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Rules for classification and labelling of chemicals—Part 14:Oxidizing liquids

Basic Information

Standard ID: GB 30000.14-2013

Standard Name:Rules for classification and labelling of chemicals—Part 14:Oxidizing liquids

Chinese Name: 化学品分类和标签规范 第14部分:氧化性液体

Standard category:National Standard (GB)

state:in force

Date of Release2013-10-10

Date of Implementation:2014-11-01

standard classification number

Standard ICS number:Environmental protection, health care and safety >> 13.300 Dangerous goods protection

Standard Classification Number:Comprehensive>>Marking, packaging, transportation, storage>>A80 Marking, packaging, transportation, storage Comprehensive

associated standards

alternative situation:Replaces GB 20589-2006

Publication information

publishing house:China Standards Press

Publication date:2014-11-01

other information

drafter:Wei Naixin, Ge Xiaojun, Fan Bin, Wang Gaosheng, Xiao Qiuping, Song Wei, Wang Xiaobing, Zhao Xiaoyang, Cao Mengran, Zhang Guangkuan, Wen Tao

Drafting unit:China Chemical Industry Economic and Technological Development Center, China Chemical Industry Information Center, Shanghai Research Institute of Chemical Industry, Zhejiang Research Institute of Chemical Industry Co., Ltd., PONY Testing Technology C

Focal point unit:National Technical Committee on Hazardous Chemicals Management Standardization (SAC/TC 251)

Proposing unit:National Technical Committee on Hazardous Chemicals Management Standardization (SAC/TC 251)

Publishing department:General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China Standardization Administration of China

competent authority:National Technical Committee on Hazardous Chemicals Management Standardization (SAC/TC 251)

Introduction to standards:

GB 30000.14-2013 Chemical Classification and Labelling Specification Part 14: Oxidizing Liquids GB30000.14-2013 Standard compression package decompression password: www.bzxz.net
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of oxidizing liquids. This part applies to the classification and labeling of oxidizing liquids in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals.
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended.
The expected structure of GB30000 "Specifications for Classification and Labelling of Chemicals" and the national standards to be replaced are:
———Part 1: General (replaces GB13690-2009);
———Part 2: Explosives (replaces GB20576-2006);
———Part 3: Flammable gases (replaces GB20577-2006);
———Part 4: Aerosols (replaces GB20578-2006);
———Part 5: Oxidizing gases (replaces GB20579-2006);
———Part 6: Gases under pressure (replaces GB20580-2006);
———Part 7: Flammable liquids (replaces GB20581-2006);
———Part 8: Flammable solids (replaces GB 20582-2006);
———Part 9: Self-reactive substances and mixtures (replaces GB 20583-2006);
———Part 10: Pyrophoric liquids (replaces GB 20585-2006);
———Part 11: Pyrophoric solids (replaces GB 20586-2006);
———Part 12: Self-heating substances and mixtures (replaces GB 20584-2006);
———Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB 20587-2006);
———Part 14: Oxidizing liquids (replaces GB 20589-2006);
——Part 15: Oxidizing solids (replaces GB 20590-2006);
——Part 16: Organic peroxides (replaces GB 20591-2006);
——Part 17: Corrosive to metals (replaces GB 20588-2006);
——Part 18: Acute toxicity (replaces GB 20592-2006);
——Part 19: Skin corrosion/irritation (replaces GB 20593-2006);
——Part 20: Serious eye damage/eye irritation (replaces GB 20594-2006);
——Part 21: Respiratory or skin sensitization (replaces GB 20595-2006);
———Part 22: Germ cell mutagenicity (replaces GB 20596-2006);
———Part 23: Carcinogenicity (replaces GB 20597-2006);
———Part 24: Reproductive toxicity (replaces GB 20598-2006);
———Part 25: Specific target organ toxicity single exposure (replaces GB 20599-2006);
———Part 26: Specific target organ toxicity repeated exposure (replaces GB 20601-2006);
———Part 27: Aspiration hazard;
———Part 28: Hazard to the aquatic environment (replaces GB 20602-2006);
———Part 29: Hazard to the ozone layer;
———Part 30: Warning signs for chemical workplaces.
This part is part 14 of GB 30000.
This part was drafted in accordance with the rules given in GB/T 1.1-2009.
This part replaces GB 20589-2006 "Safety Specification for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Oxidizing Liquids".
This part is consistent with the relevant technical content of the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition).
Compared with GB 20589-2006, the main technical content changes of this part are as follows:
———The name of the standard has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals—Part 14: Oxidizing liquids" and the English name is "Rules for classification and labelling of chemicals—Part 14: Oxidizing liquids";
———The scope of Chapter 1 has been modified, "Warning label" has been changed to "label", and "Warning statement" has been deleted;
———The introductory words of Chapter 2 "Normative references" have been modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" has been added as a reference document;
———The introductory words of Chapter 3 "Terms and Definitions" have been added;
———Figure 1 "Decision Logic Diagram" and "Guidance" in Chapter 5 have been made informative Appendix A;
———Deleted the original Chapter 7, and revised Table 3 of the original Chapter 7 as normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition);
———In accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition), revised and integrated the original Chapters 6, 7 and 8 into Chapter 6; revised Table 2 as normative Appendix C;
———Deleted the original Chapter 8, and added the relevant "Hazard Statements" and "Precautionary Statements" as informative Appendix D; ———
Added informative Appendix E "Examples of Labels".
This part was proposed and coordinated by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251).
Drafting units of this part: China Chemical Economic and Technological Development Center, China Chemical Information Center, Shanghai Research Institute of Chemical Industry, Zhejiang Research Institute of Chemical Industry Co., Ltd., Pony Testing Technology Co., Ltd., Huafeng Group Co., Ltd.
The main drafters of this part are: Wei Naixin, Ge Xiaojun, Fan Bin, Wang Gaosheng, Xiao Qiuping, Song Wei, Wang Xiaobing, Zhao Xiaoyang, Cao Mengran, Zhang Guangkuan, Wen Tao. The
previous versions of the standards replaced by this part are:
———GB 20589—2006.
The following documents are indispensable for the application of this document. For all dated referenced documents, only the dated versions apply to this document. For all undated referenced documents, the latest versions (including all amendments) apply to this document.
GB6944—2012 Classification and Product Name Numbering of Dangerous Goods
GB13690 General Rules for Classification and Hazard Communication of Chemicals
United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria (Fifth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition)

Some standard content:

ICS13.300
National Standard of the People's Republic of China
GB30000.14—2013
Replaces GB205892006
Rules for classification and labelling of chemicals-Part 14:Oxidizing liquids
Promulgated on October 10, 2013
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China
Administrative Committee of Standardization of the People's Republic of China
Implementation on November 1, 2014
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. The expected structure of GB 30000 Chemical Classification and Labelling Specification and the national standards to be replaced are: Part 1: General (replaces GB13690-2009); Part 2: Explosives (replaces GB20576-2006); Part 3: Flammable gases (replaces GB20577-2006); Part 4: Aerosols (replaces GB20578-2006); Part 5: Oxidizing gases (replaces GB20579-2006); Part 6: Pressurized gases (replaces GB20580-2006); Part 7: Flammable liquids (replaces GB20581-2006); Part 8: Flammable liquids (replaces GB20582-2006); Part 9: Flammable liquids (replaces GB20583-2006); Part 10: Flammable liquids (replaces GB20584-2006); Part 11: Flammable liquids (replaces GB20585-2006); Part 12: Flammable liquids (replaces GB20586-2006); Part 13: Flammable liquids (replaces GB20587-2006); Part 14: Flammable liquids (replaces GB20588-2006); Part 15: Flammable gases (replaces GB20589-2006); Part 16: Flammable liquids (replaces GB20581-2006); Part 17: Flammable liquids (replaces GB20583-2006); Part 18: Flammable liquids (replaces GB20584-2006); Part 19: Flammable liquids Part 8: Flammable solids (replaces GB20582-2006); Part 9: Self-reactive substances and mixtures (replaces GB20583-2006); Part 10: Pyrophoric liquids (replaces GB20585-2006); Part 11: Pyrophoric solids (replaces GB20586-2006); Part 12: Self-heating substances and mixtures (replaces GB20584-2006); Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB20587-2006); Part 14: Oxidizing liquids (replaces GB20589-2006); Part 15: Oxidizing solids (Replace GB205902006); Part 16: Organic peroxides (Replace GB20591-2006); Part 17: Metal corrosion (Replace GB20588-2006); Part 18: Acute toxicity (Replace GB20592-2006); Part 19: Skin corrosion/irritation (Replace GB205932006); Part 20: Serious eye damage/eye irritation (Replace GB20594-2006); Part 21: Respiratory or skin sensitization (Replace GB205952006); Part 22: Germ cell mutagenicity (Replace GB20596 2006): Part 23: Carcinogenicity (replaces GB20597-2006): Part 24: Reproductive toxicity (replaces GB20598-2006): Part 25: Specific target organ toxicity single exposure (replaces GB20599-2006): Part 26: Specific target organ toxicity repeated exposure (replaces GB20601-2006): Part 27: Inhalation hazard:
Part 28: Hazards to the aquatic environment (replaces GB20602-2006); Part 29: Hazards to the ozone layer;
Part 30: Warning signs for chemical workplaces. This part is Part 14 of GB30000.
This part was drafted in accordance with the rules given in GB/T1.1-2009. GB30000.14—2013
This part replaces GB20589—2006 "Safety Rules for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Oxidizing Liquids". This part is consistent with the technical content related to the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition). Compared with GB20589—2006, the main technical content changes of this part are as follows: 1
GB30000.14—2013
The standard name has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals-Part 14: Oxidizing Liquids", and the English name is \Rules for classification and labelling of chemicals-Part 14: Oxidizing Liquids". liquids\Modified the scope of Chapter 1, changed "warning label" to "label" and deleted "warning statements"; modified the introductory words of Chapter 2 "Normative References" and added "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)\ as a reference document; added the introductory words of Chapter 3 "Terms and Definitions"; made Figure 1 "Decision Logic Diagram" and "Guidelines" of Chapter 5 as informative Appendix A; deleted the original Chapter 7, and modified Table 3 of the original Chapter 7 as normative Appendix B in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition);
In accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition), the original Chapters 6, 7 and 8 were modified and integrated into Chapter 6: the original Table 2 was modified as normative Appendix C; deleted the original Chapter 8, and made the relevant "Hazard Statements" and "Precautionary Statements" contents as informative Appendix D; added informative Appendix E\Label Examples". This part was proposed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251) and is under the jurisdiction of the following drafting organizations: China Chemical Economic and Technological Development Center, China Chemical Information Center, Shanghai Research Institute of Chemical Industry, Zhejiang Research Institute of Chemical Industry Co., Ltd., PONY Testing Technology Co., Ltd., Huafeng Group Co., Ltd. The main drafters of this part are: Wei Naixin, Ge Xiaojun, Fan Bin, Wang Gaosheng, Xiao Qiuping, Song Wei, Wang Xiaobing, Zhao Xiaoyang, Cao Mengran, Zhang Guangkuan, Wen Tao.
The previous versions of the standards replaced by this part are: GB205892006.
1 Scope
Chemical Classification and Labeling Specification
Part 14: Oxidizing Liquids
GB30000.14—2013
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labels for oxidizing liquids. This part applies to the classification and labeling of oxidizing liquids in accordance with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (hereinafter referred to as GHS).
2 Normative References
The following documents are essential for the application of this document. For all dated references, only the dated version applies to this document. For all undated references, the latest version (including all amendments) applies to this document. GB6944—2012 Classification and product name numbering of dangerous goods GB13690 General Rules for Classification and Hazard Communication of Chemicals United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (4th revised edition) United Nations "Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria" (5th revised edition) United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (17th revised edition) 3 Terms and Definitions
The terms and definitions defined in GB13690 and the following terms and definitions apply to this document. 3.1
Oxidizing liquids
Liquids that may not be flammable in themselves, but usually release oxygen that may cause or promote the combustion of other substances. 4 Classification standards
4.1 For the general principles of classification and labelling of oxidizing liquids, see GB13690. 4.2 For the classification of oxidizing liquids, see Table 1.
Oxidizing liquids are classified according to test 0.2 in Part 3, 34.4.2 of the United Nations "Manual of Tests and Criteria for the Transport of Dangerous Goods" (Fifth Revised Edition) (hereinafter referred to as the "Manual of Tests and Criteria"), see Table 1. Table 1 Classification of oxidizing liquids
Self-ignition when the test substance (or mixture) is tested in a 1:1 ratio of mass to cellulose: or any substance or mixture for which the average pressure rise time of a 1:1 ratio of mass to cellulose is less than 50% of the average pressure rise time of a 1:1 ratio of mass to perchloric acid to cellulose 1
GB30000.14—2013
Table 1 (continued)
Any substance or mixture which, when tested as a 1:1 mixture by mass of the substance (or mixture) and cellulose, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture by mass of 40 % aqueous sodium chlorate and cellulose; and which does not meet the criteria for Category 1
Any substance or mixture which, when tested as a 1:1 mixture by mass of the substance (or mixture) and cellulose, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture by mass of 65 % aqueous nitric acid and cellulose; and which does not meet the criteria for Categories 1 and 2
5 Decision logic and guidance
The decision logic and guidance are for reference only. See Annex A for the decision logic and guidance. It is particularly recommended that the person responsible for classification study Chapter 4 before using the decision logic and in the range of the decision logic. 6 Labels
6.1 Overview
6.1.1 For the labeling of oxidizing liquids, the hazard categories shall be listed in the order of the designated pictograms, signal words and hazard statements. The hazard classes or categories covered by the United Nations "Model Regulations" (Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition) (hereinafter referred to as "Recommendations on the Transport of Dangerous Goods Model Regulations") shall be listed on the label with the designated corresponding graphic symbol abbreviation for each category. The allocation of label elements for oxidizing liquids is shown in the Appendix. For the classification criteria and labeling requirements for oxidizing liquids, see Appendix C. 6.1.2 Information required on the relevant
including hazard pictograms, signal words, hazard statements, precautionary statements, product identification and supplier identification. 6.1.3 Labels
Note that for other label elements that have not yet been standardized, precautionary statements need to be included on the label. The competent authorities may also require additional information, and the supplier may also add supplementary information.
6.2 Hazard pictograms
Hazard pictograms should use black symbols on a colored background, and the red frame should be wide enough to stand out. The hazard pictograms, graphics, color numbers and minimum sizes specified in the Model Regulations are shown in Appendix B. 6.3 Signal words
Signal words are words used on labels to indicate the relative severity of the hazard and to alert the reader to potential hazards. For oxidizing liquids, use the signal words "Danger" and "Warning". 6.4 Hazard statements
Hazard statements are phrases assigned to a hazard class and category that describe the hazardous properties of a hazardous product and, where appropriate, its degree of hazard. Hazard statements for oxidizing liquids are shown in Appendix D. 6.5 Precautionary statements
A precautionary statement is a word (and/or pictogram) used to describe the precautions to minimize or prevent the risk of exposure to hazardous products or inappropriate Measures recommended for adverse effects of storing or handling hazardous products. To meet the requirements, there are 5 types of precautionary statements: general, prevention, emergency, storage and disposal. See Appendix D for precautionary statements for oxidizing liquids. 6.6 Product identifiers
GB30000.14—2013
6.6.1 The product identifier should be used on the label and should be consistent with the product identifier used on the material safety data sheet. If a substance or mixture is included in the Model Regulations, the correct UN shipping name should also be used on the packaging. 6.6.2 The label should include the chemical name of the substance. For mixtures or alloys, when acute toxicity, skin or respiratory sensitization or specific target organ toxicity appear on the label, the label should include all ingredients that may cause these hazards. or alloying elements. The competent authority may also require that the chemical names of all ingredients or alloying elements that may contribute to the hazard of the mixture or alloy be listed on the label. 6.7
Supplier identification
The name, address and telephone number of the manufacturer or supplier of the substance or mixture should be provided on the label. 6.8 Label examples
For examples of labels for oxidizing liquids, see Appendix E. TrKANKAca-
GB30000.14—2013
A.1 Decision logic
Appendix A
(Informative Appendix)
Decision logic and guidance
For the classification of oxidizing liquids, test method 0.2 as described in Part 3, 34.4.2 of the United Nations Manual of Tests and Criteria should be used. Classification is carried out according to decision logic diagram A.1.
A.2 Guidance
A2.1 Experience in transport and use has shown that substances and mixtures have oxidizing properties and this is an important additional factor in considering classification under this class. If there is a disagreement between test results and known experience, judgement based on known experience should take precedence over test results. A2.2 Sometimes a substance or mixture may produce a pressure rise (too high or too low) due to a chemical reaction that does not indicate that the substance or mixture has oxidizing properties. In such cases, it may be necessary to repeat the test of Part 3, 34.4.2 of the United Nations Manual of Tests and Criteria using an inert material such as diatomaceous earth instead of cellulose to clarify the nature of the reaction. A.2.3 This classification procedure does not apply to organic substances or mixtures if: the substance or mixture does not contain oxygen, fluorine or chlorine; or a)
b) the substance or mixture contains oxygen, fluorine or chlorine but these elements are chemically bonded only to carbon or hydrogen. A.2.4 This classification procedure does not apply to inorganic substances or mixtures if they do not contain oxygen or halogen atoms. Substance/mixture is a liquid
When a 1:1 mixture by mass of the substance (or mixture) and cellulose is tested, does it display a pressure rise of ≥ 2070 kPa gauge? When a 1:1 mixture by mass of the substance (or mixture) and cellulose is tested, does it display a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture by mass of 65% aqueous nitric acid and cellulose?
When a 1:1 mixture by mass of the substance (or mixture) and cellulose is tested, does it display a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture by mass of 40% aqueous sodium chlorate and cellulose?
When a 1:1 mixture by mass of the substance (or mixture) and cellulose is tested, does it show a white hair fire, or does the mean pressure rise time of a 1:1 mixture by mass of the substance and cellulose be less than the mean pressure rise time of a 1:1 mixture by mass of 50% peroxyacid and cellulose? Fragrance
Determination logic for oxidizing liquids
irkAoNrKAca
GB30000.14—2013
Not this category
Not this category
Category 3
Category 2
Category 1
GB30000.14—2013
Appendix B
(Normative Appendix)
Allocation of label elements for oxidizing liquids
See Table B.1 for the allocation of label elements for oxidizing liquids. Table B.1 Allocation of label elements for oxidizing liquids Oxidizing liquids bZxz.net
Category 1
May cause combustion or
explosion Strong oxidizer
Category 2
May intensify combustion;
Oxidizer
Category 3
May intensify combustion;
Oxidizer
In the "Model Regulations":
1) Color of graphic symbol
Graphic symbol (flame on a circle): black :
·Background: yellow.
2) The number "5.1" in the figure refers to the first item of the fifth category in
GB6944-2012.
3) The minimum size of the graphic sign for cargo transportation is 100mm×
100mm.
Appendix C
(Normative Appendix)
Classification standards and label elements for oxidizing liquids The classification standards and label elements for oxidizing liquids are shown in Table C, 1. Table C.1 Classification criteria and labelling elements for oxidising liquids Hazard category
When testing a mixture of the test substance (or compound) with cellulose in a 1+1 ratio by mass, or a mixture of the test substance and cellulose in a 1:1 ratio by mass, the average pressure rise time is less than 50% of the average pressure rise time of a 1:1 mixture of perchloric acid and cellulose in a 1:1 ratio by mass. Any substance or mixture when testing the test substance (or compound) with
cellulose in a 1:1 ratio by mass of
dry cellulose. |tt||Comparative quality I:
The average pressure rise time of the mixture is less than or equal to 40% acid-free aqueous solution
The average pressure rise time of the mixture is: and any standard substance or mixture
When the test substance (or mixture) is tested with a 1:1 ratio by mass, the average pressure rise time shown is less than or equal to the average pressure rise time of the mixture with a 65% nitric acid aqueous solution and cellulose ratio by mass: and does not meet the category Any substance or mixture of Category 1 and Category 2 standards TrKANTKAca-
GB30000.14—2013
Label elements
Graphic symbol
Signal word
Hazard statement
Graphic symbol
Hazard statement
Graphic box number
Signal word
Hazard statement
Can cause combustion or
Explosion: Strong oxidizer
Can intensify combustion:||tt ||Oxidizer
Can intensify combustion;
Oxidizer
GB30000.14—2013
D.1 Overview
Appendix D
(Informative Appendix)
Hazard statements and precautionary statements for oxidizing liquids D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for oxidizing liquids, and lists the recommended hazard statements and precautionary statements for each hazard class and hazard category of oxidizing liquids, see GB13690. D.1.2 Coding of hazard statements:
D.1.2.1 See Annex 3 of GHS for the coding of hazard statements. D.1.2.2 Each hazard statement is assigned a specific alphanumeric code consisting of one letter and three digits as follows;
The letter "H" (for "hazard statement"); a)
b) The first digit represents the type of hazard to which the hazard statement refers in the different part numbers as follows: "2\ for physical hazards;
"3" for health hazards;
"4\ for environmental hazards;
e) The last two digits correspond to the sequence number of the hazard caused by the inherent properties of the substance or mixture, such as: explosiveness (codes 200 to 210), flammability (codes 220 to 230), etc. D.1.2.3 Unless otherwise specified, all specified hazard statements shall appear on the label. The competent authority may specify the order in which the hazard statements appear on the label. In addition, when two or more hazard statements are provided in a combined hazard statement, the competent authority may specify whether the combined hazard statement or the corresponding individual statement shall be included on the label, or whether it shall be left to the manufacturer/supplier to decide. D.1.3 Precautionary statements shall be included on the label together with the uniform hazard communication elements (pictograms, signal words and hazard statements). Additional supplementary information, such as instructions for use, may also be provided at the discretion of the manufacturer/supplier and/or the competent authority. D.1.3.1 See Annex 3 of the GHS for the codes of precautionary statements. D.1.3.2 Coding of precautionary statements:
D.1.3.2.1 Each precautionary statement is assigned a unique alphanumeric code consisting of one letter and three numbers, as follows
The letter P" (stands for "precautionary statement")
b) The first number, representing the type of precautionary statement, as follows: "1\ for general precautionary statement;
"2\ for prevention precautionary statement;
"3\ for reaction precautionary statement;
"4" for storage precautionary statement;
"5" for disposal precautionary statement;
c) The last two numbers (corresponding to the serial number of the precautionary statement). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used in place of the precautionary statement text.
D.2 General precautionary statements
General precautionary measures should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels under the given conditions (see Table D.1). Table D.1
-General public
Production workers
Supplementary information
Label, supplementary label information
General precautionary statements
Label, supplementary label information, safety data sheets, workplace directives
Precautionary statements for oxidizing liquids
Precautionary statements for oxidizing liquids Category 1 are shown in Table D.2. GB30000.14—2013
General precautionary statements
If medical attention is required: Keep product container or label with you and out of reach of children.
Read label before use
irkAoNrKAca2 General precautionary statements
General precautions should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels (see Table D.1) under the given conditions. Table D.1
-General public
Production workers
Supplementary information
Label, supplementary label information
General precautionary statements
Label, supplementary label information, safety data sheets, workplace directives
Precautionary statements for oxidizing liquids
Precautionary statements for oxidizing liquids Category 1 are shown in Table D.2. GB30000.14—2013
General precautionary statements
If medical attention is required: Keep product container or label with you and out of reach of children.
Read label before use
irkAoNrKAca2 General precautionary statements
General precautions should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels (see Table D.1) under the given conditions. Table D.1
-General public
Production workers
Supplementary information
Label, supplementary label information
General precautionary statements
Label, supplementary label information, safety data sheets, workplace directives
Precautionary statements for oxidizing liquids
Precautionary statements for oxidizing liquids Category 1 are shown in Table D.2. GB30000.14—2013
General precautionary statements
If medical attention is required: Keep product container or label with you and out of reach of children.
Read label before use
irkAoNrKAca
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