This standard applies to the emission management of all units and garbage dumps that emit odorous gases into the atmosphere nationwide, as well as the environmental impact assessment, design, completion acceptance and post-completion emission management of construction projects. GB 14554-1993 Odor Pollutant Emission Standard GB14554-1993 Standard download and decompression password: www.bzxz.net

National Standards of the People's Republic of China
Emission standards for odor pollutants
Emission standards for odor pollutantsGB 14554--93
Replacing GBJ4-731>
In order to implement the " "Atmospheric Pollution Prevention and Control Law", to control the pollution of the atmosphere by odorous pollutants, protect and improve the environment, and formulate this standard.
1 Subject content and scope of application
1.1 Subject content
This standard specifies the maximum emission limits of eight kinds of odor pollutants and the odor concentration limit of compound odor substances by years. values ??and factory boundary concentration limits for unorganized emission sources. || tt | Emissions management. 2 Reference Standards
GB3095 Atmospheric Environmental Quality Standard
GB12348 Industrial Enterprise Boundary Noise Standard
GB/T14675 Determination of Air Quality Odor Three-point Comparative Odor Bag Method Air Quality Trimethylamine Determination of gas chromatography GB/T 146763
Air quality Determination of toluene, xylene, styrene gas chromatography
GB/T146771
GB/T 14678
GB /T 14679
GB/T 14680
3 terminology
Air quality Determination of hydrogen sulfide, methyl mercaptan, methyl sulfide and dimethyl disulfide Gas chromatography Air quality Ammonia Determination of sodium hypofluorite-salicylic acid spectrophotometry Air quality Determination of carbon disulfide Diethylamine spectrophotometry 3. 1 Odor pollutants refer to all gaseous substances that stimulate the olfactory organs, cause discomfort to people and damage the living environment. 3.2 Odor concentration refers to the dilution factor required when malodorous gas (including odor) is diluted with odorless air until it is just odorless. 3.3 Unorganized emission sources
refer to emission sources that have no exhaust pipe or the height of the exhaust pipe is less than 15m. 4 Technical content
4.1 Standard classification
The factory boundary standard values ??of odor pollutants in this standard are divided into three levels. Note: 1) This standard replaces the hydrogen sulfide and carbon disulfide indicators in GBJ4-73. The National Environmental Protection Administration approved the implementation of 772
1994-01-15 on 1993-07-15
GB14554-93
4.1.1 and discharged it into the first-level standard for the first-class area in GB3095 , no new sewage discharge units shall be built in Class I areas. 4.1.2 Execute the second-level standard for discharge into the second-category area in GB3095. 4.1.3 The implementation of Level 3 standards for products classified into Category 3 areas in GB3095. 4.2 Standard value
4.2.1 The factory boundary standard value of odor pollutants is the limit value for unorganized emission sources, see Table 1. New, expanded, and reconstructed construction projects initiated on June 1, 1994 and their Enterprises that are put into operation after completion shall implement the corresponding standard values ????in the second- and third-level standards.
Table 1
Factory boundary standard value of odor pollutants
Serial number
1
2
3
4| |tt||5
6
7
8
9
Control Project
Ammonia
Lanmethylamine
Hydrogen sulfide
methyl mercaptan
methyl sulfide
dimethyl sulfide
carbon disulfide
styrene
Austrian gas concentration
unit
mg/m3
mg/m2
mg/m
mg/m3
mg/m8| |tt||mg/ma
mg/m2
mg/m*
Dimensionless
Odor pollutant emission standard value, see Table 2. 4.2.2
Level 1
1.0
0.05
0.03
0.004
0.03
0.03
2.0| |tt||3.0
10
Level 2
New expansion and reconstruction
1.5
0.08
0.06
0.007
0.07
0.06
3.0
5.0
20
Table 2
2 Emission standard values ??of odor pollutants
Serial number
1
2
Control item
Hydrogen sulfide
Methyl mercaptan
Exhaust height, m
15
20
25
30
35
40
60
80| |tt||100
120
15
20
25
30
existing
2.0|| tt||0.15
0.10
0.010
0.15
0.13
5.0
7.0
30||tt| |Level 3
New expansion and reconstruction
4.0
0.45
0.32
0.020
0.55
0.42||tt ||8.0
14
60
Emissions, kg/h
0.33
Q.58
0.90||tt| |1.3
1.8
2.3
5.2
9.3
14
21
0. 04||tt| |0.08
0.12
0.17
Existing
5.0
0.80
0.60
0.035
1.10
0.71
10
19
70
773
774
serial number
2| |tt||3
4
5
6
Control items
Methyl mercaptan
Methylthioal||tt| |Dimethyl disulfide
Carbon disulfide
Nitrogen
GB 14554—93
Continued Table 2
Exhaust height, m||tt| |35
40
60
15
20
25
30
35
40
60
15
20
25
30
35
40
60|| tt||15
20
25
30
35
40
60
80||tt| |100
120
15
20
25
30
35
40
60
Emissions, kg/h
0.24
.0.31
0.69
0.33
0.58
0.90|| tt||1.3
1.8
2.3
5.2
0.43
0.77
1.2
1.7||tt| |2.4
3.1
7.0
1.5
2.7
4.2
6.1
8.3
11
24
43
68bzxZ.net
97
4.9
8.7
14
20
27
35
75
serial number
?
8| |tt||9
5 Standard Implementation
Control Project
Trimethylamine
Styrene
Odor Concentration
GB14554— 93
Continued Table 2
Exhaust height, m
15
20
25
30
35
40
60
80
100
120
15
20
25|| tt||30
35
40
60
Exhaust height, m
15
25
35
40
50.
≥60
Emissions, kg/h
0.54
0.97
1.5
2.2
3.0
3.9
8.7
15
24
35
6.5|| tt||12
18
26
35
46
104
Standard value (dimensionless)
2000
6 000
15000
20 000
40 000
60 000
5.1 Sewage unit emissions (including leakage and unorganized For odor pollutants emitted), the maximum monitoring value (including odor concentration) at the specified monitoring point (without other interference factors) at the boundary of the sewage unit must be lower than or equal to the factory boundary standard value of odor pollutants. 5.2 The emission volume and odor concentration of odorous pollutants emitted by sewage discharge units through smoke and gas exhaust pipes (height above 15m) must be lower than or equal to the odorous pollutant emission standards.
5.3 The odor pollutants and odor concentration discharged and emitted by the sewage discharge unit through drainage must be lower than or equal to the factory boundary standard value of odor pollutants, 6 Monitoring
6.1 Organized emission source monitoring||tt ||6.1.1 The minimum height of the exhaust pipe shall not be less than 15m. 6.1.2 For exhaust pipes between the two heights listed in Table 2, the rounding method is used to calculate the height of the exhaust pipe. The exhaust pipe height listed in Table 2 refers to the vertical height from the ground (zero ground) to the exhaust port. 775 | | tt | | GB14554-93 | The lower part is sampled and monitored to measure the odor concentration or convert it to obtain the actual emissions. The monitoring point of the treated pollution source is located at the exhaust outlet of the treatment device, and a permanent sign should be set. 6.1.4 The sampling frequency of organized emission sources should be determined according to the production cycle. If the production cycle is within 8 hours, the sampling frequency will be every 2 hours. If the production cycle is greater than 8 hours, the monitoring frequency will be collected once every 4 hours. The maximum measured value will be used. 6.2 Unorganized emission source monitoring
6.2.1 Sampling points
The monitoring sampling points at the factory boundary should be set on the downwind side of the factory boundary, or on the boundary line in the direction of odor. 6.2.2 Sampling frequency
Continuous emission sources are sampled every 2 hours, for a total of 4 times, and the maximum measured value is taken. For intermittent emission sources, sampling is selected during the maximum odor time, and the number of sample collection times is no less than 3 times, and the maximum measured value is taken. 6.3 Water area monitoring
Water area monitoring (including oceans, rivers, lakes, drainage ditches, canals) should use the shore as the factory boundary line, and its sampling point setting and sampling frequency are the same as those for unorganized emission source monitoring.
6.4 Determination
For the determination methods of individual odor pollutants and odor concentrations in the standards, see Table 3. Table 3 Odor pollutants and odor concentration determination method serial number
1
2
3
4
5
7|| tt||8
776
Control items
Ammonia
Trimethylamine
Hydrogen sulfide
Methyl mercaptan
Methyl sulfide
Dimethyl disulfide
Carbon disulfide
Styrene
Ogas concentration
Measurement method
GB/T 14679
GB/T14676
GB/T14678
GB/T14678
GB/T14678
GB/T14678
GB/T14680|| tt||GB/T14677
GB/T14675
A1 emission concentration
GB 14554—93
Appendix
A
, Calculation of emissions
(supplement)
CE
×10″
where: C--concentration of odor pollutants, mg/m (dry standard state): g
Vnd
-the weight·name of the odor pollutants sampled; sampling volume, L (dry standard state) A2 emission amount
G=. C.Qrnd )/h. Additional notes:
This standard is proposed by the Science and Technology Standards Department of the National Environmental Protection Administration. This standard is mainly drafted by the Tianjin Environmental Protection Science Institute and the Beijing Institute of Mechanical and Electrical Engineering. Shi Lei, Wang Yanji, Li Xiurong, Jiang Ju, Wang Hongzhi, Wei Hongmei. This standard is interpreted by the National Environmental Protection Administration. (Al)
(A2)
777
2 For exhaust pipes between the two heights listed in Table 2, the height of the exhaust pipe shall be calculated by rounding off. The exhaust pipe height listed in Table 2 refers to the vertical height from the ground (zero ground) to the exhaust port. 775
GB14554—93
6.1.3 Sampling point: The monitoring sampling point of the organized emission source should be the exhaust port where the odor enters the atmosphere. It can also be sampled and monitored at the horizontal exhaust duct and the lower part of the exhaust pipe to measure the odor concentration or convert it to obtain the actual emission. The monitoring point of the treated pollution source is set at the exhaust port of the treatment device and a permanent sign should be set. 6.1.4 The sampling frequency of the organized emission source should be determined according to the production cycle. If the production cycle is within 8 hours, the sampling should be once every 2 hours. If the production cycle is greater than 8 hours, the sampling should be once every 4 hours. The maximum measured value is taken. 6.2 Monitoring of unorganized emission sources
6.2.1 Sampling points
The monitoring sampling points at the factory boundary are set on the downwind side of the factory boundary or on the boundary line where the odor is located. 6.2.2 Sampling frequency
The continuous emission source is sampled once every 2 hours, for a total of 4 times, and the maximum measured value is taken. The intermittent emission source is selected to sample during the maximum odor time, and the number of sample collection times is not less than 3 times, and the maximum measured value is taken. 6.3 Water area monitoring
The monitoring of water areas (including oceans, rivers, lakes, drainage ditches, and canals) should use the shore as the factory boundary line, and the sampling point setting and sampling frequency are the same as those for monitoring unorganized emission sources.
6.4 Determination
The determination methods of each single odor pollutant and odor concentration in the standard are shown in Table 3. Table 3 Odor pollutants and odor concentration determination methods No.
1
2
3
4
5
7
8
776
Control item
Ammonia
Trimethylamine
Hydrogen sulfide
Methyl mercaptan
Methyl sulfide
Dimethyl disulfide
Carbon disulfide
Styrene
Ozone concentration
Determination method
GB/T 14679
GB/T14676
GB/T14678
GB/T14678
GB/T14678
GB/T14678
GB/T14678
GB/T14680
GB/T14677
GB/T14675
A1 Emission concentration
GB 14554—93
Appendix
A
Calculation of emission concentration and emission amount
(Supplement)
CE
×10″
Where: C——Concentration of odor pollutants, mg/m (dry standard state): g
Vnd
-The weight of the odor pollutant obtained by sampling·name; sampling volume, L (dry standard state). A2 Emission
G= C·Qrnd × 10-6
Where: G--Emission of odor pollutants, kg/hQand -
Gas flow rate of smokestack or exhaust pipe, m (dry standard state)/h. Additional notes:
This standard is proposed by the Science and Technology Standards Department of the State Environmental Protection Administration. This standard is edited by the Tianjin Environmental Protection Science Research Institute and the Environmental Protection Technology Research Institute of Beijing Institute of Mechanical and Electrical Engineering. The main drafters of this standard are Shi Lei, Wang Yanji, Li Xiurong, Jiang Ju, Wang Hongzhi, and Wei Hongmei. This standard is interpreted by the State Environmental Protection Administration. .(Al)
(A2)
777
2 For exhaust pipes between the two heights listed in Table 2, the height of the exhaust pipe shall be calculated using the rounding method. The exhaust pipe height listed in Table 2 refers to the vertical height from the ground (zero ground) to the exhaust port. 775 | | tt | | GB14554-93 | The lower part is sampled and monitored to measure the odor concentration or convert it to obtain the actual emissions. The monitoring point of the treated pollution source is located at the exhaust outlet of the treatment device, and a permanent sign should be set up. 6.1.4 The sampling frequency of organized emission sources should be determined according to the production cycle. If the production cycle is within 8 hours, the sampling frequency will be every 2 hours. If the production cycle is greater than 8 hours, the monitoring frequency will be collected once every 4 hours. The maximum measured value will be used. 6.2 Unorganized emission source monitoring
6.2.1 Sampling points
The monitoring sampling points at the factory boundary should be set on the downwind side of the factory boundary, or on the boundary line in the direction of odor. 6.2.2 Sampling frequency
Continuous emission sources are sampled every 2 hours, for a total of 4 times, and the maximum measured value is taken. For intermittent emission sources, sampling is selected during the maximum odor time, and the number of sample collection times is no less than 3 times, and the maximum measured value is taken. 6.3 Water area monitoring
Water area monitoring (including oceans, rivers, lakes, drainage ditches, canals) should use the shore as the factory boundary line, and its sampling point setting and sampling frequency are the same as those for unorganized emission source monitoring.
6.4 Determination
For the determination methods of individual odor pollutants and odor concentrations in the standards, see Table 3. Table 3 Odor pollutants and odor concentration determination method serial number
1
2
3
4
5
7|| tt||8
776
Control items
Ammonia
Trimethylamine
Hydrogen sulfide
Methyl mercaptan
Methyl sulfide
Dimethyl disulfide
Carbon disulfide
Styrene
Ogas concentration
Measurement method
GB/T 14679
GB/T14676
GB/T14678
GB/T14678
GB/T14678
GB/T14678
GB/T14680|| tt||GB/T14677
GB/T14675
A1 emission concentration
GB 14554—93
Appendix
A
, Calculation of emissions
(supplement)
CE
standard state): g
Vnd
-the weight·name of the odor pollutants sampled; sampling volume, L (dry standard state) A2 emission amount
G=. C.Qrnd )/h. Additional notes:
This standard is proposed by the Science and Technology Standards Department of the State Environmental Protection Administration. This standard is mainly drafted by the Tianjin Environmental Protection Science Institute and the Beijing Institute of Mechanical and Electrical Engineering. Shi Lei, Wang Yanji, Li Xiurong, Jiang Ju, Wang Hongzhi, Wei Hongmei. This standard is interpreted by the National Environmental Protection Administration. (Al)
(A2)
777
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