Some standard content:
Petroleum and Natural Gas Industry Standard of the People's Republic of China SY/T5679-93
Lignite resin for drilling fluid
Published on September 9, 1993
Published by China National Petroleum Corporation
Implementation on March 1, 1994
Subject content and scope of application
Petroleum and Natural Gas Industry Standard of the People's Republic of China Lignite resin for drilling fluid
This standard specifies the quality indicators, test methods and packaging marks of lignite resin for drilling fluid. This standard applies to lignite resin for drilling fluid, which is a filtrate reducer, and its code is SPNH. 2 Reference standards
ZB/TE13004--90 "Drilling fluid test procedures" 3 Technical requirements
Lignite resin for drilling fluid should meet the performance indicators in the following table. SPNH performance indicators
Moisture content. %www.bzxz.net
Water insoluble matter, %
Medium pressure filtration loss at room temperature, ml
High temperature dripping pressure filtration loss, m1
Apparent viscosity, mPa-s
Test method
4.1 Reagents and materials
a, Sodium chloride: chemically pure,
b, Sodium hydroxide: chemically pure,
c, Distilled water,
Fresh water slurry
Sodium chloride contaminated slurry
Light Tai slurry
Sodium chloride contaminated slurry
Fresh water slurry
Sodium chloride contaminated slurry
d, Bentonite: Sodium bentonite for drilling fluid test in accordance with SY5490-92#e: Filter paper: Whatman 5o filter paper or similar products, approved by China National Petroleum and Natural Gas Corporation on September 9, 1993 SY/T 5679--93
Black brown powder wood
1994-03-01 implementation
f. Lens paper: 10x15cms
9. Absorbent cotton.
4.2 Instruments and instruments
SY/T 5679--93
a, direct reading viscometer, Fann-35 type or similar products! b, room pressure filter loss instrument: volume is 300-400mI, filtration area is 45.8±0.6cm\, center. High temperature and high pressure filter loss instrument
d. Extractor: as shown in the figure
e, acidity meter: graduation value 0.1pH unit, f, balance: sensitivity 0.0001g*
9, weighing bottle, Φ50×30,
h, oven: control sensitivity ±2Gs
i. Magnetic stirrer
1. High-speed stirrer, load speed of 11000±300r/min, stirring shaft equipped with a single corrugated blade, blade diameter of 2.5cm, mass of 5.5g, with a taste cup, its height is 19cm, upper diameter is 9.7cm, lower diameter is 70cm, made of stainless steel or corrosion-resistant material
k, roller heating furnace: 701-40 model or similar products. p130
Schematic diagram of the ejector
4. 3 Test procedure
4.3.1 Appearance
Observe with naked eyes under natural light.
4.3.2 Moisture
4.3.2.1 Use a weighing bottle that has been dried at 105±3℃ to weigh 1~~2g of the sample (accurate to 0.0001g), place the weighing bottle with the sample in an oven at 105±3℃, dry for 2h, take out the weighing bottle, place it in a desiccator, cool it to room temperature (not less than 50min), and weigh it.
4.3.2.2 Calculation
X=mm=×100%.
Where: X is water content;
$Y/T 5679—93
m1——mass of weighing bottle and sample, gtma mass of weighing bottle and sample after dehumidification, g1m. mass of weighing bottle, g.
4.3.3 Water-insoluble matter
4.3.3.1 Take 0.2-0.3g of absorbent cotton and put it into a roll made of lens paper, put it into a weighing bottle and dry it at 105±3°C until constant weight for later use.
4.3.3.2 Take 0.5±0.1 of the sample, put it into the above paper roll, wrap it tightly, and weigh it together with the weighing bottle (weighing to 0.0001g), then put the paper roll into the sample cup of the extractor, and hang the sample cup under the micro condenser of the extractor. 4.3.3.3 Pour 250~300ml of distilled water into the extractor, put the extractor into the electric heating jacket to heat and keep it boiling, and extract until the effluent in the sample cup is colorless (about 3h). Take out the paper and put it into the weighing bottle, put it in an oven at 105±3°C for 2h, then take out the weighing bottle and put it in a desiccator, cool it to room temperature (not less than 30min), and weigh it. 4.3,3.4 Calculation
S=m*=×100%.
S-water insoluble matter
m-mass of the absorbent cotton, lens paper, weighing bottle and sample after drying, gms-mass of the absorbent cotton, lens paper and weighing bottle, gsm4
4,3.4 pH value
-mass of the absorbent cotton, lens paper, weighing bottle and sample, g. (2)
Weigh 0.3g of sample and place it in a 50ml beaker, add 30ml of distilled water, and stir with a magnetic stirrer at room temperature for 1h to dissolve. Measure the pH value of the solution with a pH meter.
4,3.5 Drilling fluid performance test method
4.3.5.1 Preparation of wood pulp
In a sample cup containing 350ml of distilled water, add 225g of sodium swellable solid for drilling fluid test, stir at high speed for 20min, interrupt at least twice to scrape off the sample adhering to the cup wall, and seal and cure at room temperature for 24h as base slurry. 4.3.5.2 Fresh water drilling fluid performance test
a, add 10.5g of SPNH to the base slurry, stir at high speed for 20min, interrupt twice to scrape off the sample adhering to the cup wall. b, transfer the above slurry into a high temperature furnace and heat it at 180°C for 16h. C. Take out the high temperature tank, cool and open it, and measure the apparent viscosity at 24±3°C, the room temperature medium pressure (24±3\C/690kPa) filtration loss and the high temperature and high pressure (150°C/3450kPa) filtration loss according to the method of ZB/TE13004-90. 4.3.5.3150g/1 Sodium chloride contaminated drilling fluid performance test a. Add 17.5g SPNH to the base slurry and stir at high speed for 20min. During the process, it should be interrupted twice to remove the product adhering to the wall of the cup. Then add 52.5g sodium chloride and stir at high speed for 10min. Add 2ml of 20% sodium oxide solution to adjust the pH. b. Follow the steps b and c in 4,3.5,2. The numerical rounding in 4,3,6 shall be carried out according to GB8176 "Numerical Rounding Rules". 4,3,7 Test report
The test report format is shown in Appendix A (Supplement). 5 Inspection rules
5.1 The product shall be inspected by the quality inspection department of the manufacturer. The manufacturer shall ensure that all products leaving the factory meet the requirements of this standard. 5.2 The manufacturer shall divide the daily output into batches, and the delivery batches shall be divided into batches, with the maximum batch not exceeding 40t. 5.3 Sampling method
SY/T5679-93
5.3.1 The sampling points of bagged SPNH shall be determined on the side in a cross shape according to the stacking height, shape and quantity. Each batch shall not be less than 15 points.
5.3.2 Use a metal sampler to take samples at different depths of the package. The total sampling shall not be less than 500g. The sample shall be mixed and evenly divided into two parts by quartering method, and respectively put into clean, dry ground-mouth bottles, and indicate the product name or code, batch number, production period, sampling date, sampler, manufacturer name, etc. One bottle shall be sent for inspection, and one bottle shall be kept for reference. 5.4 If the inspection fails to meet the standard requirements, samples should be taken from the packaging of the two batches for re-inspection. If the re-inspection still fails, the batch of products is unqualified.
5.5 The user unit has the right to inspect the products according to the standards, and the sampling and acceptance work should be completed within the period specified in the contract. 6 When the supply and demand parties have objections to the product quality, the two parties shall negotiate. 6 Packaging, marking and quality inspection form
6.1 Packaging
The packaging bag of SPNH should have sufficient strength and should have at least two layers. The outer layer is a three-in-one paper-plastic composite packaging with a plastic lining. The net weight of each bag is 25kg, and the allowable error is ±2%. For each batch of products, 40 bags are inspected, and the average value should be no less than 25kg. 6.2 Marking
The following content should be printed on the outside of the packaging bag: registered trademark, product name, code, net weight, quality level, batch number, date of manufacture, and manufacturer.
6.3 Quality Inspection Sheet
Each batch of products shall be accompanied by a quality inspection sheet for the product, the format of which is shown in Appendix B (Supplement). Entrusting unit:
Sample number:
Manufacturer name,
Sampling date:
Water content, %
Water insoluble matter, %
Room temperature medium pressure filtration loss, m1
High temperature high pressure filtration loss, m1
Apparent viscosity, mPa·s
Tester:
Auditor,
SY/T5679—93
Appendix A
Test report of SPNH filtrate reducer for drilling fluid (Supplement)
Report number:
Sample date.
Test period:
Sampling person.
Fresh water slurry
Sodium amide contaminated slurry
Fresh water slurry
Sodium chloride contaminated slurry
Fresh water slurry
Sodium chloride contaminated slurry
Stamp of the unit
Dark brown powder
9,010,2
Sent to the unit
Quantity,
Factory batch number:
Product performance:
Permanent fraction,
Ice insoluble matter, %
Bag (t)
Mid-temperature and medium-pressure filtration loss, world 1
High-temperature and high-pressure filtration loss, also 1
Apparent viscosity, mPa·s
Additional instructions:
SY/T 5679—93
Appendix B
Product quality inspection form for SPNH fluid loss reducer for drilling fluid (supplement)
Contract No.:
Mode of transportation:
Product name:
Fresh water slurry
Sodium chloride contaminated slurry
Fresh water slurry
Sodium chloride contaminated slurry
Fresh water slurry
Sodium chloride contaminated slurry
Inspector,
This standard is proposed and technically managed by the Petroleum Drilling Engineering Professional Standardization Committee. This standard is jointly drafted by the Drilling Technology Research Institute of the Petroleum Exploration and Development Research Institute of China National Petroleum Corporation and Chongqing Synthetic Chemical Plant.
The main drafters of this standard are Shi Yongli, He Shengfang and Rong Xiuying. 8
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