GB 30000.8-2013 Chemical Classification and Labelling Specification Part 8: Flammable Solids GB30000.8-2013 |tt||Standard compression package decompression password: www.bzxz.net
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of flammable solids. This part applies to the classification and labeling of flammable solids in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals.
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended.
The expected structure of GB30000 "Specifications for Classification and Labelling of Chemicals" and the national standards to be replaced are:
———Part 1: General (replaces GB13690-2009);
———Part 2: Explosives (replaces GB20576-2006);
———Part 3: Flammable gases (replaces GB20577-2006);
———Part 4: Aerosols (replaces GB20578-2006);
———Part 5: Oxidizing gases (replaces GB20579-2006);
———Part 6: Gases under pressure (replaces GB20580-2006);
———Part 7: Flammable liquids (replaces GB20581-2006);
———Part 8: Flammable solids (replaces GB 20582-2006);
———Part 9: Self-reactive substances and mixtures (replaces GB 20583-2006);
———Part 10: Pyrophoric liquids (replaces GB 20585-2006);
———Part 11: Pyrophoric solids (replaces GB 20586-2006);
———Part 12: Self-heating substances and mixtures (replaces GB 20584-2006);
———Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB 20587-2006);
———Part 14: Oxidizing liquids (replaces GB 20589-2006);
——Part 15: Oxidizing solids (replaces GB 20590-2006);
——Part 16: Organic peroxides (replaces GB 20591-2006);
——Part 17: Corrosive to metals (replaces GB 20588-2006);
——Part 18: Acute toxicity (replaces GB 20592-2006);
——Part 19: Skin corrosion/irritation (replaces GB 20593-2006);
——Part 20: Serious eye damage/eye irritation (replaces GB 20594-2006);
——Part 21: Respiratory or skin sensitization (replaces GB 20595-2006);
———Part 22: Germ cell mutagenicity (replaces GB 20596-2006);
———Part 23: Carcinogenicity (replaces GB 20597-2006);
———Part 24: Reproductive toxicity (replaces GB 20598-2006);
———Part 25: Specific target organ toxicity single exposure (replaces GB 20599-2006);
———Part 26: Specific target organ toxicity repeated exposure (replaces GB 20601-2006);
———Part 27: Aspiration hazard;
———Part 28: Hazard to the aquatic environment (replaces GB 20602-2006);
———Part 29: Hazard to the ozone layer;
———Part 30: Warning signs for chemical workplaces.
This part is Part 8 of GB 30000.
This part was drafted in accordance with the rules given in GB/T 1.1-2009.
This part replaces GB 20582-2006 "Safety Specification for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Flammable Solids".
This part is consistent with the relevant technical content of the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition).
Compared with GB 20582-2006, the main technical content changes of this part are as follows:
———The name of the standard has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals—Part 8: Flammable solids" and the English name is "Rules for classification and labelling of chemicals—Part 8: Flammable solids";
———The scope of Chapter 1 has been modified, "Warning label" has been changed to "label", and "Warning statement" has been deleted; ||tt
|| ———The introductory words of Chapter 2 "Normative references" have been modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" has been added as a reference document;
———The introductory words of Chapter 3 "Terms and Definitions" have been added;
———Figure 1 "Decision Logic Diagram" and "Guidance" in Chapter 5 have been made informative Appendix A;
——Deleted the original Chapter 7, and modified Table 3 of the original Chapter 7 as normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition);
——In accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition), modified and integrated the original Chapter 6, Chapter 7 and Chapter 8 into Chapter 6; the original Table 2 was modified as normative Appendix C;
——Deleted the original Chapter 8, and added the relevant "Hazard Statements" and "Precautionary Statements" as informative Appendix D;
——Added informative Appendix E "Label Examples".
This part was proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251).
Drafting units of this part: China Chemical Economic and Technological Development Center, Shanghai Research Institute of Chemical Industry, China Chemical Information Center, Zhejiang Research Institute of Chemical Industry Co., Ltd., Pony Testing Technology Co., Ltd., Huafeng Group Co., Ltd.
The main drafters of this section are Wang Xiaobing, Ge Xiaojun, Fan Bin, Fang Lu, Song Wei, Zhu Tao, Guan Shitai, Zhu Yan, Cao Mengran, Gao Yang, Yang Ting and Wen Tao.
The previous versions of the standards replaced by this part are as follows:
———GB20582—2006.
The following documents are indispensable for the application of this document. For any dated referenced document, only the dated version applies to this document. For any undated referenced document, the latest version (including all amendments) applies to this document.
GB6944—2012 Classification and product name numbering of dangerous goods
GB13690 General principles for classification and hazard communication of chemicals
GB30000.4 Specifications for classification and labeling of chemicals Part 4: Aerosols
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (Fourth Revised Edition)
United Nations Manual of Tests and Criteria for the Transport of Dangerous Goods (Fifth Revised Edition)
United Nations Model Regulations for the Transport of Dangerous Goods (Seventeenth Revised Edition)

ICS13.300
National Standard of the People's Republic of China
GB30000.8—2013
Replaces GB20582-2006
Rules for classification and labelling of chemicals
Flammable solids
Part 8:
Rules for classification and labelling of chemicals-Part 8: Flammable solids
2013-10-10 Issued
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China
Standardization Administration of the People's Republic of China
2014-11-01 Implementation
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. The expected structure of GB30000 "Chemical Classification and Labeling Specification" and the national standards to be replaced are: Part 1: General (replaces GB13690-2009); Part 2: Explosives (replaces GB20576-2006); Part 3: Flammable gases (replaces GB20577-2006); Part 4: Aerosols (replaces GB20578-2006); Part 5: Oxidizing gases (replaces GB20579-2006); Part 6: Gases under pressure (replaces GB20580-2006); Part 7: Flammable liquids (replaces GB20581-2006); Part 8: Flammable solids (replaces GB20582-2006); Part 0: Self-reactive substances and mixtures (replaces GB20583-2006); Part 10: Pyrophoric liquids (replaces GB20585-2006); Part 11: Pyrophoric solids (replaces GB20586-2006); Part 12: Self-heating substances and mixtures (replaces GB20584-2006); Part 13: Flammable substances which, in contact with water, emit flammable gases Substances and mixtures (replacing GB20587-2006); Part 11: Oxidizing liquids (replacing GB20589-2006); Part 15: Oxidizing solids (replacing GB20590-2006); Part 16: Organic peroxides (replacing GB20591-2006); Part 17: Metal corrosion (replacing GB20588-2006); Part 18: Acute toxicity (replacing GB20592-2006); Part 19: Skin corrosion/irritation (replacing GB20593-2006); Part 20: Serious eye damage/eye irritation (replacing GB20594-2006); Part 21: Respiratory or skin sensitization (replacing GB2059 5-2006): Part 22: Germ cell mutagenicity (replaces GB20596-2006); Part 23: Carcinogenicity (replaces GB20597-2006); Part 24: Reproductive toxicity (replaces GB205982006): Part 25: Specific target organ toxicity single exposure (replaces GB20599-2006): Part 26: Specific target organ toxicity repeated exposure (replaces GB20601-2006): Part 27: Inhalation hazard:
Part 28: Hazards to the aquatic environment (replaces GB20602-2006); Part 29: Hazards to the ozone layer;
Part 30: Warning signs for chemical workplaces. This part is Part 8 of GB30000.
This part was drafted in accordance with the rules given in GB/T1.1-2009. GB30000.8—2013
This part replaces GB20582-2006 "Safety Rules for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Flammable Solids". This part is consistent with the technical content related to the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition). Compared with GB20582-2006, the main technical content changes of this part are as follows: 1
GB30000.8-2013
The standard name has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals-Part eighth: Flammable solids", and the English name is \Rules for classification and labelling of chemicals-Part eighth: Flammable solids\; The scope of Chapter 1 was modified, "Warning Label" was changed to "Label", and "Warning Statement" was deleted; the introductory words of Chapter 2 "Normative References" were modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" was added as a reference document; the introductory words of Chapter 3 "Terms and Definitions" were added; Figure 1 "Decision Logic Diagram" and "Guide" in Chapter 5 were used as informative appendix A; the original Chapter 7 was deleted, and Table 3 of the original Chapter 7 was modified as normative appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition):
According to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition), the original Chapters 6, 7, and 8 were modified and integrated into Chapter 6: The original Table 2 was modified as normative appendix C; the original Chapter 8 was deleted, and the relevant "Hazard Statements" and "Precautionary Statements" were used as informative appendix D; Informative Appendix E "Label Examples" was added. This part is from the National Hazardous Chemicals Management Standard The drafting units of this part are: China Chemical Economic and Technological Development Center, Shanghai Research Institute of Chemical Industry, China Chemical Information Center, Zhejiang Research Institute of Chemical Industry Co., Ltd., Pony Testing Technology Co., Ltd., Huafeng Group Co., Ltd. The main drafters of this part are: Wang Xiaobing, Ge Xiaojun, Fan Bin, Fang Lu, Song Wei, Zhu Tao, Guan Shitai, Zhu Yan, Cao Mengran, Gao Yang, Yang Ting, Wen Tao.
The previous versions of the standards replaced by this part are as follows: ：GB20582-2006
1 Scope
Chemical Classification and Labeling Specification
Flammable Solids
Part 8：
GB30000.8—2013
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of flammable solids. This part applies to the classification and labeling of flammable solids in accordance with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (hereinafter referred to as GHS). Normative references
The following documents are essential for the application of
documents. For all references with dates, the versions with dates apply to this document. For all undated references, the latest versions (including all amendments) apply to this document. GB6944
GB13690
GB3000bzxz.net
Classification and product name numbering of dangerous goods
General rules for classification and hazard communication of general chemical products
Classification and labelling of chemicals - United Nations Convention on the Global Chemical Standards - Part 4, Classification and labelling system for use with gases - Fourth revised edition - United Nations Recommendations on the Transport of Dangerous Goods - Manual of Tests and Criteria - United Nations Recommendations on the Transport of Dangerous Goods - Draft Model Specifications - Section 3 Terms and Definitions - GB 13690 and the following terms and definitions apply to non-flammable goods 3.1 Flammable goods lesolids
Flammable solids
Solids which are easily combustible, solids which ignite or support combustion by friction, (Fifth revised edition)
Unrevisioned edition
Solids in the form of powders, granules or pastes which ignite readily and spread rapidly on brief contact with an ignition source, such as a lit match
4 Classification criteria
4.1 General principles for the classification and labelling of flammable solids are given in GB 136904.2 Powders, granules or pastes or mixtures shall be classified as flammable solids if, in one or more tests according to the test method specified in section 33.2.1 of Part 3 of the United Nations Recommendations on the Transport of Dangerous Goods (Fifth revised edition) (hereinafter referred to as the "Manual of Tests and Criteria"), the burning time is less than 45 s or the burning rate is greater than 2.2 mm/s. 4.3 When metal or metal alloy powders can be ignited and spread over the entire length of the sample in 10 min or less, the substance shall be classified as a flammable solid.
4.4 Until clear principles are established, solids that can catch fire by friction should be classified as flammable solids by analogy with existing entries (e.g. matches).
4.5 Flammable solids are divided into 2 categories according to the N.1 test in 33.2.1 of Part 3 of the United Nations "Recommendations on the Transport of Dangerous Goods: Manual of Tests and Criteria" (Fifth Revised Edition) (hereinafter referred to as the "Manual of Tests and Criteria"), see Table 1. 1
GB30000.8-2013
Burning rate test:
Table 1 Classification of "Flammable Solids"
Standard!
Substances or mixtures other than metal powder: the wet part cannot be flame retardant, and
b): the burning time is less than 45s or the burning rate is greater than 2.2mm/s; metal powder:
The burning time is not more than 5min
Burning rate test:
Substances or mixtures other than metal powder: a) the wet part can Flame retardant for at least 4 minutes, and b) the burning time is less than 45 seconds or the burning rate is greater than 2.2 mm/s Metal powder:
The burning time is greater than 5 minutes and the month is not more than 10 minutes For classification tests on solid substances or mixtures, the test should be carried out as provided. For example, for supply or transport purposes, if the same chemical is submitted in a shape different from the shape used in the test and it is considered that the performance may actually be different from that in the classification test, the substance should also be tested in the new shape.
Aerosols cannot be classified as flammable solids, see GB30000.4. 5 Decision logic and guidance
The decision logic and guidance are for reference only. See Appendix A for decision logic and guidance. It is particularly recommended that those responsible for classification study the decision logic before and during use. Chapter 4.
6 Labels
6.1 Overview
6.1.1 For the labels of flammable solids, hazard categories are listed in the order of designated pictograms, signal words and hazard statements. The hazard classes or categories covered by the United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (Seventeenth Revised Edition) (hereinafter referred to as the "Model Regulations") should list the designated corresponding graphic signs for each category on the label. The allocation of flammable solid label elements is shown in Appendix B. 6.1.2 For the classification criteria and label elements for flammable solids, see Appendix C6.1.3 The information required on the label includes hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and supplier logos. Note: For other label elements that have not yet been standardized, such as precautionary statements, they also need to be included on the label. Competent authorities Additional information may be required and the supplier may add supplementary information.
6.2 Hazard pictograms
Hazard pictograms shall use black symbols on a white background with a red frame wide enough to be visible. The colours, numbers and minimum sizes of hazard pictograms and graphic symbols specified in the Model Regulations are shown in Appendix B.6.3 Signal words
Signal words are words used to indicate the relative severity of a hazard and to alert the reader to potential hazards. The signal words used for flammable solids are "Danger" and "Warning". 6.4 Hazard statements
GB30000.8—2013
A hazard statement is a phrase assigned to a hazard class and category that describes the hazardous nature of a hazardous product and, where appropriate, its degree of hazard. For flammable solids hazard statements, see Appendix D. 6.5 Precautionary statements
A precautionary statement is a word (and/or pictogram) used to describe recommended measures to minimize or prevent adverse effects of exposure to a hazardous product or improper storage or handling of a hazardous product. For the purpose of this requirement, there are five categories of precautionary statements: general, prevention, emergency, storage and disposal. Precautionary statements for flammable solids are listed in Annex D. 6.6 Product identifiers
6.6.1 The product identifier should be used on the label and should be consistent with the product identifier used on the MSDS. If a substance or mixture is listed in the Model Regulations, the correct UN shipping name should also be used on the packaging. 6.6.2 The label should include the chemical name of the substance. For mixtures or alloys, when acute toxicity, skin or respiratory sensitization or specific organ toxicity appear on the label, the label should include the chemical composition of all ingredients or alloying elements that may contribute to these hazards. The competent authority may require that the chemical names of all ingredients or alloying elements that may contribute to the hazards of the mixture or alloy be listed on the label. 6.7
Supplier identification
The name, address and telephone number of the manufacturer or supplier of the substance or mixture should be provided on the label. 6.8 Examples of flammable solid labels
See Annex E for examples of flammable solid labels. irkANikAca
GB30000.8—2013
Appendix A
(Informative)
Decision logic and guidance
For the classification of flammable solids, the test method N.1 described in Section 33.2.1 of Part III of the United Nations Recommendations on the Transport of Dangerous Goods: Manual of Tests and Criteria should be used. The procedure consists of two tests: a preliminary screening test and a burning rate test. Classification is carried out in accordance with decision logic diagram A.1.
The substance/mixture is a solid
Screening test
Fast burning test
) The burning time of the substance or mixture other than metal powder is less than or the burning rate is greater than
b) Metal powder
The burning time is less than or equal to
a) Does the wetted section of the substance or mixture other than metal powder prevent the propagation of flame?
b) Metal powder
Burning time greater than 5 min?
Figure A1 Decision logic for flammable solids
For this category
Category 1
For the allocation of label elements, see Table B.1.
Category 1
Flammable solids
Category 2
Flammable solids
Appendix B
(Normative Appendix)
Allocation of label elements
Allocation of label elements for flammable solids
Flammable solids
TrKANTKAca-
GB30000.8—2013
In the Model Regulations:
Color change of graphic symbols
Special number (flame): Black:
Background: White with seven vertical
red stripes:||tt ||The number "4\ is located in the lower corner:
Black.
The number 4 in the figure is Class 4 in GB6944—
2012.
The minimum
size of the graphic sign for cargo transport is 100mmx100mm
GB30000.8—2013
Appendix C
(Normative Appendix)
Classification standards and label elements for flammable solids
The classification standards and label elements for flammable solids are shown in Table C.1. Table C.1 Classification standards and label elements for flammable solids Hazard category
Burning rate test:|| tt||Substances or mixtures other than metal powders: a) The wet part cannot be flame retardant, and
b) The burning time is less than 45s or the burning rate is greater than 2.2mm/8; Metal powder:
The burning time is not more than 5min
Burning rate test:
Substances or mixtures other than metal powders: a) The wet part can be flame retardant for at least 4min, and b) The burning time is less than 45s or the burning rate is greater than 2.2mm/s Metal powder:
The burning time is greater than 5min and less than or equal to 10min Graphic symbol
Signal word||tt| |Hazard Statements
Graphic Symbols
Signal Words
Hazard Statements
Label Elements
Flammable Solids
Flammable Solids
D.1 Overview
Appendix D
(Informative Appendix)
Hazard Statements and Precautionary Statements for Flammable Solids GB30000.8—2013
D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for flammable solids, and lists the hazard statements and precautionary statements for each hazard class and hazard category of flammable solids, see GB13690. D.1.2 The coding of hazard statements is as follows: The coding of hazard statements can be found in Annex 3 of GHS. Each hazard statement is assigned a special alphanumeric code consisting of 1 letter and 3 numbers, specifically the letter "H" (standing for "hazard statement"); b) The first number represents the type of hazard referred to by the hazard statement set in the different part numbers, as follows: 2 represents physical hazard: 3 represents health hazard: 4 represents environmental hazard: The last two numbers correspond to the serial number of the hazard caused by the inherent properties of the substance or mixture, such as: explosiveness (codes 200 to 210), flammability (codes 220 to 230), etc. D.1.2.3 Unless otherwise specified, all specified hazard statements should appear on the label. The competent authority may specify the order in which the hazard statements appear on the label. In addition, where a combined hazard statement provides two or more hazard statements, the competent authority may specify whether the combined hazard statement or the corresponding individual statements shall appear on the label, or whether this shall be left to the discretion of the manufacturer/supplier. D.1.3 Precautionary statements shall appear on compliant labels together with the harmonized hazard communication elements (pictogram, signal word and hazard statement): Additional supplementary information, such as directions for use, may also be provided at the discretion of the manufacturer/supplier and/or the competent authority. D.1.3.1 Coding of precautionary statements See Annex 3 of GHS D.1.3.2 Coding of precautionary statements
D.1.3.2.1
Each precautionary statement is assigned a unique alphanumeric code consisting of 1 letter and 3 digits, as follows:
The letter "P\ (standing for "precautionary statement\"); the first digit represents the type of precautionary statement, as follows: "1\ stands for general precautionary statement;
"2\ stands for prevention precautionary statement;
"3" stands for emergency precautionary statement;
"4" stands for storage precautionary statement;
"5" stands for disposal precautionary statement;
c) The last 2 digits (corresponding to the serial number of the precautionary statement) D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used to replace the precautionary statement text.
D.2 General precautionary statements
General precautions should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels under the given conditions (see Table D.1). TrKAoNTKAca
GB30000.8—2013
-General public
Production workers
Supplementary information
Table D.1 General precautionary statements
Labels, supplementary label information
Labels, supplementary label information, safety data sheets, workplace signs
Precautionary statements for flammable solids
Precautionary statements for flammable solids Category and Category 2 are shown in Table D.2. General precautionary statements
If medical attention is required: Keep product container or label at hand Keep out of reach of children
Read label before use
Table D.2 Precautionary statements for flammable solids
Graphic symbol
Hazard category
Signal word
Hazard statement
11228 Flammable solid
H228 Flammable solid
Precautionary statements
P370+P378
Keep away from heat/sparks/open flames/hot surfaces No smokingIn case of fire: Use fire extinguisher
Manufacturer/supplier or competent authority to specify suitable ignition source.
Ground/bond container and containment equipment. If explosive is static sensitive
Use explosion proof electrical/ventilating/lighting//equipotential bonding equipment *Manufacturer/supplier or competent authority to specify other equipment.
If dust is generated.
Wear protective gloves/wear protective goggles/wear protective mask Manufacturer/supplier or government authority to specify type of equipment.
Manufacturer/supplier or government authority to specify appropriate media
Water may increase the risk
GB30000.8—2013
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