This standard specifies the product classification, technical requirements, test methods, inspection rules, marking, packaging, transportation and storage of paper-based composite materials for aseptic packaging of liquid foods. This standard applies to materials with base paper as the base, extruded and compounded with plastic, aluminum foil or other barrier materials, etc., for use in roll-fed aseptic filling machines to package liquid foods, and composite materials with base paper as the base, extruded and compounded with plastic, aluminum foil or other barrier materials, etc., for aseptic packaging of liquid foods, which are supplied in the form of semi-finished packaging containers. GB 18192-2000 Paper-based composite materials for aseptic packaging of liquid instruments GB18192-2000 Standard download decompression password: www.bzxz.net
This standard specifies the product classification, technical requirements, test methods, inspection rules, marking, packaging, transportation and storage of paper-based composite materials for aseptic packaging of liquid foods. This standard applies to materials with base paper as the matrix, extruded and compounded with plastic, aluminum foil or other barrier materials, for use in roll-fed aseptic filling machines to package liquid foods, and composite materials with base paper as the matrix, extruded and compounded with plastic, aluminum foil or other barrier materials, for aseptic packaging of liquid foods, which are supplied in the form of semi-finished packaging containers.

GB 18192—2000
The mandatory clauses of this standard are:
1. Quantitative deviation of the inner plastic film in Table 1 of 5.2.1 of the standard; 2. Physical properties and mechanical properties in 5.4 of the standard; 3. Hygiene index in 5.5 of the standard.
The strips on the inner surface of the liquid food packaging box made of this material that contact the food surface, the box cover that contacts the food, and all materials that contact the food must comply with the relevant national health standards or regulations. Appendix A, Appendix B, and Appendix C of this standard are all appendices of the standard. This standard is proposed by China National Packaging Corporation. This standard is under the jurisdiction of the National Packaging Standardization Technical Committee. The drafting units of this standard are: China Standardization Association, National Packaging Improvement Office, and Tetra Pak China Co., Ltd. The main drafters of this standard are: Li Shuliang, Li Shiyuan, Lan Qintang, Xu Yaoming, and Wang Li. The drafting units of this standard are: Danyang Composite Packaging Material Factory, Shanghai Office of SIG Combibloc Co., Ltd., Shanghai Zhongbao International Paper Co., Ltd., Guangdong Yuandong Food Packaging Machinery Co., Ltd., etc. 406
1 Scope
National Standard of the People's Republic of China
Paper based laminated material using foraseptic package of liquid foodGB18192—2000
This standard specifies the product classification, technical requirements, test methods, inspection rules, marking, packaging, transportation and storage of paper based laminated materials for aseptic packaging of liquid food.
This standard applies to materials with base paper as the base material, extruded and laminated with plastic, aluminum foil or other barrier materials, etc., for use in roll-fed aseptic filling machines to package liquid food, and composite materials with base paper as the base material, extruded and laminated with plastic, aluminum foil or other barrier materials, etc., supplied in the form of semi-finished packaging containers, for aseptic packaging of liquid food. 2 Referenced Standards
The provisions contained in the following standards constitute the provisions of this standard by reference in this standard. When this standard was published, the versions shown were all valid. All standards are subject to revision. Parties using this standard should explore the possibility of using the latest versions of the following standards. GB191-2000 Pictorial markings for packaging storage and transportation
GB/T1038--1970 Test method for air permeability of plastic films GB/T2679.3-1996 Determination of stiffness of paper and paperboard GB/T5009.60-1996 Analysis method for hygienic standards of polyethylene, polystyrene and polypropylene molded products for food packaging GB/T6673-1986 Determination of length and width of plastic films and sheets GB/T8808-1988 Peel test method for soft composite plastic materials GB9687-1988 Hygienic standard for polyethylene molded products for food packaging GB9683-1988 Hygienic standard for composite food packaging bags GB/T13022-1991 Test method for tensile properties of plastic films 3 Definitions
This standard adopts the following definitions.
3.1 Liquid food
Includes liquids, liquids with particles, sauces, etc. that can flow in pipes. 3.2 Aseptic packaging
Packaging sterilized food (beverages, dairy products, etc.) in a sterile environment and sealing it in a sterilized container to obtain a longer shelf life without preservatives and refrigeration. 3.3 Overlap
The outer surface of the material is in contact with the inner surface of the material that contacts food. 3.4 Butt joint
The inner surface of the material that contacts food is in contact. Approved by the State Administration of Quality and Technical Supervision on September 26, 2000, and implemented on March 1, 2001
4 Product classification
GB18192.---2000
Products are divided into two categories according to the supply status: roll form and semi-finished product form. 5 Technical requirements
5.1 Appearance quality
5.1.1 No pollution, no dust.
5.1.2 The printed pattern is clear and complete, without obvious deformation and color difference, and without incompleteness and misprinting. 5.1.3 The inner and outer surfaces are flat, without wrinkles, holes, cracks, bubbles, and aluminum foil and plastic film are not damaged. 5.1.4 The indentation line is straight and without cracks
5.1.5 The materials supplied in the form of rolls should be rolled with a round core, smooth surface, uniform tightness, neat end faces, and no burrs. 5.2 Dimension and quality deviation
5.2.1 The dimension and quality deviation of the two types of supplied materials shall comply with the provisions in Table 1. Table 1 Dimension and quality deviation of supplied materials
Width deviation
Roll inner diameter deviation
Inner plastic film quantitative
Dimension deviation
Dimension and quality deviation
≥28 g/m2
The dimensional deviation of the printed pattern shall comply with the provisions in Table 2, 5.2.21
Table 2 Dimensional deviation of printed pattern
Overprint accuracy
Overprint of indentation line and printed pattern
Cutting position
Cursor overprint spacing
5.3 Number and quality of joints
Deviation, mm
Material supplied in roll form
Material supplied in roll form
Material supplied in two forms
Material supplied in semi-finished product form
Material supplied in two forms
Material supplied in two forms
Material supplied in roll form
Material supplied in roll form
The number of joints in each roll shall not exceed 3 per 1000m. The joints should be aligned and aligned with the pattern, and there should be obvious markings; the joints should be firmly connected and cannot be disconnected during use. The distance between adjacent joints should not be less than 25m. The distance between the joint and the end of each roll should not be less than 25m.
5.4 Physical and mechanical properties
The physical and mechanical properties should comply with the requirements in Table 3. Table 3 Physical and mechanical properties
Tensile strength, MPa
Sealing strength, N/15mm
Peeling strength of inner plastic film, N/15mm
Adhesion between the composite plastic film and paper, %
Longitudinal ≥30
Transverse ≥20
Overlap ≥60
Butt ≥15
Oxygen permeability, cm2/(m2·24 h·0.1MPa) Stiffness\,mN/38mm
GB18192-2000
Table 3 (end)
Container capacity <500mL
Longitudinal ≥120
500mL≤Container capacity ≤1000mL
Longitudinal ≥160
Transverse ≥64
Container capacity>1000 mL
1) Composite materials suitable for brick-type and roof-type packaging containers. 5.5 Hygienic indicators
5.5.1 The overall hygienic indicators of the material shall comply with the provisions of GB9683. 5.5.2 The hygienic indicators of the inner layer polyethylene material shall comply with the provisions of GB9687. 6 Inspection method
Appearance quality shall be inspected by visual inspection under natural light in accordance with the provisions of 5.1. 6.1
The inner diameter deviation and size deviation of the roll shall be measured and tested with a vernier caliper. 6.2
6.3 The quantity of the inner plastic film shall be tested in accordance with the provisions of Appendix A. The width deviation of the roll shall be tested in accordance with the provisions of GB/T6673. 6.4
6.5 The tensile strength shall be tested in accordance with the provisions of GB/T13022. 6.6 The sealing strength shall be tested in accordance with the provisions of Appendix B. 6.7
The peel strength of the inner plastic film shall be tested in accordance with the provisions of GB/T8808. The adhesion between the composite plastic film and paper shall be tested in accordance with the provisions of Appendix C. The oxygen permeability shall be tested in accordance with the provisions of GB/T1038. 6.9
The stiffness shall be tested in accordance with the provisions of GB/T2679.3. The hygienic indicators of the inner plastic film shall be tested in accordance with the method specified in GB/T5009.60. The overall hygiene index shall be inspected according to the method specified in GB/T5009.60. Longitudinal ≥200
Horizontal ≥80
The overprint accuracy, the registration of the indentation line and the printed pattern and the slitting position shall be inspected with a 10x scale magnifying glass. The cursor overprint spacing shall be measured and inspected with a vernier caliper. Inspection rules
The inspection of products is divided into outgoing inspection and type inspection. 7.1
7.2 Factory inspection
7.2.1 The outgoing inspection items shall be carried out in accordance with the provisions in Table 4. Table 4 Factory inspection items
Appearance quality
Dimensional deviation
Dimensional deviation of printed pattern
Number of joints per roll
Tensile strength
Sealing strength
Technical requirements
5.1
5.2.1 Table 1
5.2.2 Table 2
5.4 Table 3
5.4 Table 3
Test method
6.13,6.14
Check the joint mark of the manufacturer
7.2.2 Group batch for factory inspection
GB 18192—2000
The same variety, the same specification, and the same-one delivery are considered as a batch. For products delivered in the form of semi-finished containers, each batch shall not exceed 2,000,000. 7.2.3 Sampling method
7.2.3.1 For products delivered in the form of rolls, sample rolls (not less than 2 rolls) shall be firstly selected at a ratio of 2%, and 2 sample sections shall be randomly selected from each sample roll along the length direction with a spacing of not less than 25m for various inspections. The length of the sample section shall not be less than 3m, and the width shall be the entire width. When the sample roll already has a joint, it is allowed to cut the sample section at the joint, and each complete printed pattern in each sample section shall be a sample.
7.2.3.2 For products delivered in the form of semi-finished containers, samples shall be randomly selected at a rate of 0.01% (not less than 50). 7.2.3.3 For the tensile strength and sealing strength test items in Table 4, one group of samples shall be selected for inspection each time according to the regulations. For other inspection items, 100% of the samples shall be inspected.
7.2.4 Product quality determination
7.2.4.1 Inspect or review the indicators in Table 4. When each sample of tensile strength, sealing strength and other items meets the technical requirements, the batch of products shall be qualified.
7.2.4.2 When the various indicators in Table 4 are tested, if more than one (including one) of the tests do not meet the technical requirements, double the samples for re-examination according to the provisions of 7.2.3:
a) When more than one (including one) of the tensile strength and sealing strength test items in Table 4 do not meet the technical requirements, the batch of products is unqualified. When more than two (including two) samples of other items do not meet the technical requirements, the batch of products is unqualified; b) When one sample other than tensile strength and sealing strength in Table 4 does not meet the technical requirements, the batch of products is still qualified. 7.3 Type inspection
7.3.1 Type inspection should be carried out in any of the following situations: a) When the variety or source of raw materials, product structure, or production process changes; b) When production is resumed after suspension for more than 6 months; c) When continuous production is completed for one year.
7.3.2 Type inspection items shall be carried out in accordance with the provisions of Table 5. Table 5 Type inspection items
Appearance quality
Dimension deviation
Dimension deviation of printed pattern
Number of joints per roll
Quantity of inner plastic film
Physical properties and mechanical properties
Hygiene index
7.3.3 Type inspection batching
Technical requirements
Specified in 5.1
5.2. 1Specified in Table 1
5.2.2Specified in Table 2
5.2.1Specified in Table 1
5.4Specified in Table 3
Specified in 5.5
Test method
6.13,6.14
Check the joint mark of the manufacturer
6.11,6.12
The same variety, the same specification, and the same-one production are considered as a batch. For products delivered in the form of semi-finished containers, each batch shall not exceed 2,000,000. 7.3.4 Sampling methodwww.bzxz.net
7.3.4.1 For products delivered in the form of rolls, sample rolls (not less than 2 rolls) shall be firstly drawn at a ratio of 2%, and 2 sample sections shall be randomly drawn from each sample roll along the length direction with a spacing of not less than 25m for various inspections. The length of the sample section shall not be less than 5m, and the width shall be the entire width. When the sample roll has a joint, it is allowed to cut a sample section at the joint. Each complete printed pattern in each sample section is a sample.
7.3.4.2 For products delivered in the form of semi-finished containers, samples are randomly selected at a rate of 0.01% (not less than 100). 410
GB 18192 —2000
7.3.4.3 For the quantitative, physical, mechanical and hygienic index inspection items of the inner plastic film in Table 5, two groups of samples are selected for inspection each time according to the regulations. For other inspection items, 100% of the samples are inspected. 7.3.5 Product Quality Determination
7.3.5.1 When the quantitative, physical, mechanical and hygienic indexes of the inner plastic film and other items are inspected or reviewed according to the indicators in Table 5, and each sample meets the technical requirements, the batch of products is qualified. 7.3.5.2 If more than one (including one) of the indicators in Table 5 fails to meet the technical requirements, double the number of samples shall be taken for re-inspection according to the provisions of 7.3.4;
a) If more than one (including one) of the items in Table 5 for the quantitative, physical, mechanical and hygienic indicators of the inner plastic film fails to meet the technical requirements, the batch of products shall be considered unqualified. If more than two (including two) samples of other items fail to meet the technical requirements, the batch of products shall be considered unqualified;
b) If one sample fails to meet the technical requirements except for the quantitative, physical, mechanical and hygienic indicators of the inner plastic film in Table 5, the batch of products shall still be qualified. 8 Marking, packaging, transportation and storage
8.1 Marking
The outer packaging of each batch of goods shall be marked with the product's order number, product name and specifications, quantity, production date, manufacturer, volume, receiving location and unit, and number of shipments in both Chinese and English in a conspicuous position in conspicuous fonts. When both the shipping unit and the consignee are in China, English labeling is not required. 8.2 Packaging
8.2.1 Packaging of products supplied in roll form8.2.1.1 Each roll of products is wrapped with shrink film. 8.2.1.2 After shrink film packaging, it can be packed in cartons or pallets according to the number of products. The packaging of each batch of products must be accompanied by the certificate of conformity of the batch of products or the word "conformity" must be marked on the label. 8.2.2 Packaging of products supplied in semi-finished form8.2.2.1 Packaging in cartons according to the number required by the user. 8.2.2.2 Place the wrapped cartons on pallets or other cartons according to the number required by the user, and then wrap them with shrink film as a whole. The packaging of each batch of products must be accompanied by the certificate of conformity of the batch of products or the word "conformity" must be marked on the label. 8.3 Transportation
8.3.1 During transportation, it should be protected from rain, sun, moisture, pollution and bruises. The marking method shall be carried out in accordance with the provisions of GB191. 8.3.2 It is strictly forbidden to collide during transportation, and the product is not allowed to be dropped from a height or rolled on the ground. 8.4 Storage
8.4.1 The product should be kept clean, cool, dry, away from heat sources and pollution sources. It is strictly forbidden to mix it with harmful and toxic substances. 8.4.2 The storage period of the product shall not exceed one year from the date of production. 411
A1 Inspection Instrument
GB18192—2000
Appendix A
(Appendix of the Standard)
Quantitative Inspection Method for Inner Layer Material Film
A balance with an accuracy of 0.001g, a mixture of toluene and ethanol in a ratio of 1:1, and a constant temperature water bath. A2 Inspection Conditions
Heat the mixture of toluene and ethanol to 60℃±5℃ in a constant temperature water bath. A3 Test steps
A3.1 For materials supplied in roll form, cut three samples with an area of ​​50cm2 or 100cm2 from the sample with a circular knife; for materials supplied in semi-finished form, cut three samples with an area of ​​50cm2 or 100cm2 according to the size. A3.2 Soak the sample in a mixture of toluene and ethanol for 10 minutes, gently separate the inner plastic film, and then place it for 120 minutes. A3.3 Weigh the three samples separately on a balance and convert them into g/m (for the quantitative value of the inner plastic film). Express the result as the average value of the three samples, accurate to one decimal place.
Appendix B
(Appendix to the standard)
Test method for sealing strength of composite materials
B1 Definition
The maximum load of a heat-sealed sample of specified width at break. B2 Instrument
B2.1 Testing machine: The reading error should be within ±1%. B2.2 Vernier caliper: accuracy 0.02mm.
B2.32 Ruler: accuracy 1mm.
B3 Sample
B3.1 Sampling method
B3.1.1 Take samples from the coiled material along the coil forming direction for butt sealing inspection, and take samples perpendicular to the forming direction for lap sealing inspection. When checking the lap strength, it is allowed to seal the protective seal that meets the use conditions at the same time. B3.1.2 For materials that have been sealed longitudinally and are supplied in the form of semi-finished containers, take samples in the direction parallel to the longitudinal seam for butt sealing inspection, and take samples in the direction perpendicular to the longitudinal seam with the longitudinal seam as the center point, and take the existing longitudinal seam as the lap seal for inspection. B3.1.3 The sealing method can be determined by each manufacturer. B3.2 Sample size
The sample is rectangular: length (100±1) mm, width (15±0.1) mm. When it is not possible to obtain a sample with an unfolded length of 100±1 mm, it is allowed to use adhesive tape to bond the same material from both ends to achieve the specified size of the sample. B3.3 Number of samples
GB18192—2000
Sampling shall not be less than 10 each time, and the test result shall be the average value of 10 samples as the result, expressed as N/15mm, and take 3 significant figures. B4 Inspection steps
The sample shall be conditioned for 4 hours at a temperature of 23℃±2C. The state-adjusted sample is unfolded 180° with the sealing part as the center line. The two ends of the sample are clamped on the fixture of the test machine. The longitudinal axis of the sample should coincide with the upper and lower center lines, and the tightness should be appropriate to prevent the sample from slipping or breaking in the fixture. The distance between the fixtures is 50mm, the test speed is 300mm/min±20mm/min, and the maximum load when the sample breaks is read. If the sample breaks in the fixture, the sample is invalid and another sample is taken to make up. Appendix C
(Appendix of Standard Push)
Test method for adhesion between composite plastic film and paper C1 For materials supplied in roll form, cut a 1m long full-width sample from the sample and place the sample flat on the table with the inner PE layer facing up. Starting from the corner of the sample, use a knife to peel off between the paper and the composite PE layer, and slowly tear off a strip with a width of 30mm~50mm, passing through the entire width. Visually inspect the exposed composite layer surface. Determine the percentage of the area on the plastic surface that has paper fibers attached to it. Repeat this step diagonally in the opposite direction.
Continue to use a knife to divide the entire sample into several groups of 80 mm width. Manually peel each group slowly from the machine direction and the reverse direction, and visually inspect the exposed composite surface of each group.
Determine the percentage of the area on the plastic surface that has paper fibers attached to it. The worse result shall prevail. C2 Materials supplied in the form of semi-finished products are first cut along the longitudinal seam, and the overlapping part of the longitudinal seam is removed. The sample is cut into the largest rectangle. Starting from the corner of the sample, use a knife to peel between the paper and the composite PE layer, and slowly tear off the composite layer. Visually inspect the exposed composite surface.
Determine the percentage of the area on the plastic surface that has paper fibers attached to it. Repeat 3 times. The worse result shall prevail. 413
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