HG/T 2284-1992 Reduced brilliant green 3B ultrafine powder (reduced brilliant green FFB ultrafine powder) HG/T2284-1992 Standard download decompression password: www.bzxz.net

Chemical Industry Standard of the People's Republic of China
HG2284—92
Vat Brilliant Green 3B Ultrafine Powder
(Vat Brilliant Green FFB Ultrafine Powder)
Published on June 1, 1992
Ministry of Chemical Industry of the People's Republic of China
Implementation on January 1, 1993
Chemical Industry Standard of the People's Republic of China
Vat Brilliant Green 3B Ultrafine Powder
(Vat Brilliant Green FFB Ultrafine Powder)
1 Subject content and scope of application
HG2284—92
This standard specifies the technical requirements, test methods, inspection rules and various requirements for marking, packaging, transportation and storage of Vat Brilliant Green 3B Ultrafine Powder.
This standard applies to the raw dye vat Brilliant Green 3B obtained by condensation of 4,4-biphenyl Brilliant Green 3B, oxidation and ring closure to dihydroxy Brilliant Green 3B, methylation, and commercial processing with auxiliaries to make vat Brilliant Green 3B ultrafine powder. This product is mainly used for dyeing and color matching of cotton fibers; it is also suitable for suspension pad dyeing and printing. Structural formula:
Molecular formula: C36H2004
Relative molecular mass: 516.55 (according to the international relative atomic mass in 1989) 2 Reference standards
General conditions for dyeing determination
GB2374
GB2377
GB2386
GB3920
GB3921
GB3922
GB4467
Determination of color light and intensity of vat dyesDetermination of moisture content of dyes and dye intermediatesTest method for color fastness of textiles to rubbing
Test method for color fastness of textiles to washing
Test method for color fastness of textiles to perspiration Test methods for fastness
Determination method for dispersion stability of vat dye suspension GB4841.11/1 Standard depth color card for dyeing with dyes GB6152
GB7069
GB7073
GB8427
Test method for color fastness of textiles to hot pressing (ironing)Test method for color fastness of textiles to hypochlorite bleachingTest method for color fastness of textiles to mercerizing
Test method for color fastness of textiles to lightXenon arc test HG2-1120Determination method for diffusion properties of dyesDetermination method for fineness of dye particlesMicroscope method HG2--1121
3 Technical requirements
3.1 The quality of vat brilliant green 3B ultrafine powder shall comply with the requirements of Table 1. Approved by the Ministry of Chemical Industry of the People's Republic of China on June 1, 1992 and implemented on January 1, 1993
W.bzsoso, con(1) Appearance
(2) Strength, points
(3) Shade
(4) Diffusion performance, level
(5) Particle fineness (number of particles>2um), pieces(6) Moisture, %
(7) Dispersion stability of suspension, %
Standard depth of dyeing
HG2284-92
The color fastness of vat brilliant green 3B ultrafine powder on cotton fabric shall not be lower than that specified in Table 2. Table 2
Lightfastness (arc)
(60℃)
Change of original
Color staining of white cloth
Change of original
Color staining of wool
Color staining of white cloth
Perspiration resistance
Color staining of wool
Note: 1) 1/1 standard depth is equivalent to 2.1% (owf). 4 Test method
4.1 Appearance
The test is carried out by visual inspection.
4.2 Determination of dyeing color and intensity
Change from original sample
Color staining of white cloth
Dark green uniform powder
is 100% of the standard
Similar to the standard~slightly
Resistant to heat pressing (dry)
(200℃)
Change from original sample
2~3Turns to dark blue
Color staining of white cloth
Change from original sample
Change from original sample
Color staining of white cloth
The specifications of the reagents used in dyeing, the preparation of the solution, the specifications of the fibers and the general provisions for dyeing shall be carried out in accordance with the relevant provisions in GB2374.
4.2.1 Preparation of dye bath
The dyeing depth is 1.2%. Use 5g cotton cloth (or 10g cotton yarn) for dyeing (when dyeing with cotton yarn, the amount of dye in Table 3 is doubled, and the bath ratio is 1:20). According to the provisions of full bath reduction in Method A of GB2377, prepare the dye bath in 5 300mL dye vats according to the provisions of Table 3. The reduction temperature is 60℃. bZxz.net
Dye bath components
Vat Brilliant Green 3B standard sample, g
Vat Brilliant Green 3B sample, 8
95% ethanol, mL
10% (m/m) Lakai powder BX solution, mL
35% (m/m) sodium hydroxide solution, mL
85% hydrosulfite
Add 60℃ distilled water to the total volume, mL
W.bzsoso: com4.2.2 Dyeing operation
HG2284-92
Perform according to the provisions of (2) in Article 3, Chapter 2 of GB2377. Dye at 60℃ for 45 minutes, take out, immediately put into running water for washing for several minutes, and then oxidize.
4.2.3 Oxidation treatment
Oxidation shall be carried out according to the provisions of 1) air oxidation in Article 4, Chapter 2 of GB2377. 4.2.4 Soap washing
Soap washing shall be carried out in accordance with the provisions of Article 5, Chapter 2 of GB2377. 4.3 Determination of moisture
Carry out in accordance with the provisions of the "drying method" in GB2386. 4.4 Determination of dispersion stability of vat dye suspension shall be carried out in accordance with the test method in GB4467. After standing for 4 hours, 2 mL of the diluted solution shall be absorbed for the second dilution, and the maximum absorption wavelength of the measurement shall be 600 nm.
4.5 Determination of diffusion performance
Carry out in accordance with the provisions of HG2-1120.
4.6 Determination of particle fineness
Carry out in accordance with the provisions of HG2-1121.
4.7 Determination of color fastness of dyeing on pure cotton fabrics First, the pure cotton fabrics are dyed with the dye to be tested to 1/1 standard depth specified in GB4841.1, and then the color fastness is measured. 4.7.1 Determination of color fastness to light
Perform according to the provisions of GB8427.
4.7.2 Determination of color fastness to washing
Perform according to the conditions of test solution 1 in method 3 of GB3921. 4.7.3 Determination of color fastness to perspiration
Perform according to the provisions of GB3922.
4.7.4 Determination of color fastness to rubbing
Perform according to the provisions of GB3920.
4.7.5 Determination of color fastness to hot pressing (ironing) shall be carried out according to the provisions of GB6152, 200℃ 15s dry pressing. 4.7.6 Determination of color fastness to mercerizing
Perform according to the provisions of GB7073.
4.7.7 Determination of color fastness to hypochlorite bleaching shall be carried out according to the provisions of GB7069.
5 Inspection rules
5.1 Inspection classification
Items (1), 2), (3), and (4) in Table 1 are factory inspection items; items (5), (6), and (7) are periodic inspection items, which are inspected once a month. All items in Table 1 are type inspection items. If one of the six situations specified in Article 6.6.1 of GB1.3 occurs, type inspection should be carried out. Among them, during normal production, it should be carried out once a year. 5.2 Sampling method
Random sampling is carried out in batches. The manufacturer considers uniform products mixed once as a batch, and the user considers products with the same batch number N
from the same manufacturer as a batch. The number of samples shall not be less than V (N is the number of barrels of each batch of products). When sampling small batches of products, the number of samples shall not be less than 3 barrels; if the whole batch of products is less than 3 barrels, samples shall be taken from each barrel. 3
W.HG2284—92
When taking samples, be careful not to let foreign impurities fall into the product. Use a stainless steel sampling tube to probe from the top, middle and bottom. After carefully mixing the samples, take about 100g and put them in two clean and dry brown glass bottles at the factory. Seal the bottle mouth with paraffin wax and label it with the product name, batch number and sampling date. One bottle is for inspection and the other is kept for future reference. 5.3 Factory inspection
Vat Brilliant Green 3B ultrafine powder should be inspected by the quality inspection department of the manufacturer. The manufacturer should ensure that the quality of all Vat Brilliant Green 3B ultrafine powder shipped out of the factory meets the requirements of this standard and attach a quality certificate in a certain format. 5.4 Re-inspection
If the inspection results do not meet the requirements of this standard, samples should be taken from twice the amount of packaging barrels for re-inspection. Even if only one indicator in the re-inspection result does not meet the requirements of this standard, the entire batch of products cannot be accepted. 5.5 User Acceptance
Users have the right to verify the quality of the received V-Brilliant Green 3B ultrafine powder according to the provisions of this standard. When the supply and demand parties have objections to the product quality, they can negotiate to resolve the dispute. When arbitration is required, the arbitration institution shall be determined by negotiation between the two parties. The arbitration method shall be carried out in accordance with the provisions of this standard.
6 Marking, packaging, transportation, purchase and storage
6.1 The product packaging barrel shall be painted with a firm and clear mark, indicating the manufacturer's name, product name, registered trademark, standard number, production date, batch, specification, net weight, gross weight, and attached with a product quality certificate. 6.2 V-Brilliant Green 3B ultrafine powder is packed in an iron barrel lined with a plastic bag. The plastic bag should be tightly tied and sealed with a cover. The net weight of each barrel is 25kg. 6.3 Be careful when transporting, prevent fire, sun and rain, and do not damage the packaging. 6.4 The product should be stored in a cool, dry and ventilated warehouse. Additional Notes:
This standard was proposed by the Science and Technology Department of the Ministry of Chemical Industry of the People's Republic of China. This standard is under the technical jurisdiction of the Shenyang Chemical Research Institute of the Ministry of Chemical Industry. This standard was drafted by the Dye Factory of Jilin Chemical Industry Company. The main drafter of this standard is Wang Shufan.
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