GB 30000.15-2013 Chemical Classification and Labelling Specification Part 15: Oxidizing Solids GB30000.15-2013 |tt||Standard compression package decompression password: www.bzxz.net
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of oxidizing solids. This part applies to the classification and labeling of oxidizing solids in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals.
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended.
The expected structure of GB30000 "Specifications for Classification and Labelling of Chemicals" and the national standards to be replaced are:
———Part 1: General (replaces GB13690-2009);
———Part 2: Explosives (replaces GB20576-2006);
———Part 3: Flammable gases (replaces GB20577-2006);
———Part 4: Aerosols (replaces GB20578-2006);
———Part 5: Oxidizing gases (replaces GB20579-2006);
———Part 6: Gases under pressure (replaces GB20580-2006);
———Part 7: Flammable liquids (replaces GB20581-2006);
———Part 8: Flammable solids (replaces GB 20582-2006);
———Part 9: Self-reactive substances and mixtures (replaces GB 20583-2006);
———Part 10: Pyrophoric liquids (replaces GB 20585-2006);
———Part 11: Pyrophoric solids (replaces GB 20586-2006);
———Part 12: Self-heating substances and mixtures (replaces GB 20584-2006);
———Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB 20587-2006);
———Part 14: Oxidizing liquids (replaces GB 20589-2006);
——Part 15: Oxidizing solids (replaces GB 20590-2006);
——Part 16: Organic peroxides (replaces GB 20591-2006);
——Part 17: Corrosive to metals (replaces GB 20588-2006);
——Part 18: Acute toxicity (replaces GB 20592-2006);
——Part 19: Skin corrosion/irritation (replaces GB 20593-2006);
——Part 20: Serious eye damage/eye irritation (replaces GB 20594-2006);
——Part 21: Respiratory or skin sensitization (replaces GB 20595-2006);
———Part 22: Germ cell mutagenicity (replaces GB 20596-2006);
———Part 23: Carcinogenicity (replaces GB 20597-2006);
———Part 24: Reproductive toxicity (replaces GB 20598-2006);
———Part 25: Specific target organ toxicity single exposure (replaces GB 20599-2006);
———Part 26: Specific target organ toxicity repeated exposure (replaces GB 20601-2006);
———Part 27: Aspiration hazard;
———Part 28: Hazard to the aquatic environment (replaces GB 20602-2006);
———Part 29: Hazard to the ozone layer;
———Part 30: Warning signs for chemical workplaces.
This part is part 15 of GB 30000.
This part was drafted in accordance with the rules given in GB/T 1.1-2009.
This part replaces GB 20590-2006 "Safety Specification for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Oxidizing Solids".
This part is consistent with the relevant technical content of the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition).
Compared with GB20590-2006, the main technical content changes of this part are as follows:
Ⅰ
GB30000.15-2013
———The name of the standard has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals—Part 15: Oxidizing solids" and the English name is "Rules for classification and labelling of chemicals—Part 15: Oxidizing solids";
———The scope of Chapter 1 has been modified, "Warning label" has been changed to "label", and "Warning statement" has been deleted;
———The introductory words of Chapter 2 "Normative references" have been modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" has been added as a reference document;
———The introductory words of Chapter 3 "Terms and Definitions" have been added;
———The "decision logic diagram" and "guidance" in Figure 1 of Chapter 5 are made informative Appendix A;
———The original Chapter 7 is deleted, and Table 3 of the original Chapter 7 is modified as Normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition);
———The original Chapter 6, Chapter 7 and Chapter 8 are modified and integrated into Chapter 6 according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition); the original Table 2 is modified as Normative Appendix C; ———The
original Chapter 8 is deleted, and the relevant "hazard statements" and "precautionary statements" are made as informative Appendix D; ———Informative
Appendix E "label examples" is added.
This part is proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251).
Drafting units of this part: China Chemical Economic and Technological Development Center, Shanghai Research Institute of Chemical Industry, Zhejiang Research Institute of Chemical Industry Co., Ltd., Pony Testing Technology Co., Ltd., Huafeng Group Co., Ltd.
The main drafters of this part are: Wang Xiaobing, Fan Bin, Yang Ting, Wang Gaosheng, Song Wei, Zhang Chunhui, Cao Chenman, Zhu Yan, Cao Mengran, Zhang Hua, Wen Tao. The
previous versions of the standards replaced by this part are:
———GB 20590—2006.
The following documents are indispensable for the application of this document. For all dated referenced documents, only the dated versions apply to this document. For all undated referenced documents, the latest versions (including all amendments) apply to this document.
GB6944—2012 Classification and Product Name Numbering of Dangerous Goods
GB13690 General Rules for Classification and Hazard Communication of Chemicals
United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)
United Nations Manual of Tests and Criteria for the Transport of Dangerous Goods (Fifth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition)
International Maritime Organization Code for Solid Bulk Cargoes (BC Code) 2005

ICS13.300
National Standard of the People's Republic of China
GB30000.15—2013
Replaces GB20590-2006
Rules for classification and labelling of chemicals-Part 15:
Rules for classification and labelling of chemicals-Part 15: Oxidizing solids
2013-10-10 Issued
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China Standardization Administration of China
2014-11-01 Implementation
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. The expected structure of GB30000 Chemical Classification and Labeling Specification and the national standards to be replaced are: Part 1: General rules (replace GB13690-2009): Part 2: Explosives (replace GB20576-2006): Part 3: Flammable gases (replace GB20577-2006): Part 4: Aerosols (replace GB205 78-2006): Part 5: Oxidizing gases (replaces GB20579-2006); Part 6: Gases under pressure (replaces GB20580-2006): Part 7: Flammable liquids (replaces GB20581-2006): Part 8: Flammable solids (replaces GB20582-2006); Part 9: Self-reactive substances and mixtures (replaces GB20583-2006); Part 10: Pyrophoric liquids (replaces GB20585-2006); Part 11: Pyrophoric solids (replaces GB20586-2006): Part 12: Self-heating substances and mixtures (replaces GB20584-2006): Part 13: Substances and mixtures which, in contact with water, emit flammable gases Compounds (replace GB20587-2006); Part 14: Oxidizing Liquids (replace GB20589-2006); Part 15: Oxidizing Solids (replace GB20590-2006); Part 16: Organic Peroxides (replace GB20591-2006); Part 17: Metal Corrosives (replace GB20588-2006); Part 18: Acute Toxicity (replace GB20592-2006); Part 19: Skin Corrosion/Irritation (replace GB20593-2006); Part 20: Serious Eye Damage/Eye Irritation (replace GB20594-2006); Part 21: Respiratory or Skin Sensitization (replace GB20595-2 006); Part 22: Germ cell mutagenicity (replaces GB20596-2006); Part 23: Carcinogenicity (replaces GB20597-2006): Part 24: Reproductive toxicity (replaces GB20598-2006); Part 25: Specific target organ toxicity single exposure (replaces GB205992006): Part 26: Specific target organ toxicity repeated exposure (replaces GB20601-2006): Part 27: Inhalation hazard:
Part 28: Hazards to the aquatic environment (replaces GB20602-2006): Part 29: Hazards to the ozone layer;
Part 30: Warning signs for chemical workplaces. This part is Part 15 of GB30000
This part was drafted in accordance with the rules given in GB/T1.12009. GB30000.15—2013
This part replaces GB20590—2006 "Safety Rules for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Oxidizing Solids". This part is consistent with the technical content related to the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (GHS) (Fourth Revised Edition). Compared with GB205902006, the main technical content changes of this part are as follows: 1
GB30000.15-—2013
The standard name has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals-Part 15: Oxidizing Solids", and the English name is \Rules for classification and labelling of chemicals-Part 15: Oxidizing Solids". solids\; Modified the scope of Chapter 1, changed "warning label" to "label", deleted "warning statement"; modified the introductory words of Chapter 2 "normative references", added "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" as a reference document, added the introductory words of Chapter 3 "Terms and Definitions"; made Figure 1 "Decision Logic Diagram" and "Guide" of Chapter 5 as informative Appendix A; deleted the original Chapter 7, and modified Table 3 of the original Chapter 7 as normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition):
According to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition), the original Chapter 6, Chapter 7, and Chapter 8 were modified and integrated into Chapter 6: the original Table 2 was modified as normative Appendix C; the original Chapter 8 was deleted, and the relevant "Hazard Statements" and "Precautionary Statements" contents were included as informative Appendix D; the informative Appendix E "Label Examples" was added. This part was proposed and coordinated by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251). Drafting units of this part: China Chemical Economic and Technological Development Center, Shanghai Research Institute of Chemical Industry, Zhejiang Research Institute of Chemical Industry Co., Ltd., PONY Testing Technology Co., Ltd., Huafeng Group Co., Ltd. The main drafters of this part: Wang Xiaobing, Fan Bin, Yang Ting, Wang Gaosheng, Song Wei, Zhang Chunhui, Cao Chenman, Zhu Yan, Cao Mengran, Zhang Hua, and Wen Tao. This The previous versions of the standard replaced by this part are as follows: GB20590—2006
1 Scope
Chemical Classification and Labelling Specification Part 15: Oxidizing Solids
GB30000.15—2013
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of oxidizing solids. This part applies to the classification and labeling of oxidizing solids in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (hereinafter referred to as GHS).
2 Normative references
The following documents are indispensable for the application of this document. For all referenced documents with dates, only the date is noted. The latest version of the date applies to this document. For any undated referenced document, the latest version (including all amendments) applies to this document. GB6944:2012 Classification and name number of dangerous goods GB13690 General Rules for Classification and Hazard Communication of Chemicals United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (4th revised edition) United Nations "Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria (5th revised edition) United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (17th revised edition) International Maritime Organization Solid Bulk Cargoes Code (BC Code) 2005 3 Terms and Definitions
The terms and definitions defined in GB13690 and the following terms and definitions apply to this document. 3.1
Oxidizing solids
Solids that are not necessarily flammable, but usually release oxygen and may cause or promote the combustion of other substances. 4 Classification standards
4.1 The general principles for the classification and labeling of oxidizing solids are shown in GB13690. 4.2 Oxidizing solids are classified according to Test 0.1 in Part 3, 34.4.1 of the United Nations Recommendations on the Transport of Dangerous Goods: Manual of Tests and Criteria (Fifth Revised Edition) (hereinafter referred to as the "Manual of Tests and Criteria"), see Table 1. Table 1 Classification of oxidizing solids
Any substance or mixture that shows a mean burning time less than the mean burning time of a mixture of potassium bromate and cellulose in a mass ratio of 3:2 (mass ratio) when the test sample (or mixture) is tested with a mixture of cellulose in a ratio of 4:1 or 1:1 (mass ratio)1
GB30000.15—2013
Table 1 (continued)
Any substance or mixture which, when tested with a 4:1 or 1:1 (mass ratio) of the test sample (or mixture) and cellulose, exhibits a mean burning time equal to 2
or less than the mean burning time of a 2:3 (mass ratio) mixture of potassium bromate and cellulose and which does not meet the criteria for category 1
Any substance or mixture which, when tested with a 4:1 or 1:1 (mass ratio) of the test sample (or mixture) and cellulose, exhibits a mean burning time equal to or less than the mean burning time of a 3:7 (mass ratio) mixture of potassium bromate and cellulose and which does not meet the criteria for categories 1 and 2
Some oxidizing solids may also present an explosion hazard under certain conditions (e.g. when stored in large quantities). For example, some types of ammonium nitrate may cause an explosion hazard under extreme conditions and this hazard may be assessed using the "welding resistance test (BC Code Amnex 3. Test 5), see IMO Solid Bulk Cargoes Code, 2005". This should be appropriately noted in the safety technical instructions. * For classification tests of solid substances or mixtures, the test should be conducted using the substance or mixture in the form in which it is supplied. For example, if the physical form of a chemical is different from that in a previous test for the purpose of supply or transport, and it is considered likely that this form will change substantially, the substance or mixture should be tested in the new form. 5 Decision logic and guidance Decision logic and guidance are provided for reference only before and during the development of the decision logic. Chapter 4. 6 Labeling
6.1 Overview
6.1.1 For the handling of oxidizing solids, the hazard categories are listed with designated pictograms. Special recommendations are given to the personnel responsible for classification in the order of using decision logic and hazard statements. The United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (Seventeenth Revised Edition) (hereinafter referred to as the "Model Regulations") stipulates that the hazard types or categories covered should be listed on the label with the designated corresponding graphic symbols for each category. The allocation of label elements for oxidizing solids is shown in Appendix B. 6.1.2 See Appendix C for the labeling of oxidizing solids. 6.1.3 The information required on the label includes hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and supplier logos, etc. Note: For other label elements that have not yet been standardized, such as precautionary statements that need to be included on the label, the competent authorities may also require additional information, and the supplier may also add Supplementary information.
6.2 Hazard pictograms
Hazard pictograms should use black symbols with a white background, and the red frame should be wide enough to be eye-catching. The colors, numbers and minimum sizes of hazard pictograms and graphic symbols specified in the Model Regulations are shown in Appendix B. 6.3 Signal words
Signal words are words used on labels to indicate the relative severity of hazards and to alert readers to potential hazards. For oxidizing solids, the signal words "Danger" and "Warning" are used. 6.4 Hazard statements
Hazard statements are phrases assigned to a hazard class and category that describe the hazardous properties of a hazardous product and, where appropriate, its degree of hazard. See Appendix D for hazard statements for oxidizing solids. 6.5 Precautionary statements
GB30000.15—2013
Precautionary statements are a Words (and/or pictograms) describing the recommended measures to minimize or prevent adverse effects resulting from exposure to hazardous products or improper storage or handling of hazardous products. To meet the requirements, there are 5 types of precautionary statements: general, prevention, emergency, storage and disposal. For precautionary statements for oxidizing solids, see Appendix D6.6 Product identifiers
6.6.1 The product identifier should be used on the label and should be consistent with the product identifier used on the chemical safety data sheet. If a substance or mixture is included in the "Model Regulations", the correct United Nations shipping name should also be used on the package. 6.6.2 The label should include the chemical name of the substance. For mixtures or alloys, when acute toxicity, skin or respiratory sensitization or specific target organ toxicity appear on the label, the label should include the chemical composition of all ingredients or alloying elements that may cause these hazards. The competent authority may also require that the chemical names of all ingredients or alloying elements that may contribute to the hazard of the mixture or alloy be listed on the label. 6.7
Supplier identification
The label should provide the name and telephone number of the manufacturer or supplier of the substance or mixture. 6.8 Label examples
For examples of labels for oxidizing solids, see Appendix EirkAoNrkAca
.
GB30000.15—2013
A.1 Decision logic
Appendix A
(Informative Appendix)
Decision logic and guidance
For the classification of oxidizing solids, the test method 0.1 described in Part 3, 34.4.1 of the Manual of Tests and Criteria should be used. Classification is carried out according to decision logic diagram A.1.
The substance/mixture is a solid
Does it ignite or burn when tested with a sample to cellulose ratio of 4:1 or 1:1 by mass?
Does its sample, in the 4:1 or 1:1 mixture of sample and cellulose tested, exhibit a mean burning time equal to or less than the mean burning time of a 3:7 mixture, by mass, of potassium bromate and cellulose? Does its sample, in the 4:1 or 1:1 mixture, by mass, of sample and cellulose tested, exhibit a mean burning time equal to or less than the mean burning time of a 2:3 mixture, by mass, of potassium bromate and cellulose? Does its sample, in the 4:1 or 1:1 mixture, by mass, of sample and cellulose tested, exhibit a mean burning time less than the mean burning time of a 3:2 mixture, by mass, of potassium bromate and cellulose? Figure A1 Decision logic for oxidizing solids
Not this category
Not this category
Category 3
Category 2
Category 1
A.2 GuidanceWww.bzxZ.net
GB30000.15—2013
A.2.1 Transport and use experience has shown that substances and mixtures have oxidizing properties, which is an important additional factor when considering classification in this category. If there is a disagreement between test results and known experience, the judgment based on known experience should take precedence over the test results. A, 2.2 Organic substances or mixtures are not subject to this classification procedure if: the substance or mixture does not contain oxygen, fluorine or chlorine; or a)
the substance or mixture contains oxygen, fluorine or chlorine, but these elements are only chemically bonded to carbon or hydrogen. b)
Inorganic substances or mixtures are not subject to this classification procedure if they do not contain oxygen or halogen atoms. TKAONTKAca-
GB30000.15—2013
The allocation of label elements is shown in Table B.1.
Category 1
Can cause combustion or
explosion: strong oxidizer
Category 2
Can intensify combustion:
Oxidizer
Appendix B
(Normative Appendix)
Allocation of label elements
Oxidizing solidsAllocation of label elements
Oxidizing solids
Category 3
Can intensify combustion;
Oxidizer
In the "Model Regulations":
1) Color of graphic symbols
·Graphic symbol (flame on a ring
): black;
·Background·yellow.
2) The number "5.1" in the figure refers to the first item of the fifth category in GB6944-2012.
3) The minimum size of the graphic sign for cargo transportation is 100mm×
100mm.
Appendix C
(Normative Appendix)
Classification standards and label elements for oxidizing solids The classification standards and label elements for oxidizing solids are shown in Table C.1. Table C.1 Classification standards and label elements for oxidizing solids1
Hazard category
Any substance or mixture which, when the test sample (or mixture) is wetted with cellulose in the ratio of 4:1 or 1 (mass ratio) to cellulose, exhibits a mean burning time equal to or less than the mean burning time of a mixture of potassium bromate and cellulose in the ratio of 3:20 (mass ratio) by mass when tested
Any substance or mixture which, when the test sample (or mixture) is wetted with cellulose or cellulose in the ratio of 3:1 (mass ratio) to cellulose, exhibits a mean burning time equal to or less than the mean burning time of a mixture of potassium bromate and cellulose in the ratio of 3:7 (mass ratio) by mass when tested
Any substance or mixture which, when the test sample (or mixture) is wetted with cellulose or cellulose in the ratio of 3:20 (mass ratio) to cellulose, exhibits a mean burning time equal to or less than the mean burning time of a mixture of potassium bromate and cellulose in the ratio of 3:7 (mass ratio) by mass and does not meet the criteria of categories 1 and 2
Graphic symbol
Signal word
Hazard statement
Signal word
Hazard statement period
Graphic symbol
Signal word
Hazard statement period
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Label elements
GB30000.15—2013
Can cause combustion or explosion: Strong oxidizer
Can add burning oxidizer||tt| |May intensify combustion; oxidizer
GB30000.15—2013
D.1 Overview
Appendix D
(Informative Appendix)
Hazard statements and precautionary statements for oxidizing solids D. 1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for oxidizing solids. It lists the recommended hazard statements and precautionary statements for each hazard class and hazard category of oxidizing solids. See GB13690. D.1.2 Coding of hazard statements:
D.1.2.1 Coding of hazard statements is provided in Annex 3 of GHS. D.1.2.2 Each hazard statement is assigned a specific alphanumeric code consisting of one letter and three digits, as follows:
The letter "H" (stands for "hazard statement"); a)
The first digit represents the type of hazard referred to by the hazard statement in the different part numbers, as follows: b)
"2\ represents physical hazard;
\3\ represents health hazard;
-"4\ represents environmental hazard;
c) The last two digits correspond to the serial number of the hazard caused by the inherent properties of the substance or mixture, such as: explosiveness (codes 200 to 210), flammability (codes 220 to 230), etc. D.1.2.3 Unless otherwise specified, all specified hazard statements shall appear on the label. The competent authority may specify the order in which the hazard statements appear on the label. In addition, when two or more hazard statements are provided in a combined hazard statement, the competent authority may specify whether the combined hazard statement or the corresponding individual statements shall be included on the label, or whether it shall be left to the discretion of the manufacturer/supplier. D.1.3 Precautionary statements shall be included on the label together with the harmonized hazard communication elements (pictograms, signal words and hazard statements). Additional supplementary information, such as instructions for use, may also be provided at the discretion of the manufacturer, supplier and/or competent authority. D.1.3.1 See Annex 3 of the GHS for the codes of precautionary statements. D.1.3.2 Coding of precautionary statements:
D.1.3.2.1 Each precautionary statement is assigned a unique alphanumeric code consisting of 1 letter and 3 numbers: as follows
a) the letter "P\ (standing for "precautionary statement\"); b) the first number, representing the type of precautionary statement, as follows: "1" for general precautionary statement;
"2\ for prevention precautionary statement;
*3" for emergency precautionary statement;
"4" for storage precautionary statement;
"5" for disposal precautionary statement;
c) the last 2 numbers (corresponding to the serial number of the precautionary statement). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used in place of the precautionary statement text.
D.2 General precautionary statements
General precautionary measures should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels under the given conditions (see Table D.1). Table D.1
General precautionary statements
General public
Production workers
Supplementary information
Labels, supplementary label information
Labels, supplementary label information, safety data sheets, workplace signs
Precautionary statements for oxidizing solids
Precautionary statements for oxidizing solids Category 1 are shown in Table D.2GB30000.15—2013
General precautionary statements
If medical attention is required: Keep product container or label with you and out of reach of children.
Read label before use.
TrKANTKAca-1
General precautionary statements
General public
Production workers
Supplementary information
Labels, supplementary label information
Labels, supplementary label information, safety data sheets, workplace signs
Precautionary statements for oxidizing solids
Precautionary statements for Category 1 oxidizing solids are shown in Table D.2GB30000.15—2013
General precautionary statements
If medical attention is required: Keep product container or label with you and keep out of reach of children.
Read label before use.
TrKANTKAca-1
General precautionary statements
General public
Production workers
Supplementary information
Labels, supplementary label information
Labels, supplementary label information, safety data sheets, workplace signs
Precautionary statements for oxidizing solids
Precautionary statements for Category 1 oxidizing solids are shown in Table D.2GB30000.15—2013
General precautionary statements
If medical attention is required: Keep product container or label with you and keep out of reach of children.
Read label before use.
TrKANTKAca-
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