GB/T 39498-2020 Guidelines for the Control of the Use of Key Chemical Substances in Consumer Products
Some standard content:
ICS 03.120.99
National Standard of the People's Republic of China
GB/T39498—2020
Guidelines for the use and control of key chemical in consumer products substancesinconsumerproduct
Issued on 2020-11-19
State Administration for Market Regulation
National Standardization Administration
Issued
Implementation on 2021-06-01
Foreword
Scope
2 Terms and Definitions
General Principles
Recommendations for Usage Control
Appendix A (Informative Appendix)
References
Standards for Detection Methods of Key Chemical Substances
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GB/T39498—2020
Foreword
This standard was drafted in accordance with the rules given in GB/T1.1-2009. This standard was proposed and managed by the National Technical Committee for Standardization of Consumer Product Safety (SAC/TC508). GB/T39498—2020
Drafting units of this standard: China National Institute of Standardization, National Quality Supervision and Inspection Center for Fine Chemicals, National Quality Supervision and Inspection Center for Incense Products (Fujian), Nan'an Zhongji Standardization Research Institute Co., Ltd., Guangdong Provincial Institute of Standardization, Hubei Provincial Institute of Standardization and Quality, China Inspection and Quarantine Scientific Research Institute, Beijing University of Technology, China Inspection and Quarantine (Tianjin) Inspection and Testing Co., Ltd., Tsinghua University, Hangzhou Huace Ruiou Technology Co., Ltd., Zhuoshang Clothing (Hangzhou) Co., Ltd., Changsha Haoming Educational Supplies Co., Ltd., Zhejiang Wangbin Decoration Materials Co., Ltd., China National Institute of Metrology, Hunan Product Quality Supervision and Inspection Institute, Shandong Product Quality Inspection Institute, Guangzhou Quality Supervision and Inspection Institute, Ningbo Yiren Toys Co., Ltd., Guangzhou Fiber Products Testing Institute, Ningbo Product Quality Supervision and Inspection Institute.
Main drafters of this standard: Liu Xia, Chen Yan, Zhu Bin, Liang Wei, Chen Xuezhang, Tang Wanjin, Li Sumei, Bai Hua, Wu Qian, Bai Liqiang, Chen Ming, Chen Yuan, Ji Yuwen, Zhuang Qi, Chen Huiming, Zhang Xueyong, Cui Benjie, Li Hongmei, Yang Xinhui, Chen Qianwen, Yao Bin, Xie Wenrong, Ye Ping, Jia Fang, Ji Weibing, Pei Fei, Huang Yinbo, Yang Ping, Chen Jinfeng, Ma Ping, Gao Cuiling, Niu Shuye, Li Jinhui, Wang Shuang, Tu Yongyuan, Dai Hangyong
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1 Scope
Guidelines for the use control of key chemical substances in consumer products This standard gives general principles and use control recommendations for key chemical substances in consumer products. This standard applies to the use control of key chemical substances in consumer products. 2 Terms and definitions
The following terms and definitions apply to this document. 2.1
consumerproduct
Consumer product
GB/T39498—2020
Products designed and produced for, but not limited to, personal use, including components, parts, accessories, packaging and instructions for use. [GB/T35246—2017, definition 3.1]
release amounts
release amounts
the amount of a chemical substance released from a sample into a medium such as a solvent, water or air according to a specified test method 2.3
migration
migration
the amount of a chemical substance migrated into a medium such as a solvent, water or air after immersion or extraction according to a specified test method.
Content
content
The ratio of the mass of a certain element or substance to the total mass of the sample 2.5
tolerablerisk
Tolerable risk
According to the current social value orientation, the risk that can be accepted within a certain range [GB/T28803—2012. Definition 3.15
banned substance
Prohibited
Chemical substance that shall not be added.
restrictedsubstance
Restricted
Chemical substance that shall not exceed the limit requirement when it exists as an impurity or by-product. 3 General principles
3.1 The content of key chemical substances in consumer products is closely related to protecting the personal health and safety of consumers and the safety of the ecological environment, and meeting social management requirements.
3.2 It is crucial to control the safety risk level of key chemical substances in consumer products within the tolerable risk range. 1
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GB/T39498—2020
For consumer products not covered by this standard, their relevant chemical substances can refer to similar products given in this standard. 3.3
Usage control recommendations
The usage control recommendations for key chemical substances in consumer products are shown in Table 1, and the detection method standards for key chemical substances are shown in Appendix A. Table 1
Recommendations for the control of key chemical substances in consumer products Sequence
Name
Trivalent chromium and its compounds
Hexavalent chromium and its compounds
CAS No.
7439-92-1, etc.
7439-97-6, etc.
16065-83-1, etc.
18540-29-9, etc.
Recommendations for control||tt ||Lead content <0.05%
Lead content ≤90mg/kg
Lead content ≤1000mg/kg
Lead migration ≤13.5mg/kg
Lead migration ≤3.4mg/kg
Lead migration ≤160mg/kg
Mercury migration ≤7.5mg/kg
Mercury migration ≤1.9mg/kg g
Migration of mercury≤94mg/kg
Prohibited
Mercury content≤1000mg/kg
Migration of trivalent chromium≤37.5mg/kg
Migration of trivalent chromium≤9.4mg/kg
Migration of trivalent chromium≤460mg/kg
Migration of hexavalent chromium≤0.02mg/kg
Migration of hexavalent chromium≤ 0.005mg/kg
Migration of hexavalent chromium≤0.053mg/kg
Content of hexavalent chromium≤2mg/kg
Content of hexavalent chromium<3mg/kgwww.bzxz.net
Content of hexavalent chromium≤1000mg/kg
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Scope of applicable consumer products
Any single component of jewelry products
All children Paints and similar surface coatings for children: Paints and similar surface coatings on some furniture for adults and children; Household paints; Electrical and electronic products; Dry, brittle, powdery or pliable toy materials; Liquid or sticky toy materials; Toy materials that can be scraped off; Dry, brittle, powdery or pliable toy materials; Liquid or sticky toy materials; Toy materials that can be scraped off; a) Thermometers; Other measuring instruments sold in public places; b) Electrical and electronic products; Dry, brittle, powdery or pliable toy materials; Liquid or sticky toy materials; Toy materials that can be scraped off; a) Thermometers; b) Other measuring instruments sold in public places; , brittle, powdery or flexible toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Cement and mixtures containing cement
Products with leather and leather products in contact with the skin
Electronic and electrical products
Name
CAS number
7440-43-9, etc.
7440-38-2||tt ||7440-36-0
7440-48-4
7440-50-8
Table 1 (continued)
Control suggestions
Migration of cadmium ≤1.3mg/kg
Migration of cadmium ≤0.3mg/kg
Migration of radiation ≤17mg/kg
Content of radiation <0.01%
Content of cadmium <0.1%
Radium content ≤100mg/kg
Migration of ≤3.8mg/kg
Migration of arsenic ≤0.9mg/kg
Migration of arsenic ≤47mg/kg
Migration of antimony ≤30mg/kg
Migration of antimony ≤45mg/kg
Migration of antimony ≤11.3mg/kg
Migration of ≤560mg/kg
Migration of cobalt ≤10.5mg/kg||tt ||Migration of cobalt ≤2.6mg/kg
Migration of diamond ≤130mg/kg
Migration of copper ≤622.5mg/kg
Migration of copper ≤156mg/kg
Migration of copper ≤7.700mg/kg
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GB/T39498—2020
Scope of applicable consumer products
Dry, brittle, powdery or flexible toy materials
Liquid or viscous Toy materials
Scrapeable toy materials
Plastic materials, including polyethylene, polyurethane, low-density polyethylene ester, cellulose acetate, butyl cellulose acetate, epoxy resin, melamine-formaldehyde, urea-formaldehyde, unsaturated polyester, polyethylene terephthalate, polybutylene terephthalate, transparent/ordinary polystyrene, acrylonitrile methacrylate, cross-linked polyethylene. High-impact polystyrene, polypropylene
Metal beads and other metal parts used in the manufacture of jewelry
Jewelry, simulation Jewelry and hair accessories, including bracelets, necklaces, rings, piercing jewelry, watches, wristbands, brooches, cufflinks
Coatings with EU CN codes 3208 and 3209 with zinc content exceeding 10%
Electronic and electrical products
Dry, brittle, powdery or flexible toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Ecological leather products (including leather products for infants, direct skin contact, indirect skin contact, and leather products for Leather decorative materials)
Dry, brittle, powdery or flexible toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Dry, brittle, powdery or flexible toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Dry, brittle, powdery or flexible toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
GB/T39498— 2020
Name
Dioctyltin compounds
Organotin compounds:
Dimethyltin;
Diphenyltin;
Dipropyltin;
Monobutyltin;
Monooctyltin;
Dimethyltin;
Phenyltin trichloride:
Tetrabutyltin;
Tetraethyltin;
Tricycloethyltin chloride;
Trimethyltin chloride:
Trioctyltin chloride;||tt ||Tri-n-propyltin chloride
CAS No.
7440-02-0 etc.
7440-31-5
1461-22-9 etc.
4618-18-2 etc.
683-18-1 etc.
870-08-6 etc.
a)753-73-1 etc.:
b)1135-99-5 etc.:
c)867-36-7 etc.;
d)1118-46 -3 etc.
e) 3091-25-6 etc.;
f) 23001-26-5 etc.;
g) 1124-19-2 etc.
h) 1461-25-2 etc.
i) 597-64-8 etc.;
j) 3091-32-5 etc.;
k) 1066-45-1 etc.:
D2587-76-0 etc.:
m) 2279-76-7 etc.
7429-90 -5
Table 1 (continued)
Control suggestions
Migration of nickel ≤75mg/kg
Migration of nickel ≤18.8mg/kg
Migration of nickel ≤930.mg/kg
Release of nickel ≤0.5ug/(cm2·week)Release of nickel ≤0.2ug/(cm2 week)
Migration of tin ≤15000mg/kg
Migration of tin ≤3750mg/kg
Migration of tin ≤ 180000mg/kg
Tin content ≤0.1%
Tin content ≤0.1%
Tin content ≤0.1%
Tin content ≤0.1%
Migration amount of single substance of organotin compound ≤0.9mg/kg
Migration amount of single substance of organotin compound ≤0.2mg/kg
Migration amount of single substance of organotin compound ≤12mg/kg
Aluminum Migration amount ≤5625mg/kg
Aluminum migration amount ≤1406mg/kg
Aluminum migration amount ≤70000mg/kg
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Applicable consumer product range
Dry, brittle, powdery or flexible toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Products that have direct or long-term contact with the skin Products used for puncture of human body parts
Dry, brittle, powdery or flexible toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Products that have direct or long-term contact with the skin Products that are used for puncture of human body parts
Crumb, powdered or pliable toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Consumer products containing dibutyltin compounds
Consumer products containing triphenyltin compounds
Consumer products containing dibutyltin compounds
Textile articles in direct contact with the skin;
b) Gloves;
Footwear or parts of footwear in contact with the skin:
d) Wall and floor coverings;
e) Children's Care products:
D) Female hygiene products;
g) Diapers
Dry, brittle, powdery or flexible toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Dry, brittle, powdery or flexible toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Name
Toluene
Formaldehyde
CAS No.
7440-39 -3
7440-42-8
7439-96-5
7782-49-2
7440-24-6
31396-84-6
71-43-2
108-88-3
50-00-0
Table 1 (continued)
Control recommendations
Migration amount of collar ≤1500mg/kg
Migration amount of collar ≤375mg/kg||tt ||Migration of lock≤18750mg/kg
Migration of boron≤1200mg/kg
Migration of boron≤300mg/kg
Migration of boron≤15000mg/kg
Migration of manganese≤1200mg/kg
Migration of manganese≤300mg/kg
Migration of manganese≤15000mg/kg
Migration of selenium≤37.5mg/kg
Migration of selenium≤9.4mg/ kg
Selenium migration≤460mg/kg
Strontium migration≤4500mg/kg
Strontium migration≤1125mg/kg
Strontium migration≤56000mg/kg
Zinc migration≤3750mg/kg
Zinc migration≤938mg/kg
Zinc migration≤46000mg/kg
Free benzene content≤5mg/kg
Toluene content<0.1%
Free and hydrolyzable formaldehyde content
Amount ≤30mg/kg
Formaldehyde content ≤30mg/kg
Formaldehyde release ≤80mg/kg
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GB/T39498—2020
Applicable consumer goods range
Dry, brittle, powdery or flexible toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off| |tt||Dry, brittle, powdery or pliable toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Dry, brittle, powdery or pliable toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Dry, brittle, powdery or pliable toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Dry, brittle, powdery or pliable toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Dry, brittle, powdery or pliable Toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Dry, brittle, powdery or pliable toy materials
Liquid or sticky toy materials
Toy materials that can be scraped off
Toys and their parts
Adhesives and spray paints
Contact textile parts of toys designed for children under 3 years of age
Contact paper parts of toys designed for children under 3 years of age Accessible materials of toys designed for children under 18 years of age and toy resin-glued wood
GB/T39498—2020
Name
Styrene
Phenol
Bisphenol A
CAS No.
100-42-5
108-95-2
80-05-7
Table 1 (continued)
Control recommendations
Migration amount of styrene monomer
≤0.7 5mg/L
Phenol migration≤5mg/L
Phenol content≤10mg/kg
Bisphenol A migration≤0.1mg/L
Bisphenol A content<0.02%
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Applicable consumer product scope
The mass of polymer material does not exceed
150g, suitable for toys that children under 3 years old hold
in their hands and toy parts that may touch
;
Toys made of polymers for children under 3 years old to be held in the mouth;
Mouthpieces of mouth-actuated toys made of polymers;
Toys made of polymers that cover the mouth and nose when worn:
Parts of drawing utensils made of polymers:
Toys and parts made of polymers that resemble food:
Toy jewelry made of polymers g)
Polymer materials in toys or toy parts that can be eaten by children under 3 years old
Preservatives in toys or toy parts that can be eaten by children under 3 years old
The mass of polymer materials shall not exceed
150g+Applicable to toys that children under 3 years old hold in their hands and toy parts that may be touched:
Toys made of polymer materials that are specially put in the mouth by children under 3 years old;
Material Mouthpieces of polymer mouth-actuated toys; Toys made of polymer that cover the mouth and nose when worn: Parts of polymer drawing utensils: Food-like toys and parts made of polymer: Toy jewelry made of polymer g) Thermal paper Name Chloroform (trichloromethane) 1,1.2 -Trichloroethane
1,1.2,2-Tetrachloroethane
1.1,1.2-Tetrachloroethane
Pentachloroethane
1,1-Dichloroethylene
Polybrominated biphenyls
Diethylene glycol monomethyl ether
Diethylene glycol butyl ether
Tricresyl phosphate
Tris(2-chloroethyl) phosphate
CAS No.
67-66-3
79-00-5
79-3 4-5
630-20-6
76-01-7
75-35-4
59536-65-1, etc.
111-77-3
112-34-5
78-30-8
115-96-8
Table 1 (continued)
Control recommendations
Chloroform content <0.1%
1,1,2-trichloroethane content||tt| |<0.1%
Content of 1,1,2,2-tetrachloroethane
0.1%
Content of 1,1.1.2-tetrachloroethane
<0.1%
Content of pentachloroethane<0.1%
Content of 1,1-dichloroethylene<0.1%
Prohibited
Content of polybrominated biphenyls≤1000mg/kg
Content of diethylene glycol monomethyl ether
<0.1%
Content of diethylene glycol monomethyl ether Content of butyl alcohol <3%
Content of tricresol phosphate
<50mg/kg
Migration amount of tricresol phosphate
<0.03mg/L
Content of tris(2-chloroethyl) phosphate
<50mg/kg
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GB/T39498—2020
Applicable consumer products
Surface cleaning agents, textile cleaning products and Textiles for direct skin contact
Electronic and electrical products
a) Dyes;
b) Paint removers;
c) Cleaners;
d) Bright varnish;
Floor sealants
a) Spray paint;
b) Spray cleaners
Toys and detachable toy parts made of textile materials designed for children under 3 years old
The mass of polymer materials does not exceed
150g, suitable for children under 3 years old Toys that children hold in their hands and toy parts that may touch them; Toys made of polymers for children under 3 years old to be held in their mouths; Mouthpieces of polymer mouth-actuated toys: Parts of polymer drawing utensils: Food-like toys and parts made of polymers: Toy jewelry made of polymers Toys and detachable toy parts made of textile materials designed for children under 3 years old
GB/T39498—2020
Name
Triphenyl phosphate
Tri(m-cresyl) phosphate
Tri(p-methylphenyl) phosphate
Aniline
Acrylamide
CAS No.
115-86-6
563-04-2
78-32-0
6 2-53-3
79-06-1
Table 1 (continued)
Control recommendations
Migration of triphenyl phosphate
<0.03mg/L
Migration of tri(m-cresyl) phosphate
<0.03mg/L
Migration of tri(p-methylphenyl) phosphate
Migration of aniline<5mg/kg
Migration of acrylamide≤0.02mg/L
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Applicable consumer goods range
The mass of polymer materials does not exceed
150g. Applicable to toys held in the hands of children under 3 years old and toy parts that may be touched
:
Toys held in the mouth for children under 3 years old made of polymers;
The mouthpiece of mouth-actuated toys made of polymers;
Parts of drawing utensils made of polymers:
Food-like
Toys and parts made of polymers:
Toy jewelry made of polymers
a) The mass of wood and paper does not exceed 150g, applicable to toys held in the hands of children under 3 years old and toy parts that may be touched
:
Material is Textiles and leather toys designed for children under 3 years old and detachable toy parts: c) Mouthpieces of mouth-actuated toys made of wood and paper: d) Toys made of textiles and paper that cover the mouth and nose after wearing; solid toy materials that can leave traces; e) Toys containing contactable colored liquids: moldable clay toys; h) Toys composed of balloons; Toy tattoos containing adhesives. The mass of polymers does not exceed 150g, and is suitable for toys that children under 3 years old hold in their hands and toy parts that may touch: b) Toys made of polymers that are held in the mouth for children under 3 years old; ||Mouthpiece:
Toys made of polymer that cover the mouth and nose when worn:
Parts of drawing utensils made of polymer:
Food-like things made of polymer
f)
Toys and parts:
Toy jewelry made of polymer
g)
Name
Tris(aziridinyl)phosphine oxide
King Phenol
Phenol polyoxyethylene ether
Formamide
Dimethyl fumarate
Perfluorooctane sulfonic acid and its
derivatives
Perfluorooctanoic acid and its salts and perfluorocarboxylic acid compounds with carbon chain length ≥ 8
N-nitrosamine
CAS No.
545-55-1
25154-52-3, etc.
9016-45 -9, etc.
75-12-7
624-49-7
1763-23-1, etc.
335-67-1, etc.
62-75-9, etc.
Table 1 (continued)
Control suggestions
Prohibited
The content of polyoxyethylene ether ... Content of ethylene oxide
0.01%
Content of formamide≤200mg/kg
Content of dimethyl fumarate
≤0.1mg/kg
Content of perfluorooctane sulfonic acid and its derivatives
<0.1%
Content of perfluorooctane sulfonic acid and its derivatives
<1.0ug/m
Content of perfluorooctanoic acid and its salts
<25 μg/kg(μg/L)
Perfluorooctanoic acid and its salts and perfluorocarboxylic acid compounds with carbon chain length
≥8, single item or
total content<1000μg/kg(μg/L)
Migration of N-nitrosamines
≤0.01mg/kg
Migration of N-nitrosamines
≤0.01mg/kg
Migration of N-nitrosamines
0.05mg/kg g
Migration amount of N-nitrosamine
≤0.02mg/kg
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GB/T39498—2020
Scope of applicable consumer products
Textiles in contact with skin
a) Household cleaning agents;
b) Other personal care products (except cosmetics)
Household cleaning agents:
b)
Other personal care b) Foam toy materials Consumer products containing dimethyl fumarate Consumer products containing perfluorooctane sulfonic acid in their structure or microstructure Coatings Consumer products coated with photographic coatings, and other consumer products other than semiconductors or compound semiconductors For children under 3 years old Elastomeric toys intended or likely to be placed in the mouth of the following children: Elastomeric or rubber nipples and pacifiers: a) Balloons; b) Toys intended to be placed in the mouth by children aged 3 years and over; Toys intended for children under 3 years old (except elastomeric toys intended or likely to be placed in the mouth for children under 3 years old); Finger paints for children under 3 years old1mg/kg
Content of perfluorooctane sulfonic acid and its derivatives<0.1%
Content of perfluorooctane sulfonic acid and its derivatives<1.0ug/m
Content of perfluorooctanoic acid and its salts
<25 μg/kg(μg/L)
Perfluorooctanoic acid and its salts and perfluorocarboxylic acid compounds with carbon chain length
≥8, single item or
total content<1000μg/kg(μg/L)
Migration of N-nitrosamines
≤0.01mg/kg
Migration of N-nitrosamines
≤0.01mg/kg
Migration of N-nitrosamines
0.05mg/kg g
Migration amount of N-nitrosamine
≤0.02mg/kg
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GB/T39498—2020
Scope of applicable consumer products
Textiles in contact with skin
a) Household cleaning agents;
b) Other personal care products (excluding cosmetics)
Household cleaning agents:
b)
Other personal care b) Foam toy materials Consumer products containing dimethyl fumarate Consumer products containing perfluorooctane sulfonic acid in their structure or microstructure Coatings Consumer products coated with photographic coatings, and other consumer products other than semiconductors or compound semiconductors For children under 3 years old Elastomeric toys intended or likely to be placed in the mouth of the following children: Elastomeric or rubber nipples and pacifiers: a) Balloons; b) Toys intended to be placed in the mouth by children aged 3 years and over; Toys intended for children under 3 years old (except elastomeric toys intended or likely to be placed in the mouth for children under 3 years old); Finger paints for children under 3 years old1mg/kg
Content of perfluorooctane sulfonic acid and its derivatives<0.1%
Content of perfluorooctane sulfonic acid and its derivatives<1.0ug/m
Content of perfluorooctanoic acid and its salts
<25 μg/kg(μg/L)
Perfluorooctanoic acid and its salts and perfluorocarboxylic acid compounds with carbon chain length
≥8, single item or
total content<1000μg/kg(μg/L)
Migration of N-nitrosamines
≤0.01mg/kg
Migration of N-nitrosamines
≤0.01mg/kg
Migration of N-nitrosamines
0.05mg/kg g
Migration amount of N-nitrosamine
≤0.02mg/kg
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GB/T39498—2020
Scope of applicable consumer products
Textiles in contact with skin
a) Household cleaning agents;
b) Other personal care products (except cosmetics)
Household cleaning agents:
b)
Other personal care b) Foam toy materials Consumer products containing dimethyl fumarate Consumer products containing perfluorooctane sulfonic acid in their structure or microstructure Coatings Consumer products coated with photographic coatings, and other consumer products other than semiconductors or compound semiconductors For children under 3 years old Elastomeric toys intended or likely to be placed in the mouth of the following children: Elastomeric or rubber nipples and pacifiers: a) Balloons; b) Toys intended to be placed in the mouth by children aged 3 years and over; Toys intended for children under 3 years old (except elastomeric toys intended or likely to be placed in the mouth for children under 3 years old); Finger paints for children under 3 years old
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