Rules for classification and labelling of chemicals—Part 29:Hazardous to the ozone layer
Some standard content:
ICS13.300
National Standard of the People's Republic of China
GB30000.29-—2013
Rules for classification and labelling of chemicals-Part 29:Hazardous to the ozone layer2013-10-10 Issued
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China Standardization Administration of China
2014-11-01 Implementation
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. The expected structure of GB30000 "Chemical Classification and Labeling Specification" and the national standards to be replaced are: Part 1: General (replaces GB13690-2009); Part 2: Explosives (replaces GB20576-2006): Part 3: Flammable gases (replaces GB20577-2006): Part 4: Aerosols (replaces GB20578-2006); Part 5 Part: Oxidizing gases (replaces GB20579-2006): Part 6: Gases under pressure (replaces GB20580-2006); Part 7: Flammable liquids (replaces GB20581-2006): Part 8: Flammable solids (replaces GB20582-2006); Part 9: Self-reactive substances and mixtures (replaces GB20583-2006); Part 10: Pyrophoric liquids (replaces GB20585-2006); Part 11: Pyrophoric solids (replaces GB20586-2006): Part 12: Self-heating substances and mixtures (replaces GB20584-2006): Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB20587-2006): Part 14: Oxidizing Liquids (Replaces GB20589-2006): Part 15: Oxidizing Solids (Replaces GB20590-2006), Part 16: Organic Peroxides (Replaces GB20591-2006): Part 17: Metal Corrosives (Replaces GB205882006); Part 18: Acute Toxicity (Replaces GB205922006): Part 19: Skin Corrosion/Irritation (Replaces GB20593-2006): Part 20: Serious Eye Damage/Eye Irritation (Replaces GB20594-2006): Part 21: Respiratory or Skin Sensitization (Replaces GB20595-2006) 6): Part 22: Germ cell mutagenicity (replaces GB20596-2006): Part 23: Carcinogenicity (replaces GB20597-2006): Part 24: Reproductive toxicity (replaces GB20598-2006): Part 25: Specific target organ toxicity single exposure (replaces GB20599-2006): Part 26: Specific target organ toxicity repeated exposure (replaces GB20601-2006); Part 27: Inhalation hazard;
Part 28: Hazards to the aquatic environment (replaces GB20602-2006): Part 29: Hazards to the ozone layer;
Part 30: Warning signs for chemical workplaces. This part is Part 29 of GB30000.
This part was drafted in accordance with the rules given in GB/T1.1-2009. GB30000.29—2013
This part is consistent with the relevant technical content of the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (Fourth Revised Edition). 1
GB30000.29—2013
This part was proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251). Drafting units of this part: Shandong Exit-Entry Inspection and Quarantine Bureau of the People's Republic of China, Chemical Registration Center of the Ministry of Environmental Protection, China Chemical Information Center
The main drafters of this part are Geng Xiangyang, Lu Ling, Che Lidong, Mao Yan, Yu Xiao, Ge Haihong, Huang Honghua, Du Gang, Feng Zhenzhen, Lu Jian, Liang Jin. 1 Scope
Chemical Classification and Labeling Specification
Part 29: Hazards to the Ozone Layer
GB30000.29--2013
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and labeling of chemicals that are hazardous to the ozone layer. This part applies to the classification and labeling of chemicals that are hazardous to the ozone layer in accordance with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (hereinafter referred to as GHS).
This part does not apply to equipment, articles and electrical appliances (such as refrigerators or air-conditioning equipment, etc.) containing substances that are hazardous to the ozone layer. 2 Normative References
The following documents are essential for the application of this document. For all dated references, only the dated version applies to this document. For all undated references, the latest version (including all amendments) applies to this document. GB13690 General Rules for Classification and Hazard Communication of Chemicals United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Fourth Revised Edition) United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (Seventeenth Revised Edition) International Convention on the Protection of the Ozone Layer "Montreal Protocol on Substances that Deplete the Ozone Layer" 3 Terms and Definitions
GB13690 defines and the following terms and definitions apply to this document. 3.1
Ozone depletion potential; ODp The ratio of the differential emissions of a certain compound to the comprehensive disturbance to the entire ozone layer relative to the same mass of trichlorofluoromethane. 4 Classification criteria
Substances and mixtures are classified as Category 1 according to Table 1. Table 1 Classification of substances and mixtures that are hazardous to the ozone layer
5 Decision logic
Any regulated substance listed in the Annex to the Montreal Protocol on Substances that Deplete the Ozone Layer (hereinafter referred to as the Montreal Protocol); or
Any mixture containing at least one component listed in the Annex to the Montreal Protocol (see Appendix A) in a concentration of not less than 0.1% The decision logic is for reference only. See Appendix B for the decision logic. It is particularly recommended that the person responsible for classification study Chapter 4 of GB30000.29—2013 before and during the use of the decision logic.
6 Labelling
6.1 Overview
6.1.1 For labels that are hazardous to the ozone layer, the hazard categories are listed in the order of the designated pictogram, signal word and hazard statement. The hazard classes or categories covered by the United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (hereinafter referred to as the "Model Regulations") should list the designated corresponding graphic symbol for each category on the label. The allocation of ozone layer hazard label elements is shown in Appendix C. 6.1.2 The classification criteria and label elements for substances and mixtures that are hazardous to the ozone layer are shown in Appendix D. 6.1.3 The information required on the label includes hazard pictograms, signal rooms, hazard statements, precautionary statements, product identifiers and supplier logos. 6.2 Hazard pictograms
Hazard pictograms should be black with a white background and the red frame should be wide enough to be visible: 6.3 Signal words
Signal words are words used on the label to indicate the relative severity of the hazard and to alert the reader to potential hazards. The signal words are "Danger" and "Warning". For hazards to the ozone layer, only the signal word "Warning" is used. 6.4 Hazard statements
Hazard statements are words assigned to hazard classes and categories. They are used to describe the hazardous nature of a hazardous product used by GHS and, where appropriate, its degree of hazard. Hazard statements and precautionary statements for hazards to the ozone layer are shown in Table D.1 and in Appendix E. 6.5 Precautionary statements
Precautionary statements A statement is a word (and or pictogram) used to summarize the recommended actions to minimize or prevent further exposure to the hazardous product or the adverse effects of improper storage or handling of the hazardous product. To achieve this, there are three types of precautionary statements: general, prevention, emergency, storage and disposal. For precautionary statements, see Appendix 6.6 Product identification. 6.6.1 The product identifier should be used on the label and should be consistent with the product identifier used on the Material Safety Data Sheet. If a substance or mixture is listed in the Model Regulations, the correct UN shipping name should also be used on the packaging. 6.6.2 The label should include the chemical name of the substance. The competent authority may require that the chemical names of all components that may cause the mixture to be hazardous be listed on the label.
6.7 Supplier identification
The name, address and telephone number of the manufacturer or supplier of the substance or mixture shall be provided on the label. 6.8 Label examples
For examples of labels for ozone layer hazards, see Appendix F. Appendix A
(Normative Appendix)
Annex to the Montreal Protocol and the controlled substances specifiedA1See Table A.1 for Annex A to the Montreal Protocol. Table A.1
Category I
Chemical formula
Annex A to the Montreal Protocol
Substance code
CFC-12
CFC-113
halon2402
GB30000.29—2013
Ozone depletion potential (ODP value)
“These ozone depletion potential values are based on currently known The estimated number of errors will be reviewed regularly. irkAoNrKAca
GB30000.29-—2013
A.2 Annex B of the Montreal Protocol is shown in Table A.2. Table A.2
Class I
Class II
Class III
Chemical formula
C,FCls
CF,CL4
Montreal Protocol Annex B to the Leyle Protocol
Substance Code
CFC-13
CFC-111
CFC-112
CFC-211
CFC-212
CFC-213
CFC-214
CFC-215
CFC-216
CFC-217||t t||Carbon Tetrachloride
1,1,1-Trifluoroethane
Ozone Depletion Potential (ODP)
These ODPs are estimates based on current knowledge and are subject to periodic review and revision. Non-1.1.2 Trichloroethane.
See Table A, 3 of Annex C of the Montreal Protocol. Table A.3
Group I
Chemical Formula
CHFCL4| | tt | ||GH,F,Cl
Annex C of the Montreal Protocol
Substance code
HCFC-214
HCFC-22
HCFC-31
HCFC121
HCFC-122
HCFC-123
HCFC-123
HCFC-124||tt| |HCFC-124
HCFC-131
HCFC-132
HCFC-133
HCFC-141
HCFC-1416
HCFC-142
HCFC-142b+
HCFC-151
HCFC-221||tt| |HCFC-22 2
HCFC-223
HCFC-224
HCFC-225
HCFC-225ca
HCFC-225cb
HCFC-226
HCFC-231
HCFC-232
HCFC-233
HCFC-2 34
H CFC-235
HCFC-241
HCFC-242
HCFC-243
Number of isomers
iKAoNiKAca-
GB30000.29—2013
Ozone depletion potential (ODP value)
0.01~0.04
0.02~0.08||tt ||0.02-0.06
0.02~~0.04
0,007-0.05
0.008~0.05
0.005~~0.07
0.0080.07
0.003~0.005
0.015~0. 07
0.01~0.09
0,01-0 .08 | |tt | 7~0.12
GB30000.29—2013||t t||First category
Second category
Chemical formula
CH,FCI
C,HF,Br
C2H,FBr
CHsFBr
CHF,Bra
CH,FBr
CHF,Br
CHFBra
CHFBrs
Table A.3 (continued)||tt ||Substance code
HCFC-244
HCFC-251
HCFC-252
HCFC-253
HCFC-261
HCFC28R
HCFC-27
HBFC-22B
Number of isomers
Ozone depletion potential (ODP value)||tt| |0.009~~0.14
0.001~0,01
0.005~0.04
0.003~-0.03
0.002~0,02
0.002~0.02
0.001~0.03
0,1~1,9
Second Class
Third Class
Chemical Formula||t t||CHF,Br
CaH,FBr
Table A.3 (continued)
Substance code
Methyl chloride
Number of isomers
"These ozone depletion potentials are estimates based on current knowledge and will be reviewed and revised regularly A.4 Annex E to the Montreal Protocol See Table A.4 Table A4 Annex E to the Montreal Protocol
Chemical weapons||tt ||Substance code
GB30000.29—2013
Ozone depletion potential (ODP value)
Ozone depletion potential (OLP value)
These ozone depletion potential values are estimated based on existing common knowledge and are subject to periodic review and replacement. The judgment logic for hazards to the ozone layer is shown in Figure B.1. Appendix B
(Informative Appendix)
Decision logic for ozone layer hazards
Substance: Is the substance listed in the Annex to the Montreal Protocol? Mixture: Does the mixture contain at least one component listed in the Annex to the Montreal Protocol, and the concentration is not less than 0.1%? Figure B.1 Decision logic for ozone layer hazardous substances and mixtures No classification required
Cannot be classified
Category 1
Appendix C
(Normative Appendix)
Allocation of ozone layer hazard label elements
The allocation of ozone layer hazard label elements is shown in Table C.1. Table C.1 Allocation of ozone layer hazard label elements Category 1
Destroys
Ozone in the upper atmosphere, which is harmful to public
health and the environment
Not required in the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations. irKAoNrKAca
GB30000.29—20138 Label examples
For examples of ozone layer hazard labels, see Appendix F. Appendix A
(Normative Appendix)
Montreal Protocol Annex and Controlled SubstancesA1See Table A.1 for Annex A of the Montreal Protocol. Table A.1
Category I
Chemical formula
Annex A of the Montreal Protocol
Substance code
CFC-12
CFC-113
halon2402
GB30000.29—2013
Ozone depletion potential (ODP value)
“These ozone depletion potential values are based on the currently known The estimated number of errors will be reviewed regularly. irkAoNrKAca
GB30000.29-—2013
A.2 Annex B of the Montreal Protocol is shown in Table A.2. Table A.2
Class I
Class II
Class III
Chemical formula
C,FCls
CF,CL4
Montreal Protocol Annex B to the Leyle Protocol
Substance Code
CFC-13
CFC-111
CFC-112
CFC-211
CFC-212
CFC-213
CFC-214
CFC-215
CFC-216
CFC-217||t t||Carbon Tetrachloride
1,1,1-Trifluoroethane
Ozone Depletion Potential (ODP)
These ODPs are estimates based on current knowledge and are subject to periodic review and revision. Non-1.1.2 Trichloroethane.
See Table A, 3 of Annex C of the Montreal Protocol. Table A.3
Group I
Chemical Formula
CHFCL4| | tt | ||GH,F,Cl
Annex C of the Montreal Protocol
Substance code
HCFC-214
HCFC-22
HCFC-31
HCFC121
HCFC-122
HCFC-123
HCFC-123
HCFC-124||tt| |HCFC-124
HCFC-131
HCFC-132
HCFC-133
HCFC-141
HCFC-1416
HCFC-142
HCFC-142b+
HCFC-151
HCFC-221||tt| |HCFC-22 2
HCFC-223
HCFC-224
HCFC-225
HCFC-225ca
HCFC-225cb
HCFC-226
HCFC-231
HCFC-232
HCFC-233
HCFC-2 34
H CFC-235
HCFC-241
HCFC-242
HCFC-243
Number of isomers
iKAoNiKAca-
GB30000.29—2013
Ozone depletion potential (ODP value)
0.01~0.04
0.02~0.08||tt ||0.02-0.06
0.02~~0.04
0,007-0.05
0.008~0.05
0.005~~0.07
0.0080.07
0.003~0.005
0.015~0. 07
0.01~0.09
0,01-0 .08 | |tt | 7~0.12
GB30000.29—2013||t t||First category
Second category
Chemical formula
CH,FCI
C,HF,Br
C2H,FBr
CHsFBr
CHF,Bra
CH,FBr
CHF,Br
CHFBra
CHFBrs
Table A.3 (continued)||tt ||Substance code
HCFC-244
HCFC-251
HCFC-252
HCFC-253
HCFC-261
HCFC28R
HCFC-27
HBFC-22B
Number of isomers
Ozone depletion potential (ODP value)||tt| |0.009~~0.14
0.001~0,01
0.005~0.04
0.003~-0.03
0.002~0,02
0.002~0.02
0.001~0.03
0,1~1,9
Second Class
Third Class
Chemical Formula||t t||CHF,Br
CaH,FBr
Table A.3 (continued)
Substance code
Methyl chloride
Number of isomers
"These ozone depletion potentials are estimates based on current knowledge and will be reviewed and revised regularly A.4 Annex E to the Montreal Protocol See Table A.4 Table A4 Annex E to the Montreal Protocol
Chemical weapons||tt ||Substance code
GB30000.29—2013
Ozone depletion potential (ODP value)
Ozone depletion potential (OLP value)
These ozone depletion potential values are estimated based on existing common knowledge and are subject to periodic review and replacement. The judgment logic for hazards to the ozone layer is shown in Figure B.1. Appendix B
(Informative Appendix)
Decision logic for ozone layer hazards
Substance: Is the substance listed in the Annex to the Montreal Protocol? Mixture: Does the mixture contain at least one component listed in the Annex to the Montreal Protocol, and the concentration is not less than 0.1%? Figure B.1 Decision logic for ozone layer hazardous substances and mixtures No classification required
Cannot be classified
Category 1
Appendix C
(Normative Appendix)
Allocation of ozone layer hazard label elements
The allocation of ozone layer hazard label elements is shown in Table C.1. Table C.1 Allocation of ozone layer hazard label elements Category 1
Destroys
Ozone in the upper atmosphere, which is harmful to public
health and the environment
Not required in the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations. irKAoNrKAca
GB30000.29—20138 Label examples
For examples of ozone layer hazard labels, see Appendix F. Appendix A
(Normative Appendix)
Montreal Protocol Annex and Controlled SubstancesA1See Table A.1 for Annex A of the Montreal Protocol. Table A.1
Category I
Chemical formula
Annex A of the Montreal Protocol
Substance code
CFC-12
CFC-113
halon2402
GB30000.29—2013
Ozone depletion potential (ODP value)
“These ozone depletion potential values are based on the currently known The estimated number of errors will be reviewed regularly. irkAoNrKAca
GB30000.29-—2013
A.2 Annex B of the Montreal Protocol is shown in Table A.2. Table A.2
Class I
Class II
Class III
Chemical formula
C,FCls
CF,CL4
Montreal Protocol Annex B to the Leyle Protocol
Substance Code
CFC-13
CFC-111
CFC-112
CFC-211
CFC-212
CFC-213
CFC-214
CFC-215
CFC-216
CFC-217||t t||Carbon Tetrachloride
1,1,1-Trifluoroethane
Ozone Depletion Potential (ODP)
These ODPs are estimates based on current knowledge and are subject to periodic review and revision. Non-1.1.2 Trichloroethane.
See Table A, 3 of Annex C of the Montreal Protocol. Table A.3
Group I
Chemical Formula
CHFCL4| | tt | ||GH,F,Cl
Annex C of the Montreal Protocol
Substance code
HCFC-214
HCFC-22
HCFC-31
HCFC121
HCFC-122
HCFC-123
HCFC-123
HCFC-124||tt| |HCFC-124
HCFC-131
HCFC-132
HCFC-133
HCFC-141
HCFC-1416
HCFC-142
HCFC-142b+
HCFC-151
HCFC-221||tt| |HCFC-22 2
HCFC-223
HCFC-224
HCFC-225
HCFC-225ca
HCFC-225cb
HCFC-226
HCFC-231
HCFC-232
HCFC-233
HCFC-2 34
H CFC-235
HCFC-241
HCFC-242
HCFC-243
Number of isomers
iKAoNiKAca-
GB30000.29—2013
Ozone depletion potential (ODP value)
0.01~0.04
0.02~0.08||tt ||0.02-0.06
0.02~~0.04
0,007-0.05
0.008~0.05
0.005~~0.07
0.0080.07
0.003~0.005
0.015~0. 07
0.01~0.09
0,01-0 .08 | |tt | 7~0.12
GB30000.29—2013||t t||First category
Second category
Chemical formula
CH,FCI
C,HF,Br
C2H,FBr
CHsFBr
CHF,Bra
CH,FBr
CHF,Br
CHFBra
CHFBrs
Table A.3 (continued)||tt ||Substance code
HCFC-244
HCFC-251
HCFC-252
HCFC-253
HCFC-261
HCFC28R
HCFC-27
HBFC-22B
Number of isomers
Ozone depletion potential (ODP value)||tt| |0.009~~0.14
0.001~0,01
0.005~0.04
0.003~-0.03
0.002~0,02
0.002~0.02
0.001~0.03
0,1~1,9
Second Class
Third Class
Chemical Formula||t t||CHF,Br
CaH,FBr
Table A.3 (continued)
Substance code
Methyl chloride
Number of isomers
"These ozone depletion potentials are estimates based on current knowledge and will be reviewed and revised regularly A.4 Annex E to the Montreal Protocol See Table A.4 Table A4 Annex E to the Montreal Protocol
Chemical weapons||tt ||Substance code
GB30000.29—2013
Ozone depletion potential (ODP value)
Ozone depletion potential (OLP value)
These ozone depletion potential values are estimated based on existing common knowledge and are subject to periodic review and replacement. The judgment logic for hazards to the ozone layer is shown in Figure B.1. Appendix B
(Informative Appendix)
Decision logic for ozone layer hazards
Substance: Is the substance listed in the Annex to the Montreal Protocol? Mixture: Does the mixture contain at least one component listed in the Annex to the Montreal Protocol, and the concentration is not less than 0.1%? Figure B.1 Decision logic for ozone layer hazardous substances and mixtures No classification required
Cannot be classified
Category 1
Appendix C
(Normative Appendix)
Allocation of ozone layer hazard label elements
The allocation of ozone layer hazard label elements is shown in Table C.1. Table C.1 Allocation of ozone layer hazard label elements Category 1
Destroys
Ozone in the upper atmosphere, which is harmful to public
health and the environment
Not required in the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations. irKAoNrKAca
GB30000.29—201329—2013
Ozone Depletion Potential (ODP)
“These ozone depletion potentials are estimates based on current knowledge and will be reviewed and revised regularly.irkAoNrKAca
GB30000.29-—2013
A.2 Annex B of the Montreal Protocol is shown in Table A.2. Table A.2
Category I
Category 2
Category 3
Chemical formula
C,FCls
CF,CL4
Annex B of the Montreal Protocol
Substance code
CFC-13
CFC-111
CFC-112
CFC-211
CFC-212
CF C-213
CFC-214
CFC-215
CFC-216
CFC-217
Carbon Tetrachloride
1,1,1-Trifluoroethane
Ozone Depletion Potential (ODP)
These ODP values are estimates based on current knowledge and are subject to periodic review and revision. Non-1. 1.2 Trichloroethane.
See Table A, 3 in Annex C of the Montreal Protocol. Table A.3
Class I
Chemical formula
CHFCL4
CHF,Cl
CHCLCE
CHFCICF
CH,FCl
CH,FCle
G,HFCls||tt ||C,HF,CI,
C,H,CL
CHF,Cl
CFCF,CHCl2
CF.CICF,CHCIF
GH,F,Cl
Annex C of the Montreal Protocol
Substance Code
HCFC-214
HCFC-22
HCFC-31
HCFC121
HCFC-122
HCFC-123
HCFC-123
HCFC-124
HCFC-124
HCFC-131
HCFC-132
HCFC-133
HCFC-141
HCFC-1416
HCFC-142
HCFC-142b+
HCFC-151
HCFC-221
HCFC-222
HCFC-223
HCFC-224
HCFC-225
HCFC-22 5ca
HCFC-225cb
HCFC-226
HCFC-231
HCFC-232
HCFC-233
HCFC-234
HCFC-235
HCFC-241
HCFC-242
HCFC-243| |t t||Number of isomers
iKAoNiKAca-
GB30000.29—2013
Ozone depletion potential (ODP value)
0.01~0.04
0.02~0.08
0.02-0.06
0.02~~0.04
0,007-0.05|| tt | .09
0.008~0.10||tt| |0.0070.23
0.01~0.28
0.03~0.52
0.004~0.09
0.005~0.13
0.007~0.12
GB30000.29—2013
First Class
Second Class
Chemical Formula
CH, FCI
C,HF,Br
C2H,FBr
CHsFBr
CHF,Bra
CH,FBr
CHF,Br
CHFBra
CHFBrs
Table A.3 (continued)
Substance code
HCFC-244
HCFC-251
HCFC-252
HCFC-253
HCFC-261
HCFC28R
HCFC-27
HBFC-22B
Number of isomers
Ozone depletion potential (ODP value)
0.009~~0.14
0. 001~0,01
0.005~0.04
0.003~-0.03
0.002~0,02
0.002~0.02
0.001~0.03
0,1~1,9
Second category
Third category
Chemical formula
CHF,Br||tt ||CaH,FBr
Table A.3 (continued)
Substance code
Methyl chloride
Number of isomers
"These ozone depletion potentials are estimates based on current knowledge and will be reviewed and revised regularly A.4 Annex E to the Montreal Protocol See Table A.4 Table A4 Annex E to the Montreal Protocol
Chemical weapons
Substance code| |tt||GB30000.29—2013
Ozone depletion potential (ODP value)
Ozone depletion potential (OLP value)
These ozone depletion potential values are estimated based on existing common knowledge and are subject to periodic review and replacement. The judgment logic for hazards to the ozone layer is shown in Figure B.1. Appendix B
(Informative Appendix)
Decision logic for ozone layer hazards
Substance: Is the substance listed in the Annex to the Montreal Protocol? Mixture: Does the mixture contain at least one component listed in the Annex to the Montreal Protocol, and the concentration is not less than 0.1%? Figure B.1 Decision logic for ozone layer hazardous substances and mixtures No classification required
Cannot be classified
Category 1
Appendix C
(Normative Appendix)
Allocation of ozone layer hazard label elements
The allocation of ozone layer hazard label elements is shown in Table C.1. Table C.1 Allocation of ozone layer hazard label elements Category 1
Destroys
Ozone in the upper atmosphere, which is harmful to public
health and the environment
Not required in the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations. irKAoNrKAca
GB30000.29—201329—2013
Ozone Depletion Potential (ODP)
“These ozone depletion potentials are estimates based on current knowledge and will be reviewed and revised regularly.irkAoNrKAca
GB30000.29-—2013
A.2 Annex B of the Montreal Protocol is shown in Table A.2. Table A.2
Category I
Category 2
Category 3
Chemical formula
C,FCls
CF,CL4
Annex B of the Montreal Protocol
Substance code
CFC-13
CFC-111
CFC-112
CFC-211
CFC-212
CF C-213
CFC-214
CFC-215
CFC-216
CFC-217
Carbon Tetrachloride
1,1,1-Trifluoroethane
Ozone Depletion Potential (ODP)
These ODP values are estimates based on current knowledge and are subject to periodic review and revision. Non-1. 1.2 Trichloroethane.
See Table A, 3 in Annex C of the Montreal Protocol. Table A.3
Class I
Chemical formula
CHFCL4
CHF,Cl
CHCLCE
CHFCICF
CH,FCl
CH,FCle
G,HFCls||tt ||C,HF,CI,
C,H,CL
CHF,Cl
CFCF,CHCl2
CF.CICF,CHCIF
GH,F,Cl
Annex C of the Montreal Protocol
Substance Code
HCFC-214
HCFC-22
HCFC-31
HCFC121
HCFC-122
HCFC-123
HCFC-123
HCFC-124
HCFC-124
HCFC-131
HCFC-132
HCFC-133
HCFC-141
HCFC-1416
HCFC-142
HCFC-142b+
HCFC-151
HCFC-221
HCFC-222
HCFC-223
HCFC-224
HCFC-225
HCFC-22 5ca
HCFC-225cb
HCFC-226
HCFC-231
HCFC-232
HCFC-233
HCFC-234
HCFC-235
HCFC-241
HCFC-242
HCFC-243| |t t||Number of isomers
iKAoNiKAca-
GB30000.29—2013
Ozone depletion potential (ODP value)
0.01~0.04
0.02~0.08
0.02-0.06
0.02~~0.04
0,007-0.05|| tt | .09
0.008~0.10||tt| |0.0070.23
0.01~0.28
0.03~0.52
0.004~0.09
0.005~0.13
0.007~0.12
GB30000.29—2013
First Class
Second Class
Chemical FormulaWww.bzxZ.net
CH, FCI
C,HF,Br
C2H,FBr
CHsFBr
CHF,Bra
CH,FBr
CHF,Br
CHFBra
CHFBrs
Table A.3 (continued)
Substance code
HCFC-244
HCFC-251
HCFC-252
HCFC-253
HCFC-261
HCFC28R
HCFC-27
HBFC-22B
Number of isomers
Ozone depletion potential (ODP value)
0.009~~0.14
0. 001~0,01
0.005~0.04
0.003~-0.03
0.002~0,02
0.002~0.02
0.001~0.03
0,1~1,9
Second category
Third category
Chemical formula
CHF,Br||tt ||CaH,FBr
Table A.3 (continued)
Substance code
Methyl chloride
Number of isomers
"These ozone depletion potentials are estimates based on current knowledge and will be reviewed and revised regularly A.4 Annex E to the Montreal Protocol See Table A.4 Table A4 Annex E to the Montreal Protocol
Chemical weapons
Substance code| |tt||GB30000.29—2013
Ozone depletion potential (ODP value)
Ozone depletion potential (OLP value)
These ozone depletion potential values are estimated based on existing common knowledge and are subject to periodic review and replacement. The judgment logic for hazards to the ozone layer is shown in Figure B.1. Appendix B
(Informative Appendix)
Decision logic for ozone layer hazards
Substance: Is the substance listed in the Annex to the Montreal Protocol? Mixture: Does the mixture contain at least one component listed in the Annex to the Montreal Protocol, and the concentration is not less than 0.1%? Figure B.1 Decision logic for ozone layer hazardous substances and mixtures No classification required
Cannot be classified
Category 1
Appendix C
(Normative Appendix)
Allocation of ozone layer hazard label elements
The allocation of ozone layer hazard label elements is shown in Table C.1. Table C.1 Allocation of ozone layer hazard label elements Category 1
Destroys
Ozone in the upper atmosphere, which is harmful to public
health and the environment
Not required in the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations. irKAoNrKAca
GB30000.29—20131-Trifluoroethane
Ozone Depletion Potential (ODP)
These ODPs are estimates based on current knowledge and are subject to periodic review and revision. Not 1.1.2 Trichloroethane.
See Table A, 3 in Annex C of the Montreal Protocol. Table A.3
Class I
Chemical formula
CHFCL4
CHF,Cl
CHCLCE
CHFCICF
CH,FCl
CH,FCle
G,HFCls
C,HF,CI,
C,H,CL
CHF,Cl
CFCF,CHCl2
CF.CICF,CHCIF
GH,F,Cl
Annex C to the Montreal Protocol
Substance code
HC FC-214 | | tt | | HCFC-22 |
HCFC-133
HCFC-141
HCFC-1416
HCFC-142
HCFC-142b+
HCFC-151| | tt | |tt||HCFC-233
HCFC-234
HCFC-235
HCFC-241
HCFC-242
HCFC-243||tt ||Number of isomers
iKAoNiKAca-
GB30000.29—2013
Ozone depletion potential (ODP value)
0.01~0.04
0.02~0.08
0.02-0.06
0.02~~0.04
0,007-0.05
0.008~0.05
0.005~~0.07
0.0080.07
0.003~0.005
0.015~0.07
0.01 ~0.09
0,01-0.08
0.05~0.09
0.008~0.10
0.0070.23
0.01~0.28
0.03~0.52
0.004~0.09
0.00 5 ~ 0.13 | | tt | | 0.007 ~ 0.12 | | tt | |tt||CHsFBr
CHF,Bra
CH,FBr
CHF,Br
CHFBra
CHFBrs
Table A.3 (continued)
Substance code
HCFC-244
HCFC-251
HCFC-252
HCFC-253
HCFC-261
HCFC28R
HCFC-27
HBFC-22B
Number of isomers
Ozone depletion potential (OD P value)
0.009~~0.14
0.001~0,01
0.005~0.04
0.003~-0.03
0.002~0,02
0.002~0.02
0.001~0.03
0,1~1,9
Second category
Third category
Chemical formula
CHF,Br
CaH,FBr
Table A.3 (continued)
Substance code
Methyl chloride
Number of isomers||tt| |"These ozone depletion potential values are estimates based on current knowledge and will be reviewed and revised periodicallyA.4 Annex E to the Montreal ProtocolSee Table A.4 Table A4 Annex E to the Montreal Protocol
Chemical Weapons
Substance Code
GB30000.29—2013
Ozone Depletion Potential (ODP Value)
Ozone Depletion Potential (OLP Value)
These ozone depletion potential values are estimates based on current knowledge and will be reviewed and revised periodicallyrKAoNrKAca
GB30000.29-—2013
The decision logic for damage to the ozone layer is shown in Figure B.1. Appendix B
(Informative Appendix)
Decision logic for ozone layer hazards
Substance: Is the substance listed in the Annex to the Montreal Protocol? Mixture: Does the mixture contain at least one component listed in the Annex to the Montreal Protocol, and the concentration is not less than 0.1%? Figure B.1 Decision logic for ozone layer hazardous substances and mixtures No classification required
Cannot be classified
Category 1
Appendix C
(Normative Appendix)
Allocation of ozone layer hazard label elements
The allocation of ozone layer hazard label elements is shown in Table C.1. Table C.1 Allocation of ozone layer hazard label elements Category 1
Destroys
Ozone in the upper atmosphere, which is harmful to public
health and the environment
Not required in the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations. irKAoNrKAca
GB30000.29—20131-Trifluoroethane
Ozone Depletion Potential (ODP)
These ODPs are estimates based on current knowledge and are subject to periodic review and revision. Not 1.1.2 Trichloroethane.
See Table A, 3 in Annex C of the Montreal Protocol. Table A.3
Class I
Chemical formula
CHFCL4
CHF,Cl
CHCLCE
CHFCICF
CH,FCl
CH,FCle
G,HFCls
C,HF,CI,
C,H,CL
CHF,Cl
CFCF,CHCl2
CF.CICF,CHCIF
GH,F,Cl
Annex C to the Montreal Protocol
Substance code
HC FC-214 | | tt | | HCFC-22 |
HCFC-133
HCFC-141
HCFC-1416
HCFC-142
HCFC-142b+
HCFC-151| | tt | |tt||HCFC-233
HCFC-234
HCFC-235
HCFC-241
HCFC-242
HCFC-243||tt ||Number of isomers
iKAoNiKAca-
GB30000.29—2013
Ozone depletion potential (ODP value)
0.01~0.04
0.02~0.08
0.02-0.06
0.02~~0.04
0,007-0.05
0.008~0.05
0.005~~0.07
0.0080.07
0.003~0.005
0.015~0.07
0.01 ~0.09
0,01-0.08
0.05~0.09
0.008~0.10
0.0070.23
0.01~0.28
0.03~0.52
0.004~0.09
0.00 5 ~ 0.13 | | tt | | 0.007 ~ 0.12 | | tt | |tt||CHsFBr
CHF,Bra
CH,FBr
CHF,Br
CHFBra
CHFBrs
Table A.3 (continued)
Substance code
HCFC-244
HCFC-251
HCFC-252
HCFC-253
HCFC-261
HCFC28R
HCFC-27
HBFC-22B
Number of isomers
Ozone depletion potential (OD P value)
0.009~~0.14
0.001~0,01
0.005~0.04
0.003~-0.03
0.002~0,02
0.002~0.02
0.001~0.03
0,1~1,9
Second category
Third category
Chemical formula
CHF,Br
CaH,FBr
Table A.3 (continued)
Substance code
Methyl chloride
Number of isomers||tt| |"These ozone depletion potential values are estimates based on current knowledge and will be reviewed and revised periodicallyA.4 Annex E to the Montreal ProtocolSee Table A.4 Table A4 Annex E to the Montreal Protocol
Chemical Weapons
Substance Code
GB30000.29—2013
Ozone Depletion Potential (ODP Value)
Ozone Depletion Potential (OLP Value)
These ozone depletion potential values are estimates based on current knowledge and will be reviewed and revised periodicallyrKAoNrKAca
GB30000.29-—2013
The decision logic for damage to the ozone layer is shown in Figure B.1. Appendix B
(Informative Appendix)
Decision logic for ozone layer hazards
Substance: Is the substance listed in the Annex to the Montreal Protocol? Mixture: Does the mixture contain at least one component listed in the Annex to the Montreal Protocol, and the concentration is not less than 0.1%? Figure B.1 Decision logic for ozone layer hazardous substances and mixtures No classification required
Cannot be classified
Category 1
Appendix C
(Normative Appendix)
Allocation of ozone layer hazard label elements
The allocation of ozone layer hazard label elements is shown in Table C.1. Table C.1 Allocation of ozone layer hazard label elements Category 1
Destroys
Ozone in the upper atmosphere, which is harmful to public
health and the environment
Not required in the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations. irKAoNrKAca
GB30000.29—2013Cl
Annex C of the Montreal Protocol
Substance code
HCFC-214
HCFC-22
HCFC-31
HCFC121
HCFC-122
HCFC-123
HCFC-123
HCFC-124
HCFC-124
HCFC-131
HCFC-132
HCFC-133
HCFC-1 41
HCFC-1416
HCFC-142
HCFC-142b+
HCFC-151
HCFC-221
HCFC-222
HCFC-223
HCFC-224
HCFC-225
HCFC- 225ca
HCFC-225cb
HCFC-226
HCFC-231
HCFC-232|| tt||HCFC-233
HCFC-234
HCFC-235
HCFC-241
HCFC-242
HCFC-243
Number of isomers
iKAoNiKAca-
GB30000.29—2013
Ozone depletion potential (ODP value)
0.01~0.04
0.02~0.08
0.02-0.06
0.02~~ 0.04 | |0,01-0.08
0.05~0.09
0.008~0.10
0.0070.23
0.01~0.28
0.03~0.52| |tt||0.004~0.09
0.005~0.13
0.007~0.12
GB30000.29—2013
First category
Second category
Chemical formula
CH,FCI
C,HF,Br
C2H,FBr
CHsFBr
CHF,Bra
CH,FBr
CHF,Br
CHFBra
CHFBrs| |tt||Table A.3 (continued)
Substance code
HCFC-244
HCFC-251
HCFC-252
HCFC-253
HCFC-261
HCFC28R
HCFC-27
HBFC-22B
Number of isomers
Ozone depletion potential (ODP value)
0.009~~0.14
0.001~0,01
0.005~ 0.04
0.003~-0.03
0.002~0,02
0.002~0.02
0.001~0.03
0,1~1,9
Group 2
Group 3
Chemical formula
CHF,Br
CaH,FBr
Table A.3 (continued)
Substance code
Methyl chloride
Number of isomers
"These ozone depletion potentials are estimates based on current knowledge. It is subject to regular review and revision A.4 Annex E to the Montreal Protocol See Table A.4 Table A4 Annex E to the Montreal Protocol
Chemical weapons
Substance code
GB30000.29—2013
Ozone depletion potential (ODP value)
Ozone depletion potential (OLP value)
These ozone depletion potential values are estimated based on existing common knowledge and are subject to regular review and revision rKAoNrKAca
GB30000.29-—2013
The judgment logic for harming the ozone layer is shown in Figure B.1. Appendix B
(Informative Appendix)
Decision logic for ozone layer hazards
Substance: Is the substance listed in the Annex to the Montreal Protocol? Mixture: Does the mixture contain at least one component listed in the Annex to the Montreal Protocol, and the concentration is not less than 0.1%? Figure B.1 Decision logic for ozone layer hazardous substances and mixtures No classification required
Cannot be classified
Category 1
Appendix C
(Normative Appendix)
Allocation of ozone layer hazard label elements
The allocation of ozone layer hazard label elements is shown in Table C.1. Table C.1 Allocation of ozone layer hazard label elements Category 1
Destroys
Ozone in the upper atmosphere, which is harmful to public
health and the environment
Not required in the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations. irKAoNrKAca
GB30000.29—2013Cl
Annex C of the Montreal Protocol
Substance code
HCFC-214
HCFC-22
HCFC-31
HCFC121
HCFC-122
HCFC-123
HCFC-123
HCFC-124
HCFC-124
HCFC-131
HCFC-132
HCFC-133
HCFC-1 41
HCFC-1416
HCFC-142
HCFC-142b+
HCFC-151
HCFC-221
HCFC-222
HCFC-223
HCFC-224
HCFC-225
HCFC- 225ca
HCFC-225cb
HCFC-226
HCFC-231
HCFC-232|| tt||HCFC-233
HCFC-234
HCFC-235
HCFC-241
HCFC-242
HCFC-243
Number of isomers
iKAoNiKAca-
GB30000.29—2013
Ozone depletion potential (ODP value)
0.01~0.04
0.02~0.08
0.02-0.06
0.02~~ 0.04 | |0,01-0.08
0.05~0.09
0.008~0.10
0.0070.23
0.01~0.28
0.03~0.52| |tt||0.004~0.09
0.005~0.13
0.007~0.12
GB30000.29—2013
First category
Second category
Chemical formula
CH,FCI
C,HF,Br
C2H,FBr
CHsFBr
CHF,Bra
CH,FBr
CHF,Br
CHFBra
CHFBrs| |tt||Table A.3 (continued)
Substance code
HCFC-244
HCFC-251
HCFC-252
HCFC-253
HCFC-261
HCFC28R
HCFC-27
HBFC-22B
Number of isomers
Ozone depletion potential (ODP value)
0.009~~0.14
0.001~0,01
0.005~ 0.04
0.003~-0.03
0.002~0,02
0.002~0.02
0.001~0.03
0,1~1,9
Group 2
Group 3
Chemical formula
CHF,Br
CaH,FBr
Table A.3 (continued)
Substance code
Methyl chloride
Number of isomers
"These ozone depletion potentials are estimates based on current knowledge. It is subject to regular review and revision A.4 Annex E to the Montreal Protocol See Table A.4 Table A4 Annex E to the Montreal Protocol
Chemical weapons
Substance code
GB30000.29—2013
Ozone depletion potential (ODP value)
Ozone depletion potential (OLP value)
These ozone depletion potential values are estimated based on existing common knowledge and are subject to regular review and revision rKAoNrKAca
GB30000.29-—2013
The judgment logic for harming the ozone layer is shown in Figure B.1. Appendix B
(Informative Appendix)
Decision logic for ozone layer hazards
Substance: Is the substance listed in the Annex to the Montreal Protocol? Mixture: Does the mixture contain at least one component listed in the Annex to the Montreal Protocol, and the concentration is not less than 0.1%? Figure B.1 Decision logic for ozone layer hazardous substances and mixtures No classification required
Cannot be classified
Category 1
Appendix C
(Normative Appendix)
Allocation of ozone layer hazard label elements
The allocation of ozone layer hazard label elements is shown in Table C.1. Table C.1 Allocation of ozone layer hazard label elements Category 1
Destroys
Ozone in the upper atmosphere, which is harmful to public
health and the environment
Not required in the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations. irKAoNrKAca
GB30000.29—20133 (continued)
Substance code
Methyl chloride
Number of isomers
"These ozone depletion potentials are estimates based on current knowledge and will be reviewed and revised regularlyA.4 Annex E to the Montreal ProtocolSee Table A.4Table A4 Annex E to the Montreal Protocol
Chemical weapons
Substance code
GB30000.29—2013||t t||Ozone depletion potential (ODP value)
Ozone depletion potential (OLP value)
These ozone depletion potential values are estimated based on existing common knowledge and are subject to periodic review and replacement. The judgment logic for ozone layer damage is shown in Figure B.1. Appendix B
(Informative Appendix)
Judgment logic for ozone layer damage Logic of judgment
Substance: Is the substance listed in the Annex to the Montreal Protocol? Mixture: Does the mixture contain at least one component listed in the Annex to the Montreal Protocol, and the concentration is not less than 0.1%? Figure B.1 Logic of judgment for substances and mixtures that endanger the ozone layer No classification
Cannot be classified
Category 1
Appendix C
(Normative Appendix)
Allocation of label elements that endanger the ozone layer
The allocation of label elements that endanger the ozone layer is shown in Table C.1. Table C.1 Allocation of label elements that endanger the ozone layer Category 1
Ozone in the upper atmosphere is damaged, which endangers public
health and the environment
Not required in the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations.irKAoNrKAca
GB30000.29—20133 (continued)
Substance code
Methyl chloride
Number of isomers
"These ozone depletion potentials are estimates based on current knowledge and will be reviewed and revised regularlyA.4 Annex E to the Montreal ProtocolSee Table A.4Table A4 Annex E to the Montreal Protocol
Chemical weapons
Substance code
GB30000.29—2013||t t||Ozone depletion potential (ODP value)
Ozone depletion potential (OLP value)
These ozone depletion potential values are estimated based on existing common knowledge and are subject to periodic review and replacement. The judgment logic for ozone layer damage is shown in Figure B.1. Appendix B
(Informative Appendix)
Judgment logic for ozone layer damage Logic of judgment
Substance: Is the substance listed in the Annex to the Montreal Protocol? Mixture: Does the mixture contain at least one component listed in the Annex to the Montreal Protocol, and the concentration is not less than 0.1%? Figure B.1 Logic of judgment for substances and mixtures that endanger the ozone layer No classification
Cannot be classified
Category 1
Appendix C
(Normative Appendix)
Allocation of label elements that endanger the ozone layer
The allocation of label elements that endanger the ozone layer is shown in Table C.1. Table C.1 Allocation of label elements that endanger the ozone layer Category 1
Ozone in the upper atmosphere is damaged, which endangers public
health and the environment
Not required in the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations.irKAoNrKAca
GB30000.29—2013
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