GB 30000.10-2013 Chemical Classification and Labelling Specification Part 10: Self-igniting Liquids GB30000.10-2013 |tt||Standard compression package decompression password: www.bzxz.net
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of self-igniting liquids. This part applies to the classification and labeling of self-igniting liquids in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals.
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended.
The expected structure of GB30000 "Specifications for Classification and Labelling of Chemicals" and the national standards to be replaced are:
———Part 1: General (replaces GB13690-2009);
———Part 2: Explosives (replaces GB20576-2006);
———Part 3: Flammable gases (replaces GB20577-2006);
———Part 4: Aerosols (replaces GB20578-2006);
———Part 5: Oxidizing gases (replaces GB20579-2006);
———Part 6: Gases under pressure (replaces GB20580-2006);
———Part 7: Flammable liquids (replaces GB20581-2006);
———Part 8: Flammable solids (replaces GB 20582-2006);
———Part 9: Self-reactive substances and mixtures (replaces GB 20583-2006);
———Part 10: Pyrophoric liquids (replaces GB 20585-2006);
———Part 11: Pyrophoric solids (replaces GB 20586-2006);
———Part 12: Self-heating substances and mixtures (replaces GB 20584-2006);
———Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB 20587-2006);
———Part 14: Oxidizing liquids (replaces GB 20589-2006);
——Part 15: Oxidizing solids (replaces GB 20590-2006);
——Part 16: Organic peroxides (replaces GB 20591-2006);
——Part 17: Corrosive to metals (replaces GB 20588-2006);
——Part 18: Acute toxicity (replaces GB 20592-2006);
——Part 19: Skin corrosion/irritation (replaces GB 20593-2006);
——Part 20: Serious eye damage/eye irritation (replaces GB 20594-2006);
——Part 21: Respiratory or skin sensitization (replaces GB 20595-2006);
———Part 22: Germ cell mutagenicity (replaces GB 20596-2006);
———Part 23: Carcinogenicity (replaces GB 20597-2006);
———Part 24: Reproductive toxicity (replaces GB 20598-2006);
———Part 25: Specific target organ toxicity single exposure (replaces GB 20599-2006);
———Part 26: Specific target organ toxicity repeated exposure (replaces GB 20601-2006);
———Part 27: Aspiration hazard;
———Part 28: Hazard to the aquatic environment (replaces GB 20602-2006);
———Part 29: Hazard to the ozone layer;
———Part 30: Warning signs for chemical workplaces.
This part is part 10 of GB 30000—2013.
This part was drafted in accordance with the rules given in GB/T 1.1—2009.
This part replaces GB 20585—2006 “Safety Specification for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Pyrophoric Liquids”.
This part is consistent with the relevant technical contents of the United Nations “Globally Harmonized System of Classification and Labelling of Chemicals” (GHS) (4th revised edition).
Compared with GB 20585-2006, the main technical content changes of this part are as follows:
———The name of the standard has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals—Part 10: Pyrophoric liquids" and the English name is "Rules for classification and labelling of chemicals—Part 10: Pyrophoric liquids";
———The scope of Chapter 1 has been modified, "Warning label" has been changed to "label", and "Warning statement" has been deleted; ||tt
|| ———The introductory words of Chapter 2 "Normative references" have been modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" has been added as a reference document;
———The introductory words of Chapter 3 "Terms and Definitions" have been added;
———Figure 1 "Decision logic diagram" and "Guidance" in Chapter 5 have been made informative Appendix A;
———Deleted the original Chapter 7, and revised Table 3 of the original Chapter 7 as normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition);
———Revised and integrated the original Chapters 6, 7 and 8 into Chapter 6 according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition); revised Table 2 as normative Appendix C;
———Deleted the original Chapter 8, and added the relevant "Hazard Statements" and "Precautionary Statements" as informative Appendix D;
———Added informative Appendix E "Label Examples".
This part was proposed and coordinated by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251).
Drafting units of this part: China Chemical Economic and Technological Development Center, Shanghai Research Institute of Chemical Industry, Beijing Entry-Exit Inspection and Quarantine Bureau, Zhejiang Chemical Research Institute Co., Ltd., Pony Testing Technology Co., Ltd., Huafeng Group Co., Ltd.
The main drafters of this part are: Yang Ting, Dong Xuesheng, Tang Shutian, Wang Gaosheng, Zhang Chunhui, Wang Xiaobing, Ma Ning, Zhang Chunli, Dai Sheng, Cao Mengran, Wen Tao. The
previous versions of the standards replaced by this part are:
———GB 20585—2006.
The following documents are indispensable for the application of this document. For all dated referenced documents, only the dated versions apply to this document. For all undated referenced documents, the latest versions (including all amendments) apply to this document.
GB6944—2012 Classification and Product Name Numbering of Dangerous Goods
GB13690 General Rules for Classification and Hazard Communication of Chemicals
United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (Fourth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria (Fifth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition)

ICS13.300
National Standard of the People's Republic of China
GB30000.10—2013
Replaces GB20585-2006
Rules for classification and labelling of chemicals-Part 10: Pyrophoric liquids
Issued on October 10, 2013
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China Administration of Standardization of the People's Republic of China
Implementation on November 1, 2014
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. The expected structure of GB30000 "Chemical Classification and Labeling Specification" and the national standards to be replaced are: Part 1: General (replaces GB136902009): Part 2: Explosives (replaces GB20576-2006): Part 3: Flammable gases (replaces GB20577-2006) Part 4: Aerosols (replaces GB20578-2006); Part 5: Oxidizing gases (replaces GB20579-2006); Part 6: Pressurized gases (replaces GB205802006); Part 7: Flammable liquids (replaces GB20581-2006); Part 8: Flammable solids (replacing GB20582-2006): Part 9: Self-reactive substances and mixtures (replacing GB20583-2006): Part 10: Pyrophoric liquids (replacing GB20585-2006); Part 11: Pyrophoric solids (replacing GB20586-2006); Part 12: Self-heating substances and mixtures (replacing GB20584-2006): Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replacing GB20587-2006); Part 14: Oxidizing liquids (replacing GB20589-2006); Part 15: Oxidizing solids (replacing GB 20590-2006); Part 16: Organic peroxides (replaces GB20591-2006); Part 17: Metal corrosion (replaces GB20588--2006); Part 18: Acute toxicity (replaces GB20592-2006); Part 19: Skin corrosion/irritation (replaces GB20593-2006); Part 20: Severe eye damage simulated eye irritation (replaces GB20594-2006); Part 21: Respiratory or skin sensitization (replaces GB20595-2006); Part 22: Germ cell mutagenicity (replaces GB20596-2006) ; Part 23: Carcinogenicity (replaces GB20597-2006); Part 24: Reproductive toxicity (replaces GB205982006); Part 25: Specific target organ toxicity
Single exposure (replaces GB20599-2006); Part 26: Specific target organ toxicity repeated exposure (replaces GB20601-2006); Part 27: Inhalation hazard:
Part 28: Hazards to the aquatic environment (replaces GB20602-2006); Part 29: Hazards to the ozone layer;
Part 30: Warning signs for chemical workplaces. This part is Part 10 of GB30000-2013. This part was drafted in accordance with the rules given in GB/T1.1-2009. GB30000.10—2013
This part replaces GB20585—2006 “Safety Rules for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Pyrophoric Liquids”. This part is consistent with the technical content related to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (Fourth Revised Edition). Compared with GB20585-2006, the main technical content changes of this part are as follows: 1
GB30000.10—2013
The standard name has been modified. The Chinese name has been changed to “Rules for classification and labelling of chemicals-Part 10: Pyrophoric Liquids” and the English name is \Rules for classification and labelling of chemicals-Part 1o: Pyrophoric liguids\; The scope of Chapter 1 was modified, "Warning Label" was changed to "Label", "Warning Statement" was deleted, the introductory words of Chapter 2 "Normative References" were modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" was added as a reference document: the introductory words of Chapter 3 "Terms and Definitions" were added; Figure 1 "Decision Logic Diagram" and "Guidance" in Chapter 5 were made into informative Appendix A; the original Chapter 7 was deleted, and Table 3 of the original Chapter 7 was modified as Normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition);
According to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition), the original Chapters 6, 7, and 8 were modified and integrated into Chapter 6; the original Table 2 was modified After the revision, it is made into normative Appendix C; the original Chapter 8 is deleted, and the relevant "Hazard Statements" and "Precautionary Statements" are made into informative Appendix D; and informative Appendix E "Label Examples" is added. This part is proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251). Drafting units of this part: China Chemical Economic and Technological Development Center, Shanghai Research Institute of Chemical Industry, Beijing Exit-Entry Inspection and Quarantine Bureau, Zhejiang Chemical Research Institute Co., Ltd., PONY Testing Technology Co., Ltd., Huafeng Group Co., Ltd. The main drafters of this part: Yang Ting, Dong Xuesheng, Tang Shutian, Wang Gaosheng, Zhang Chunhui, Wang Xiaobing, Ma Ning, Zhang Chunli, Dai Sheng, Cao Mengran, Wen Tao.
The previous versions of the standards replaced by this part are: GB2058520 06.
1 Scope
Chemical Classification and Labelling Specification
Part 10: Self-igniting Liquids
GB30000.10—2013
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of self-igniting liquids. This part applies to the classification and labeling of self-igniting liquids in accordance with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (hereinafter referred to as GHS). Normative references
The following documents are indispensable for the application of this document. For any dated referenced document, only the version with the legal date shall apply to this document. For any undated referenced document, the latest version (including all amendments) shall apply to this document GB6944
GB13690
Classification and numbering of dangerous goods
General rules for classification and hazard communication of chemicals
United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (GH) (fourth revision) in the recommendations on the transport of dangerous goods
United Nations "US Recommendations for the Transport of Dangerous Goods"
United Nations "US Manual of Terms and Definitions for the Transport of Dangerous Goods" (United Nations US Manual of Tests and Criteria Model Specifications) (No. 1) GB13690 is defined and the following provisions and definitions apply to this document 3.1
Pyrophoric liquids
Liquids which can ignite within 5 minutes after contact with air even in small quantities. 4 Classification criteriabZxz.net
General principles for the classification and labelling of self-igniting liquids are given in GB 136904.1
4.2 Classification criteria
Fifth revised edition
Revised edition
4.2.1 Self-igniting liquids are classified according to the N.3 test in 33.3.1.5 of Part III of the United Nations Recommendations on the Transport of Dangerous Goods: Manual of Tests and Criteria (Fifth revised edition) (hereinafter referred to as the Manual of Tests and Criteria), see Table 1. Table
Classification of self-igniting liquids
Liquids added to an inert carrier and exposed to air will burn within 5 minutes, or will ignite or carbonize filter paper within 5 minutes of contact with air GB 30000.10—2013
5 Decision logic and guidance
Decision logic and guidance are for reference only. See Appendix A for decision logic and guidance. It is particularly recommended that the person responsible for classification study Chapter 4 before and during the use of decision logic.
6 Tags
6.1 Overview
6.1.1 For labels of self-igniting liquids, hazard categories are listed in the order of designated pictograms, signal words and hazard statements. The hazard classes or categories covered by the United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (17th revised edition) (hereinafter referred to as the "Model Regulations") should list the designated corresponding graphic signs for each category on the label. The allocation of label elements for self-igniting liquids is shown in Appendix B6.1.2. For classification standards and label elements for self-igniting liquids, see Appendix C. 6.1.3 The information required on the label includes hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and supplier logos. Note: For other label elements that have not yet been standardized, such as precautionary statements, they also need to be included on the label. The competent authority may also require additional information, and the supplier may also add supplementary information.
6.2 Hazard pictograms
Hazard pictograms should use black symbols with a white background, and the red frame should be wide enough to be eye-catching. The colors, numbers and minimum sizes of hazard pictograms and graphic symbols specified in the "Model Regulations" are shown in Appendix B. 6.3 Signal Words
Signal words are words used on labels to indicate the relative severity of a hazard and to alert the reader to potential hazards: for pyrophoric liquids the signal word "Danger" is used.
6.4 Hazard Statements
Hazard statements are phrases assigned to a hazard class and category that describe the hazardous nature of a hazardous product and, where appropriate, its degree of hazard. Hazard Statements for Pyrophoric Liquids See Appendix D6.5 Precautionary Statements
A precautionary statement is a word (and/or pictogram) that describes recommended measures to minimize or prevent adverse effects resulting from exposure to the hazardous product or from improper storage or handling of the hazardous product. For this purpose, there are five categories of precautionary statements: general, prevention, emergency, storage and disposal. Precautionary Statements for Pyrophoric Liquids See Appendix D. 6.6 Product Identifiers
6.6.1 Product identifiers should be used on labels and should be consistent with those used on the Material Safety Data Sheet. If a substance or mixture is listed in the Model Regulations, the correct UN shipping name should also be used on the packaging. 6.6.2 The label shall include the chemical name of the substance. For mixtures or alloys, when acute toxicity, skin or respiratory sensitization or specific target organ toxicity appear on the label, the label shall include the chemical composition of all ingredients or alloying elements that may cause these hazards. The competent authority may also require that the chemical names of all ingredients or alloying elements that may contribute to the hazards of the mixture or alloy be listed on the label. 2
Supplier identification
The name, address and telephone number of the manufacturer or supplier of the substance or mixture shall be provided on the label. Example of a label for a pyrophoric liquid
For an example of a label for a pyrophoric liquid, see Appendix E. KANKAca-
GB30000.10—2013
GB30000.10—2013
A.1 Decision logic
Appendix A
(Informative Appendix)
Decision logic and guidance
For the classification of pyrophoric liquids, the test method N.3 described in subsection 33.3.1.5 of Part III of the Manual of Tests and Criteria should be used. The procedure is divided into two steps. The classification is carried out according to the decision logic diagram A, 1. The substance/mixture is a liquid
Category 1
It cools down to 5 min after being placed in a porcelain cup filled with diatomaceous earth or silica gel
Pyrophoric liquid Decision logic diagram
A.2 Guidance
Not this category
If production or handling experience shows that the substance or mixture will not ignite spontaneously when exposed to air at normal temperature (i.e. the substance is known to be stable for a long time (several days) at room temperature), the pyrophoric liquid classification procedure is not applicable. The allocation of label elements is shown in Table B.1.
Category 1
Spontaneous combustion when exposed to air
Appendix B
(Normative Appendix)
Allocation of label elements
Allocation of label elements for spontaneous combustion liquids
Spontaneous combustion liquids
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GB30000.10-—2013
In the "Model Regulations":
Color of graphic symbols
Graphic symbol (flame): black:
Background: white in the upper half,
red in the lower half; the number "4" is located in the lower corner:
black,
the number 4 in the figure is Category 4 in GB6944
2012.
The minimum
size of the cargo transport graphic mark is 100mm×100mm
GB30000.10—2013
Appendix C
(Normative Appendix)
Classification standards and label elements for self-igniting liquids
The classification standards and label elements for self-igniting liquids are shown in Table C.1. Table C.1
Hazard categories
Classification criteria and label elements for self-igniting liquids
Liquid added to an inert carrier and exposed to air will burn within 5 minutes, or will ignite or carbonize filter paper within 5 minutes of contact with air
Graphic symbols
Signal words
Hazard statements
Label elements
Spontaneous combustion when exposed to air
D.1 Overview
Appendix D
(Informative Appendix)
Hazard statements and precautionary statements for self-igniting liquids GB30000.10-2013
D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for self-igniting liquids. It lists the hazard statements and precautionary statements for each hazard class and hazard category of self-igniting liquids. See GB13690. D.1.2 Coding of hazard statements
D.1.2.1 The coding of hazard statements is shown in Annex 3 of GHS. Each hazard statement is assigned a special alphanumeric code consisting of 1 letter and 3 numbers, as follows:
The letter \H\ (stands for \hazard statement"); the first number represents the type of hazard referred to by the hazard statement with different part numbers, as follows: b)
"2\ represents physical hazard;
"3" represents health hazard;
"4\ represents environmental hazard;
c) The last two numbers correspond to the serial number of the hazard caused by the inherent properties of the substance or mixture, such as: explosiveness (codes 200 to 210), flammability (codes 220 to 230), etc. D.1.2.3 Unless otherwise specified, all specified All hazard statements shall appear on the label. The competent authority may specify the order in which the hazard statements shall appear on the label. In addition, when two or more hazard statements are provided in a combined hazard statement, the competent authority may specify whether the combined hazard statement or the corresponding individual statements shall appear on the label, or whether this is left to the manufacturer/supplier to decide at their own discretion. D.1.3 Precautionary statements shall appear on compliant labels together with the harmonized hazard communication elements (pictograms, signal words and hazard statements). Additional supplementary information, such as instructions for use, may also be provided at the discretion of the manufacturer/supplier and/or the competent authority. D.1.3.1 See Annex 3 of the GHS for the coding of precautionary statements. D.1.3.2 Coding of precautionary statements
D.1.3.2.1 Each precautionary statement shall be assigned a A special alphanumeric code consisting of 1 letter and 3 numbers, as follows:
The letter P\ (stands for "Precautionary Statement\); a)
The first number represents the type of precautionary statement, as follows: b)
"1\ represents general precautionary statement;
"2\ represents prevention precautionary statement;
-"3" represents emergency precautionary statement;
"4\ represents storage precautionary statement;
-"5" represents disposal precautionary statement;
c) The last 2 numbers (corresponding to the serial number of the precautionary statement). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement clause and should not be used to replace the precautionary statement clause .
D.2 General precautionary statements
General precautions should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels (see Table D.1) under the given conditions7
TKAONiKAca
GB30000.10—2013
Table D.1—General precautionary statements
General public
Production workers
Supplementary information
Labels, supplementary label information
Labels, supplementary label information, safety data sheets, workplace signs
D.3 Precautionary statements for self-igniting liquids
D.3.1 Precautionary statements for self-igniting liquids See Table D.2.
General precautionary statements
If medical attention is required: Keep product container or label at hand. Keep out of reach of children.
Read label before use.
Table D.2 Precautionary statements for spontaneously igniting liquids
Hazard category
Market wording
Exclusion statement
11250 Will spontaneously ignite in the air
Precautionary statements
P302+P334
Keep away from heat/sparks/open flames/hot surfaces No smoking Manufacturer/supplier or the competent authority to specify applicable ignition sources.
Do not expose to air,
Wear protective gloves/protective clothing/eye protection/face protection.
Manufacturer/supplier or the competent authority to specify type of equipment. IF ON SKIN: Wrap with wet bandage in cold water
P370+P378
In case of fire: Use. ... Fire
Manufacturer/supplier or the competent authority to specify appropriate media.
Contact with water may increase the hazard.
Store contents in
liquids
or inert gases
as specified by the manufacturer, supplier or the competent authority.
Symbol
GB30000.10—2013
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