GB 30000.5-2013 Chemical Classification and Labelling Specification Part 5: Oxidizing Gases GB30000.5-2013 Standard compression package decompression password: www.bzxz.net
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of oxidizing gases. This part applies to the classification and labeling of oxidizing gases in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals.
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended.
The expected structure of GB30000 "Specifications for Classification and Labelling of Chemicals" and the national standards to be replaced are:
———Part 1: General (replaces GB13690-2009);
———Part 2: Explosives (replaces GB20576-2006);
———Part 3: Flammable gases (replaces GB20577-2006);
———Part 4: Aerosols (replaces GB20578-2006);
———Part 5: Oxidizing gases (replaces GB20579-2006);
———Part 6: Gases under pressure (replaces GB20580-2006);
———Part 7: Flammable liquids (replaces GB20581-2006);
———Part 8: Flammable solids (replaces GB 20582-2006);
———Part 9: Self-reactive substances and mixtures (replaces GB 20583-2006);
———Part 10: Pyrophoric liquids (replaces GB 20585-2006);
———Part 11: Pyrophoric solids (replaces GB 20586-2006);
———Part 12: Self-heating substances and mixtures (replaces GB 20584-2006);
———Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB 20587-2006);
———Part 14: Oxidizing liquids (replaces GB 20589-2006);
——Part 15: Oxidizing solids (replaces GB 20590-2006);
——Part 16: Organic peroxides (replaces GB 20591-2006);
——Part 17: Corrosive to metals (replaces GB 20588-2006);
——Part 18: Acute toxicity (replaces GB 20592-2006);
——Part 19: Skin corrosion/irritation (replaces GB 20593-2006);
——Part 20: Serious eye damage/eye irritation (replaces GB 20594-2006);
——Part 21: Respiratory or skin sensitization (replaces GB 20595-2006);
———Part 22: Germ cell mutagenicity (replaces GB 20596-2006);
———Part 23: Carcinogenicity (replaces GB 20597-2006);
———Part 24: Reproductive toxicity (replaces GB 20598-2006);
———Part 25: Specific target organ toxicity single exposure (replaces GB 20599-2006);
———Part 26: Specific target organ toxicity repeated exposure (replaces GB 20601-2006);
———Part 27: Aspiration hazard;
———Part 28: Hazard to the aquatic environment (replaces GB 20602-2006);
———Part 29: Hazard to the ozone layer;
———Part 30: Warning signs for chemical workplaces.
This part is part 5 of GB 30000.
This part was drafted in accordance with the rules given in GB/T 1.1-2009.
This part replaces GB 20579-2006 "Safety Specification for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Oxidizing Gases".
This part is consistent with the relevant technical content of the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition).
Compared with GB20579-2006, the main technical content changes are as follows:
———The name of the standard has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals—Part 5: Oxidizing gases" and the English name is "Rules for classification and labelling of chemicals—Part 5: Oxidizing gases";
———The scope of Chapter 1 has been modified, "Warning labels" has been changed to "labels", and "Warning instructions" has been deleted; ||tt
|| ———The introductory words of Chapter 2 "Normative references" have been modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" has been added as a reference document;
———The introductory words of Chapter 3 "Terms and Definitions" have been added;
———Figure 1 "Decision Logic Diagram" and "Guidance" in Chapter 5 have been made informative Appendix A;
———Deleted the original Chapter 7, and revised Table 3 of the original Chapter 7 as normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition);
———Revised and integrated the original Chapters 6, 7 and 8 into Chapter 6 according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition); revised Table 2 as normative Appendix C;
———Deleted the original Chapter 8, and made the relevant "Hazard Statements" and "Precautionary Statements" as informative Appendix D;
———Added informative Appendix E "Label Examples".
This part was proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251).
Drafting units of this part: China Chemical Economic and Technological Development Center, China Chemical Information Center, Shanghai Research Institute of Chemical Industry, Zhejiang Research Institute of Chemical Industry Co., Ltd., Huafeng Group Co., Ltd.
The main drafters of this part: Zhang Junxi, Liang Jin, Feng Zhuo, Fang Lu, Xiao Qiuping, Cao Mengran, Wen Tao, Xue Jingqin, Cheng Lihong, Li Tie, Yang Ting, An Chao.
The previous versions of the standards replaced by this part are as follows:
———GB20579—2006.
The following documents are indispensable for the application of this document. For any dated referenced document, only the dated version applies to this document. For any undated referenced document, the latest version (including all amendments) applies to this document.
GB6944—2012 Classification and product name numbering of dangerous goods
GB13690 General principles for classification and hazard communication of chemicals
GB/T27862 Test methods for hazard classification of chemicals - Combustion potential and oxidizing power of gases and gas mixtures
United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition)

ICS13.300
National Standard of the People's Republic of China
GB30000.5—2013
Replaces GB20579—2006
Rules for classification and labelling of chemicals-Part 5:Oxidizing gases gases
2013-10-10 Issued
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China
Standardization Administration of the People's Republic of China
2014-11-01 Implementation
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. The expected structure of GB30000≤Chemical Classification and Labeling Specification" and the national standards to be replaced are: Part 1: General (replaces GB13690-2009): Part 2: Explosives (replaces GB20576-2006); Part 3: Flammable gases (replaces GB20577-2006): Part 4: Aerosols (replaces GB20578-2006): Part Part 5: Oxidizing gases (replaces GB20579-2006); Part 6: Gases under pressure (replaces GB20580-2006); Part 7: Flammable liquids (replaces GB20581-2006); Part 8: Flammable solids (replaces GB20582-2006); Part 9: White-reactive substances and mixtures (replaces GB20583-2006); Part 10: Pyrophoric liquids (replaces GB20585-2006); Part 11: Pyrophoric solids (replaces GB20586-2006); Part 12: Self-heating substances and mixtures (replaces GB20584-2006); Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB20587-2006); 2006): Part 14: Oxidizing Liquids (replaces GB20589-2006); Part 15: Oxidizing Solids (replaces GB20590-2006): Part 16: Organic Peroxides (replaces GB20591-2006): Part 17: Metal Corrosives (replaces GB20588-2006); Part 18: Acute Toxicity (replaces GB20592-2006): Part 19: Skin Corrosion/Irritation (replaces GB20593-2006); Part 20: Serious Eye Damage/Irritation (replaces GB20594-2006); Part 21: Respiratory or Skin Sensitization (replaces GB20595-2006): Part 22: Germ Cell Mutagenicity Denaturation (replaces GB20596-2006); Part 23: Carcinogenicity (replaces GB20597-2006); Part 24: Reproductive toxicity (replaces GB205982006); Secondary exposure (replaces GB205992006); Part 25: Specific target organ toxicity
Part 26: Specific target organ toxicity repeated exposure (replaces GB20601-2006); Part 27: Inhalation hazard;
Part 28: Hazards to the aquatic environment (replaces GB20602-2006); Part 29: Hazards to the ozone layer;
Part 30: Warning signs for chemical workplaces: This part is Part 5 of GB30000.
This part was drafted in accordance with the rules given in GB/T1.1-2009. GB30000.5—2013bzxz.net
This part replaces GB205792006 "Safety Rules for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Oxidizing Gases". This part is consistent with the technical content related to the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition). Compared with GB205792006, the main technical content changes are as follows: 1
GB30000.5—2013
The standard name has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals Part 5: Oxidizing gases", and the English name is \Rules for classification and labelling of chemicals Part 5 Oxidizing gases; modified the scope of Chapter 1, changed "warning label" to "label", deleted "warning statement"; modified the introduction of Chapter 2 "normative references", and added "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" as a reference document; added the introduction of Chapter 3 "Terms and Definitions"; made Figure 1 "Decision Logic Diagram" and "Guide" of Chapter 5 as informative Appendix A; deleted the original Chapter 7, and modified Table 3 of the original Chapter 7 as normative Appendix B according to the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Fourth Revised Edition);
According to the United Nations Global Chemicals The "Harmonized Classification and Labelling System" (4th revised edition) revised and integrated the original Chapter 6, Chapter 7 and Chapter 8 into Chapter 6; the original Table 2 was revised as normative Appendix C; the original Chapter 8 was deleted, and the relevant "Hazard Statements" and "Precautionary Statements" were included as informative Appendix D; and the informative Appendix E "Label Examples" was added. This part was proposed and coordinated by the National Technical Committee for the Management of Hazardous Chemicals (SAC/TC251). Drafting units of this part: China Chemical Economic and Technological Development Center, China Chemical Information Center, Shanghai Research Institute of Chemical Industry, Zhejiang Chemical Research Institute Co., Ltd., Huafeng Group Co., Ltd. The main drafters of this part: Zhang Junxi, Liang Jin, Feng Zhuo, Fang Lu, Xiao Qiuping, Cao Mengran, Wen Tao, Xue Jing Qin, Cheng Lihong, Li Tie, Yang Ting, An Chao.
The previous versions of the standard replaced by this part are: GB20579-2006.
Chemical classification and labeling specifications
Part 5: Oxidizing gases
GB30000.5-2013
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of oxidizing gases. This part applies to the classification and labeling of oxidizing gases in accordance with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (hereinafter referred to as GHS).
2 Normative references
The following documents are indispensable for the application of this document. For any dated reference, only the dated version applies to this document. For any undated reference, the latest version (including all amendments) applies to this document. GB6944-2012 Classification and name numbering of dangerous goods GB13690 General rules for classification and hazard communication of chemicals GB/T27862 Test methods for hazard classification of chemicals Combustion potential and oxidizing capacity of gases and gas mixtures United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Fourth Revised Edition) Model Regulations (Seventeenth Revised Edition)
United Nations "Recommendations on the Transport of Dangerous Goods 3 Terms and Definitions
The terms and definitions defined in GB13690 and the following terms and definitions apply to this document. 3.1
oxidizinggases
oxidizing gas
any gas that can cause or contribute to the combustion of other substances more than air, generally by providing oxygen" 4 Classification standards
For the general principles of classification and labeling of oxidizing gases, see GB13690. 4.1
4.2For the classification of oxidizing gases, see Table 1.
Table 1 Classification of oxidizing gases
Decision logic and guidance
Any gas that can cause or contribute to the combustion of other substances more than air, generally by providing oxygen. The decision logic and guidance are for reference only. See Appendix A for decision logic and guidance. It is particularly recommended that those responsible for classification use decision logic 1) "Any gas that can cause or contribute to the combustion of other substances more than air" , refers to pure gas or gas mixture with an oxidizing power greater than 23.5 as determined by the method specified in GB/T27862 GB30000.5-2013
Research before and during use Chapter 4.
6 Label
6.1 Overview
6.1.1 For the labels of oxidizing gases, the hazard categories are listed in the order of designated pictograms, signal words and hazard statements. The hazard types or categories covered by the United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (Seventeenth Revised Edition) (hereinafter referred to as the Model Regulations) should list the designated corresponding graphic signs for each category on the label. The allocation of label elements for oxidizing gases is shown in Appendix B. 6.1.2 For the classification standards and label elements for oxidizing gases, see Appendix C6.1.3 The information required on the label includes hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and supplier identification. Note: For other label elements that have not been standardized, such as additional instructions, they also need to be included on the label. The competent authority may also require additional information, and the supplier may also add supplementary information.
6.2 Hazard pictograms
Hazard pictograms should use black symbols with a white background and a red frame that is wide enough to make them eye-catching. The hazard pictograms specified in the Model Regulations are shown in Appendix B. 6.3 Signals
Signals are words used on labels to indicate the relative severity of a hazard and to alert readers to potential hazards. For oxidizing gases, the signal word "Danger" is used.
Hazard Statements
Hazard statements are phrases assigned to a hazard category that describe the hazardous nature of the hazard and, where appropriate, the degree of hazard of the hazard.
Oxidizing gas hazard statements refer to Appendix
6.5 Precautionary statements
Precautionary statements are words (and/or pictograms) describing recommended measures to minimize or prevent adverse effects resulting from exposure to the hazardous product or from improper storage or handling of the hazardous product. For this purpose, there are five categories of precautionary statements: general, prevention, emergency, storage and disposal. For oxidizing gas precautionary statements refer to Appendix D. 6.6 Product identifiers
6.6.1 The product identifier shall be used on the label and shall be consistent with the product identifier used on the full technical instructions for the chemical product. If a substance or mixture is listed in the Model Regulations, the correct UN shipping name shall also be used on the packaging. 6.6.2 The label shall include the chemical name of the substance. For mixtures or alloys: When acute toxicity, skin or respiratory sensitization or specific target organ toxicity appear on the label, the label shall include the chemical composition of all ingredients or alloying elements that may contribute to these hazards. The competent authority may require that the chemical names of all ingredients or alloying elements that may contribute to the hazards of the mixture or alloy be listed on the label. 6.7 Supplier identification
The name, address and telephone number of the manufacturer or supplier of the substance or mixture shall be provided on the label. 6.8 Label examples
For examples of labels for oxidizing gases, see Appendix E. 2
A.1 Decision logic
Appendix A
(Informative)
Decision logic and guidance
GB30000.5—2013
For the classification of oxidizing gases, the test or calculation method described in GB/T 27862 shall be used. The classification shall be carried out according to the decision logic in Figure A.1.
Gaseous substances or gas humidification
Is the gas more flammable than air? Hazard
Decision logic for oxidizing gases
A.2 Guidance
An example of the classification of oxidizing gas mixtures by calculation according to GB/T 27862. The classification method described in GB/T27862 adopts the standard that if the oxidizing power of a gas mixture is greater than 23.5%, it is considered that the oxidizing power of the gas mixture is greater than that of air. The oxidizing power (OP) is calculated by formula (A, 1): Op
Wherein:
The molar concentration of the main oxidizing gas in the mixture: C
The oxygen equivalence coefficient of the oxidizing gas in the mixture; The equivalence coefficient of the inert gas and nitrogen: The molar concentration of the largest inert gas in the mixture; X100%
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.(A.1)
GB30000.5—2013
The total number of oxidizing gases in the mixture:
The total number of inert gases in the mixture.
Example of a mixture:
9%(O,)+16%(N,O)+75%(He)
Calculation steps:
Step 1: For non-flammable and non-oxidizing gases, determine the oxygen equivalence coefficient (C) of the oxidizing gas in the mixture and the equivalence coefficient (K,) of the inert gas in the mixture compared to nitrogen. C,(N,O) 0.6 (nitrous oxide)
C(02)=1 (oxygen)
K,(He)=0.9 (ammonia)
b) Step 2: Calculate the oxidizing capacity of the gas mixture. rc
OP=20.1%<23.5%
0.09X1+0.16X0.6
X100%=20.1%
0.09+0.16+0.75×0.9
Therefore, the mixture is not considered to be an oxidizing gas. The allocation of label elements is shown in Table B.1.
Category 1
Can cause combustion or
intensify combustion;
Oxidizer
Appendix B
(Normative Appendix)
Allocation of label elements
Allocation of label elements for oxidizing gases
Oxidizing gases
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GB30000.5—2013
In the model regulations:
Color of graphic symbols
Graphic symbols and numbers
Black:
Background: Yellow.
2) Number 5.1 in the figure is the first item of the
5th category in
GB6944—2012.
Cargo transport graphic
The minimum size of the sign is
100mm×100mm
GB30000.5—2013
Appendix C
(Normative Appendix)
Classification standards and label elements for oxidizing gases Classification standards and label elements for oxidizing gases are shown in Table C.1. Table C.1 Classification standards and label elements for oxidizing gases Hazard category
Any gas that can cause or promote the combustion of other substances more than air, generally by providing oxygen.
Label elements
Graphic symbols
May cause combustion or
Hazard statements
Intensify combustion:
Oxidizers
D.1 Overview
Appendix D
(Informative Appendix)
Hazard statements and precautionary statements for oxidizing gases GB30000.5—2013
D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for oxidizing gases. It lists the hazard statements and precautionary statements for each hazard type and hazard category of oxidizing gases. See GB13690. D.1.2 Coding of hazard statements:
D.1.2.1 For the coding of hazard statements, see Annex 3 of CHS. D.1.2.2 Each hazard statement shall be assigned a specific alphanumeric code consisting of one letter and three digits, as follows:
a) the letter \"(representing \"hazard statement"); b) the
th digit representing the type of hazard referred to by the hazard statement specified in this part, such as
representing physical hazard;
representing health hazard;
representing environmental hazard; the last two digits corresponding to the sequence number of the hazard caused by the inherent properties of the substance or mixture, such as: explosiveness (codes 200 to 210), flammability (codes 220 to 250), etc. D.1.2.3
Unless otherwise specified, all specified hazard statements shall appear on the label. The competent authority may specify the order in which the hazard statements appear on the label. In addition, when two or more hazard statements are provided in combination, the competent authority may specify whether the order in which they appear shall be grouped together.
Combined hazard statements or corresponding individual statements shall be written on the label, etc., at the discretion of the manufacturer or supplier. The combined hazard statement shall be marked on the label together with the harmonized hazard communication elements (pictograms, signal words and hazard statements) D.1.3 Precautionary statements
.
Additional supplementary information, such as instructions for use, may also be added at the discretion of the manufacturer/supplier and/or the competent authority: D.1.3.1 The code for precautionary statements is shown in Annex 3 of the HS. D.1.3.2 Coding of precautionary statements
D.1.3.2.1 Each precautionary statement is assigned a special alphanumeric code consisting of 1 letter and 3 numbers, as follows:
The letter "P" (standing for "precautionary statement"); the first number represents the type of precautionary statement, as follows: "1" represents general precautionary statement;
"2\ represents prevention precautionary statement;
"3\ represents emergency precautionary statement;
"4\ represents storage precautionary statement;
"5\ represents disposal precautionary statement;
c) the last 2 numbers (corresponding to the serial number of the precautionary statement). D.1.3.2.2 Precautionary statement codes are for reference only. Precautionary statement codes are not part of the precautionary statement text and should not be used in place of the precautionary statement text.
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GB30000.5-—2013
D.2 General precautionary statements
General precautions should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels under the given conditions (see Table D.1). Table D.1 General precautionary statements
General public
Production workers
Supplementary information
Labels, supplementary label information
Labels, supplementary label information, safety data sheets, workplace instructions
D.3 Precautionary statements for oxidizing gases
Precautionary statements for oxidizing gases are shown in Table D.2. Code
-General precautionary statements
If medical attention is required: Keep product container or label with you and keep out of the reach of children.
Read the label before use.
Table D.2 Precautionary statements for oxidizing gases
Graphic special number
Hazard category
Signal word
Hazard statement
H270 May cause or intensify fire; Precautionary statements for oxidizers
P370+P376
Avoid storage away from clothing. Combustible materials. Manufacturer/supplier or competent authority to specify other incompatible materials.
Doors or fastenings must not be greased or oiled. In case of fire: Stop leaks if safe to do so.
Store in a well-ventilated
place.
GB30000.5—2013
Chuangtai Villa
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