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Test method of classfication for import and export dangerous goods—Part17:Marine pollutant

Basic Information

Standard ID: SN/T 1828.17-2013

Standard Name:Test method of classfication for import and export dangerous goods—Part17:Marine pollutant

Chinese Name: 进出口危险货物分类试验方法 第17部分:海洋污染物

Standard category:Commodity Inspection Industry Standard (SN)

state:in force

Date of Release2013-11-06

Date of Implementation:2014-06-01

standard classification number

Standard ICS number:Packaging and transportation of goods>> Freight transportation>> 55.180.01 Freight transportation general

Standard Classification Number:Comprehensive>>Marking, packaging, transportation, storage>>A80 Marking, packaging, transportation, storage Comprehensive

associated standards

alternative situation:Announcement: Notice of the National Certification and Accreditation Administration on the Announcement of the Review Conclusions of the Inspection and Quarantine Industry Standards in 2017 (CNCA [2017] No. 146)

Publication information

publishing house:China Standards Press

Publication date:2014-06-01

other information

Review date:2017-12-22

drafter:Han Wei et al.

Drafting unit:Tianjin Entry-Exit Inspection and Quarantine Bureau of the People's Republic of China, etc.

Focal point unit:Certification and Accreditation Administration of the People's Republic of China

Publishing department:General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China

Introduction to standards:

SN/T 1828.17-2013. Test method of classification for import and export dangerous goods-Part 17: Marine pollutant.
1 Scope
SN/T 1828.17 specifies the test and classification of marine pollutants for import and export dangerous goods.
SN/T 1828.17 applies to the test of hazardous characteristics of marine pollutants for import and export dangerous goods.
2 Normative references
The following documents are indispensable for the application of this document. For all dated application documents, only the dated version applies to this document. For all undated referenced documents, the latest version (including all amendments) applies to this document.
GB/T21281Test methods for classification of acute toxicity of hazardous chemicals to fish
GB/T 21800Flow-through fish test for bioaccumulation of chemicals
GB/T 21801Respirometry test for rapid biodegradability of chemicals
GB/T 21802Modified MITI test (I) for rapid biodegradability of chemicals
GB/T21803DOC reduction test for rapid biodegradability of chemicals
GB/T 21805Algae growth inhibition test for chemicals
GB/T 21815.1Shake flask test for biodegradability of chemicals in seawater
GB/T21828Reproduction test for chemicals with large mites
GB/T 21830Acute activity inhibition test for chemicals with mites
GB/T21831Rapid biodegradability of chemicals: Closed flask test
GB/T 21852 Chemical Partition Coefficient (n-octanol-water) High Performance Liquid Chromatography Test
GB/T 21853 Chemical Partition Coefficient (n-octanol-water) Shake Flask Test
3 Terms and Definitions
The terms and definitions defined in the Recommendations on the Transport of Dangerous Goods Model Regulations and the following terms and definitions apply to this document.
3.1 Acute aquatic toxicityacute aquatic toxicity
The inherent property of a substance to cause harm to organisms exposed to it for a short period of time.
3.2 Chronic aquatic toxicitychronic aquatic toxicity
The potential or actual property of a substance to cause harmful effects to aquatic organisms during exposure periods relevant to the life cycle of the organism.
This part of SN/T 1828 specifies the tests and category determination of marine pollutants for dangerous goods for import and export. This part applies to the test of hazardous characteristics of marine pollutants for dangerous goods for import and export.


Some standard content:

People's Republic of China Entry-Exit Inspection and Quarantine Industry Standard SN/T1828.17—2013
Test method of classification for import and export dangerous goods-Part17:Marinepollutant
Published on November 6, 2013
People's Republic of China
General Administration of Quality Supervision, Inspection and Quarantine
Implementation on June 1, 2014
SN/T1828 "Test method of classification for import and export dangerous goods" is divided into 17 parts: Part 1: General;
Part 2: Civilian explosives;
Part 3: Oxidizers;
Part 4: Corrosive substances;
Part 5: Gas mixtures Part 6: Substances which emit flammable gases in contact with water; Part 7: Compressed gases; Part 8: Organic peroxides: Part 9: Toxic substances; Part 10: Toxic gases; Part 11: Flammable solids; Part 12: Flammable gases; Part 13: Flammable liquids; Part 14: Lithium batteries; Part 15: Self-heating solids: Part 16: Nitrates; Part 17: Marine pollutants. This part is Part 17 of SN/T 1828. This part was drafted in accordance with the rules given in GB/T 1.1-2009. SN/T 1828.17—2013
This part is modified to adopt the United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations (17th revised edition), and its relevant technical contents are completely consistent with the above regulations.
This part is proposed and managed by the National Certification and Accreditation Administration. Drafting units of this part: Tianjin Exit-Entry Inspection and Quarantine Bureau of the People's Republic of China, Shandong Exit-Entry Inspection and Quarantine Bureau of the People's Republic of China.
Main drafters of this part: Han Wei, Yu Yanjun, Wan Min, Xiong Zhongqiang, Zhao Lihua, Pang Zhen. I
1 Scope
Classification test methods for dangerous goods for import and export
Part 17: Marine pollutants
This part of SN/T 1828 specifies the test and category determination of marine pollutants for dangerous goods for import and export. This part applies to the hazardous characteristics test of marine pollutants for dangerous goods for import and export. 2 Normative references
SN/T1828.17—2013
The following documents are indispensable for the application of this document. For any dated application document, only the dated version applies to this document. For any undated referenced document, the latest version (including all amendments) applies to this document. GB/T21281
GB/T21800
GB/T21801
GB/T21802
GB/T21803
GB/T21805
Dangerous chemicals-Test method for acute toxicity of fish-Biological enrichment flow-through fish test
Chemicals
Chemicals
Chemicals
Chemicals
Chemicals
Chemicals
Chemicals
Chemicals
|GB/T21815.1
GB/T21828
GB/T21830
GB/T21831
GB/T21852
GB/T21853
GB/T21854
GB/T21856
GB/T21857
Ready biodegradability Respirometric test Modified MITI test for rapid biodegradability ( I) Ready biodegradabilityDOC reduction testbZxz.net
Algal growth inhibition test
Chemical
Biodegradation in seawaterShake flask testChemical
Daphnia magna reproduction test
Chemical
Chemical
Chemical
Chemical
Chemical
Chemical
Chemical
Neat acute immobilization test
Ready biodegradability: closed bottle testPartition coefficient (n-octanol-water)HPLC testPartition coefficient (n-octanol-water)Shake flask testToxicity test for fish early life stages
Ready biodegradabilityCarbon dioxide generation testModified OECD screening test for ready biodegradabilityRecommendations on the Transport of Dangerous Goods Model Regulations (United Nations, 17th revised edition) 3 Terms and definitions
For the purpose of this document, the terms and definitions defined in the Recommendations on the Transport of Dangerous Goods Model Regulations and the following apply. 3.1
acute aquatic toxicity
Acute aquatic toxicity
The inherent property of a substance to cause harm to organisms exposed to it in the short term. 3.2
chronic aquatic toxicityThe potential or actual property of a substance to produce harmful effects on aquatic organisms during exposure periods relevant to the life cycle of the organism. 3.3
bioaccumulation
The net result of the uptake, transformation and elimination of a substance by an organism through all exposure pathways (air, water, sediment/soil and food, etc.). SN/T1828.17—2013
degradation
The decomposition of organic molecules into smaller molecules and finally into carbon dioxide, water and salts. 3.5
no observed effect concentration
no observed effect concentration; NOECThe test concentration is just below the lowest measured concentration that produces a statistically significant adverse effect. 3.6
Median lethal dose 50%, LDso is the dose that causes 50% (half) death of a group of test organisms. 3.7
Median lethal concentration, LCso is the concentration that causes 50% (half) death of a group of test organisms. 3.8
The concentration that causes % of organisms in a group of test organisms to show a certain observed effect. 3.9
Marine pollutantsmarinepollutant
Includes liquid or solid substances that pollute the aquatic environment, as well as mixtures of such substances. The basic elements for the classification of marine pollutants include acute aquatic toxicity, chronic aquatic toxicity, actual or potential bioaccumulation capacity, and organic chemicals (biological or abiotic) degradation capacity. 3.10
Biochemical oxygen demand, BOD. It is 5d biochemical oxygen demand. 3.11
Chemical oxygen demand.
4 General requirements
Warning—Due to their inherent hazards, testing laboratories should pay special attention to the health and safety requirements required by regulations. 4.1 Laboratory requirements
In general, toxicity data for freshwater and marine species can be considered as equivalent data, preferably data obtained using OECD test guidelines or equivalent data obtained according to the principles of Good Laboratory Practice (GLP). In the event that such data are not available, classification should be based on the most reliable data available.
4.2 Data requirements
4.2.1 Acute aquatic toxicity data
Acute aquatic toxicity data should meet the following requirements: a) 96h LCsa for fish (GB/T 21281 or equivalent test); b) 48h ECso test for crustaceans (GB/T 21830 or equivalent test), and/or; ce) 72h or 96h ECso test for seaweed (GB/T 21805 or equivalent test). These species can be considered as surrogate species for all aquatic organisms. Data on other species, such as duckweed, may also be considered if the test methods are appropriate.
4.2.2 Chronic toxicity Aquatic toxicity data
Chronic toxicity Aquatic toxicity data should meet the following requirements: data obtained from early life stages of fish GB/T 21854a)
b) data obtained from reproduction of Daphnia GB/T 21828, and; c) data obtained from inhibition of algal growth GB/T 21805. SN/T 1828.17—2013
Other valid and internationally accepted tests may also be used. "No Observed Effect Concentrations" (NOECs) or other equivalent EC4.2.3 Bioaccumulation Capacity
The bioaccumulation capacity is usually determined by the octanol partition coefficient, usually reported as logK according to GB/T21853 or GB/T21852. Although it also reflects the bioaccumulation capacity, the "bioconcentration factor" (BCF) determined by experiment is a better method and should be used in preference when possible. The bioconcentration factor should be determined in accordance with GB/T21800. 4.2.4 Environmental Degradation
Environmental degradation can be biological or abiotic (such as hydrolysis). Biodegradability tests (GB/T21801, GB/T21802, GB/T21803, GB/T21831. GB/T21856, GB/T21857) can be used to determine whether it is readily biodegradable. A pass level in the test can be considered to be rapidly degradable in most environments. Since this is a freshwater test, the results of GB/T21815.1 are also included, which is more suitable for marine environments. In the absence of such data, BOD (5d) / COD ≥ 0.5 is also considered to indicate rapid degradation.
4.2.5 Rapid environmental degradation
, reaching the following degradation levels!
4.2.5.1 In a 28-day rapid biodegradation study a) Based on tests on dissolved organic carbon: 70%: b) Based on tests measuring oxygen consumption or carbon dioxide production: 60% Theoretical peak: The above biodegradation level should be reached within 10 days after the start of degradation, when the start of degradation is when 10% of the substance has been degraded; unless the substance is a mixture with multiple components of similar structure. In this case, the 10-day window condition can be abandoned and the pass level can be applied at 28 days.
4.2.5.2 Where only BOD and COD data are available, BODs/COD ≥ 0.54.2.5.3 Where other credible scientific evidence is available to show that the substance or mixture can be degraded by more than 70% in the aquatic environment (through biotic and/or abiotic pathways) within 28 days. 5 Classification categories and standards
Categories and standards for substance classification
Substances meet the acute, chronic, or class II categories based on their aquatic toxicity hazards. 5.1.2 Acute (short-term) aquatic hazards shall meet the following requirements: a) 96h, LCsa (fish) ≤ 1mg/L; and/or b) 48h, ECso (crustacea) ≤ 1mg/L; and/or c) 72 or 96h, ECso (algae or other aquatic plants) ≤ 1mg/L. 5.1.3 Long-term aquatic hazards should meet the following requirements:
a) Non-rapidly degradable substances with sufficient chronic toxicity data 1) Chronic Category I:
SN/T1828.17—2013
Chronic NOEC or EC. (fish) ≤0.1mg/L: and/or chronic NOEC or EC. (crustacea) ≤0.1mg/L: and/or chronic NOEC or EC, (algae or other aquatic plants) ≤0.1mg/L 2) Chronic Category II:
-Chronic NOEC or EC (fish) ≤1mg/L: and/or chronic NOEC or EC (crustacea) ≤1mg/L; and/or chronic NOEC or EC. (algae or other aquatic plants) ≤1mg/L. b) Rapidly degradable substances with sufficient chronic toxicity data 1) Chronic Category I:
Chronic NOEC or EC (fish) ≤ 0.01 mg/L; and/or Chronic NOEC or EC, (crustacea) ≤ 0.01 mg/L: and/or Chronic NOEC or EC. (algae or other aquatic plants) ≤ 0.01 mg/L. 2) Chronic Category II:
Chronic NOEC or EC. (fish) ≤ 0.1 mg/L: and/or Chronic NOEC or EC (crustacea) ≤ 0.1 mg/L; and/or Chronic NOEC or EC, (algae or other aquatic plants) ≤ 0.1 mg/L. Substances without sufficient chronic toxicity data c
1) Chronic Category I:
-96h, LCso (fish) ≤1mg/L and/or -48h, EC50 (crustacea) ≤1mg/L: and/or -72h or 96h, ECso (algae or other aquatic plants) ≤1mg/L non-rapidly degradable substances and/or experimentally determined BCF≥500 (or lack of data for logKw≥4). 2) Chronic Category II:
-96h, LCso (fish)>1 but ≤10mg/L and/or -48h, ECso (crustacea)>1 but ≤10mg/L; and/or -72h or 96h, ECso (algae or other aquatic plants)>1 but ≤10mg/L and/or -72h or 96h, ECso (algae or other aquatic plants)>1 but ≤10mg/L and/or a non-rapidly degradable substance and/or experimentally determined BCF≥500 (or lack of data for logKw≥4). NOTE 1: Fish crustaceans and algae are tested as alternatives, covering all trophic levels and taxa, and the test methods are highly standardized. Data from other organisms may also be considered, however, they should be provided as equivalent substances and test endpoints. NOTE 2: When classifying a substance as acute I and/or chronic I, also indicate the appropriate M factor to obtain the sum. NOTE 3: When the reduction in algal toxicity ErC[=ECa (growth rate) is greater than 100 times that of the next most sensitive species, and classification is based solely on this result, consider whether this toxicity data can be replaced by equivalent plant toxicity data. If it can be demonstrated that this is not the case, professional judgement is used. Classification is based on ErCso data. In the absence of ECse data, classification is based on the lowest available ECso NOTE 4: Lack of rapid degradation data refers to the lack of biodegradability and other rapid degradation data. When no degradation data, other empirical or predictive data are available, the substance is considered to be non-rapidly degradable. NOTE 5: Bioaccumulation potential is based on an experimentally derived BCF ≥ 500, or, in the absence of data on logKw ≥ 4. logKw data is better than the estimated value, and BCF data is better than logK value.
The classification scheme of substances that are harmful to the aquatic environment is shown in Table 1 based on their aquatic toxicity hazards. 4
Acute toxicity*
Category: Acute I
L(E)Cso≤1mg/L
Classification scheme of substances that are harmful to the aquatic environment
Classification category
Chronic toxicity.
Adequate chronic toxicity data
Non-rapidly degradable substances
Category: Chronic industrial
NOEC or
EC,≤0.1 mg/L
Category: Chronic II
Rapidly degradable substances.
Category: Chronic I
NOEC or
EC≤0.01mg/L
Category: Chronic II
0.1mg/L3 If other credible scientific evidence is available to show that the substance or mixture can be degraded by more than 70% in the aquatic environment (through biotic and/or abiotic pathways) within 28 days. 5 Classification categories and standards
Categories and standards for substance classification
Substances meet the acute, chronic or class II categories based on their aquatic toxicity hazards. 5.1.2 Acute (short-term) aquatic hazards should meet the following requirements: a) 96h, LCsa (fish) ≤1mg/L; and/or b) 48h, ECso (crustacea) ≤1mg/L; and/or c) 72 or 96h, ECso (algae or other aquatic plants) ≤1mg/L. 5.1.3 Long-term aquatic hazards should meet the following requirements:
a) Non-rapidly degradable substances with sufficient chronic toxicity data 1) Chronic Category I:
SN/T1828.17—2013
Chronic NOEC or EC. (fish) ≤0.1mg/L: and/or chronic NOEC or EC. (crustacea) ≤0.1mg/L: and/or chronic NOEC or EC, (algae or other aquatic plants) ≤0.1mg/L 2) Chronic Category II:
-Chronic NOEC or EC (fish) ≤1mg/L: and/or chronic NOEC or EC (crustacea) ≤1mg/L; and/or chronic NOEC or EC. (algae or other aquatic plants) ≤1mg/L. b) Rapidly degradable substances with sufficient chronic toxicity data 1) Chronic Category I:
Chronic NOEC or EC (fish) ≤ 0.01 mg/L; and/or Chronic NOEC or EC, (crustacea) ≤ 0.01 mg/L: and/or Chronic NOEC or EC. (algae or other aquatic plants) ≤ 0.01 mg/L. 2) Chronic Category II:
Chronic NOEC or EC. (fish) ≤ 0.1 mg/L: and/or Chronic NOEC or EC (crustacea) ≤ 0.1 mg/L; and/or Chronic NOEC or EC, (algae or other aquatic plants) ≤ 0.1 mg/L. Substances without sufficient chronic toxicity data c
1) Chronic Category I:
-96h, LCso (fish) ≤1mg/L and/or -48h, EC50 (crustacea) ≤1mg/L: and/or -72h or 96h, ECso (algae or other aquatic plants) ≤1mg/L non-rapidly degradable substances and/or experimentally determined BCF≥500 (or lack of data for logKw≥4). 2) Chronic Category II:
-96h, LCso (fish)>1 but ≤10mg/L and/or -48h, ECso (crustacea)>1 but ≤10mg/L; and/or -72h or 96h, ECso (algae or other aquatic plants)>1 but ≤10mg/L and/or -72h or 96h, ECso (algae or other aquatic plants)>1 but ≤10mg/L and/or a non-rapidly degradable substance and/or experimentally determined BCF≥500 (or lack of data for logKw≥4). NOTE 1: Fish crustaceans and algae are tested as alternatives, covering all trophic levels and taxa, and the test methods are highly standardized. Data from other organisms may also be considered, however, they should be provided as equivalent substances and test endpoints. NOTE 2: When classifying a substance as acute I and/or chronic I, also indicate the appropriate M factor to obtain the sum. NOTE 3: When the reduction in algal toxicity ErC[=ECa (growth rate) is greater than 100 times that of the next most sensitive species, and classification is based solely on this result, consider whether this toxicity data can be replaced by equivalent plant toxicity data. If it can be demonstrated that this is not the case, professional judgement is used. Classification is based on ErCso data. In the absence of ECse data, classification is based on the lowest available ECso NOTE 4: Lack of rapid degradation data refers to the lack of biodegradability and other rapid degradation data. When no degradation data, other empirical or predictive data are available, the substance is considered to be non-rapidly degradable. NOTE 5: Bioaccumulation potential is based on an experimentally derived BCF ≥ 500, or, in the absence of data on logKw ≥ 4. logKw data is better than the estimated value, and BCF data is better than logK value.
The classification scheme of substances that are harmful to the aquatic environment is shown in Table 1 based on their aquatic toxicity hazards. 4
Acute toxicity*
Category: Acute I
L(E)Cso≤1mg/L
Classification scheme of substances that are harmful to the aquatic environment
Classification category
Chronic toxicity.
Adequate chronic toxicity data
Non-rapidly degradable substances
Category: Chronic industrial
NOEC or
EC,≤0.1 mg/L
Category: Chronic II
Rapidly degradable substances.
Category: Chronic I
NOEC or
EC≤0.01mg/L
Category: Chronic II
0.1mg/L3 If other credible scientific evidence is available to show that the substance or mixture can be degraded by more than 70% in the aquatic environment (through biotic and/or abiotic pathways) within 28 days. 5 Classification categories and standards
Categories and standards for substance classification
Substances meet the acute, chronic or class II categories based on their aquatic toxicity hazards. 5.1.2 Acute (short-term) aquatic hazards should meet the following requirements: a) 96h, LCsa (fish) ≤1mg/L; and/or b) 48h, ECso (crustacea) ≤1mg/L; and/or c) 72 or 96h, ECso (algae or other aquatic plants) ≤1mg/L. 5.1.3 Long-term aquatic hazards should meet the following requirements:
a) Non-rapidly degradable substances with sufficient chronic toxicity data 1) Chronic Category I:
SN/T1828.17—2013
Chronic NOEC or EC. (fish) ≤0.1mg/L: and/or chronic NOEC or EC. (crustacea) ≤0.1mg/L: and/or chronic NOEC or EC, (algae or other aquatic plants) ≤0.1mg/L 2) Chronic Category II:
-Chronic NOEC or EC (fish) ≤1mg/L: and/or chronic NOEC or EC (crustacea) ≤1mg/L; and/or chronic NOEC or EC. (algae or other aquatic plants) ≤1mg/L. b) Rapidly degradable substances with sufficient chronic toxicity data 1) Chronic Category I:
Chronic NOEC or EC (fish) ≤ 0.01 mg/L; and/or Chronic NOEC or EC, (crustacea) ≤ 0.01 mg/L: and/or Chronic NOEC or EC. (algae or other aquatic plants) ≤ 0.01 mg/L. 2) Chronic Category II:
Chronic NOEC or EC. (fish) ≤ 0.1 mg/L: and/or Chronic NOEC or EC (crustacea) ≤ 0.1 mg/L; and/or Chronic NOEC or EC, (algae or other aquatic plants) ≤ 0.1 mg/L. Substances without sufficient chronic toxicity data c
1) Chronic Category I:
-96h, LCso (fish) ≤1mg/L and/or -48h, EC50 (crustacea) ≤1mg/L: and/or -72h or 96h, ECso (algae or other aquatic plants) ≤1mg/L non-rapidly degradable substances and/or experimentally determined BCF≥500 (or lack of data for logKw≥4). 2) Chronic Category II:
-96h, LCso (fish)>1 but ≤10mg/L and/or -48h, ECso (crustacea)>1 but ≤10mg/L; and/or -72h or 96h, ECso (algae or other aquatic plants)>1 but ≤10mg/L and/or -72h or 96h, ECso (algae or other aquatic plants)>1 but ≤10mg/L and/or a non-rapidly degradable substance and/or experimentally determined BCF≥500 (or lack of data for logKw≥4). NOTE 1: Fish crustaceans and algae are tested as alternatives, covering all trophic levels and taxa, and the test methods are highly standardized. Data from other organisms may also be considered, however, they should be provided as equivalent substances and test endpoints. NOTE 2: When classifying a substance as acute I and/or chronic I, also indicate the appropriate M factor to obtain the sum. NOTE 3: When the reduction in algal toxicity ErC[=ECa (growth rate) is greater than 100 times that of the next most sensitive species, and classification is based solely on this result, consider whether this toxicity data can be replaced by equivalent plant toxicity data. If it can be demonstrated that this is not the case, professional judgement is used. Classification is based on ErCso data. In the absence of ECse data, classification is based on the lowest available ECso NOTE 4: Lack of rapid degradation data refers to the lack of biodegradability and other rapid degradation data. When no degradation data, other empirical or predictive data are available, the substance is considered to be non-rapidly degradable. NOTE 5: Bioaccumulation potential is based on an experimentally derived BCF ≥ 500, or, in the absence of data on logKw ≥ 4. logKw data is better than the estimated value, and BCF data is better than logK value.
The classification scheme of substances that are harmful to the aquatic environment is shown in Table 1 based on their aquatic toxicity hazards. 4
Acute toxicity*
Category: Acute I
L(E)Cso≤1mg/L
Classification scheme of substances that are harmful to the aquatic environment
Classification category
Chronic toxicity.
Adequate chronic toxicity data
Non-rapidly degradable substances
Category: Chronic industrial
NOEC or
EC,≤0.1 mg/L
Category: Chronic II
Rapidly degradable substances.
Category: Chronic I
NOEC or
EC≤0.01mg/L
Category: Chronic II
0.1mg/L1mg/L. Substances without sufficient chronic toxicity data c
1) Chronic Category I:
-96h, LCso (fish) ≤1mg/L and/or -48h, EC50 (crustacea) ≤1mg/L: and/or -72h or 96h, ECso (algae or other aquatic plants) ≤1mg/L Non-rapidly degradable substances and/or experimentally determined BCF≥500 (or lack of data for logKw≥4). 2) Chronic Category II:
-96h, LCso (fish)>1 but ≤10mg/L and/or -48h, ECso (crustacea)>1 but ≤10mg/L; and/or -72h or 96h, ECso (algae or other aquatic plants)>1 but ≤10mg/L and/or -72h or 96h, ECso (algae or other aquatic plants)>1 but ≤10mg/L and/or Non-rapidly degradable substances and/or experimentally determined BCF≥500 (or lack of data for logKw≥4). NOTE 1: Fish crustaceans and algae are tested as alternatives, covering all trophic levels and taxa, and the test methods are highly standardized. Data from other organisms may also be considered, however, they should be provided as equivalent substances and test endpoints. NOTE 2: When classifying a substance as acute I and/or chronic I, the appropriate M factor to obtain the sum is also indicated. NOTE 3: When the reduction in algal toxicity ErC[=ECa (growth rate) is greater than 100 times that of the next most sensitive species, and classification is based solely on this result, consider whether the toxicity data can be replaced by equivalent plant toxicity data. If it can be demonstrated that this is not the case, professional judgement is used. Classification is based on ErCso data. In the absence of ECse data, classification is based on the lowest available ECso NOTE 4: Lack of rapid degradation data refers to the lack of biodegradability and other rapid degradation data. When no degradation data, other empirical or predictive data are available, the substance is considered to be non-rapidly degradable. NOTE 5: Bioaccumulation potential is based on an experimentally derived BCF ≥ 500, or, in the absence of data on logKw ≥ 4. logKw data is better than the estimated value, and BCF data is better than logK value.
The classification scheme of substances that are harmful to the aquatic environment is shown in Table 1 based on their aquatic toxicity hazards. 4
Acute toxicity*
Category: Acute I
L(E)Cso≤1mg/L
Classification scheme of substances that are harmful to the aquatic environment
Classification category
Chronic toxicity.
Adequate chronic toxicity data
Non-rapidly degradable substances
Category: Chronic industrial
NOEC or
EC,≤0.1 mg/L
Category: Chronic II
Rapidly degradable substances.
Category: Chronic I
NOEC or
EC≤0.01mg/L
Category: Chronic II
0.1mg/L1mg/L. Substances without sufficient chronic toxicity data c
1) Chronic Category I:
-96h, LCso (fish) ≤1mg/L and/or -48h, EC50 (crustacea) ≤1mg/L: and/or -72h or 96h, ECso (algae or other aquatic plants) ≤1mg/L Non-rapidly degradable substances and/or experimentally determined BCF≥500 (or lack of data for logKw≥4). 2) Chronic Category II:
-96h, LCso (fish)>1 but ≤10mg/L and/or -48h, ECso (crustacea)>1 but ≤10mg/L; and/or -72h or 96h, ECso (algae or other aquatic plants)>1 but ≤10mg/L and/or -72h or 96h, ECso (algae or other aquatic plants)>1 but ≤10mg/L and/or Non-rapidly degradable substances and/or experimentally determined BCF≥500 (or lack of data for logKw≥4). NOTE 1: Fish crustaceans and algae are tested as alternatives, covering all trophic levels and taxa, and the test methods are highly standardized. Data from other organisms may also be considered, however, they should be provided as equivalent substances and test endpoints. NOTE 2: When classifying a substance as acute I and/or chronic I, the appropriate M factor to obtain the sum is also indicated. NOTE 3: When the reduction in algal toxicity ErC[=ECa (growth rate) is greater than 100 times that of the next most sensitive species, and classification is based solely on this result, consider whether the toxicity data can be replaced by equivalent plant toxicity data. If it can be demonstrated that this is not the case, professional judgement is used. Classification is based on ErCso data. In the absence of ECse data, classification is based on the lowest available ECso NOTE 4: Lack of rapid degradation data refers to the lack of biodegradability and other rapid degradation data. When no degradation data, other empirical or predictive data are available, the substance is considered to be non-rapidly degradable. NOTE 5: Bioaccumulation potential is based on an experimentally derived BCF ≥ 500, or, in the absence of data on logKw ≥ 4. logKw data is better than the estimated value, and BCF data is better than logK value.
The classification scheme of substances that are harmful to the aquatic environment is shown in Table 1 based on their aquatic toxicity hazards. 4
Acute toxicity*
Category: Acute I
L(E)Cso≤1mg/L
Classification scheme of substances that are harmful to the aquatic environment
Classification category
Chronic toxicity.
Adequate chronic toxicity data
Non-rapidly degradable substances
Category: Chronic industrial
NOEC or
EC,≤0.1 mg/L
Category: Chronic II
Rapidly degradable substances.
Category: Chronic I
NOEC or
EC≤0.01mg/L
Category: Chronic II
0.1mg/L
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