Some standard content:
GB 17916—1999
This standard is formulated to regulate the storage management of toxic chemicals among dangerous chemicals and to ensure the safety of toxic chemicals during storage. This standard is based on the experience and scientific research results in the storage and maintenance of toxic chemicals over the years, based on scientific test data, and in reference to the national laws and regulations on the storage and transportation of dangerous goods, and the international transportation rules for dangerous goods, and makes specific provisions on the storage and maintenance technology of toxic chemicals.
Appendix A and Appendix B of this standard are both standard appendices. The appendixes in this standard are informative appendices.
This standard is proposed by the State Bureau of Domestic Trade. The drafting units of this standard are: State Bureau of Domestic Trade, Beijing Commercial Storage and Transportation Company. The main contributors to this standard are: Zhang Guicai, Chai Baoshen, and Chen Feng. 1 Scope
National Standard of the People's Republic of China
Technical conditions for storage and preservation of toxic goods
Specifications for storage and preservation of toxic goods
GB179161999
This standard specifies the storage conditions, storage technology, storage period and other technical requirements for toxic goods. This standard is based on the toxic goods specified in GB60.14 and GB12268. 2 Referenced standards
The provisions contained in the following standards constitute the provisions of this standard through reference in this standard. At the time of publication of this standard, the versions shown are valid. All standards are subject to revision. Parties using this standard should explore the possibility of using the latest versions of the following standards. GB190-1000 Dangerous Goods Packaging Marking
GB191-1990 Packaging Storage and Transportation Pictorial Marking
GB5944-1985 Classification and Name Number of Dangerous Goods GB11651~1589 Rules for Selection of Animal Husbandry Protection Supplies GB12268-1990 Dangerous Goods Name List
GB12163-1990 General Technical Conditions for Dangerous Goods Transport Packaging GB12175-1990 Storage, Transportation, Sales and Use of Pesticides 3 Storage Conditions
3.1 Warehouse Conditions
3.1.1 The room structure is complete, dry, and well ventilated. Mechanical ventilation and detoxification must have necessary safety protection measures. 3.1.2 The fire resistance level of the warehouse is not less than Level 2
3.2 Enterprise Conditions
3.2.1 The warehouse should be far away from residential areas and water sources. 3.2.2 The goods should be kept away from direct sunlight, exposure to the sun, heat sources, power sources, and fire sources. Firefighting equipment, alarm devices, and emergency medicine boxes suitable for the nature of the toxic substances should be installed in a fixed and convenient place in the warehouse. 3-2.3 Different types of toxic substances should be stored separately. Those with different danger levels and fire extinguishing methods should be stored separately. The same storage performance of chemical hazardous substances is prohibited. Appendix A (Appendix to the standard) provides a table of the performance of mixed storage of chemical hazardous substances: 3.2.4 The toxic substances should be stored in a special place or in a single room that is not covered by the room. An anti-theft alarm device should be installed and the door of the warehouse should be double-locked. 3.3 Sanitary conditions
The warehouse area and the warehouse should be kept clean at all times. Scattered toxic substances, flammable and combustible items and weeds in the warehouse area should be removed in time. Used work clothes, gloves and other supplies must be placed in a safe place outside the warehouse and properly kept or disposed of in time. When changing the type of stored toxic substances, the warehouse should be cleaned thoroughly.
3.4 Temperature and humidity conditions
Approved by the State Administration of Quality and Technical Supervision on November 29, 1999, implemented on April 1, 2000
GB 179161999
The temperature in the warehouse area should not exceed 35℃. The temperature of easily decomposed products should be controlled below 32℃. The relative humidity should be below 85%. For easily deliquescent drugs, the temperature should be controlled below 80℃.
4 Warehouse acceptance
4.1 Acceptance principles
4.1.1 Warehoused goods must be accompanied by production licenses and product inspection certificates. Imported goods must be accompanied by Chinese safety instructions and quality specifications.
4.1.2 The internal quality of the goods should meet the company's product standards and the inventory party shall be responsible for inspection. 4.1.3 The storage force shall conduct sensory inspection on the product appearance, internal and external labels, container packaging, Liu pads, etc. 4.1.4 Unpack and inspect 2-5 cartons of each product (except for exempted products). If a large proportion of the same problems are found, the product packaging shall be restored after inspection and marked.
4.1.5 The acceptance shall be carried out at a location outside the warehouse or in the delivery room. 4.2 Acceptance items
4.2.1 Packaging
Should comply with the provisions of GB12463.
4.2.1.1 The outer packaging should have the following signs: a) Product name;
b) Specification;
c) Grade +
d) Quantity (weight):
e) Production date or batch number:
f) Manufacturer name;
) Storage and transportation diagram: It should comply with the provisions of GH19I: h) Toxicity mark; It should comply with the provisions of GB190. 4.2.1.2 The packaging is intact, free of moisture and pollution. The packaging materials, container lining, etc. should comply with the requirements of CB12463. 4.2.2 Quality
4.2.2.1 The properties and color of the product should comply with the product standards. 4.2.2.2 Liquid products have no color change, no precipitation, and no impurities. 4.2.2.3 Solid products have no color change, no caking, no deliquescence, and no melting. 4.2.3 Acceptance result handling
4.2.3.1 Acceptance that does not meet the requirements of 1.2 shall not be put into storage, but shall be temporarily stored in the observation room, and the storage party shall be notified and handled separately. 4.2.3.2 After acceptance, qualified ones shall be signed and put into storage, and the acceptance record shall be filled and transferred to the storage party. 4.2.3.3 When the packaging is broken or leaking, the packaging must be replaced before it can be put into storage. The repair of packaging must be carried out in a special place. The drugs scattered on the ground must be cleaned up, stored in a centralized manner, and handled in a unified manner.
5 Stacking
The stacking of goods must meet the principles of safety and convenience: it is convenient for stacking, inspection and fire fighting, and the cushioning materials must be dedicated. 5.1 Stacking method
5.1.1 Goods shall not be stacked on the spot: there should be moisture-proof facilities under the stack, and the bottom of the stack shall generally not be less than 15cm5.1.2 Generally, it can be stacked into large stacks. Volatile liquid thin products should not be stacked into large stacks, but can be stacked into rows. The cargo stacks are required to be solid, neat and beautiful, and the stack height shall not exceed 3m.
5.2 Stacking distance
a) In the channel, it is greater than or equal to 180cm;
b) In the branch channel, it is greater than or equal to 8u cm
c) The distance between the wall and the person is equal to 30rm
d) The distance between the columns is greater than or equal to 10 cm;
\) The stack is greater than or equal to 10m;
f) The height of the top is less than 50cm.
6 Maintenance technology
6.1 Temperature and humidity management
GE 17916 - 1999
6.1.1 A temperature and humidity meter shall be set up in the warehouse, and the temperature and humidity shall be observed and recorded in time. 6.1.2 Strictly control the temperature and humidity in the warehouse and keep it within the appropriate range. 6.1.3 The volatile liquid drug warehouse shall be ventilated and detoxified frequently. If mechanical ventilation is used, necessary safety protection measures shall be taken. 6.2 Inspection in the warehouse
6.2.1 Safety inspection
6.2.1.1 Check the warehouse area every day to check whether the flammable materials are cleaned up, whether the goods are firm and whether there are any abnormalities. 6.2.1.2 Check whether the goods are damaged in time in special weather. 6.2-1.3 Regularly check whether the facilities, fire-fighting equipment and protective equipment in the warehouse are complete and effective: 6.2-2 Product quality inspection
6.2.2.3 According to the nature of the goods, regular quality inspections are carried out. Select 1 to 2 items of each product and expand the inspection ratio if problems are found. 6.2.2-2 Check whether the packaging, seals and lining of the goods are damaged, and whether the appearance and quality of the goods have changed. 6.2.3 Problem handling of inspection and storage results
6.2.3.1 Record the inspection results and mark them on the outer packaging of the goods. 6-2.3.2 Make a record of the problems found and notify the storage party. At the same time, take measures to deal with them. 6.2.3.3 For defective products, a transfer form should be filled out and reported to the stock party. 7 Safe operation
7.1 Loading and unloading personnel should have general knowledge of handling toxic substances. They should be careful when operating, and should not touch or invert the products to prevent the damaged products from being exposed.
7.2 Operators should wear gloves and corresponding gas masks or masks, and wear anti-expansion clothing. 73 Do not eat or drink during operation, and do not wipe your mouth, face, or eyes with your hands. After each operation, you must wash your face and hands with soap (or special detergent) and rinse with clean water. Anti-expansion tools should be cleaned in time and stored in a centralized manner. 8 Storage period
According to the production period and validity period of various toxic substances. 9 Delivery
9.1 Strictly sort the products in the warehouse according to the production date.
9.2 Strictly implement the effective lock and double-check system. 10 Emergency handling
10.1 Fire fighting methods are shown in Appendix B (Standard Appendix). 10.2 Personal protection see GB116 yuan 1 and GB12475. 10.3 Zhonghe First Aid Refer to the Appendix (Appendix of Prompt): Classification of Chemical Hazardous Materials Explosive Oxidants Compressible Gases and Liquid Gases Spontaneous Combustion Materials Combustible Materials in Contact with Water Flammable Liquids Combustible Solids Toxic Materials [Acidic Materials! Degradable Materials Radioactive Materials Classification of Chemical Hazardous Materials GB 17916—1999
Appendix A
(Standard Appendix)
Table of mutual compensation of mixed storage performance of dangerous chemical materials
Explosive materials
Positive gas
[Oxidizing agent
Stop and liquid
Chemical gas
Ignition, ignition, sweeping
[Bridge materials and equipment
Explosive
[Drugs
Ignition equipment
Initiating equipment
Explosive and explosive fuels
Other explosives
First-level inorganic
First-level organic
, First-level inorganic
Second-level organic
(Liquid silver and liquid gas are inorganic, organic, toxic, non-toxic, organic, and non-toxic. Note: "\Number indicates that it can be stored" "\Number indicates that it cannot be stored, solid, corrosive, slightly acidic, and has no element"
The research is this
[No toxic, thermal, extremely high, non-organic, anti-toxic, and non-material material
District
x district
Division
xxxxxx x
XxxxXxxXX
X风xx风xxxxx
District District ... "Division" means that the hazardous chemicals should be stored in different areas according to their classification. If the items are not similar or the warehouse is not large enough, they can be stored separately because their properties do not conflict with each other. "Division" means that the properties of two items do not conflict with each other and their fire rescue methods are different. It is best to store them separately. It is not suitable for peroxides such as sodium peroxide to be mixed with inorganic oxidants. It is not suitable for reducing salts such as sodium phosphite to be mixed with other inorganic chemicals. For mixed items, there must be a distance of more than 0.000 meters between the stacks, and the packaging containers must be complete to prevent the two items from contacting each other. Inorganic
arsenic acid, sodium arsenate
GH 179161999www.bzxz.net
Appendix B
(Appendix to the standard)
All toxic fire fighting methods
Fire extinguishing agents
Acid salts, arsenic acid and its compounds, arsenic acid, selenite, selenite anhydride, pre-skinned chemical powder
Rat pulp
Cyanide, cyanide melt fire pan
Hydrogen peroxide solution
Dimethicone, oxycyanate, phosphate isolactone, 1210 emulsion 3811.1110
Tetraethyl lead
Molybdenum alkali
Dimethyl sulfate
1605 emulsion, 1359 emulsion
Sodium fluoride, fluoride, silicate, Lead oxide, barium sulfate, chlorinated barium, its compounds, modified compounds, carbonate, chlorinated compounds, diazomethane, other amino compounds (polychlorinated compounds), amino acid esters, bromoalkanes (alkanes), other aldehydes, enzymes, esters, benzene compounds, etc., various organic salts. Organic compounds of para-nitroxy (bromo) methane, oxalic acid, oxalates, oxalates, sulfates, enzyme acid esters, amine compounds, various compounds of amine, hydrochloric acid method - toxic, amine (etc., meta, para) || tt|| digingeryl toluene, prohibited amines, dinitrodiphenylamine, pyridine and its compounds, foreign Organic compounds, nitro apple enzyme sodium super, nitrophenol, benzene compounds, nitronaphthalene, distilled water powder, toxaphene powder, 666 powder, marathon, smoke oxygen, An'an, sodium salt of Rongbabi, Ashutol and its sodium salt, Chalisan powder, 1-ban armor, suspected pox tooth brain seedling, bird four, total coarse, Yiqinding and its salts, picric acid, pibabib and true sodium salt water, sand, powder, water, sand king, water, sand king, oxide, dry powder, foam, king sand, paulownia, dry sand, foam. Carbon dioxide, mist water, water, sand ten, soil, water t||Dihydrogen monoxide, water, acid ten
soil, foam, carbon dioxide, mist water
foam, water, carbon dioxide
foam, sand
sand, foam, mist water
soil, foam, carbon dioxide
foam, water, dihydrogen monoxide
sand, concentrated, mist water
sand, foam, etc. water, dioxide
foam, carbon dioxide, mist water, sand
foam, nitrate
water, sand, foam
fire extinguishing agent
acid foam
acid magnetic foam
C1 respiratory tract poisoning
GB 17916 - 1999
Appendix C
(Appendix of Suggestions)
Chinese and Italian Teaching Methods
Poisonous vapors, fumes, and dusts are inhaled into the respiratory tract, causing poisoning symptoms, such as itchy throat, cough, runny nose, dyspnea, dizziness, and headache. Upon discovery of the above situation: the poisoned person should leave the scene immediately and lie down in fresh air. For those who have difficulty breathing, they can breathe oxygen or perform artificial respiration. Before performing artificial respiration, the upper clothes should be unbuttoned, but the person should not be exposed to cold. Artificial respiration can be stopped only after normal breathing is restored. Treatment should not be given immediately. Non-alert poisons are more dangerous, such as methyl bromide. The gas concentration in the air should be measured before operation to ensure personal safety.
C2 Poisoning in the digestive tract
In case of poisoning through the digestive tract: the poisoned person can use finger pricking of the throat, or inject 0.5mL of 1% apomorphine to induce vomiting, or use three liang of Langui, one liang of Renhuang, and five qian of raw licorice, boiled in water and taken to induce purgation. If it is poisoning by oil-soluble drugs such as 059 and 1605, it is forbidden to use oily purgatives such as narcotic wine and liquid paraffin. The poisoned person should rest in bed after vomiting, pay attention to maintaining body temperature, and drink hot tea. C3 In case of skin poisoning or burns by corrosive substances, rinse with plenty of water immediately, then wash with soapy water, and then apply a layer of zinc oxide ointment or boric acid ointment to protect the skin. Severe cases should be sent to hospital for treatment. C4 When the poison enters the eyes, it should be immediately rinsed with plenty of water or low-concentration medical sodium cyanide (food benefit) water for 10-15 minutes, and then go to hospital for treatment.
Customer standard industry information free downloadTake 50 cents of raw licorice root, boil it in water and drink it to induce purgation. If you are poisoned by oil-soluble drugs such as 059 and 1605, it is forbidden to use oily purgatives such as narcotic wine and liquid paraffin. The poisoned person should rest in bed after vomiting, pay attention to maintaining body temperature, and drink hot tea. C3 In case of skin poisoning or burns by corrosive substances, rinse with plenty of water immediately, then wash with soapy water, and then apply a layer of zinc oxide ointment or boric acid ointment to protect the skin. Severe cases should be sent to hospital for treatment. C4 When the poison enters the eyes, rinse with plenty of water or low-concentration medical sodium cyanide (food benefit) water for 10-15 minutes, and then go to the hospital for treatment.
Customer standard industry information free downloadTake 50 cents of raw licorice root, boil it in water and drink it to induce purgation. If you are poisoned by oil-soluble drugs such as 059 and 1605, it is forbidden to use oily purgatives such as narcotic wine and liquid paraffin. The poisoned person should rest in bed after vomiting, pay attention to maintaining body temperature, and drink hot tea. C3 In case of skin poisoning or burns by corrosive substances, rinse with plenty of water immediately, then wash with soapy water, and then apply a layer of zinc oxide ointment or boric acid ointment to protect the skin. Severe cases should be sent to hospital for treatment. C4 When the poison enters the eyes, rinse with plenty of water or low-concentration medical sodium cyanide (food benefit) water for 10-15 minutes, and then go to the hospital for treatment.
Customer standard industry information free downloadTake 50 cents of raw licorice root, boil it in water and drink it to induce purgation. If you are poisoned by oil-soluble drugs such as 059 and 1605, it is forbidden to use oily purgatives such as narcotic wine and liquid paraffin. The poisoned person should rest in bed after vomiting, pay attention to maintaining body temperature, and drink hot tea. C3 In case of skin poisoning or burns by corrosive substances, rinse with plenty of water immediately, then wash with soapy water, and then apply a layer of zinc oxide ointment or boric acid ointment to protect the skin. Severe cases should be sent to hospital for treatment. C4 When the poison enters the eyes, rinse with plenty of water or low-concentration medical sodium cyanide (food benefit) water for 10-15 minutes, and then go to the hospital for treatment.
Customer standard industry information free downloadTake 50 cents of raw licorice root, boil it in water and drink it to induce purgation. If you are poisoned by oil-soluble drugs such as 059 and 1605, it is forbidden to use oily purgatives such as narcotic wine and liquid paraffin. The poisoned person should rest in bed after vomiting, pay attention to maintaining body temperature, and drink hot tea. C3 In case of skin poisoning or burns by corrosive substances, rinse with plenty of water immediately, then wash with soapy water, and then apply a layer of zinc oxide ointment or boric acid ointment to protect the skin. Severe cases should be sent to hospital for treatment. C4 When the poison enters the eyes, rinse with plenty of water or low-concentration medical sodium cyanide (food benefit) water for 10-15 minutes, and then go to the hospital for treatment.
Customer standard industry information free downloadTake 50 cents of raw licorice root, boil it in water and drink it to induce purgation. If you are poisoned by oil-soluble drugs such as 059 and 1605, it is forbidden to use oily purgatives such as narcotic wine and liquid paraffin. The poisoned person should rest in bed after vomiting, pay attention to maintaining body temperature, and drink hot tea. C3 In case of skin poisoning or burns by corrosive substances, rinse with plenty of water immediately, then wash with soapy water, and then apply a layer of zinc oxide ointment or boric acid ointment to protect the skin. Severe cases should be sent to hospital for treatment. C4 When the poison enters the eyes, rinse with plenty of water or low-concentration medical sodium cyanide (food benefit) water for 10-15 minutes, and then go to the hospital for treatment.
Customer standard industry information free downloadTake 50 cents of raw licorice root, boil it in water and drink it to induce purgation. If you are poisoned by oil-soluble drugs such as 059 and 1605, it is forbidden to use oily purgatives such as narcotic wine and liquid paraffin. The poisoned person should rest in bed after vomiting, pay attention to maintaining body temperature, and drink hot tea. C3 In case of skin poisoning or burns by corrosive substances, rinse with plenty of water immediately, then wash with soapy water, and then apply a layer of zinc oxide ointment or boric acid ointment to protect the skin. Severe cases should be sent to hospital for treatment. C4 When the poison enters the eyes, rinse with plenty of water or low-concentration medical sodium cyanide (food benefit) water for 10-15 minutes, and then go to the hospital for treatment.
Customer standard industry information free downloadNitronaphthalene
Didi boiling powder, chloranil powder, 666 powder, marathon, smoke oxygen, An'an, sodium salt of Rongbabi, Ashutol and its sodium salt, Chalisan powder, 1-banjia membrane, suspected pox brain seedling, bird four, coarse total, Yiqinding and its salts, picric acid, pibabib and true sodium salt water
sand, powder
water, sand king
water, sand king
oxidized embedded, dry powder, foam
king sand, paulownia
dry sand, foam. Carbon dioxide, mist water
water, sand ten
soil, water
diamine base, paraform water, acid ten| |tt||Soil, foam, carbon dioxide, mist water
Foam, water, carbon dioxide
Foam, sand
Sand, foam, mist water
Soil, foam, carbon dioxide
Foam, water, carbon dihydrogen
Sand, thick, mist water
Sand, foam, equal water, dioxide
Foam, carbon dioxide, mist water, sand
Foam, foundation
Water, sand, foam
Use fire extinguishing agent
Acid foam
Acid magnetic foam
C1 respiratory poisoning
GB 17916 - 1999
Appendix C
(Appendix of Suggestions)
Chinese and Italian Teaching Methods
Poisonous vapors, fumes, and dusts are inhaled into the respiratory tract, causing poisoning symptoms, such as itchy throat, cough, runny nose, dyspnea, dizziness, and headache. Upon discovery of the above situation: the poisoned person should leave the scene immediately and lie down in fresh air. For those who have difficulty breathing, they can breathe oxygen or perform artificial respiration. Before performing artificial respiration, the upper clothes should be unbuttoned, but the person should not be exposed to cold. Artificial respiration can be stopped only after normal breathing is restored. Treatment should not be given immediately. Non-alert poisons are more dangerous, such as methyl bromide. The gas concentration in the air should be measured before operation to ensure personal safety.
C2 Poisoning in the digestive tract
In case of poisoning through the digestive tract: the poisoned person can use finger pricking of the throat, or inject 0.5mL of 1% apomorphine to induce vomiting, or use three liang of Langui, one liang of Renhuang, and five qian of raw licorice, boiled in water and taken to induce purgation. If it is poisoning by oil-soluble drugs such as 059 and 1605, it is forbidden to use oily purgatives such as narcotic wine and liquid paraffin. The poisoned person should rest in bed after vomiting, pay attention to maintaining body temperature, and drink hot tea. C3 In case of skin poisoning or burns by corrosive substances, rinse with plenty of water immediately, then wash with soapy water, and then apply a layer of zinc oxide ointment or boric acid ointment to protect the skin. Severe cases should be sent to hospital for treatment. C4 When the poison enters the eyes, it should be immediately rinsed with plenty of water or low-concentration medical sodium cyanide (food benefit) water for 10-15 minutes, and then go to hospital for treatment.
Customer standard industry information free downloadNitronaphthalene
Didi boiling powder, chloranil powder, 666 powder, marathon, smoke oxygen, An'an, sodium salt of Rongbabi, Ashutol and its sodium salt, Chalisan powder, 1-banjia membrane, suspected pox brain seedling, bird four, coarse total, Yiqinding and its salts, picric acid, pibabib and true sodium salt water
sand, powder
water, sand king
water, sand king
oxidized embedded, dry powder, foam
king sand, paulownia
dry sand, foam. Carbon dioxide, mist water
water, sand ten
soil, water
diamine base, paraform water, acid ten| |tt||Soil, foam, carbon dioxide, mist water
Foam, water, carbon dioxide
Foam, sand
Sand, foam, mist water
Soil, foam, carbon dioxide
Foam, water, carbon dihydrogen
Sand, thick, mist water
Sand, foam, equal water, dioxide
Foam, carbon dioxide, mist water, sand
Foam, foundation
Water, sand, foam
Use fire extinguishing agent
Acid foam
Acid magnetic foam
C1 respiratory poisoning
GB 17916 - 1999
Appendix C
(Appendix of Suggestions)
Chinese and Italian Teaching Methods
Poisonous vapors, fumes, and dusts are inhaled into the respiratory tract, causing poisoning symptoms, such as itchy throat, cough, runny nose, dyspnea, dizziness, and headache. Upon discovery of the above situation: the poisoned person should leave the scene immediately and lie down in fresh air. For those who have difficulty breathing, they can breathe oxygen or perform artificial respiration. Before performing artificial respiration, the upper clothes should be unbuttoned, but the person should not be exposed to cold. Artificial respiration can be stopped only after normal breathing is restored. Treatment should not be given immediately. Non-alert poisons are more dangerous, such as methyl bromide. The gas concentration in the air should be measured before operation to ensure personal safety.
C2 Poisoning in the digestive tract
In case of poisoning through the digestive tract: the poisoned person can use finger pricking of the throat, or inject 0.5mL of 1% apomorphine to induce vomiting, or use three liang of Langui, one liang of Renhuang, and five qian of raw licorice, boiled in water and taken to induce purgation. If it is poisoning by oil-soluble drugs such as 059 and 1605, it is forbidden to use oily purgatives such as narcotic wine and liquid paraffin. The poisoned person should rest in bed after vomiting, pay attention to maintaining body temperature, and drink hot tea. C3 In case of skin poisoning or burns by corrosive substances, rinse with plenty of water immediately, then wash with soapy water, and then apply a layer of zinc oxide ointment or boric acid ointment to protect the skin. Severe cases should be sent to hospital for treatment. C4 When the poison enters the eyes, it should be immediately rinsed with plenty of water or low-concentration medical sodium cyanide (food benefit) water for 10-15 minutes, and then go to hospital for treatment.
Customer standard industry information free download
Tip: This standard content only shows part of the intercepted content of the complete standard. If you need the complete standard, please go to the top to download the complete standard document for free.