Some standard content:
Chemical Industry Standard of the People's Republic of China
HG2282—92
Disperse Red S-3GFL
Issued on June 1, 1992
Ministry of Chemical Industry of the People's Republic of China
Implementation on January 1, 1993
W Chemical Industry Standard of the People's Republic of China
Disperse Red S-3GL
(Disperse Red S-3GFL)
1 Subject content and scope of application
HG2282—92
This standard specifies the technical requirements, test methods, inspection rules and various requirements for marking, packaging, transportation and storage of Disperse Red S-3GL products.
This standard applies to the product obtained by coupling 2-chloro-4-nitroaniline with N-β-cyanoethyl-(-β-acetoxyethyl)aniline after diazotization, and the commercialized disperse red S-3-GL. This product is mainly used for dyeing polyester fibers. Molecular formula: C19H18CIN.04
Structural formula:
C2HOCO1CH
Relative molecular mass: 415.84 (according to the international relative atomic mass in 1989) 2 Reference standards
GB2374
GB2386
GB2394
GB2397bzxZ.net
GB3920
GB3921
GB3922
General conditions for dyeing determination
Determination of moisture content in dyes and dye intermediates Method for determination of color tone and intensity of disperse dyes Method for determination of lifting power of disperse dyes
Test method for color fastness of textiles to rubbing
Test method for color fastness of textiles to washing
Perspiration resistance of textiles Test method for color fastness to staining
GB5540
GB5541
GB5718
GB6152
GB8427
1/1 Standard depth color chart for dyeing with dyes
Determination method for dispersion properties of disperse dyes Double-layer filter paper filtration method Determination method for high-temperature dispersion stability of disperse dyes Test method for color fastness to dry heat (sublimation) of textiles Resistance to hot pressing (ironing)
Test method for color fastness
Test method for color fastness to light of textiles Xenon arc HG2-1120
HG2--1121
Determination method for diffusion properties of dyes
Determination method for fineness of dye particles
Microscope method
Editor's note: 1) The original version is \c", and this version is changed to \o". Approved by the Ministry of Chemical Industry of the People's Republic of China on June 1, 1992 and implemented on January 1, 1993
W.bzsoso.cOm3 Technical Requirements
3.1 Appearance: Brownish red uniform powder or granules. HG2282-92
3.2 The quality of Disperse Red S-3GL shall conform to the requirements of Table 1. Table 1
1. Strength (1) High temperature pressure method, points
(2) Hot melt method, points
2. Color light, high temperature pressure method
3. Particle fineness (number of particles>2um), pieces4. Diffusion performance, grade
5. Dispersibility, grade/grade
6. Moisture, %
7. Color uptake (130℃, 60min), %
8. Lifting power, grade
9. High temperature dispersion stability, grade-grade
The color fastness of dispersed red S-3GL on pure polyester fabric shall comply with the provisions of Table 2. Table 2
Light fastness (xenon arc)
Abrasion resistance
(60℃, 30min)
Note: 1/1 depth is equivalent to 2.0% (owf). 4 Test methods
4.1 Appearance
Measured by visual method.
4.2 Determination of dyeing color and intensity
Dry heat resistance
(210℃)
Hot pressing resistance
(200℃)
(immediately)
(4h)
100% of the standard
95% of the standard
Similar to the standard~slightly
Performed in accordance with the provisions of GB2394. The reagents and standards used meet the requirements of GB2374. High temperature and pressure method: dyeing depth 2%, pH value 5-6. Hot melt method: dyeing depth 20g/L, pre-baking temperature 100℃, pre-baking time 120s, hot melt temperature 200℃, hot melt time 120s, synthetic dragon glue is used as anti-migration agent.
4.3 Determination of particle fineness
According to the provisions of HG2-1121.
4.4 Determination of diffusion performance
According to the provisions of HG2-1120.
4.5 Determination of dispersibility and high-temperature dispersion stability
According to the provisions of double-layer filter paper filtration method in GB5540-5541. 4.6 Determination of moisture
According to the provisions of GB2386, the drying temperature is 100-105℃. 2
W.bzsoso:com4.7 Determination of lifting power
According to the provisions of GB2397.
4.8 Determination of color uptake
4.8.1 Method overview
HG2282-92
After dyeing according to the standard dyeing method, the ratio of the amount of dye on the dye sample to the total amount of dye in the dye bath is determined. 4.8.2 Reagents and instruments
The reagents used shall comply with the relevant provisions of GB2374. 4.8.2.1 Chlorobenzene-phenol mixture: prepared in a weight ratio of 1+1: 4.8.2.2 Volumetric flask: 50mL,
4.8.2.3 721 type or other type of photoelectric spectrophotometer; 4.8.2.4 Water bath;
4.8.2.5 Analytical balance: sensitivity 0.0001g. 4.8.3 Determination steps
According to the provisions of GB2374 and GB2394, the dye concentration is 0.5g/500mL, the dyeing depth is 2%, and the pH is 5~6. A sample is dyed by high temperature and pressure method. After reduction cleaning and drying, the sample is cut into pieces and fully mixed. 0.100g (accurate to 0.0001g) is weighed and placed in a 50mL volumetric flask. 3mL of chlorobenzene-phenol mixture is added to immerse the fiber in the above solvent. Then, it is placed in a boiling water bath for 2~3min. After the fiber is completely dissolved, it is diluted to the scale with acetone solution after cooling, shaken, covered and left to stand. Make sure that all polyester resin floccules are deposited at the bottom of the bottle for use (solution 1).
Use a pipette to draw 2mL of the above prepared dye solution into a 50mL volumetric flask, add 3mL of chlorobenzene-phenol mixture, and then place it in a boiling water bath for 2~3min. After cooling, it is diluted to the scale with acetone, shaken, covered and left to stand for use (solution 2). Use a glass dropper to carefully draw the clear colored solution from the top of solution 1 and 2 respectively. Use the acetone solution as the blank solution and measure the optical density on the photoelectric spectrophotometer (4.8.2.3). The maximum absorption wavelength is 470nm (the measured optical density values of the samples are all converted into the optical density values of 0.1g fiber).
Coloring rate (%) is calculated as follows:
Coloring rate (%)=
Where: E1——optical density value of solution 1; E2——optical density value of solution 2.
4.9 Determination of color fastness
All color fastness test samples are dyed to 1/1 depth according to the provisions of GB4841.1. 4.9.1 Determination of color fastness to light
Carry out according to the provisions of GB8427.
4.9.2 Determination of color fastness to rubbing
Carry out according to the provisions of GB3920.
4.9.3 Determination of color fastness to washing
Perform in accordance with the provisions of GB3921, using the conditions of method 3 and test solution 1. 4.9.4 Determination of color fastness to perspiration
Perform in accordance with the provisions of GB3922.
4.9.5 Determination of color fastness to hot pressing (ironing) shall be carried out in accordance with the provisions of GB6152 using the dry pressing method. 4.9.6 Determination of color fastness to dry heat (sublimation) shall be carried out in accordance with the provisions of GB5718.
Wbzsoso,cO5 Inspection rules
5.1 Inspection classification
HG2282-92
Items (1), (3), (4), (5) and (6) in Table 1 of 3.1 and 3.2 of this standard are factory inspection items. All items in the technical requirements are type inspection items. If one of the six situations described in 6.6.1 of GB1.3 occurs, type inspection should be carried out. During normal production, it should be carried out once a year.
5.2 Inspection by the manufacturer
Disperse Red S-3GL should be inspected by the quality inspection department of the manufacturer. The manufacturer should ensure that the quality of all Disperse Red S-3GL shipped out of the factory meets the requirements of this standard and is accompanied by a quality certificate in a certain format. If the user requires the hot melt method to be used for the strength determination of the product, the supply and demand parties can reach another agreement. 5.3 Sampling method
Random sampling is carried out in batches. The manufacturer considers uniform products mixed at one time as a batch, while the user considers products with the same batch number N
received from the same manufacturer as a batch. The number of samples shall not be less than (N is the number of barrels of each batch of products). The number of samples for small batches shall not be less than 3 barrels. When sampling, do not allow foreign impurities to fall into the product. Use a sampler to take samples from the upper, middle and lower parts respectively. After fully mixing and reducing the samples, take about 200g and pack them in two clean and dry ground-mouth bottles. Seal them with paraffin wax and label them with the manufacturer's name, product name, batch number, sampling date, one bottle for inspection and one bottle for future reference. 5.4 User Acceptance
The user shall verify the quality of the received dispersed red S-3GL in accordance with the provisions of this standard. When the supply and demand parties have objections to the product quality, they can negotiate and resolve the issue. 5.5 Re-inspection
If the inspection results do not meet the requirements of this standard, samples should be taken from twice the amount of packaging barrels for re-inspection. Even if only one indicator does not meet the requirements of this standard, the entire batch of products cannot be accepted. 5.6 Arbitration
When arbitration is required, the arbitration institution shall be determined by negotiation between the two parties. The arbitration method shall be in accordance with the provisions of this standard. 6 Marking, packaging, transportation, purchase and storage
6.1 The finished product packaging barrel should have clear markings, indicating the manufacturer's name, product name, trademark, production date, batch number, standard number, specifications, gross weight, net weight, and attach a product quality certificate. 6.2 Disperse Red S-3GL is packed in an iron barrel lined with a plastic bag. The plastic bag should be tied. Other packaging can be negotiated with the user. 6.3 Handle with care during transportation, prevent fire, sun and rain, and do not damage the packaging. 6.4 The product should be stored in a cool, dry and ventilated warehouse. Additional notes:
This standard was proposed by the Science and Technology Department of the Ministry of Chemical Industry of the People's Republic of China. This standard is under the technical jurisdiction of the Shenyang Chemical Industry Research Institute of the Ministry of Chemical Industry. This standard was drafted by the Beijing Dyestuff Factory. The main drafters of this standard are Zhang Junyi, Zhang Jianjin and Ding Lan. 4
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