QB/T 4539-2013 Alcohol-soluble and alcohol-water-soluble ink resin acrylates (including copolymerization modification) QB/T4539-2013 |tt||Standard compression package decompression password: www.bzxz.net
This standard specifies the product requirements, test methods, inspection rules, marking, packaging, transportation and storage of alcohol-soluble and alcohol-water-soluble ink resin acrylates (including copolymerization modification). This standard is applicable to acrylate (including copolymerization modification) ink resin solutions with alcohols, alcohol esters or alcohol-water mixtures as solvents.

ICS87.080
Classification number: A17
Registration number: 42346-2013
Light Industry Standard of the People's Republic of China
QB/T4539-2013
Alcohol and alcohol-water soluble resin for printing ink Acrylic type(including modified by copolymerization)Published on October 17, 2013
Published by the Ministry of Industry and Information Technology of the People's Republic of China
Implementation on March 1, 2014
This standard was drafted according to the rules given in GB/T1.1-2009. QB/T4539-2013
This standard was formulated with reference to the EU REACH Regulation, the Commission Regulation on Plastic Materials and Articles in Contact with Food, the Exclusion List of Printing Inks and Related Products issued by the European Printing Ink Association (EuPLA) in 2011, and GB9685-2008 "Hygiene Standards for Additives for Food Containers and Packaging Materials". This standard was proposed by the China Light Industry Federation. This standard is under the jurisdiction of the National Ink Standardization Technical Committee (SAC/TC127). The drafting units of this standard: Sichuan Guohe New Materials Co., Ltd., Zhejiang Yongzai Chemical Co., Ltd., Hanghua Ink Chemical Co., Ltd., Huangshan Xinli Ink Technology Co., Ltd., and Sun Yat-sen University. The main drafters of this standard: Li Guangming, Wu Min, Gao Jiusheng, Luo Pingping, and Wang Xiaomei. QB/T4539-2013
Alcohol-soluble and alcohol-water-soluble ink resin acrylates (including copolymerization modification) 1 Scope
This standard specifies the requirements, test methods, inspection rules, marking, packaging, transportation and storage of acrylates (including copolymerization modification) in alcohol-soluble and alcohol-water-soluble ink resins. This standard applies to acrylates (including copolymerization modification) ink resin solutions with alcohols, alcohol esters or alcohol-water mixtures as solvents. Normative reference documents
The following documents are essential for the application of this document. For all dated references, only the dated version applies to this document. For all undated references, the latest version (including all amendments) applies to this document. GB190 Dangerous goods packaging mark
GB/T191 Pictorial mark for packaging storage and transportation (GB/T191-2008, ISO780:1997, MOD) GB/T325.1
Packaging containers Steel drums Part 1: General technical requirements Packaging containers Plastic drums for packaging of dangerous goods
GB18191
GB/T6680
GB/T2793
General rules for sampling of liquid chemical products
Determination of non-volatile content of adhesives
GB/T2794-2013 Determination of viscosity of adhesives Single cylinder rotation viscometer method GB/T22312-2008 Plastic Determination method of residual olefin amide content in polyacrylamide HJ/T371-2007 Technical requirements for environmental labeling products Gravure ink and flexographic ink JJF1070-2005 Rules for metrological inspection of net content of quantitatively packaged goods SN/T2251 Determination of benzene, toluene, xylene and toluene diisocyanate in solvent-based coatings Headspace GC-MS method 3 Requirements
Prohibited artificial addition of substances
During the production, transportation and storage of the product, it is prohibited to artificially add methanol, benzene solvents (benzene, toluene, ethylbenzene, trimethylbenzene), ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol butyl ether, ethylene glycol methyl ether acetate, ethylene glycol ethyl ether acetate, phthalate and other toxic and hazardous substances. The content of methanol and benzene solvents brought into the product as trace impurities in other raw materials should meet the requirements of Table 1. Note: "Artificial addition" refers to the act of adding a substance to meet the relevant intended use. 3.2 Appearance
The product should be a transparent viscous solution without lumps or stratification. 3.3 Physical and chemical indicators
The physical and chemical indicators of the product shall comply with the requirements of Table 1 Table 1 Physical and chemical indicators
Viscosity (25℃)/(mPa·s)
Non-volatile matter content/%
Solubility (alcohol soluble, alcohol-water soluble)
Benzene content/(mg/kg)
When viscosity <1000,
Nominal value ±100
When 1000≤viscosity <3000,
Nominal value ±200
Nominal value ±2
The solution is not turbid and remains transparent
When viscosity ≥3000
Nominal value ±300
QB/T4539-2013
Benzene solvent content/(mg/kg)
Methanol content/(ng/kg)
Residual acrylamide content/%
Toluene diisocyanate (TDI)
Residual monomer content
Note 1: Specific values ​​of viscosity and non-volatile content
Note 2: Benzene solvent content refers to benzene and toluene
Note 3: Not using acrylamide
Note 4: Not using methanol as raw material
Isomonate
Table 1 (continued)
Requirements are set. The value of the volume is determined by the supplier based on the total toluene content of the buyer. Ethylbenzene and diisocyanate do not need to be tested.
TDI) as raw material does not need to be tested
3.4 ​​Net content and tolerance
2005 Table 3,
The allowable shortage should comply with JF1070-
Net content of single quantitative packaged goods
Evaluation Net content should not be lower than the net content marked on the label 4 Test method
4.1 Appearance
No visual inspection under natural light conditions.
4.2 Physical and chemical indicators
Samples taken from the same batch of products
4.2.1 Viscosity
Test according to 5.1 of GB/T2794-2013. The constant temperature water bath temperature is (25±0.1), the sample temperature is 25±0.2)℃, and bubbles should be avoided in the sample.
4.2.2 Non-volatile content
According to the test method specified in GB/T2793, the sample size is 1.2g~1.5g, and the test temperature is (110±2)℃.
Production (alcohol solubility, alcohol-water solubility)
4.2.3 Solubility
Test time is 120min
4.2.3.1 Alcohol solubility
Take an appropriate amount of solution sample in a transparent plastic bottle or glass, mix the resin solution and anhydrous alcohol in a ratio of 1:1, and visually inspect under natural light.
Alcohol-water solubility
Take an appropriate amount of bath sample in a transparent plastic bottle or glass, mix the resin solution and 90% ethanol-water solution in a ratio of 1:1, and visually inspect under natural light
4.2.4 Benzene content, benzene solvent content and methanol content shall be tested according to the provisions of Appendix B of HJ/T. a) To avoid the misjudgment caused by the overlap of baseline impurity peaks with solvent components, the residual components in the sample should be removed thoroughly after the test (programmed temperature increase can also be selected: test at a low column temperature, and then remove the residual components under high column temperature conditions) b) During the test operation (sample preparation, headspace injector, chromatographic column), the residual components of the previous sample should be avoided from affecting the next sample. c) The samples of non-benzene solvent products to be tested should be separated from benzene solvents during storage and testing to avoid contamination; d) The possible reasons for detecting trace amounts of benzene solvents in non-benzene solvent products are: wrong test results (it cannot be determined whether it is a benzene solvent based solely on the peak time of the gas phase chromatogram): benzene impurities in raw materials: contamination in the production, storage and testing environment, etc. When benzene solvents are detected in the product, use another chromatographic column with a larger difference in polarity to retest the same sample. e) In the case of non-benzene solvents, the reliability of the presence of benzene solvents increases. If the two results are the same, the reliability of the presence of benzene solvents increases. The final determination can be made:
SN/T2251)
General-MS/MS, while comparing with the mass spectrum database, the mass spectrum obtained in the actual test should be analyzed. f) The use of gas chromatography
completely relies on the database.
4.2.5 Residual acrylamide
should be tested according to the provisions of GB/T22312-2008 Method B. 4.2.6 Toluene diisocyanate (TDL
Monomer residue
See the regulations for inspection.
According to the regulations of SN/T2251
4.3 Net content and tolerance
Inspect according to the method specified in JJF1070-2005
.
Inspection regulationswwW.bzxz.Net
5.1 Batching and sampling
5.1.1 Batching
Products with the same formula, the same shift, and one-time feeding of a single machine or unit are considered a batch. 5.1.2 Sampling
Randomly take samples from the products according to the regulations of GB/TL6680. The samples are divided into two parts, one for manual inspection and the other for sealed and reserved for reference (retention period is not less than 3 months).
5.2 Inspection Inspection classification
5.2.1 Classification
Product inspection is divided into factory inspection and type inspection5.2.2 Factory inspection
The factory inspection items are appearance, viscosity, non-volatile content, and net content. 5.2.3 Type inspection
Type inspection items are all items specified in the requirements of this standard. Type inspection should be carried out in the following situations:
One time,
a) Trial and development identification of new products or old products transferred to factory production:b) When there are major changes in structure, materials,
process, which may affect product performance: The type inspection cycle is 6 months:
c) After normal production,
When resuming production:
d) After long-term suspension of production,
e) When the superior quality supervision department conducts random inspections.
5.3 Judgment rules
When all the indicators in the test results meet the requirements of this standard, the batch of products shall be judged as qualified products. If one or more indicators do not meet the requirements of this standard, the batch of products shall be doubled and re-sampled from the same batch of products for re-inspection of the unqualified items. If one or more indicators still do not meet the requirements of this standard after re-inspection, the batch of products shall be judged as unqualified products.
6 Marking, packaging, transportation, storage
6.1 Marking
The packaging container shall have obvious and firm markings, including the trademark, enterprise name and address, product name, model, batch number, production date, shelf life, net content and product quality inspection certificate, production license mark and number. The manufacturer shall provide the user with instructions for use or material safety data sheet (MSDS). The packaging, storage and transportation icons and signs shall comply with the provisions of GB190 and GB/T191.
6.2 Packaging
The product shall be filled in steel drums that comply with the provisions of GB/T325.1 or plastic drums that comply with the provisions of GB18191, in accordance with the provisions for the packaging of flammable goods. The containers used shall be strictly inspected before filling and shall be used only if they meet the standard requirements. 6.3 Transportation
The product can be transported by vehicles, ships and other means of transportation if it meets the packaging requirements of 6.2. However, during transportation and handling, it should not be thrown, dropped or collided, and should be protected from rain and sun. The provisions for flammable goods shall be followed during transportation. 6.4 Storage
6.4.1 The product shall not be stored in the open air, and direct sunlight is strictly prohibited. It shall be stored in a well-ventilated warehouse with a room temperature of 5℃~40℃, moisture-proof and away from fire sources.
6.4.2 The shelf life of the product is 12 months from the date of production.1 The product should not be stored in the open air and is strictly prohibited from being exposed to direct sunlight. It should be stored in a well-ventilated warehouse with a room temperature of 5℃~40℃, moisture-proof and away from fire sources.
6.4.2 The shelf life of the product is 12 months from the date of production.1 The product should not be stored in the open air and is strictly prohibited from being exposed to direct sunlight. It should be stored in a well-ventilated warehouse with a room temperature of 5℃~40℃, moisture-proof and away from fire sources.
6.4.2 The shelf life of the product is 12 months from the date of production.
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