Some standard content:
Chemical Industry Standard of the People's Republic of China
HG/T2550—93
Cationic Brilliant Blue X-RRL
(Cationic Blue X-GRRL)
Issued on September 25, 1993
Ministry of Chemical Industry of the People's Republic of China
Implementation on July 1, 1994
W Chemical Industry Standard of the People's Republic of China
Cationic Brilliant Blue X-RRL
(Cationic Blue X-GRRL)
Subject Content and Scope of Application
HG/T2550—93
This standard specifies the technical requirements, test methods, inspection rules, as well as marking, packaging, transportation and storage of cationic brilliant blue X-RRL.
This standard applies to cationic brilliant blue X-RRL obtained by coupling 2-amino-6-methoxybenzothiazole with N-methyl-N-(β-hydroxyethyl)aniline through diazotization, methylation, and commercialization. This dye is mainly used for dyeing acrylic. Its compatibility index K is C. Structural formula:
Molecular formula: C18H2iNO2S·ZnCls
Relative molecular mass: 529.20 (according to the international relative atomic mass in 1989) 2 Reference standards
GB2374
GB2381
GB2383
GB2386
GB2399
GB3920
GB3921
GB3922
GB6152
GB8427
3 Technical Technical requirements
General conditions for dye staining determination
Determination method for insoluble matter content in dyes
Determination method for screening fineness of dyes
Determination method for moisture content of dyes and dye intermediatesDetermination method for color shade and strength of cationic dyesTest method for color fastness to rubbing of textiles
Test method for color fastness to washing of textiles
Test method for color fastness to perspiration of textiles
Test method for color fastness to hot pressing of textiles
Test method for color fastness to light of textilesXenon arc 3.1 Appearance: blue-green uniform powder.
3.2The quality indicators of cationic brilliant blue X-RRL shall comply with the requirements of Table 1. Approved by the Ministry of Chemical Industry of the People's Republic of China on September 25, 1993, CH
·Zncl
Implementation on July 1, 1994
W.bzsoso,com Strength (for standard product), points
Color (with standard product)
Moisture, %
Water insoluble matter content, %
Fineness (250um sieve residue), %
Note: The strength of the standard sample is 250%.
HG/T2550-93
Approximately ~ slightly
3.3 The dyeing fastness of cationic brilliant blue X-RRL on acrylic fabric (1/1 standard depth) shall not be lower than that specified in Table 2. Table 2
(Xenon Arc)
Washing resistance (60℃)
Perspiration resistance
Note: ①Under the conditions specified in this standard, 1/1 standard depth is equivalent to 4%owf. ②The data in this table are measured on nylon whose third monomer is sodium methyl propylene sulfonate. 4 Test method
4.1 Appearance
Evaluate by visual method.
4.2 Dyeing strength and color
4.2.1 Dyeing conditions shall comply with the relevant provisions of GB2374. Discolorationbzxz.net
Friction resistance
Use 2g of acrylic bulked yarn for dyeing, the dyeing depth is 0.4%owf, the bath ratio is 1:100, and the pH is 4.5±0.2. 4.2.2 Pretreatment of acrylic bulked yarn
Hot pressing resistance
(150℃)
Take 5 skeins of acrylic bulked yarn weighed 2.00g (accurate to 0.001g) and treat them in 0.5g/L detergent JU solution at 40℃ for 15min at a bath ratio of 1:50, then take them out, wash them with running water, and number them for use. 4.2.3 Preparation of dye liquor
Weigh 0.500g (accurate to 0.0004g) of standard sample and dye sample respectively, put them into 500mL beakers, add 0.5mL of 80% (V/V) acetic acid to make a slurry, then add 200mL of hot distilled water (about 90℃), stir to fully dissolve, cool and transfer to a 500mL volumetric flask, add distilled water to dilute to the scale, shake well and set aside. The concentration is 0.5g/500mL. Prepare dye liquor in five 300mL dye vats according to Table 3. Table 3
Dyeing liquid components
0.5g/500mL standard solution
0.5g/500mL sample solution
1% (V/V) acetic acid solution
1% (m/m) sodium acetate solution
1% (V/V) spoon dye 1227 solution
5% (m/m) anhydrous sodium sulfate solution
Make up to total volume with distilled water
Dyeing tank number
W.bzsoso：com4.2.4 Dyeing operation
HG/T2550—93
When the temperature of the dye liquor reaches 70℃, dye the numbered acrylic bulked yarn in order (turn it over continuously during dyeing), keep it warm for 10 minutes, then evenly heat it to 100℃ within 45 minutes, boil it for 60 minutes, gradually cool it to about 60℃, take out the yarn sample and wash it with clean water, then dry the acrylic yarn at 60℃ in a loose state. 4.2.5 The evaluation of color light and intensity shall be carried out in accordance with the provisions of GB2374. 4.3 Determination of moisture content of dye
Carry out in accordance with the provisions of "drying method" in GB2386. 4.4 Determination of water-insoluble matter content in dye
Carry out in accordance with the relevant provisions of GB2381. Weigh about 1.0g of sample (accurate to 0.0004g), beat with 1mL of 80% (V/V) acetic acid, add 600mL of hot distilled water (about 90℃) to fully dissolve, and filter quickly. 4.5 Determination of dye fineness
Perform in accordance with the provisions of GB2383.
4.6 Determination of color fastness
4.6.1 The determination of color fastness to light shall be carried out in accordance with the provisions of GB8427. 4.6.2 The determination of color fastness to washing shall be carried out in accordance with the conditions of test solution 1 and method 3 of GB3921. 4.6.3 The determination of color fastness to perspiration shall be carried out in accordance with the provisions of GB3922. 4.6.4 The determination of color fastness to rubbing shall be carried out in accordance with the provisions of GB3920. 4.6.5 The determination of color fastness to heat pressing shall be carried out in accordance with the provisions of GB6152, 150℃ 10000 pressure. 5 Inspection rules
5.1 Inspection classification
3.1~3.2 are factory inspection items.
Type inspection is carried out when one of the six situations described in Article 6.6.1 of GB1.3 occurs. Among them, it is carried out once every two years in normal continuous production.
5.2 Sampling method
Select 10% of the barrels from each batch (a batch of uniform products mixed once) for sampling. The small batch shall not be less than 3 barrels. If the whole batch is less than 3 barrels, sample from each barrel.
Do not let foreign impurities fall into the product during sampling. Use stainless steel (or aluminum, copper) sampling tubes to sample from the upper, middle and lower parts respectively. After the samples are fully mixed, take about 50g from them and divide them into two clean and dry ground-mouth bottles, seal them with paraffin wax, and label them. Indicate the manufacturer's name, product name, strength specification, batch number, sampling date, one bottle for inspection, one bottle for reference, and the shelf life is 1 year. 5.3 Manufacturer Inspection
Cationic Brilliant Blue X-RRL should be inspected by the manufacturer's quality supervision and inspection department. The manufacturer should ensure that all products leaving the factory meet the requirements of this standard and be accompanied by a quality inspection certificate in a certain format. 5.4 User Acceptance
The user has the right to accept the received Cationic Brilliant Blue X-RRL in accordance with the provisions of this standard. When the supply and demand parties have objections to the quality of the product, they can negotiate to resolve the issue. 5.5 Re-inspection
If one of the inspection results does not meet the requirements of this standard, samples should be taken from twice the amount of packaging barrels for re-inspection. Even if only one indicator is unqualified in the re-inspection result, the entire batch of products cannot be accepted. 5.6 Arbitration
When arbitration is required, the arbitration institution can be selected by agreement between the two parties. And arbitration appraisal should be conducted in accordance with the methods of this standard. 6 Marking, packaging, transportation, purchase and storage
6.1 The packaging barrel should be firmly and clearly marked with the manufacturer's name, product name, registered trademark, production date, batch number, specification, gross weight and net weight. Each batch of packaging should be accompanied by a product quality certificate, which should be marked with the number of this standard. 6.2 Cationic brilliant blue X-RRL should be packed in iron barrels lined with plastic bags. The plastic bags should be tied and then sealed with a lid. Net weight of each barrel is 50kg. Other packaging can be negotiated with the user.
6.3 Handle with care during transportation to prevent moisture and heat. 6.4 The product should be stored in a cool, dry and ventilated warehouse. Additional notes:
This standard was proposed by the Science and Technology Department of the Ministry of Chemical Industry of the People's Republic of China. This standard is under the technical jurisdiction of the Shenyang Chemical Research Institute of the Ministry of Chemical Industry. This standard was drafted by Shanghai Dyestuff Chemical Plant No. 3. The main drafters of this standard are Yang Qishan and Gao Hua. 4
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