GB 16483-2000 Provisions for the preparation of chemical safety data sheets
Some standard content:
GB 16483--2000
In order to make the format and content of my country's chemical safety data sheet consistent with international standards as much as possible, so as to adapt to the needs of international trade, technology and economic exchanges as soon as possible, this standard is equivalent to IS0) 11014-1: 1994 "Chemical Safety Data Sheet". The main differences between this standard and IS0) 11014-1: 1994 are: ① Added Appendix B and Appendix C; ② Added "referenced standards" chapter. When this standard revised GB16483--1996 based on the international ISO) 11014-1 standard, it retained the clauses in GB16483-1996 that were proven to be suitable for my country's national conditions and did not affect the content of the international standard, made appropriate adjustments to the combustion and explosion hazard characteristics and toxicity and health hazards, and made necessary supplements to safety, environmental protection and other aspects. The main technical differences between this version of the standard and GB16483-1996 are as follows: First, in order to be consistent with the ISO11014 international standard, the name of this standard is redefined. 1. Adjust the original eight items and increase them to sixteen items. 1. Move health hazards to the newly set "hazard overview" item H. Move the sub-item "hazard characteristics" set in the combustion and explosion hazard characteristics to the newly set "fire protection measures" item. 1. Move the sub-items "flash point, ignition temperature, upper explosion limit, lower explosion limit" set in the combustion and explosion hazard characteristics to the "physical and chemical properties" item.
1. Combine packaging and transportation into the "transportation information" item, and set packaging in the sub-item of transportation information; at the same time, add the following clauses:
1. Hazard overview;
2. Fire protection measures;
3. Toxicological information;
4. Ecological information;
5. Regulatory information;
6. Other information.
Appendix A of this standard is the appendix to the standard.
Appendices B and C of this standard are It is a prompt appendix. This standard replaces GB16483-1996 from the date of implementation. This standard is proposed and coordinated by the Economic and Trade Commission of the People's Republic of China. Drafting unit of this standard: Occupational Safety and Health Research Institute of the Ministry of Chemical Industry. The main drafters of this standard are Zhang Haifeng, Li Xuehua, Li Yuncai, Zhang Qibo, 46
GB16483-2000
ISO Foreword
ISO (International Organization for Standardization) is a worldwide federation composed of standardization bodies (ISO member bodies) of various countries. The work of formulating international standards is usually completed by ISO's technical committees. If each member body is interested in a project established by a technical committee, it has the right to participate in the work of the committee. International organizations (official or Unofficial) can also participate in the relevant work. In the field of electrotechnical standardization, ISO maintains a close cooperative relationship with the International Electrotechnical Commission (IEC). The draft international standard adopted by the technical committee is submitted to the member groups for voting. It must obtain the consent of at least 75% of the member groups participating in the vote before it can be officially published as an international standard. The international standard ISO11014-1 was prepared by the Technical Committee ISO/TC47 Chemical Group. ISO11014 consists of the following two parts:
Part 1: Content and order of clauses;
Part 2: Examples.
Appendix A describes SO11014 in detail. 46
GB16483-2000
Chemical Safety Technical Instructions The Material Safety Data Sheet (SDS) provides various information on safety, health and environmental protection for chemical substances and their products, and can provide information on basic knowledge, protective measures and emergency actions of chemicals. In some countries, SDS is also called Material Safety Data Sheet (MSDS), and ISO11014 adopts the term SDS. SDS is a tool for chemical production and supply companies to provide users with basic hazard information (including transportation, handling, storage and emergency actions, etc.). The purpose of ISO11014 is to achieve consistency in the expression of chemical safety information among countries through the implementation of this standard. In order to establish a unified format for writing technical specifications, some basic principles need to be formulated (such as the wording of the title, the determination of the numbering and the order of the front and back). ISO11014 can be flexibly applied to the dissemination of information between different languages. ISO1101.4 has been widely used worldwide. For example, EC Commission Directive 91/155/EEC has made a detailed design for the structure and items of technical specifications for hazardous chemicals, and the MSDS guide compiled by the Chemical Manufacturers Association (CMA) has only made minor changes in the title part. ISO11014 does not take into account the special requirements of different national or regional regulations. This standard prepares this information for SDS compilers so that different countries can compile generally consistent SDSs. The responsibilities of SDS users are not within the scope of ISO11014. Nevertheless, it also contains some information in this regard, but the responsibilities of SDS manufacturers and SDS users are significantly different. 47
1 Scope
National Standard of the People's Republic of China
General rules for preparation of chemical safety data sheet
This standard specifies the content and preparation requirements of chemical safety data sheets (CSDS). This standard applies to industrial chemicals, including chemical elements, compounds and mixtures. GB16483—2000
eqvISo11014-1:1994
Replaces GB16483—1996
This standard does not apply to civilian controlled consumer products, small quantities of samples for scientific research purposes and special hazardous chemicals specified by the state.
2 Referenced standards
The provisions contained in the following standards constitute the provisions of this standard through reference in this standard. When this standard is published, the versions shown are valid. All standards will be revised, and parties using this standard should explore the possibility of using the latest versions of the following standards. GB6944--1986 Classification and name number of dangerous goods GB13690-1992 Classification and marking of commonly used dangerous chemicals GB/T15098-1994 Principles for classification of dangerous goods transport packaging United Nations "Recommendations on the Transport of Dangerous Goods" (abbreviated as UNRTDG) "Dangerous Goods Transport Management Rules" (issued by the Ministry of Railways) 1995 Note: The United Nations "Recommendations on the Transport of Dangerous Goods" can be obtained from the National Chemical Registration Center. 3 Contents
The Chemical Safety Data Sheet (CSDS) includes the following sixteen parts. 3.1 Chemical and Company Identification
Mainly indicate the name of the chemical, name of the manufacturer, address, zip code, telephone number, emergency telephone number, fax number and other information. 3.2 Ingredients/Composition Information
Indicate whether the chemical is a pure chemical or a mixture. For pure chemicals, the chemical name or trade name and common name should be given. For mixtures, the concentration or concentration range of hazardous components should be given. Whether it is a pure chemical or a mixture, if it contains hazardous components, the Chemical Abstracts Index Registration Number (CAS Number) should be given. 3.3 Hazard Overview
Briefly summarize the most important hazards and effects of this chemical, mainly including: hazard category, invasion route, health hazard, environmental hazard, explosion hazard and other information. 3.4 First Aid Measures
Refers to the brief treatment methods for on-site self-rescue or mutual rescue that need to be taken when the operator is accidentally injured, including: first aid measures for eye contact, skin contact, inhalation, and ingestion. 3.5 Firefighting measures
Mainly refers to the physical and chemical special hazards of chemicals, suitable fire extinguishing media, unsuitable fire extinguishing media and individual firefighters' protection, including:
GB 16483-2000
hazardous characteristics, fire extinguishing media and methods, fire extinguishing precautions, etc. 3.6 Leakage emergency treatment
Refers to the simple and effective emergency measures, precautions and elimination methods that can be adopted on site after chemical leakage, including: emergency actions, emergency personnel protection, environmental protection measures, elimination methods, etc. 3.7 Operation and storage
Mainly refers to the information and materials on chemical operation and safe storage, including: safety precautions, safe storage conditions and precautions in operation and disposal operations. 3.8 Contact Control/Personal Protection
Protection methods and means taken to protect workers from chemical hazards during the production, operation, handling and use of chemicals. Including:
Maximum allowable concentration, engineering control, respiratory system protection, eye protection, body protection, hand protection, and other protection requirements. 3.9 Physical and chemical properties
Mainly describe the appearance and physical and chemical properties of chemicals, including: appearance and properties, pH value, boiling point, melting point, relative density (water = 1), relative vapor density (air - 1), saturated vapor pressure, heat of combustion, critical temperature, critical pressure, octanol/water partition coefficient, flash point, ignition temperature, explosion limit, solubility, main uses and other special physical and chemical properties.
3.10 Stability and reactivity
Mainly describe the stability and reactivity of chemicals, including: stability, prohibited incompatible materials, conditions to avoid contact, polymerization hazards, decomposition products.
3.11 Toxicological information
Provide toxicological information of chemicals, including: acute toxicity (LDso, LC5o) of different contact modes, irritation, sensitization, subacute and chronic toxicity, mutagenicity, teratogenicity, carcinogenicity, etc.
3.12 Ecological information
Mainly describes the environmental ecological effects, behaviors and fate of chemicals, including: biological effects (such as LD5o, LC5o), biodegradability, bioaccumulation, environmental migration and other harmful environmental impacts. 3.13 Waste disposal
Refers to the safe treatment methods for packaging contaminated by chemicals and chemicals with no use value, including waste disposal methods and precautions. 3.14 Transportation information
Mainly refers to the requirements for domestic and international chemical packaging and transportation and the classification and numbering of transportation regulations, including: dangerous goods number, packaging category, packaging mark, packaging method, UN number and transportation precautions. 3.15 Regulatory information
Mainly refers to the legal provisions and standards for chemical management. 3.16 Other information
Mainly provides other information that is important to safety, including: references, filling time, filling department, data review unit, etc. 4 Requirements for preparation and use
4.1 Requirements for preparation
The sixteen major items specified in the safety technical manual cannot be deleted or merged at will during preparation, and their order cannot be changed at will. The requirements, boundaries and levels for filling in each item shall be carried out in accordance with the "Filling Guide". Among them, the sixteen major items are required, and each small item can have three options. Those marked with 49
GB16483—2000
[A] items are required; those marked with [B] items, if there is no data for this item, the reason for no data (such as no information, meaningless) should be stated; those marked with [C] items, if there is no data, this item can be omitted.
The main text of the safety technical manual should be expressed in concise, clear and easy-to-understand standardized Chinese characters. Digital data should be accurate, reliable, systematic and comprehensive.
The content of the safety technical manual shall be updated every five years from the date of production of the chemical. If new hazards are discovered, the manufacturer must revise the content of the safety technical manual within six months after the relevant information is released. 4.2 Types
The safety technical manual is written in the form of "one card for one variety". The technical manuals of the same type and homologues cannot replace each other; the mixture must fill in the harmful components and their content range. The data filled in should be reliable and well-founded. When a chemical has more than one hazard, its primary and secondary hazards as well as first aid and protective measures shall be comprehensively stated. 4.3 Use
The safety technical manual is compiled and printed by the production and supply company of the chemical and provided to the user when the goods are delivered. It circulates with the goods in the market as a service to the user.
When receiving and using chemicals, users of chemicals should carefully read the technical manual, understand and master the hazards of the chemicals, formulate safe operating procedures according to the circumstances of use, and select appropriate Protective equipment, training for operators. 4.4 Reliability of data
The values and data in the safety data sheet should be accurate and reliable, the selected reference materials should be authoritative, and if necessary, consult with specialized occupational safety and health institutions at or above the provincial level.
A1 Chemicals and corporate identification
GB16483—2000
Appendix A
(Appendix to the standard)
Guide to filling out the safety data sheet for chemicalsA1.1 For the Chinese name of the chemical, fill in the scientific name, common name or product name [A]. A1.2 For the English name of the chemical, fill in the scientific name, common name or product name [A]. A1.3 For the name of the manufacturer, fill in the full Chinese and English name of the chemical manufacturer [A]. A1.4 For the address, fill in the detailed address of the chemical manufacturer LA]. A1.5 Postal code: Fill in the postal code of the chemical manufacturer [A]. A1.6 Fax number: Fill in the fax number of the chemical manufacturer [A]. A1.7 Enterprise emergency telephone: Fill in the emergency telephone number of the chemical manufacturer to be dialed in an emergency [A]. A1.8 Email address: Fill in the email address of the chemical manufacturer [C]. A1.9 Technical specification code: Fill in the product safety data sheet code [A]. A1.10 Effective date: Fill in the date on which the safety data sheet was compiled or revised EA]. A1.11 National emergency telephone: Fill in the national chemical accident emergency telephone number and fire emergency telephone number to be dialed in an emergency [A]. A2 Ingredients/Composition Information
A2.1 Main ingredients [B]||tt ||a) For mixtures, fill in the main hazardous components and their concentration or concentration range. b) For pure products, fill in the name and concentration range of the hazardous components. A2.2 CAS number: Fill in the Chemical Abstracts Index registration number of the hazardous components in the chemical product [B]. A3 Hazard Overview
A3.1 Hazard category: Fill in according to GB13690 [B]. A3.2 Invasion pathways: Fill in the pathways by which chemical substances enter the body and cause harm, such as inhalation, ingestion, and skin contact [B]. A3.3 Health hazards: Fill in the typical clinical manifestations of poisoning, including the main target organs, symptoms and manifestations of acute poisoning, chronic poisoning, and carcinogenicity [B].
A3.4 Environmental hazards: Briefly describe the hazards caused by chemicals to various organisms at a certain concentration and the extent of the hazards [B]. A3.5 Explosion hazards: Briefly describe the hazards that chemicals can cause when they are exposed to open flames, high temperatures, or come into contact with oxidants in the air [B]. A4 First aid measures
Refers to the brief treatment methods for self-rescue and mutual rescue that on-site workers need to take when they are accidentally harmed by chemicals. A4.1 Skin contact [B]
a) For highly toxic substances, remove clothing immediately and rinse with the recommended cleaning medium. Seek medical attention. b) For moderately toxic substances, remove clothing immediately and rinse with the recommended cleaning medium. Seek medical attention. c) For hazardous substances, remove contaminated clothing and rinse the skin with the recommended medium. d) For corrosive substances, rinse with the recommended medium. If burns occur, seek medical attention. A4.2 Eye contact [B]
a) For highly toxic substances, lift the eyelids immediately and rinse with plenty of water for at least 15 minutes. Seek medical attention. b) For moderately toxic substances, lift the eyelids immediately and rinse with plenty of water for at least 15 minutes. Seek medical attention. 51
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c) For hazardous substances, lift the eyelids immediately and rinse with plenty of clean water. d) For corrosive substances, lift the eyelids immediately and rinse with running clean water or saline, and seek medical attention. A4.3 Inhalation [B]
a) For highly toxic, moderately toxic, or hazardous substances, evacuate the scene immediately to a place with fresh air; if breathing stops, perform artificial respiration; if breathing is difficult, give oxygen (if appropriate antidotes are available, take them immediately). b) For corrosive substances, leave the scene immediately to a place with fresh air and perform artificial respiration if necessary. Seek medical attention. A4.4 Ingestion [B]
a) For highly toxic substances, seek medical attention immediately.
b) For moderately toxic substances, seek medical attention immediately.
c) For hazardous substances, seek medical attention immediately.
d) For corrosive substances, seek medical attention immediately.
A5 Firefighting measures
A5.1 Hazard characteristics: mainly fill in the possible hazards caused by open flames, high temperatures, oxidants, etc., the reactivity with water, acids, alkalis, and some active substances, as well as oxidizing and corrosive properties, etc. [B]. A5.2 Hazardous combustion products: fill in the products after combustion, such as harmful gases [B]A5.3 Fire extinguishing methods: fill in the fire extinguishing methods and extinguishing agents. For different types of chemicals, appropriate extinguishing media should be selected according to their properties and states [B].
A5.4 Fire-fighting precautions and measures [B]
a) Personal protection for firefighters: Fill in the protective clothing that should be used, such as full-body fire protection clothing, fire-proof and anti-gas clothing, fire protection boots, positive pressure self-contained breathing apparatus, etc.
b) Prohibited fire extinguishing agents: Fill in the fire extinguishing agents that should be prohibited from use, such as water, carbon dioxide, dry powder, foam, sand, etc. A6 Leakage emergency treatment
A6.1 Emergency treatment can be filled in with reference to the following levels [B]: a) Quickly call the police, evacuate relevant personnel, and isolate the contaminated area. The number of evacuees and the size of the isolated contaminated area are determined according to the amount of leakage and the toxicity of the leaked material.
b) Cut off the fire source. For flammable and explosive leaks, the fire source must be cut off before cleaning. c) Emergency treatment personnel protection. Leakage is an emergency, and the protection requirements are relatively strict. d) Precautions. Some substances cannot be directly contacted, some substances can be sprayed with water mist to reduce volatility, some cannot be sprayed with water, and some substances need to be cooled and shockproof. This must be selected according to the specific substances and the leakage site. e) Elimination method. According to the physical state of the chemical (gas, liquid, solid) and its hazard (combustion and explosion characteristics, toxicity) and environmental protection requirements, give a specific elimination method.
f) Equipment and materials. Give the names of the equipment and materials required for emergency treatment. A7 Operation, disposal and storage
A7.1 Operation precautions refer to the safety precautions and personal protection during the operation of chemicals [B7. A7.2 Storage precautions are filled in with reference to the following levels. Basic conditions and requirements for storage → Storage limit → Precautions → Prohibited materials → Fire and explosion prevention requirements → Precautions for repackaging [B]. A8 Contact control/personal protection
A8.1 The maximum allowable concentration is filled in based on the national health standards. If there is no national standard, refer to the relevant foreign standards and express it in mg/m2 [B].
GB16483--2000
A8.2 Monitoring method Fill in the monitoring method of harmful substances in workshop air [B]. A8.3 Engineering control mainly fills in the protection and isolation measures such as sealing and ventilation in the production process, not specifically referring to the automation control of industrial production processes [B].
A8.4 Respiratory system protection Protective equipment to prevent harmful substances from entering the body from the respiratory system mainly considers the following three factors, namely the working environment, the degree of harm of toxic substances entering the body from the respiratory system and the protective ability of protective equipment. It is recommended to use air respirators, self-contained respirators, oxygen respirators, filter-type gas masks (half- and full-face masks), dust masks, etc. [B]. A8.5 Eye protection: Equipment to protect the eyes from poisons. Safety masks, safety glasses, chemical safety glasses, safety goggles, and safety masks are recommended [B]. A8.6 Body protection: Protection to prevent skin damage. According to the toxicity of the poison and the concentration of contact, choose: mask-type adhesive tape anti-toxic clothing, one-piece adhesive tape anti-toxic clothing, rubber work clothes, anti-poison penetration work clothes, breathable anti-poison clothing, general work anti-poison clothing [B]. A8.7 Hand protection: Mainly protective gloves, rubber gloves, latex gloves, acid and alkali resistant gloves, chemical resistant gloves, skin protection film, etc. EBJ.
A8.8 Other protection: mainly fill in the personal hygiene requirements of the operators, on-site precautions, monitoring of poisons, and medical examinations during the trial [EC].
A9 Physical and chemical properties
A9.1 The appearance and properties of the product mainly refer to the color, smell and existence state of the substance at room temperature and pressure [A]. A9.2 pH value Fill in the pH value LB".
A9.3 Melting point Fill in the value at room temperature and pressure. The value under special conditions should be marked with the technical conditions [B]. A9.4 Boiling point Fill in the boiling point value at room temperature and pressure. The value obtained under special conditions should be marked with the technical conditions. The sublimation value or decomposition value before boiling should be explained and the technical conditions should be marked [B]. A9.5 Relative density (water = 1) Fill in the ratio of the density of the substance at 20°C to the density of water at 4°C [B]. A9.6 Relative vapor density (air = 1) Fill in the ratio of the vapor density of the substance at 0°C to the density of air [B]. A9.7 Saturated vapor pressure At a certain temperature, the pressure when the pure liquid and vapor reach equilibrium in a vacuum container is expressed in kPa, and the temperature is indicated [C".
A9.8 Heat of combustion The heat generated when 1 mole of a substance is completely burned, expressed in kJ/mol [C]. A9.9 Critical temperature The highest temperature allowed when a gas is liquefied under pressure, expressed in C [C]. A9.10 Critical pressure The minimum pressure required to liquefy a gas at the critical temperature, expressed in MPa [C]. A9.11 The octanol/water partition coefficient is an important parameter used to predict the adsorption, bioabsorption, octanol storage and bioaccumulation of a chemical in soil. When a chemical is dissolved in an octanol/water mixture, the ratio of the concentration of the chemical in octanol and water is called the partition coefficient, usually expressed in logarithmic form with a base of 10 (logpow) [B]. A9.12 Flash point The lowest temperature at which a sample can flash when its vapor and air mixture are heated to a flame under specified conditions. When filling in the value, indicate the open cup or closed cup value [B]. A9.13 Ignition temperature (auto-ignition temperature) refers to the lowest temperature of the reaction container wall when a mixture of combustible gas and air in a container begins to ignite at room temperature and pressure [B]. A9.14 Upper explosion limit The upper limit of the combustible mixture formed by the mixture of combustible gas and air. The unit for gas and liquid is expressed in % (V/V), and the unit for dust is expressed in mg/m2. A9.15 Lower explosion limit The lower limit of the combustible mixture formed by the mixture of combustible gas and air. The unit is the same as the upper explosion limit [B]. A9.16 Solubility The solubility of a substance in a solvent at room temperature and pressure is expressed by miscible, easily soluble, soluble in, slightly soluble, and insoluble [BI.
A9.17 Main use Fill in its main use [C]. A9.18 Other physical and chemical properties Non-fixed data items are set for the properties unique to certain substances, such as: particle size, volatile organic matter content, evaporation rate, viscosity, radioactivity, freezing point, corrosiveness, deflagration point, detonation velocity, minimum ignition energy, etc. [C]. 53
A10 Stability and reactivity
GB16483—2000
A10.1 Stability Whether the chemical behavior of the substance is stable under normal temperature and pressure or expected storage conditions, expressed as stable or unstable [LB].
A10.2 Prohibited incompatibilities Clearly mark the substances that conflict with the chemical properties of the chemical [B]. A10.3 Conditions to avoid Indicate the external conditions that may cause harmful effects on the chemical, such as heat, light, contact with air and moisture, vibration, extrusion, etc. [B].
A10.4 Polymerization hazard Indicates whether the substance can undergo unexpected polymerization reactions under external conditions, expressed as can occur or cannot occur [B].
A10.5 Decomposition products Qualitative description of the final harmful substances that may be produced when the substance burns or undergoes chemical reactions [B]. A11 Toxicological information
A11.1 Acute toxicity Use LDso and LCso to indicate acute toxicity [B]. A11.2 Subacute and chronic toxicity Mainly fill in the toxic effects and histopathological examination results of animals after subacute and chronic exposure [C].
A11.3 Irritation Fill in the results of irritation experiments on animal eyes and skin. Use mild, moderate and severe to indicate the intensity of irritation [B].
A11.4 Sensitization Fill in the experimental results after animal exposure [C]. A11.5 Mutagenicity Fill in the test results of rats, mice, humans and others, mainly based on the Salmonella reversion test (Ames test). Use the lowest dose [C].
A11.6 Teratogenicity Fill in the experimental results of whether the chemical is teratogenic. Use the lowest dose [C]. A11.7 Carcinogenicity: Fill in the assessment conclusion of the expert group of the International Agency for Research on Cancer (IARC). It can be expressed as the lowest dose [C]. A11.8 Others: Fill in other relevant data, such as reproductive toxicity, neurotoxicity, etc. [C]. A12 Ecological data
A12.1 Ecotoxicity: Indicates the toxicity of the chemical to aquatic organisms (algae, invertebrates, fish), terrestrial organisms (plants, locusts, birds), and beneficial microorganisms. It can be expressed as median lethal dose (LDs.), median lethal concentration (LCso), no-effect dose (NOEL), and median tolerance dose (TLm) [B].
A12.2 Biodegradability: Indicates whether the chemical is biodegradable. Experimental data is used to illustrate its biodegradability. LB is expressed as the percentage of biodegradation within a period of time.
A12.3 Non-biodegradability: Indicates whether the chemical is non-biodegradable, such as photolysis and hydrolysis [B]. A12.4 Bioaccumulation: Indicates whether the chemical has the characteristics of bioaccumulation. It can be divided into bioaccumulation in aquatic and terrestrial environments. After the chemical is ingested by the organism and remains for a period of time, when the four interrelated processes of ingestion, distribution, transformation and excretion form a dynamic balance, the concentration of the chemical in the organism and the environmental medium is equal to the equilibrium value. For example, fill in the bioconcentration factor (BCF) value of fish [C].
A12.5 Other harmful effects refer to the potential impact on the destruction of the ozone layer and global warming [C]. A13 Waste disposal
A13.1 Waste nature Indicate whether the waste is hazardous waste. The judgment standard is the national hazardous waste list [B]. A13.2 Waste disposal method Only fill in the final treatment method for harmless treatment of hazardous chemicals that cannot be reused, such as: incinerator burning, chemical oxidation, dissolution, deep burial, etc. [B]. A13.3 Waste precautions When disposing of chemicals and their outer packaging, the conditions required to protect operators and the environment [B].
A14 Transportation information
GB16483—2000
A14.1 Dangerous goods number Fill in its hazard category and classification number according to GB6944 [B]. A14.2 UN number The number specified in the United Nations "Recommendations on the Transport of Dangerous Goods" [B]. A14.3 Packaging mark Fill in the degree of hazard of dangerous goods and clearly mark the (primary and secondary) hazard [B]. A14.4 Packaging category Determine the packaging category according to the classification principle of GB/T15098 [B]. A14.5 Packaging method Fill in according to the "Dangerous Goods Transport Management Rules" (issued by the Ministry of Railways) and the United Nations "Recommendations on the Transport of Dangerous Goods" [B].
A14.6 Transportation Precautions
Fill in the transportation conditions, precautions, packaging methods and materials, signs, etc. that should be paid attention to when transporting chemicals. At the same time, attention should be paid to the prevention of possible accidents (shipping, shipping, rail transportation, road transportation, etc.) [B]. A15 Regulatory Information
A15.1 Domestic chemical safety management regulations mainly provide domestic regulatory information on chemicals for chemical management, use and operators. For example, "Regulations on the Safety Management of Chemical Hazardous Materials" [A]. A15.2 International regulations mainly provide international regulatory information on chemical management and operation [C]. A16 Other Information
A16.1 References [C].
A16.2 Filling time Fill in the time of this CSDS [A]. A16.3 Filling department Fill in the department of this CSDS [EA]. A16.4 Data review unit: fill in the unit that reviews this CSDS [A]. A16.5 Modification instructions: fill in the brief instructions that need to be made when modifying this CSDS [A] A16.6 Other information: other information or instructions that need to be supplemented [C]. Appendix B
(Suggested Appendix)
General format of chemical safety data sheet Chemical safety data sheet
Part I
Chinese name of chemical:
Common name or trade name of chemical:
English name of chemical:
Company name:
Address:
Postal code:
Email address:
Fax number: (country or region code) (area code)
Company emergency telephone number: (country or region code) Technical specification code:
Chemical and company identification
(Telephone number)
(Area code)
(Telephone number)
Effective date:
National emergency telephone number:
Chemical name:
Harmful ingredients
Hazard category:Www.bzxZ.net
Invasion route:
Health hazard:
Environmental hazard:
Explosion hazard:
Skin contact:
Eye contact:
Hazardous characteristics:
Harmful combustion products:
Fire extinguishing method and fire extinguishing agent:
Fire extinguishing precautions
Emergency treatment:
Elimination method:
Operation precautions:
Storage precautions:
GB 16483--2000
Section 2
Mixture
Section 3
Composition/Information on Ingredients
Hazards Identification
Section 4
Section 5
Section 6
First Aid Measures
Fire Fighting Measures
Emergency Measures for Release
Section 7 Handling and Storage
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