, flush with plenty of water for at least 15 minutes. If necessary, seek medical advice. Irrigate the open eye with diluted water for at least 15 minutes. If glasses are worn, remove them and seek medical attention immediately. First rinse with plenty of water (if contact lenses can be removed) and then seek medical attention immediately. In case of contact with eyes, rinse thoroughly with slow-moving water and keep the eyes open for 5 minutes to 20 minutes. For contact lens wearers, remove contact lenses after the first 5 minutes and then continue rinsing.
8.5 Instructions for environmental protection and appropriate disposal
Environmental protection
Use appropriate containment measures to avoid environmental contamination, avoid release into the surrounding environment, (refer to the chemical safety data sheet) to prevent accumulation in the surrounding environment.
Use appropriate containment measures
Do not allow this chemical/product to enter the surrounding environment. Do not add directly to water, or use in areas with surface water or in areas below the mean water mark, and do not pollute the overall water quality when discharging equipment or handling equipment. Do not add directly to water.
Nuclear chemicals have the properties and characteristics of combining with chemicals detected in groundwater. Use of this chemical in areas where the soil is permeable, especially in areas with a shallow groundwater table, can lead to groundwater contamination: this chemical has been known to enter the groundwater under certain conditions. Use of this chemical in areas where the soil is permeable, especially in areas with shallow groundwater, can lead to groundwater contamination. 8.5.2 Disposal
Send the container to a hazardous or special waste collection station. This substance and its container must be treated as hazardous waste. This substance and its container must be disposed of as hazardous waste. Do not dispose of with household waste, garbage or other body waste in an approved waste disposal facility. Do not enter the sewer.
Do not enter the sewer: Dispose of this substance and its container in a safe manner. Do not enter the sewer; take the substance and its container to a hazardous or special waste collection station. This substance and its container must be disposed of in a safe manner. Do not come into contact with water, food or feed when stored. Do not allow waste to enter any body of water or soil. Dispose of in an approved recycling, compression or incineration plant. Incinerate in a municipal incinerator. Do not pour used product into any indoor or outdoor sewer. 5 Special instructions for consumers. Keep away from food, drink and animal feed: Avoid contact. GB20582-2006 GB20582-2006 People's Republic of China International Standard for Classification, Precautionary Labelling and Universal Declaration of Safety for Chemicals Flammable Solids Gl1 205x2:20n6
Published and distributed by China Publishing House
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1Le Ying 60 Infant5 Instructions for environmental protection and appropriate disposal
Environmental protection
Use appropriate containment measures to avoid environmental contamination, avoid release into the surrounding environment, (refer to the chemical safety data sheet) prevent accumulation in the surrounding environment.
Use appropriate containment measures
Do not allow the chemical/product to enter the surrounding environment. Do not add directly to water, or use in areas with surface water or in areas below the mean water level, do not pollute the overall water quality when discharging equipment or handling equipment. Do not add directly to water.
The chemical has the properties and characteristics of combining with other chemicals detected in groundwater. The use of the chemical in areas where the soil is permeable, especially in areas below the groundwater table, can lead to sewage contamination: the chemical is known to enter groundwater through the soil under certain conditions. In areas where the main residue is permeable, use of this chemical in areas with shallow groundwater may lead to groundwater contamination. 8.5.2 Disposal
The container must be sent to a hazardous or special waste collection station. The substance and its container must be treated as hazardous waste. The substance and its container must not be disposed of with household waste, garbage or other waste in an approved waste disposal facility. Do not enter the sewer.
Do not enter the sewer: Dispose of the substance and its container in a safe manner. Do not enter the sewer; take the substance and container to a hazardous or special waste collection station. The substance and container must be disposed of in a safe manner and do not contaminate water, food or feed when stored. Do not allow it to enter any body of water. Please consult the manufacturer and supplier for information on waste management/disposal. (The waste management options are (choose the appropriate word from the following): Use sparingly. Reuse or recycle. Dispose of in approved recycling, compression or incineration equipment Incinerate in a municipal incinerator Do not pour used product into any indoor or outdoor sewer 5 Special instructions for consumers
Follow contact
Keep away from food, drink and animal feed:
Avoid contact.
GB20582-2006
GB20582-2006
People's Republic of China
International
Safety Code for Classification, Precautionary Labelling and Universal Statements of Chemicals Flammable Solids
Gl1 205x2:20n6
Published and distributed by China Publishing House
Beijing Fuxingwai Sanjia Hebei Street Bookstore
Postal code: 180945
Website i sre. et. en
Tel: 1832392618517348
China Times Bad Asian Case Volume Additive
Distributed by Xinhua Mapei in various places
Open 3×1230 1/1n sheet 1 word count 19 「
2007 first edition, 2007 first printing
No.: 15306G·1-29586 Price 17.00 Yuan If there is any printing error, the distribution center of our company will replace it. Copyright infringement will be investigated.
Report phone: (010)68533533
Brown Yaoguai 17bzw.cnCrispy Dai Brown Marrow Drink Dai Brown Color Yuhen Zhang Ke 5
17izw.comHuifeng
Tengzhong Yaofengjia Parrot Hair
1Le Ying 60 Infant5 Instructions for environmental protection and appropriate disposal
Environmental protection
Use appropriate containment measures to avoid environmental contamination, avoid release into the surrounding environment, (refer to the chemical safety data sheet) prevent accumulation in the surrounding environment.
Use appropriate containment measures
Do not allow the chemical/product to enter the surrounding environment. Do not add directly to water, or use in areas with surface water or in areas below the mean water level, do not pollute the overall water quality when discharging equipment or handling equipment. Do not add directly to water.
The chemical has the properties and characteristics of combining with other chemicals detected in groundwater. The use of the chemical in areas where the soil is permeable, especially in areas below the groundwater table, can lead to sewage contamination: the chemical is known to enter groundwater through the soil under certain conditions. In areas where the main residue is permeable, use of this chemical in areas with shallow groundwater may lead to groundwater contamination. 8.5.2 Disposal
The container must be sent to a hazardous or special waste collection station. The substance and its container must be treated as hazardous waste. The substance and its container must not be disposed of with household waste, garbage or other waste in an approved waste disposal facility. Do not enter the sewer.
Do not enter the sewer: Dispose of the substance and its container in a safe manner. Do not enter the sewer; take the substance and container to a hazardous or special waste collection station. The substance and container must be disposed of in a safe manner and do not contaminate water, food or feed when stored. Do not allow it to enter any body of water. Please consult the manufacturer and supplier for information on waste management/disposal. (The waste management options are (choose the appropriate word from the following): Use sparingly. Reuse or recycle. Dispose of in approved recycling, compression or incineration equipment Incinerate in a municipal incinerator Do not pour used product into any indoor or outdoor sewer 5 Special instructions for consumers
Follow contact
Keep away from food, drink and animal feed:
Avoid contact.
GB20582-2006
GB20582-2006
People's Republic of China
International
Safety Code for Classification, Precautionary Labelling and Universal Statements of Chemicals Flammable Solids
Gl1 205x2:20n6
Published and distributed by China Publishing House
Beijing Fuxingwai Sanjia Hebei Street Bookstore
Postal code: 180945
Website i sre. et. en
Tel: 1832392618517348
China Times Bad Asian Case Volume Additive
Distributed by Xinhua Mapei in various places
Open 3×1230 1/1n sheet 1 word count 19 「
2007 first edition, 2007 first printing
No.: 15306G·1-29586 Price 17.00 Yuan If there is any printing error, the distribution center of our company will replace it. Copyright infringement will be investigated.
Report phone: (010)68533533
Brown Yaoguai 17bzw.cnCrispy Dai Brown Marrow Drink Dai Brown Color Yuhen Zhang Ke 5
17izw.comHuifeng
Tengzhong Yaofengjia Parrot Hair
1Le Ying 60 Infant
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