GB 30000.3-2013 Chemical Classification and Labelling Specification Part 3: Flammable Gases GB30000.3-2013 Standard compression package decompression password: www.bzxz.net
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of flammable gases. This part applies to the classification and labeling of flammable gases in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals.
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended.
The expected structure of GB30000 "Specifications for Classification and Labelling of Chemicals" and the national standards to be replaced are:
———Part 1: General (replaces GB13690-2009);
———Part 2: Explosives (replaces GB20576-2006);
———Part 3: Flammable gases (replaces GB20577-2006);
———Part 4: Aerosols (replaces GB20578-2006);
———Part 5: Oxidizing gases (replaces GB20579-2006);
———Part 6: Gases under pressure (replaces GB20580-2006);
———Part 7: Flammable liquids (replaces GB20581-2006);
———Part 8: Flammable solids (replaces GB 20582-2006);
———Part 9: Self-reactive substances and mixtures (replaces GB 20583-2006);
———Part 10: Pyrophoric liquids (replaces GB 20585-2006);
———Part 11: Pyrophoric solids (replaces GB 20586-2006);
———Part 12: Self-heating substances and mixtures (replaces GB 20584-2006);
———Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB 20587-2006);
———Part 14: Oxidizing liquids (replaces GB 20589-2006);
——Part 15: Oxidizing solids (replaces GB 20590-2006);
——Part 16: Organic peroxides (replaces GB 20591-2006);
——Part 17: Corrosive to metals (replaces GB 20588-2006);
——Part 18: Acute toxicity (replaces GB 20592-2006);
——Part 19: Skin corrosion/irritation (replaces GB 20593-2006);
——Part 20: Serious eye damage/eye irritation (replaces GB 20594-2006);
——Part 21: Respiratory or skin sensitization (replaces GB 20595-2006);
———Part 22: Germ cell mutagenicity (replaces GB 20596-2006);
———Part 23: Carcinogenicity (replaces GB 20597-2006);
———Part 24: Reproductive toxicity (replaces GB 20598-2006);
———Part 25: Specific target organ toxicity single exposure (replaces GB 20599-2006);
———Part 26: Specific target organ toxicity repeated exposure (replaces GB 20601-2006);
———Part 27: Aspiration hazard;
———Part 28: Hazard to the aquatic environment (replaces GB 20602-2006);
———Part 29: Hazard to the ozone layer;
———Part 30: Warning signs for chemical workplaces.
This part is part 3 of GB 30000.
This part was drafted in accordance with the rules given in GB/T 1.1-2009.
This part replaces GB 20577-2006 "Safety Specification for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Flammable Gases".
This part is consistent with the relevant technical content of the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition).
Compared with GB 20577-2006, the main technical content changes of this part are as follows:
———The name of the standard has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals—Part 3: Flammable gases" and the English name is "Rules for classification and labelling of chemicals—Part 3: Flammable gases";
———The scope of Chapter 1 has been modified, "Warning labels" has been changed to "labels", and "Warning instructions" has been deleted; ||tt
|| ———The introductory words of Chapter 2 "Normative references" have been modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" has been added as a reference document;
———The introductory words of Chapter 3 "Terms and Definitions" have been added;
———Figure 1 "Decision logic diagram" and "Guidance" in Chapter 5 have been made informative Appendix A;
———Deleted the original Chapter 7, and revised Table 3 of the original Chapter 7 as normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition);
———In accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition), revised and integrated the original Chapters 6, 7 and 8 into Chapter 6; revised Table 2 as normative Appendix C;
———Deleted the original Chapter 8, and added the relevant "Hazard Statements" and "Precautionary Statements" as informative Appendix D; ———
Added informative Appendix E "Label Examples".
This part was proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251).
Drafting units of this part: China Chemical Economic and Technological Development Center, Shanghai Research Institute of Chemical Industry, China Chemical Information Center, Zhejiang Research Institute of Chemical Industry Co., Ltd., Huafeng Group Co., Ltd.
The main drafters of this part are Zhang Junxi, Feng Zhuo, Ge Xiaojun, Fang Lu, Dong Xuesheng, Cao Mengran, Wen Tao, Zhang Qibin, Cheng Lihong, Yang Ting and Li Tie.
The previous versions of the standards replaced by this part are:
———GB 20577—2006.
The following documents are indispensable for the application of this document. For any dated referenced document, only the dated version applies to this document. For any undated referenced document, the latest version (including all amendments) applies to this document.
GB6944—2012 Classification and product name numbering of dangerous goods
GB13690 General rules for classification and hazard communication of chemicals
GB30000.4 Specification for classification and labeling of chemicals Part 4: Aerosols
GB/T27862 Test methods for hazard classification of chemicals Combustion potential and oxidizing power of gases and gas mixtures
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (Fourth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria (Fifth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition)

ICS13.300
National Standard of the People's Republic of China
GB30000.3—2013
Replaces GB20577—2006
Rules for classification and labelling of chemicals-Part 3:Flammable gases
Promulgated on October 10, 2013
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China Administration of Standardization of the People's Republic of China
Implementation on November 1, 2014
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. GB30000 "Chemical Classification and Labelling Specification" is expected to have the following structure and national standards: Part 1: General (replaces GB13690-2009); Part 2: Explosives (replaces GB20576-2006); Part 3: Flammable gases (replaces GB20577-2006); Part 4: Aerosols (replaces GB20578-2006); Part 5: Oxidizing gases (replaces GB20579-2006); Part 6: Gases under pressure (replaces GB20580-2006); Part 7: Flammable liquids (replaces GB20581-2006); Part 8: Flammable Flammable solids (replacing GB20582-2006): Part 9: Self-reactive substances and mixtures (replacing GB20583-2006): Part 10: Pyrophoric liquids (replacing GB20585-2006); Part 11: Pyrophoric solids (replacing GB20586-2006): Part 12: Self-heating substances and mixtures (replacing GB20584-2006): Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replacing GB20587-2006); Part 14: Oxidizing liquids (replacing GB20589-2006): Part 15: Hydrogenating solids (replacing GB20 5902006); Part 16: Organic Peroxides (Replaces GB20591-2006); Part 17: Metal Corrosives (Replaces GB20588-2006); Part 18: Acute Toxicity (Replaces GB20592-2006); Part 19: Skin Corrosion/Irritation (Replaces GB20593-2006); Part 20: Serious Eye Damage/Eye Irritation (Replaces GB20594-2006); Part 21: Respiratory or Skin Sensitization (Replaces GB20595-2006); Part 22: Germ Cell Mutagenicity (Replaces GB20596-2006); Part 23: : Carcinogenicity (replaces GB20597-2006): Part 24: Reproductive toxicity (replaces GB20598-2006): Part 25: Specific target organ toxicity single exposure (replaces GB20599-2006); Part 26: Specific target organ toxicity repeated exposure (replaces GB20601-2006); Part 27: Inhalation hazard;
Part 28: Hazards to the aquatic environment (replaces GB20602-2006): Part 29: Hazards to the ozone layer;
Part 30: Warning signs for chemical workplaces: This part is the third part of GB30000.
This part is drafted in accordance with the rules given in GB/T1.1-2009. GB30000.3-2013
This part replaces GB20577-2006 "Safety Specification for Classification, Warning Labels and Warning Statements of Chemicals - Flammable Gases". This part is consistent with the technical content of the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (Fourth Revised Edition). Compared with GB20577-2006, the main technical content changes of this part are as follows: 1
GB30000.3-2013
The standard name has been modified. The Chinese name has been changed to "Chemical Classification and Labelling Specifications Part 3: Flammable Gases" and the English name is \Rules for classification and labelling of chemicals-Part3.Flammablegases\; The scope of Chapter 1 was modified, "Warning label" was changed to "label", and "Warning statement" was deleted; the introduction of Chapter 2 "Normative references" was modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" was added as a reference document; the introduction of Chapter 3 "Terms and Definitions" was added; Figure 1 "Decision Logic Diagram" and "Guidance" in Chapter 5 were made as informative Appendix A; the original Chapter 7 was deleted, and Table 3 of the original Chapter 7 was revised according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition) After modification, it is made into normative appendix B
According to the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (fourth revised edition), the original Chapter 6, Chapter 7 and Chapter 8 are modified and integrated into Chapter 6; the original Table 2 is modified as normative appendix C; the original Chapter 8 is deleted, and the relevant "hazard statements" and "precautionary statements" are made into informative appendix D; informative appendix E "label examples" is added. This part is proposed and coordinated by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251). Drafting units of this part: China Chemical Economic and Technological Development Center, Shanghai Research Institute of Chemical Industry, China Chemical Information Center, Zhejiang Provincial Chemical Research Institute Institute Co., Ltd., Huafeng Group Co., Ltd. The main drafters of this part: Zhang Junxi, Feng Zhuo, Ge Xiaojun, Fang Lu, Dong Xuesheng, Cao Mengran, Wen Tao, Zhang Qibin, Cheng Lihong, Yang Ting, Li Tie The previous versions of the standard replaced by this part are: GB205772006.
1 Scope
Chemical Classification and Labeling Specifications
Part 3: Flammable Gases
GB30000.3—2013
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, labeling of flammable gases. This part applies to flammable gases in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (hereinafter referred to as GHS) Classification and Labelling 2 Normative References
The following documents are indispensable for the application of this document. For all dated references, only the dated versions apply to this document. For all undated references, the latest versions (including all amendments) apply to this document GB6944
GB13690
GB30000
Classification and Product Name Numbering of Risky Goods
General Rules for Classification and Hazard Communication of Chemicals
Classification and Labelling of Chemicals by the Ministry of Industry and Information Technology
GB/T 27862
Test methods for hazard classification of chemicals
United Nations Global Chemicals Statistics
US and Standards
East Signature System
Gas Bath Gel
Combustion Potential and Oxidizing Capacity of Gas and Gas Mixtures (Fourth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods
Test and Standard Methods
United Nations "Construction Specifications for the Transport of Dangerous Goods 3 Terms and Definitions
Model Children's Guide" (No.
GB13690) and the following terms and definitions apply to this document. 3.1
flammablegases
Flammable gases
Fifth revised edition
Chemical revision
Gases which have a certain flammable range when mixed with air at 20℃ and standard pressure of 101.3kPa 3.2
Chemically unstable gases chemically unstablegases A flammable gas that reacts extremely rapidly even in the absence of air and/or oxygen. 4 Classification Standards
4.1 General principles for classification and labeling of flammable gases See GB136904.2 Flammable gases are divided into two categories, see Table 1, 4.3 According to the method described in Part 3 of the United Nations "Manual of Tests and Criteria for the Transport of Dangerous Goods Recommendations" (Fifth Revised Edition) (hereinafter referred to as the Manual of Tests and Criteria), chemically unstable flammable gases are divided into two categories, see Table 2. 1
GB30000.3—2013
Table 1 Classification of "Flammable Gases"
At 20°C and standard atmospheric pressure 101.Gases at 3 kPa: male
a) Gases that are ignitable when the volume fraction in a mixture with air is 13% or less: or 6) Gases that have a flammable range of at least 12 percentage points when mixed with air, regardless of the lower flammable limit. Gases that have a flammable range when mixed with air, other than gases in Category 1, at 20°C and standard atmospheric pressure of 101.3 kPa. Note: Nitrogen and methyl compounds may be considered as exceptions when there are regulations. Aerosols should not be classified as flammable gases, see GB30000.4. Table 2 Classification of chemically unstable gases
Flammable gases that are chemically unstable at 20°C and standard atmospheric pressure of 101.3 kPa Flammable gases that are chemically unstable at temperatures exceeding 20°C and/or pressures above 101.3 kPa 5 Decision logic and guidance
Decision logic and guidance are for reference only. See Appendix A for decision logic and guidance. It is particularly recommended that the person responsible for classification study Chapter 4 before and during the use of decision logics.
6 Labels
6.1 Overview
6.1.1 For the labels of flammable gases, the hazard categories are listed in the order of the designated pictograms, signal words and hazard statements. The hazard classes or categories covered by the United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (10th revised edition) (hereinafter referred to as the "Model Regulations") should list the designated corresponding graphic signs for each category on the label. The allocation of flammable gas label elements is shown in Appendix B. 6.1.2 For the classification standards and label requirements for flammable gases, see Appendix C6.1.3 The information required on the label includes hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and supplier logos. Note: For other label elements that have not yet been standardized, such as precautionary statements, they also need to be included on the label. The competent authority may also require additional information, and the supplier may also add supplementary information.
6.2 Hazard pictograms
Hazard pictograms should use black symbols with white backgrounds, and the red frame should be wide enough to be eye-catching. The hazard pictograms, graphic symbol colors, numbers and minimum sizes specified in the Model Regulations are shown in Appendix B.6.3 Signal words
Signal words are words used on labels to indicate the relative severity of the hazard and to alert readers to potential hazards. For extremely flammable gases, the signal word "Danger" is used. For flammable gases, the signal word "Warning" is used.2
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6.4 Hazard statements
GB30000.3—2013
Hazard statements are phrases assigned to a hazard class and category that describe the hazardous nature of a dangerous product and, where appropriate, its degree of hazard. For flammable gas hazard statements, see Appendix D. 6.5
Precautionary statements
A precautionary statement is a word (and/or pictogram) describing the recommended action to minimize or prevent adverse effects resulting from exposure to, or improper storage or handling of, the hazardous product. For this purpose, there are five categories of precautionary statements: general, prevention, emergency, storage and disposal. See Annex D for precautionary statements regarding flammable gases. 6.6 Product identifiers
6.6.1 The product identifier should be used on the label and should be consistent with the product identifier used on the MSDS. If a substance or mixture is listed in the Model Regulations, the correct UN shipping name should also be used on the package. 6.6.2 The label should include the chemical name of the substance. For mixtures or alloys, when acute toxicity, skin or respiratory sensitization or specific target organ toxicity appear on the label, the label should include the chemical composition of all ingredients or alloying elements that may give rise to these hazards. The competent authority may require that the chemical names of all ingredients or alloying elements that may contribute to the hazard of the mixture or alloy be listed on the label. 6.7 Supplier identification
The name, address and telephone number of the manufacturer or supplier of the substance or mixture should be provided on the label. 6.8 Label examples
For examples of flammable gas labels, see Appendix E. 3
GB30000.3—2013
A.1 Decision logic
Appendix A
(Informative Appendix)
Decision logic and guidance
A.1.1 Gas flammability data are required to classify flammable gases. Classification should be carried out according to the decision logic in Figure A.1. Gaseous substances or gas mixtures
Is the gas flammable at 20°C and 101.3kP: standard pressure below the flammable range?
At 20℃ and 101.3kPa standard pressure, if the gas ignites when it occupies 13% or less by volume in a mixture with air, is it a)
irrespective of its lower flammability limit, and mixed with air, has a flammable range of at least b)
12 percentage points?
Figure A.1 Decision logic for flammable gases
Category 2
No graphic symbol
A.1.2 Chemical instability data are required for the classification of a gas as a chemically unstable gas. The classification shall be made according to the decision logic of Figure A.2. ifKAoNrKAca
is the flammable gas or gas mixture
a chemically unstable gas at 20℃ and/or standard atmospheric pressure 101.3kPa?
When the gas pressure is higher than 200 and/or the atmospheric pressure is higher than 101.3kPa, it is a chemically unstable gas.
A.2 Guidance
Decision logic for chemically unstable gases
A.2.1 Flammability shall be determined by tests in accordance with GB/T 27862 or similar methods approved by the competent authority GB30000.3—2013
Category A
(Chemically unstable gas)
No additional graphic symbol
No additional signal word
(Chemically unstable gas)
No additional graphic symbol
No additional signal word
Not otherwise
When the data required for the use of these methods are insufficient, 4.2.2 Chemical instability shall be determined by tests or calculations in accordance with Part 3 of the Manual of Tests and Criteria. If the calculation results according to GB/T 27862 show that the gas mixture is not flammable, the test for determining chemical instability for the classification date does not need to be carried out. A.2.3 Example of classification of flammable gas mixtures based on the calculation results of GB/T 27862. The calculation formula for the flammability (R) of flammable gas mixtures is shown in formula (A.1): A.2.4
Wherein:
Volume fraction of flammable gas. Expressed in %:
The maximum non-flammable concentration of a mixture of flammable gas in nitrogen and air; The first gas in the mixture;
The number of gases in the mixture;
..(A.1)
GB30000.3—2013
K, the equivalent coefficient of an inert gas to nitrogen. When the gas mixture contains an inert diluent gas other than nitrogen, the corresponding coefficient (K,) of the inert gas should be used to adjust the volume of the inert diluent gas to the volume of the diluent equivalent to the volume of nitrogen. A.2.5 The principle of flammability determination is shown in formula (A.2): V
A.2.6 Example: Using the following gas mixture 2% (H) + 6% (CH) + 27% (Ar) + 65% (He) to calculate
A.2.6.1 Determine the equivalent coefficient (K) of the inert gas to ammonia: K, (Ar) = 0.5
K(He) = 0.5
2 Use the K value of the inert gas to calculate the equivalent gas mixture with nitrogen as the balance gas: A.2.6.2
2% (H) + 6% (CH,) + [27% × 0.5 + 65% × 0.5] (N) = 2% (H2) + 6% (CH) + 46% (N) = 54%A.2 .6.3 Adjust the content to 100%:
×［2%（H）+6%(CH4)+46%(N4)I=3.7%（H2)+11.1%（CH4)+85.2%(N4)100
A.2.6.4 Determine the T. coefficient of the flammable gas: T.(H)=5.7%
T(CH4)=14.3%
Use the following formula to calculate the flammability of the equivalent mixed gas: R=
R1, so the mixed gas is flammable in air XV_3.7+111www.bzxz.net
2T.-5.7+14.3
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The allocation of flammable gas label elements is shown in Table B.1. Appendix B
(Normative Appendix)
Assignment of label elements
Assignment of label elements for flammable gases
Flammable gases (including chemically unstable gases)Flammable gases
Category 1
Extremely flammable gases
Category 2
No pictogram
Flammable gases
Chemically unstable gases
Category A
No pictogram
No additional signal word
No air may also||tt ||Rapid response
No requirement in the Model Regulations
Category B
No pictogram
No additional signal word
Rapid response is also possible in the absence of air at elevated atmospheric pressure
and/or temperature
GB30000.3—2013
In the Model Regulations:
Color of graphic symbols
Graphic symbols, numbers and borders
may be black and not necessarily
white.
·The background color remains
red in both cases.
The number 2 in the figure is Category 2 in GB6944-
2012.
The minimum
size of the cargo transport graphic sign is 100mm×100mm
GB30000.3—2013
Appendix C
(Normative Appendix)
Classification standards and label elements for flammable gases
Classification standards and label elements for flammable gases are shown in Table C.1. Table C.1 Classification standards and label elements for flammable gases Hazard category
Gases and gas mixtures at 20°C and standard atmospheric pressure of 101.3kPa
Ignites when they account for 13% or less in air: or what is the lower flammable limit, when mixed with air, the flammable range is at least 12 percentage points.
Gases or gas mixtures which are fusible but not Category 1 when mixed with air at 20°C and standard atmospheric pressure IC1k. Graphical symbol
Hazard statement
Hazard statement
(Chemically unstable gas)
(Chemically unstable gas)
Flammable gas which is chemically unstable at 20°C and standard atmospheric pressure IC1k
Flammable gas which is chemically unstable at above 20°C and/or above standard atmospheric pressure 101.3kP
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Graphic symbol
Hazard statement
Graphic symbol
Signal word
Hazard statement
Label elements
Extremely flammable gas
No graphic symbol
Flammable gas
Additional graphic symbol
No additional signal word
Also may react
Quickly
No additional graphic symbol
No additional signal word
Also may react rapidly in the absence of air
at elevated atmospheric pressure
and/or temperature
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