This standard specifies the label elements (symbols, warning words, hazard statements, etc.) based on the GHS hazard categories and levels of chemical substances. This standard applies to chemical labeling specifications based on GHS. GB/T 22234-2008 Chemical labeling specifications based on GHS GB/T22234-2008 Standard download decompression password: www.bzxz.net
This standard specifies the label elements (symbols, warning words, hazard statements, etc.) based on the GHS hazard categories and levels of chemical substances. This standard applies to chemical labeling specifications based on GHS.
class="f14" style="padding-top:10px; padding-left:12px; padding-bottom:10px;"> This standard is equivalent to JISZ7251:2006 "Chemical Labeling Specifications Based on GHS" (Japanese version).
For the convenience of use, the following editorial changes have been made:
a) Delete the original standard table of contents and preface;
b) Delete the original standard preface;
c) Use punctuation marks to replace the symbols represented by · in the original standard;
d) Use punctuation marks to replace the comma represented by , in the original standard.
Appendix A of this standard is a normative appendix.
This standard is proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251).
Participating drafting units of this standard: Sinochem Standardization Research Institute, Anhui Entry-Exit Inspection and Quarantine Bureau, Shanghai Chemical Industry Research Institute.
Drafters of this standard: Wen Jinsong, Fan Bin, Yao Jian, Wang Xiaobing, Mei Jian, Ji Ruwu, Zheng Ping, Gao Feng, Han Ping, Sun Zheng.
The clauses in the following documents become the clauses of this standard through reference in this standard. For dated references, all subsequent amendments (excluding errata) or revisions are not applicable to this standard. However, parties to agreements based on this standard are encouraged to study whether the latest versions of these documents can be used. For undated references, the latest versions are applicable to this standard.
JISZ7250 Material Safety Data Sheet (MSDS) Part 1: Content and order of items

ICS13.300
National Standard of the People's Republic of China
GB/T22234—2008
Labelling of chemicals based on GHS
Published on 2008-06-19
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China Administration of Standardization of the People's Republic of China
Digital Anti-Counterfeiting
All Products Qiuban Network
Implemented on 2009-02-01
This standard is equivalent to JIS Z 7251:2006 "Labeling of Chemicals Based on GHS" (Japanese version). For ease of use, the following editorial changes have been made: the original table of contents and preface have been deleted; the source text has been removed; the punctuation mark ", is used to replace the symbol "·" in the original standard; d) the punctuation mark "\" is used to replace the punctuation mark "\" in the original standard. Appendix A of this standard is a normative appendix. This standard was proposed and coordinated by the National Technical Committee for the Management of Hazardous Chemicals (SAC/TC251): GB/T22234-2008. The drafting units of this standard include: China Chemical Standardization Research Institute, Anhui Exit-Entry Inspection and Quarantine Bureau, Shanghai Chemical Industry Research Institute. The drafters of this standard include: Wen Jinsong, Fan Bin, Yao Jian, Wang Xiaobing, Mei Jian, Ji Ruwu, Zheng Ping, Gao Feng, Han Deping, and Sun Zheng. T
http://foodmate.net1 Scope
Chemical Labeling Specifications Based on GHS
GB/T 22234—2008
This standard specifies label elements (symbols, warning words, hazard statements, etc.) based on the GHS hazard categories and levels of chemical substances. This standard applies to chemical labeling specifications based on GHS. 2 Normative references
The clauses in the following documents become clauses of this standard through reference in this standard. For any dated reference, all subsequent amendments (excluding errata) or revisions are not applicable to this standard. However, parties that reach an agreement based on this standard are encouraged to study whether the latest versions of these documents can be used. For any undated reference, the latest version applies to this standard. JISZ7250 Material safety data sheet (MSDS) for chemical substances Part 1: Order of contents and items 3 Terms and definitions
The following terms and definitions apply to this standard. 3.1
Hazard
Hazard potential source of.
Substance
Chemical elements and their compounds that exist naturally or are obtained through synthesis. 3.3
Mixture
Material in a mixed state (including solutions) consisting of two or more chemical substances. 3.4
Chemical substances
Chemical substances or mixtures.
Note: "Chemical substances" can be understood as a synonym for "chemicals" or "products". 3.5
Ingredient
Ingredients of chemical substances.
Alloy
Metals that are not easily separated by physical means and are combined by two or more elements, appearing to be homogeneous metal bodies. Note: Alloys are considered mixtures in the classification of G-1S. 3.7
GHS Globally Harmonized System of Classification and Labeling of ChemicalsInternationally coordinated organization on the classification and labeling of chemicals. 3.8
GHS classification GHS elassifitalion
Classification of GB/T 22234-2008
based on the physical and chemical hazards, health hazards and environmental hazards of chemical substances and their mixtures according to GHS.
Hazard class
is divided into physical and chemical hazards such as flammable solids, health hazards such as carcinogenic substances and oral toxicity, and environmental hazards such as harmful to the aquatic environment.
Hazard level
is classified according to the judgment criteria within various hazard categories. For example: acute oral toxicity is divided into five levels, and flammable liquids are divided into four hazard levels. These classifications are relatively classified according to the degree of hazard within the hazard category and should not be regarded as a comparison of general hazard classifications.
Label
A label is a summary of the main information about dangerous and harmful products in written, printed or graphic form. The relevant department selects relevant content and directly sticks, prints or attaches it to the container1 of the hazardous substance or its outer packaging. 3.12
Label element
The label provides users with internationally recognized information, such as symbols, warning words, hazard statements and precautions. 3.13
Symbol: symbol
An image created to convey information concisely and clearly. For example: flame, etc. 3.14
Pictogram
It consists of elements such as symbols, border lines, background patterns and colors to convey specific information. 3.15
Material safety data sheet; MSDS is a written document that states the ingredients, product name, supplier, hazards, safety precautions, and countermeasures in case of accidents of hazardous chemicals and mixtures. Note: Material Safety Data Sheet (MSDS) is called Safety Data Sheet (SIDS) in GHS. 3.16
recomnendations on the transport of dangerous goods, model regulations
A written document officially published with the title of Annex to the United Nations Recommendations on the Transport of Dangerous Goods, Model Regulations, approved by the International Economic Council. 4 General matters
Information about a chemical substance, etc. is recorded on a label. Note: If the object is a mixture, and there are not enough labels for each component, a label can be made for the mixture. 5 Necessary information on labels and order of presentation of contents 5.1 Necessary information on labels
Necessary information on labels is as follows:
Pictograms indicating hazards:
Warning words:
c) Hazard statements;
Precautions:
e) Product name:
f) Manufacturer/supplier.
GB/T22234—2008
5.2 Order of presentation of label contents
When corresponding to a hazard category and level according to the classification results of GHS, the corresponding pictograms, warning words and hazard statements are used to make labels. Various correspondences are shown in Appendix A. Pictograms indicating hazards
Standard pictograms used in GHS are shown in Tables 1 to 3. The pictograms on labels cannot be significantly different from the standard pictograms used in CHS.
Name (symbol)
Pictogram
Hazard categories indicated by this graphic
Name (symbol)
Pictogram
Hazard categories indicated by this graphic
Flammable gases, flammable
Flammable gases under pressure
Flammable substrates
Flammable solids
Self-reactive chemicals
Pyrophoric liquids and solids||tt| |Self-heating chemicals
Water-discharging flammable gas chemicals
Organic peroxides
Corrosive
Metal corrosives
Leather corrosion/thorn
Serious damage to clothing, irritating
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Flames on the door
Bomb explosion
Explosives
Combustible, oxidizing gases, oxidizing
Self-reactive chemicals
Liquids.Solid
Organic peroxide
Gas cylinder
Gas under pressurewww.bzxz.net
Negative toxicity/acute year
GB/T 22234—2008
Name (Symbol)
Pictogram
Hazard category indicated by this graphic
Exclamation mark
Acute/very toxic
Skin corrosion, irritation
Eye damage/eye irritation
Causes skin allergy
Toxic to target organs and systemic
Harmful to the aquatic environment
Harmful to health
Causes respiratory allergy
Causes germ cell mutation
Carcinogenic
Toxic to reproduction
Harmful to target organs, systemic
Harmful to inhalers
The pictogram used in the label is: a black symbol on a white background in a diamond (square) shape for eye-catching. Then use a thicker red line as a border. For non-export packaging, the label can also use a line border. An example of a pictogram is shown in Figure 1.
Figure 1 Pictogram of skin irritants
Warning||The so-called warning word refers to a sentence that indicates the relative degree of severity of the danger and harm, and warns the user of potential hazards. The warning words used by GIIS are "Danger" and "Warning". "Danger" is used for more serious hazard levels and "Warning" is used for lower hazard levels. There are also cases where no warning word is written for even lower hazards. The warning words corresponding to each level of GHS hazard are shown in Appendix A.
Hazard Statement
Hazard statements correspond to various types of hazards and grade standards, indicating the nature and degree of the hazard of the product. The hazard statements corresponding to each level of GHS hazard are shown in Appendix A. Precautions
Recommended measures to be taken to prevent exposure to hazardous products or hazards caused by improper storage and handling, or to minimize the risk, expressed in words (or pictograms). The label contains appropriate precautions, and its selection is determined by the indication to be made. Note: The format of the precautionary items is the same as that of GHs Annex 3 Precautionary stutcinents. e) Product name
The product name is as follows:
1) The name or general name of the product is recorded on the label. The name and the product specific name of the MSDS should be consistent. If the substance or mixture meets the United Nations standard for the transportation of dangerous goods, the United Nations product name should be marked on the package at the same time.
MSDS items, recorded contents and overall composition can be based on JIS Z7250. The label should contain the name of the chemical substance.
On the label of a mixture or alloy, if it indicates acute toxicity (extremely toxic), skin corrosion, severe eye damage, germ cell mutation, carcinogenicity, reproductive toxicity, skin allergy, respiratory allergy, or toxicity to specific target organs or systemic damage (TOST), the chemical names of all ingredients or alloying elements related to these hazards should be indicated on the label. GB/T 22234—2008
All ingredients or alloying elements related to skin irritation and eye irritation can also be recorded on the label. Manufacturer name
The name of the manufacturer or supplier of the substance or mixture must be indicated on the label, and the address and telephone number should be indicated at the same time. If possible, the contact person in case of emergency should also be recorded on the label. 5.3 Regarding the order of multiple hazards and hazard information When indicating that chemical substances have several hazards, follow the following procedures. a) Regarding the order of pictograms
For health hazards, the following order can usually be adopted: 1) If "lin" can be used, it is best not to use "exclamation mark". 2) If "corrosive\" can be used, it is best not to use "exclamation mark" to indicate irritation to skin and eyes. When using "health hazard" to indicate respiratory sensitization, it is best not to use the "exclamation mark" to indicate skin sensitization or skin and eye irritation.
Regarding the order of warning words
When "danger" can be used, it is best not to use the warning word "warning". c) Regarding the order of hazard information
It is hoped that all corresponding hazard information will be recorded on the label. 6 Information not included in this standard or use of supplementary information Although it is not included in this standard, when there are other contents that should be included in the label as precautions, etc., you can actively a) add supplementary information. However, in order to prevent the label elements indicated in this standard from being ignored due to the addition of unnecessary information, it is hoped that the use of supplementary information is limited to the following two aspects: 1) Provide detailed information, but there is no contradiction with the appropriateness of the information on the hazards indicated in this standard, and it does not cause doubts.
2) Provide information on hazards that are not yet listed in GHS. In either case, the supplementary information shall not reduce the level of protection for health and the environment.
b) Supplementary information on hazards such as physical state and exposure route is not presented in the supplementary information section of the label, but is expected to be presented together with the hazard information.
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GB/T 22234-2008
Appendix A
(Normative Appendix)
Hazard classification (hazard categories and their classification) and label elements The label elements (pictograms, warning words, hazard information) corresponding to the various hazard categories and their classification of GHS are as follows. A. 1 Physical and chemical hazards
Explosives See Table A, 1.
Hazard level
Unstable explosive
Pictogram
Warning spectrum
Hazard statement
Pictogram
Alternative words
Hazard statement
Pictogram
Answer words
Hazard statement
Pictogram
Answer words
Hazard statement
Pictogram
Combined words
Hazard statement
Product partnership
Hazard disclosure notice
Unstable explosives
Explosives: Overall explosion hazard
Explosives: Violent projection hazard
Explosives: Fire, detonation, projection hazard warning
Fire, projection hazard
Hazard level
Warning word
Hazard statement
Pictogram
Warning spectrum
Hazard statement
For combustible and flammable gases, see Table A.2.
Hazard level
Pictogram
Warning word
Hazard statement
Pictogram
Hazard statement
A.1.3For combustible and flammable compressed gases, see Table A.3. Hazard level
Pictogram
Warning word
Hazard statement
Pictogram
Warning word
Hazard statement
All product partner network ht
Table A.1 (continued)
Hazard communication case
1.5 (background is orange)
Massive explosion may occur in case of fire
1.6 (background is orange)||tt| |No warning
No hazard statement
Hazard communication key points
Extremely flammable gas
No pictogram
Flammable, flammable gas
Hazard communication elements
Extremely flammable gas under pressure
Flammable, flammable gas under pressure
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GB/T 22234—2008
GB/T 22234—2008
A. 1. 4 Combustible and oxidizing gases See Table A. 4. Hazard level
Pictogram
Comfortable words
Hazard statement
A.1.5 Gas under pressure See Table A.5.
Hazard level
Pictogram
Compressed gas
Warning word
Hazard statement
Pictogram
Liquefied gas
Warning word
Hazard statement
Pictogram
Refrigerated liquefied gas
Hazard statement
Pictogram
Freezing gas
Registration word| |tt||Hazard Statements
Hazard Communication Essentials
May cause or intensify combustion: Oxidizers
Hazard Communication Essentials
Gases under pressure: May explode when heated
Gases under pressure: May explode when heated
Refrigerated liquefied gases: May cause low-temperature burns or injuries
Gases under pressure: May explode when heated
For flammable liquids, see Table A.6.
Hazard level
Pictogram
Advisory words
Hazard statement
Pictogram
Alternative words
Hazard statement
Pictogram
Warning words
Hazard statement
Pictogram
Hazard statement
A, 1.7 Combustible solids See Table A.7. Hazard level
Pictogram
Signal
Hazard statement
Pictogram
Signal
Hazard statement
Partner network
Hazard communication elements
Highly flammable vapors
Highly flammable liquids and vapors
Flammable liquids and vapors
No pictogram
Flammable gases
Hazard communication requirements
Flammable solids
Flammable solids
GB/T 22234--2008
GB/T 22234—2008
Self-reactive chemicals see Table A.8
Hazard level
Pictogram
Hazard statement
Pictogram
Warning word
Hazard statement
Pictogram
Type C and D
Warning word
Hazard statement
Pictogram
Type E and F
Warning word
Hazard statement
Pictogram
Warning word
Hazard statement
Pictogram
Warning word
Hazard statement
Self-reactive liquids see Table A.9.
Hazard level
Pictogram
Alternative wording
Hazard statement
Hazard communication elements
Heating may cause explosion
Heating may cause fire or explosion
Heating may cause fire
Heating may cause fire
No label elements for this level
Hazard communication elements
Spontaneous combustion may occur in contact with air
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