This standard specifies the label elements (symbols, warning words, hazard statements, etc.) based on the GHS hazard categories and levels of chemical substances. This standard applies to chemical labeling specifications based on GHS. GB/T 22234-2008 Chemical labeling specifications based on GHS GB/T22234-2008 Standard download decompression password: www.bzxz.net
This standard specifies the label elements (symbols, warning words, hazard statements, etc.) based on the GHS hazard categories and levels of chemical substances. This standard applies to chemical labeling specifications based on GHS. class="f14" style="padding-top:10px; padding-left:12px; padding-bottom:10px;">
This standard is equivalent to JISZ7251:2006 "Chemical Labeling Specifications Based on GHS" (Japanese version).
For the convenience of use, the following editorial changes have been made:
a) Delete the original standard table of contents and preface;
b) Delete the original standard preface;
c) Use punctuation marks to replace the symbols represented by · in the original standard;
d) Use punctuation marks to replace the comma represented by , in the original standard.
Appendix A of this standard is a normative appendix.
This standard is proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251).
Participating drafting units of this standard: Sinochem Standardization Research Institute, Anhui Entry-Exit Inspection and Quarantine Bureau, Shanghai Chemical Industry Research Institute.
Drafters of this standard: Wen Jinsong, Fan Bin, Yao Jian, Wang Xiaobing, Mei Jian, Ji Ruwu, Zheng Ping, Gao Feng, Han Ping, Sun Zheng. The clauses in the following documents become the clauses of this standard through reference in this standard. For dated references, all subsequent amendments (excluding errata) or revisions are not applicable to this standard. However, parties to agreements based on this standard are encouraged to study whether the latest versions of these documents can be used. For undated references, the latest versions are applicable to this standard.
JISZ7250 Material Safety Data Sheet (MSDS) Part 1: Content and order of items
Some standard content:
ICS13.300 National Standard of the People's Republic of China GB/T22234—2008 Labelling of chemicals based on GHS Published on 2008-06-19 General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China Administration of Standardization of the People's Republic of China Digital Anti-Counterfeiting All Products Qiuban Network Implemented on 2009-02-01 This standard is equivalent to JIS Z 7251:2006 "Labeling of Chemicals Based on GHS" (Japanese version). For ease of use, the following editorial changes have been made: the original table of contents and preface have been deleted; the source text has been removed; the punctuation mark ", is used to replace the symbol "·" in the original standard; d) the punctuation mark "\" is used to replace the punctuation mark "\" in the original standard. Appendix A of this standard is a normative appendix. This standard was proposed and coordinated by the National Technical Committee for the Management of Hazardous Chemicals (SAC/TC251): GB/T22234-2008. The drafting units of this standard include: China Chemical Standardization Research Institute, Anhui Exit-Entry Inspection and Quarantine Bureau, Shanghai Chemical Industry Research Institute. The drafters of this standard include: Wen Jinsong, Fan Bin, Yao Jian, Wang Xiaobing, Mei Jian, Ji Ruwu, Zheng Ping, Gao Feng, Han Deping, and Sun Zheng. T http://foodmate.net1 Scope Chemical Labeling Specifications Based on GHS GB/T 22234—2008 This standard specifies label elements (symbols, warning words, hazard statements, etc.) based on the GHS hazard categories and levels of chemical substances. This standard applies to chemical labeling specifications based on GHS. 2 Normative references The clauses in the following documents become clauses of this standard through reference in this standard. For any dated reference, all subsequent amendments (excluding errata) or revisions are not applicable to this standard. However, parties that reach an agreement based on this standard are encouraged to study whether the latest versions of these documents can be used. For any undated reference, the latest version applies to this standard. JISZ7250 Material safety data sheet (MSDS) for chemical substances Part 1: Order of contents and items 3 Terms and definitions The following terms and definitions apply to this standard. 3.1 Hazard Hazard potential source of. Substance Chemical elements and their compounds that exist naturally or are obtained through synthesis. 3.3 Mixture Material in a mixed state (including solutions) consisting of two or more chemical substances. 3.4 Chemical substances Chemical substances or mixtures. Note: "Chemical substances" can be understood as a synonym for "chemicals" or "products". 3.5 Ingredient Ingredients of chemical substances. Alloy Metals that are not easily separated by physical means and are combined by two or more elements, appearing to be homogeneous metal bodies. Note: Alloys are considered mixtures in the classification of G-1S. 3.7 GHS Globally Harmonized System of Classification and Labeling of ChemicalsInternationally coordinated organization on the classification and labeling of chemicals. 3.8 GHS classification GHS elassifitalion Classification of GB/T 22234-2008 based on the physical and chemical hazards, health hazards and environmental hazards of chemical substances and their mixtures according to GHS. Hazard class is divided into physical and chemical hazards such as flammable solids, health hazards such as carcinogenic substances and oral toxicity, and environmental hazards such as harmful to the aquatic environment. Hazard level is classified according to the judgment criteria within various hazard categories. For example: acute oral toxicity is divided into five levels, and flammable liquids are divided into four hazard levels. These classifications are relatively classified according to the degree of hazard within the hazard category and should not be regarded as a comparison of general hazard classifications. Label A label is a summary of the main information about dangerous and harmful products in written, printed or graphic form. The relevant department selects relevant content and directly sticks, prints or attaches it to the container1 of the hazardous substance or its outer packaging. 3.12 Label element The label provides users with internationally recognized information, such as symbols, warning words, hazard statements and precautions. 3.13 Symbol: symbol An image created to convey information concisely and clearly. For example: flame, etc. 3.14 Pictogram It consists of elements such as symbols, border lines, background patterns and colors to convey specific information. 3.15 Material safety data sheet; MSDS is a written document that states the ingredients, product name, supplier, hazards, safety precautions, and countermeasures in case of accidents of hazardous chemicals and mixtures. Note: Material Safety Data Sheet (MSDS) is called Safety Data Sheet (SIDS) in GHS. 3.16 recomnendations on the transport of dangerous goods, model regulations A written document officially published with the title of Annex to the United Nations Recommendations on the Transport of Dangerous Goods, Model Regulations, approved by the International Economic Council. 4 General matters Information about a chemical substance, etc. is recorded on a label. Note: If the object is a mixture, and there are not enough labels for each component, a label can be made for the mixture. 5 Necessary information on labels and order of presentation of contents 5.1 Necessary information on labels Necessary information on labels is as follows: Pictograms indicating hazards: Warning words: c) Hazard statements; Precautions: e) Product name: f) Manufacturer/supplier. GB/T22234—2008 5.2 Order of presentation of label contents When corresponding to a hazard category and level according to the classification results of GHS, the corresponding pictograms, warning words and hazard statements are used to make labels. Various correspondences are shown in Appendix A. Pictograms indicating hazards Standard pictograms used in GHS are shown in Tables 1 to 3. The pictograms on labels cannot be significantly different from the standard pictograms used in CHS. Name (symbol) Pictogram Hazard categories indicated by this graphic Name (symbol) Pictogram Hazard categories indicated by this graphic Flammable gases, flammable Flammable gases under pressure Flammable substrates Flammable solids Self-reactive chemicals Pyrophoric liquids and solids||tt| |Self-heating chemicalsbzxZ.net Water-discharging flammable gas chemicals Organic peroxides Corrosive Metal corrosives Leather corrosion/thorn Serious damage to clothing, irritating http:// Flames on the door Bomb explosion Explosives Combustible, oxidizing gases, oxidizing Self-reactive chemicals Liquids.Solid Organic peroxide Gas cylinder Gas under pressure Negative toxicity/acute year GB/T 22234—2008 Name (Symbol) Pictogram Hazard category indicated by this graphic Exclamation mark Acute/very toxic Skin corrosion, irritation Eye damage/eye irritation Causes skin allergy Toxic to target organs and systemic Harmful to the aquatic environment Harmful to health Causes respiratory allergy Causes germ cell mutation Carcinogenic Toxic to reproduction Harmful to target organs, systemic Harmful to inhalers The pictogram used in the label is: a black symbol on a white background in a diamond (square) shape for eye-catching. Then use a thicker red line as a border. For non-export packaging, the label can also use a line border. An example of a pictogram is shown in Figure 1. Figure 1 Pictogram of skin irritants Warning||The so-called warning word refers to a sentence that indicates the relative degree of severity of the danger and harm, and warns the user of potential hazards. The warning words used by GIIS are "Danger" and "Warning". "Danger" is used for more serious hazard levels and "Warning" is used for lower hazard levels. There are also cases where no warning word is written for even lower hazards. The warning words corresponding to each level of GHS hazard are shown in Appendix A. Hazard Statement Hazard statements correspond to various types of hazards and grade standards, indicating the nature and degree of the hazard of the product. The hazard statements corresponding to each level of GHS hazard are shown in Appendix A. Precautions Recommended measures to be taken to prevent exposure to hazardous products or hazards caused by improper storage and handling, or to minimize the risk, expressed in words (or pictograms). The label contains appropriate precautions, and its selection is determined by the indication to be made. Note: The format of the precautionary items is the same as that of GHs Annex 3 Precautionary stutcinents. e) Product name The product name is as follows: 1) The name or general name of the product is recorded on the label. The name and the product specific name of the MSDS should be consistent. If the substance or mixture meets the United Nations standard for the transportation of dangerous goods, the United Nations product name should be marked on the package at the same time. MSDS items, recorded contents and overall composition can be based on JIS Z7250. The label should contain the name of the chemical substance. On the label of a mixture or alloy, if it indicates acute toxicity (extremely toxic), skin corrosion, severe eye damage, germ cell mutation, carcinogenicity, reproductive toxicity, skin allergy, respiratory allergy, or toxicity to specific target organs or systemic damage (TOST), the chemical names of all ingredients or alloying elements related to these hazards should be indicated on the label. GB/T 22234—2008 All ingredients or alloying elements related to skin irritation and eye irritation can also be recorded on the label. Manufacturer name The name of the manufacturer or supplier of the substance or mixture must be indicated on the label, and the address and telephone number should be indicated at the same time. If possible, the contact person in case of emergency should also be recorded on the label. 5.3 Regarding the order of multiple hazards and hazard information When indicating that chemical substances have several hazards, follow the following procedures. a) Regarding the order of pictograms For health hazards, the following order can usually be adopted: 1) If "lin" can be used, it is best not to use "exclamation mark". 2) If "corrosive\" can be used, it is best not to use "exclamation mark" to indicate irritation to skin and eyes. When using "health hazard" to indicate respiratory sensitization, it is best not to use the "exclamation mark" to indicate skin sensitization or skin and eye irritation. Regarding the order of warning words When "danger" can be used, it is best not to use the warning word "warning". c) Regarding the order of hazard information It is hoped that all corresponding hazard information will be recorded on the label. 6 Information not included in this standard or use of supplementary information Although it is not included in this standard, when there are other contents that should be included in the label as precautions, etc., you can actively a) add supplementary information. However, in order to prevent the label elements indicated in this standard from being ignored due to the addition of unnecessary information, it is hoped that the use of supplementary information is limited to the following two aspects: 1) Provide detailed information, but there is no contradiction with the appropriateness of the information on the hazards indicated in this standard, and it does not cause doubts. 2) Provide information on hazards that are not yet listed in GHS. In either case, the supplementary information shall not reduce the level of protection for health and the environment. b) Supplementary information on hazards such as physical state and exposure route is not presented in the supplementary information section of the label, but is expected to be presented together with the hazard information. http GB/T 22234-2008 Appendix A (Normative Appendix) Hazard classification (hazard categories and their classification) and label elements The label elements (pictograms, warning words, hazard information) corresponding to the various hazard categories and their classification of GHS are as follows. A. 1 Physical and chemical hazards Explosives See Table A, 1. Hazard level Unstable explosive Pictogram Warning spectrum Hazard statement Pictogram Alternative words Hazard statement Pictogram Answer words Hazard statement Pictogram Answer words Hazard statement Pictogram Combined words Hazard statement Product partnership Hazard disclosure notice Unstable explosives Explosives: Overall explosion hazard Explosives: Violent projection hazard Explosives: Fire, detonation, projection hazard warning Fire, projection hazard Hazard level Warning word Hazard statement Pictogram Warning spectrum Hazard statement For combustible and flammable gases, see Table A.2. Hazard level Pictogram Warning word Hazard statement Pictogram Hazard statement A.1.3For combustible and flammable compressed gases, see Table A.3. Hazard level Pictogram Warning word Hazard statement Pictogram Warning word Hazard statement All product partner network ht Table A.1 (continued) Hazard communication case 1.5 (background is orange) Massive explosion may occur in case of fire 1.6 (background is orange)||tt| |No warning No hazard statement Hazard communication key points Extremely flammable gas No pictogram Flammable, flammable gas Hazard communication elements Extremely flammable gas under pressure Flammable, flammable gas under pressure ndmatn-no GB/T 22234—2008 GB/T 22234—2008 A. 1. 4 Combustible and oxidizing gases See Table A. 4. Hazard level Pictogram Comfortable words Hazard statement A.1.5 Gas under pressure See Table A.5. Hazard level Pictogram Compressed gas Warning word Hazard statement Pictogram Liquefied gas Warning word Hazard statement Pictogram Refrigerated liquefied gas Hazard statement Pictogram Freezing gas Registration word| |tt||Hazard Statements Hazard Communication Essentials May cause or intensify combustion: Oxidizers Hazard Communication Essentials Gases under pressure: May explode when heated Gases under pressure: May explode when heated Refrigerated liquefied gases: May cause low-temperature burns or injuries Gases under pressure: May explode when heated For flammable liquids, see Table A.6. Hazard level Pictogram Advisory words Hazard statement Pictogram Alternative words Hazard statement Pictogram Warning words Hazard statement Pictogram Hazard statement A, 1.7 Combustible solids See Table A.7. Hazard level Pictogram Signal Hazard statement Pictogram Signal Hazard statement Partner network Hazard communication elements Highly flammable vapors Highly flammable liquids and vapors Flammable liquids and vapors No pictogram Flammable gases Hazard communication requirements Flammable solids Flammable solids GB/T 22234--2008 GB/T 22234—2008 Self-reactive chemicals see Table A.8 Hazard level Pictogram Hazard statement Pictogram Warning word Hazard statement Pictogram Type C and D Warning word Hazard statement Pictogram Type E and F Warning word Hazard statement Pictogram Warning word Hazard statement Pictogram Warning word Hazard statement Self-reactive liquids see Table A.9. Hazard level Pictogram Alternative wording Hazard statement Hazard communication elements Heating may cause explosion Heating may cause fire or explosion Heating may cause fire Heating may cause fire No label elements for this level Hazard communication elements Spontaneous combustion may occur in contact with air s口件网htt Tip: This standard content only shows part of the intercepted content of the complete standard. If you need the complete standard, please go to the top to download the complete standard document for free.