This standard specifies the product classification, technical requirements, test methods, inspection rules and requirements for marking, packaging, transportation, storage, etc. of hair spray. This standard applies to liquid hair sprays that are made of high molecular weight polymers and other raw materials to fix, modify and beautify hair styles. QB 1644-1998 Hair spray QB1644-1998 Standard download decompression password: www.bzxz.net

QB1644-1998
This standard is revised and compiled based on QB1644-1992 "Hairspray", in accordance with GB/T1.1-1993 "Guidelines for Standardization Work Unit 1: Drafting and Expression Rules of Standards Part 1: Basic Provisions for Standard Compilation". As a mandatory industry standard, this standard deletes the total solid index requirements and inspection methods from its technical indicators, adds mercury, arsenic, and lead indicators in the hygiene indicators, and adopts GB/T14449-1993 "Test Methods for Aerosol Products" in the test method. The packaging mark is revised, and its net capacity index is implemented in accordance with the quantitative packaging commodity measurement supervision regulations. This standard was proposed by the Industry Management Department of the State Light Industry Bureau. This standard is under the jurisdiction of the National Cosmetics Standardization Center. The drafting units of this standard are: Shanghai Jahwa Co., Ltd., Shanghai Daily Chemical Industry Research Institute. The main drafters of this standard are: Yao Huimin, Chen Yafang, Guan Baolin, and Xue Zhigang. From the date of implementation of this standard, the light industry standard QB16441992 Hairspray issued by the former Ministry of Light Industry will be invalidated. 1 Scope
Light Industry Standard of the People's Republic of China
Hairspray
QB16441998
Replaces QB1644-1992
This standard specifies the product classification, technical requirements, test methods, inspection rules and marking, packaging, transportation, storage and other requirements of hairspray.
This standard applies to liquid hairsprays that are made of raw materials such as high molecular polymers to fix, modify and beautify hairstyles. 2 Referenced Standards
The provisions contained in the following standards constitute the provisions of this standard through reference in this standard. When this standard is published, the versions shown are valid. All standards will be revised, and parties using this standard should explore the possibility of using the latest versions of the following standards. GB5296.3--1995 Instructions for use of consumer products General labeling of cosmetics GB/T7917.1-1987 Standard test methods for cosmetic hygiene and chemistry Mercury GB/T7917.2-1987 Standard test methods for cosmetic hygiene and chemistry Monument GB/T7917.3-1987 Standard test methods for cosmetic hygiene and chemistry Lead GB/T7918-1987 Standard test methods for cosmetic microbiology GB/T11449-1993
Test methods for aerosol products
BB0005--1995 Labeling of aerosol products
QB/T1684-1993 Cosmetics inspection rules
QB/T1685-1993 Requirements for the appearance of cosmetic product packaging State Bureau of Technical Supervision Order (95) No. 43 Regulations on Metrological Supervision of Pre-packaged Commodities 3 Product classification
According to the spraying power of styling spray, it is divided into air pressure spray and pump spray. 4 Technical requirements
4.1 Sensory, physical and chemical and hygienic indicators shall comply with the provisions of Table 1. 4.2 Net content
The net content of single-piece quantitative packaged goods shall comply with Table (I) of the State Administration of Technical Supervision Order (95) No. 43: Average deviation 4Q ≥ 0 for batch quantitative packaged goods.
4.3 Packaging appearance requirements
It shall comply with the provisions of 3.6, 3.10.2 and 3.10.3 of QB/T1685-1993. National whole industry monthly 10001125 batch import
10001201##
Spray rate (air pressure type), %
Leakage test (air pressure type)
Internal pressure (air pressure type), MPa
Number of spraying times (pump type),
Methanol, %
Mercury, mg/kg
(As), mg/kg
Lead (Pb), mg/kg
Total number of bacteria (pump type)
Pseudomonas aeruginosa (pump type)
Staphylococcus aureus (pump type)
Escherichia coli (pump type)
5 Test method
5.1 Color
Spray the sample according to the product usage method and test it daily. 5.2 Aroma
QB1644-1998
Comply with enterprise regulations
Comply with enterprise regulations
No leakage in the 50℃ constant temperature water bath. In the 25℃ warm water bath, the test should be less than 0.8
No detection
No detection
No detection
Spray on the scent paper according to the product usage instructions, and spray it intermittently to identify whether the aroma meets the specified aroma type. 5.3 Spray rate
Test according to 4.10 of GB/T14449-1993. 5.4 Leakage test
Pre-adjust the constant temperature water bath to (50±2)℃, then put in three cans and shake them well. Remove the plastic cover of the sample and put it upright in the water bath. Within 5 minutes, each can is qualified if no more than 5 bubbles emerge. 5.5 Internal pressure
Test according to 4.1 of GB/T14449--1993
5.6 Number of sprays
Take three bottles of pump-type hair spray, press until liquid starts to spray, and calculate the number of presses for each bottle. The number of sprays for each bottle shall not exceed 5 times. 5.7 Methanol
5.7.7 Reagents
5.7.1.1 Methanol-free ethanol, take 1.0uL of anhydrous ethanol (superior grade) and inject it into the chromatograph, and no impurity peaks should appear. 5.7.1.2
Ethanol (CH, 0H=75%) Take 75mL of ethanol (5.7.1.1) and dilute it to 100mL with pure water. 5.7.1.3 Gas chromatography reagent: GDX-102 (60~80 mesh). 5.7.1.4 Gas chromatography reagent: polyethylene glycol 1540 (or 1500). 5.7.1.5 Methanol standard solution (CH,OH=1%): Take 1.0mL of chromatographically pure methanol and place it in a 100mL volumetric flask, dilute to the mark with 75% ethanol (5.7.1.2), and store in a refrigerator. 5.7.1.6
5 Sodium nitride: analytical grade.
5.7.1.7 Defoaming agent: emulsified silicone oil, such as 284P5, Shanghai Resin Factory: comQB1644-1998
5.7.2.1 Gas chromatograph: equipped with hydrogen flame ionization detector. 5.7.2.2 Chromatographic column, specification 2m×2mm, filled with GDX-102, suitable for samples without dimethyl ether. 5.7.2.3 Chromatographic column, size 2mX4mm, filled with GDX-102 (5.7.1.3) carrier coated with 25% ethylene glycol 1540 (or 1500). This column is suitable for samples containing dimethyl ether. 5.7.2.4 All-glass ground mouth water distillation device. 5.7.2.5 Super constant temperature water bath: temperature range 0℃~100℃, temperature control accuracy ±0.5℃. 5.7.2.6 Syringe: 0.5μL, 1uL, 1ml. 5.7.3 Analysis Steps
5.7.3.1 Start the chromatograph
Make necessary adjustments to achieve the best working conditions of the instrument. The chromatographic conditions are selected according to the specific situation. The reference conditions are: a) Chromatographic Condition 1 (applicable to samples without dimethyl ether)-column temperature: 170℃, vaporization chamber, detector temperature: 200℃ nitrogen flow rate: 40mL/min: hydrogen flow rate: 40mL/min; air flow rate: 500mL/min (the flow rate can be adjusted according to the specific instrument).
b) Chromatographic Condition 2 (applicable to samples containing dimethyl ether)-column temperature: 75℃ vaporization temperature 90℃. Detector temperature: 150℃-nitrogen flow rate: 30mL/min; hydrogen flow rate: 30mL/min: air flow rate: 300mL/min (the flow rate can be adjusted according to the specific instrument).
5.7.3.2 Sampling
Direct sampling of cosmetics without propellant. For samples containing propellants, take samples as follows: take a certain amount of 75% ethanol (5.7.1.2) in a filling steaming bottle, replace the original nozzle with a nozzle with a catheter, insert the other end of the catheter below the ethanol liquid surface, and slowly press the nozzle to allow the sample to flow into the ethanol solution. Calculate the sampling volume using the subtraction method. 5.7.3.3 Sample pretreatment (distillation method)
Take 10mL of the sample and put it in a filling steaming bottle (5.7.2.4). Add 50mL of distilled water, 2g of sodium chloride (5.7.1.6), 1 drop of defoaming agent (5.7.1.7) and 30mL of methanol-free ethanol (5.7.1.1). Steam the filling in a boiling water bath, collect about 40mL of the steaming liquid, and add methanol-free ethanol to the mark in a 50mL volumetric flask to use as the sample solution.
5.7.3.4 Drawing of standard curve
Take 7 50mL volumetric flasks and add 0.25, 0.50, 1.00, 2.00, 4.007.00, 10.00ml of methanol standard solution (5.7.1.5) respectively. Then add 75% ethanol (5.7.1.2) to the scale respectively. The methanol content of this standard series is: 0.005%, 0.01%, 0.02%, 0.04%, 0.08%, 0.14% and 0.20%.
5.7.3.5 Determination
Take 1L of the sample solution to be tested and 1L of the standard solution in sequence, inject them into the gas chromatograph, record the area of ​​each chromatographic peak and draw a peak area-methanol concentration (V/V) curve.
5.7.4 Calculation
Where: 9——the volume fraction of methanol in the sample, %; P——the volume fraction of methanol in the sample solution obtained from the standard curve, %; K——the sample dilution factor.
Test according to GB/T7917.1.
(1)
Test according to GB/T7917.3. Www.bzxZ.net
5.11 Total bacterial count
Test according to GB/T7918.2.
QB16441998
5.12 Pseudomonas aeruginosa, Staphylococcus aureus and Escherichia coli are tested in accordance with GB/T7918.3~GB/T7918.5. 5.13 Net content
Implemented in accordance with Order (95) No. 43 of the State Administration of Technical Supervision. 6 Inspection rules
Implemented in accordance with QB/T1684:
7 Marking, packaging, transportation and storage
7.1 Sales packaging marking
Implemented in accordance with the requirements of GB5296.3 and BB0005. 7.2 Transport packaging marking
Should include product name, trademark, manufacturer's name and address, standard number, net content, quantity, gross weight, volume, storage and transportation diagram, production period and shelf life or production batch number and final use date.
7.3 Packaging
Bottles can be packed in corrugated paper depending on the needs of the manufacturer. The corrugated paper has a gap in the middle packaging paper. The large packaging uses a double-wafer carton. The inside is solid and has no gaps. The qualified mark or certificate is placed. 7.4 Transportation
Must be placed and unloaded gently, and stacked according to the arrow mark on the box to avoid severe vibration, impact, sun and rain. If it is a dangerous product, it should be transported according to the requirements of dangerous goods.
7.5 Storage
7.5.1 It should be stored in a ventilated and dry warehouse with a temperature not higher than 38C. It should not be close to the stove or heater. When stacking, it must be 20cm away from the ground and 50cm away from the wall. There should be a passage in the middle. Stack according to the arrow mark on the box and do not put it upside down. If it is a dangerous product, it should be stored according to the requirements of dangerous goods. 7.5.2 Shelf life
Under the specified transportation and storage conditions, the shelf life of the product shall be in accordance with the relevant shelf life provisions in QB/T1685 if the packaging is intact and unopened.
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