Rules for classification and labelling of chemicals—Part 27:Aspiration hazard
Some standard content:
ICS13.300
National Standard of the People's Republic of China
GB30000.27—2013
Rules for classification and labelling of chemicals
Part 27: Aspiration hazard
chemicals-Part27:Aspirationhazard
2013-10-10 Issued
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China Administration of Standardization of the People's Republic of China
2014-11-01 Implementation
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. The expected structure of GB30000 "Chemical Classification and Labeling Specification" and the national standards to be replaced are: Part 1: General rules (replace GB13690-2009); Part 2: Explosives (replace GB20576-2006); Part 3: Flammable gases (replace GB20577-2006); Part 4: Aerosols (replace GB20 578-2006): Part 5: Oxidizing gases (replaces GB 20579-2006): Part 6: Gases under pressure (replaces GB 20580-2006); Part 7: Flammable liquids (replaces GB 20581-2006); Part 8: Flammable solids (replaces GB 20582-2006): Part 9: Self-reactive substances and mixtures (replaces GB 20583-2006); Part 10: Pyrophoric liquids (replaces GB 20585-2006): Part 11: Pyrophoric solids (replaces GB 20586-2006); Part 12: Self-heating substances and mixtures (replaces GB 20584-2006): Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB 20587-2006); 006); Part 14: Oxidizing Liquids (replaces GB20589-2006); Part 15: Oxidizing Solids (replaces GB20590-2006); Part 16: Organic Peroxides (replaces GB20591-2006); Part 17: Corrosive to Metals (replaces GB20588-2006); Part 18: Acute Toxicity (replaces GB20592-2006); Part 19: Skin Corrosion/Irritation (replaces GB20593-2006); Part 20: Serious Eye Damage/Irritation (replaces GB20594-2006); Part 21: Respiratory or Skin Sensitization (replaces GB20595-2006); Part 22: Germ Cell Mutagenicity (replaces GB20596-2006); Part 23: 006): Part 23: Carcinogenicity (replaces GB20597-2006): Part 24: Reproductive toxicity (replaces GB205982006); Part 25: Specific target organ toxicity single exposure (replaces GB20599-2006); Part 26: Specific target organ toxicity repeated exposure (replaces GB20601-2006); Part 27: Aspiration hazard;
Part 28: Hazards to the aquatic environment (replaces GB20602-2006): Part 29: Hazards to the ozone layer;
Part 30: Warning signs in chemical workplaces This part is Part 27 of GB30000
This part is drafted according to the rules given in GB/T1:1-2009. GB30000.27—2013
This part is consistent with the technical content of the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (4th revised edition). This part was proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251). Drafting units of this part: Shandong Entry-Exit Inspection and Quarantine Bureau of the People's Republic of China, Institute of Occupational Health and Poisoning Control, Chinese Center for Disease Control and Prevention.
Main drafters of this part: Zhang Shaoyan, Huang Honghua, Lin Zheng, Geng Xiangyang, Song Zhenqian, Che Lidong, Wan Min, Wu Wei. I
1 Scope
Chemical Classification and Labeling Specification
Part 27: Aspiration Hazard
GB30000.27—2013
This part of GB3Q000 specifies the terms and definitions, classification criteria, decision logic and labeling of chemicals with inhalation hazards. This part applies to chemicals with inhalation hazards classified and labeled according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (hereinafter referred to as GHS).
2 Normative references
The following documents are essential for the application of this document. For all references with an entry date, only the dated version applies to this document. For all undated references, the latest version (including all amendments) applies to this document. GB13690 General Principles for Classification and Hazard Communication of Chemicals United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (Fourth Revised Edition) United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition) 3 Terms and Definitions
The terms and definitions defined in GB13690 and the following terms and definitions apply to this document. 3.1
Aspiration
Specially refers to liquid or solid chemicals entering directly into the human body through the oral or nasal cavity or indirectly entering the trachea and lower respiratory system due to vomiting. 4 Classification criteria
General principles for classification and labeling of aspiration hazards 4.1
General principles for classification and labeling of aspiration hazards are shown in GB 13690. 4.2 Precautions
General and specific precautions for aspiration hazards are shown in Appendix A. 4.3 Classification criteria for substances
Hazard categories for aspiration toxicity are shown in Table 1.
Table 1 Hazard categories for aspiration toxicity
Category 1:
Chemicals known to cause human aspiration toxicity hazard or chemicals considered to cause human aspiration toxicity hazard
Substances are classified in Category 1:
a) based on reliable high-quality human evidence\; or b) if they are hydrocarbons and the kinematic viscosity measured at 40°C is not more than 20.5mm/sGB30000.27-2013
Category 2:
Chemicals that are of concern because they are presumed to cause human aspiration toxicity hazard
Table 1 (continued)
Substances with a kinematic viscosity measured at 40°C not more than 14mm2/s, based on available animal studies and expert judgment taking into account surface tension, water solubility, boiling point and volatility, except substances classified in Category 1
Examples of substances classified in Category 1 are certain hydrocarbons, rosin oil and pine oil. Under these conditions, some competent authorities may consider the following substances for inclusion in this category: n-primary alcohols with at least 3 but not more than 13 carbon atoms, isobutyl alcohol and isobutyl alcohol with not more than 13 carbon atoms. Classification 4.4 Criteria for classification of mixtures 4.4.1 Classification of mixtures when data are available for the mixture as a whole Mixtures are classified in Category 1 based on reliable good quality human evidence. 4.4.2 Bridging principles for classification of mixtures when data are not available for the mixture as a whole 4.4.2.1 Where the mixture itself has not been tested for inhalation toxicity, but there are sufficient data on the individual ingredients and on similar tested mixtures to allow additional testing to be performed that ensures that the hazards of the mixture can be properly characterized, then the mixture should be classified in accordance with the agreed bridging principles. The hazards of the mixture shall be characterized to the greatest extent possible using available evidence without the need for testing in animals. If a tested mixture is diluted with a diluent which does not present an inhalation toxicity hazard and which does not affect the inhalation toxicity of the other ingredients or the mixture, the new mixture may be classified as such. The concentration of the substance should not be reduced to a lower concentration. 4.4.2.3 Product batches A tested mixture shall be classified as such. However, the inhalation toxicity of one production batch may be considered to be substantially equivalent to that of an untested batch of the same commercial product produced by or under the control of the same manufacturer unless there is reason to suspect a significant change in the toxicity of the untested batch. If the latter occurs, a new classification is required.
4.4.2.4 Strength of Category 1 mixtures
If a tested mixture is classified as Category 1 and the concentration of a Category 1 ingredient in the mixture is increased, the resulting mixture should be classified as Category 1 without additional testing.
4.4.2.5 Interpolation within a toxicity category For three mixtures (A, B and C) with identical ingredients, where mixtures A and B are tested and in the same toxicity category, and untested mixture C, but containing the same toxicologically active ingredients as mixtures A and B, but with concentrations of toxicologically active ingredients intermediate to those in mixtures A and B, mixture C can be assumed to be in the same toxicity category as A and B. 4.4.2.6 Substantially similar mixtures
Assume the following:
a) Two mixtures:
1) A+B;
2) C+B.
b) The concentration of component B is essentially the same in both mixtures. 2
c) The concentration of component A in mixture 1) is equal to the concentration of component C in mixture 2). GB30000.27—2013
d) The inhalation toxicity of A and C is substantially the same, i.e. they belong to the same hazard category and are not expected to affect the toxicity of B; if mixture 1) or 2) has been classified according to the criteria in Table 1, then the other mixture may be classified in the same hazard category. 4.4.3 Classification of mixtures when data on all or only some of the components of the mixture are available 4.4.3.1 Category 1
4.4.3.1.1 A mixture shall be classified as Category 1 if it contains not less than 10% of one or more components classified as Category 1 in total and the kinematic viscosity measured at 40°C is not greater than 20.5 mm/s. 4.4.3.1.2 If the mixture is divided into two or more layers, one of which contains not less than 10% of one or more components classified as Category 1 and the kinematic viscosity measured at 40°C is not greater than 20.5 mm/s, then the entire mixture shall be classified as Category 1. 4.3.2 Category 2 4.4.3.2.1 A mixture shall be classified as Category 2 if it contains in total not less than 10% of one or more ingredients classified as Category 2 and has a kinematic viscosity measured at 40°C not greater than 14 mm2/s. 4.4.3.2.2 The use of expert judgement based on surface tension, water solubility, boiling point and flammability is particularly important in classifying a mixture as Category 2, particularly in the case of a mixture with a Category 2 substance. 4.4.3.2.3 If a mixture is separated into two or more layers, the layers are separated and the kinematic viscosity measured at 40°C is not greater than 5 % Decision Logic The decision logic is provided for reference. The decision logic is provided in Annex B. Section 4. 6 Labelling 6.1 General A mixture shall be classified as Category 2 if it contains in total not less than 10% of one or more ingredients classified as Category 2. Special recommendations for the personnel responsible for classification
to study this section when using the judgment logic. 6.1.1 For labels of aspiration hazards, hazard categories are listed in the order of designated pictograms, signal words and hazard statements. The hazard types or categories covered by the United Nations "Recommendations on the Transport of Dangerous Goods Regulations" (17th revised edition) (hereinafter referred to as the indirect regulations) should list the designated corresponding graphic symbols for each category on the label. The allocation of aspiration hazard labeling elements is shown in Appendix C. 6.1.2 Classification and labeling for aspiration hazards are shown in Appendix D. 6.1.3 For other label elements that have not yet been standardized, such as precautionary statements, they also need to be included on the label. The competent authority may also require additional information, and the supplier may also add supplementary information. The information required on the label includes hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and supplier logos, etc. 6.2 Hazard pictograms
Hazard pictograms should use black graphic symbols with a white background, and the red frame should be wide enough to be eye-catching. 6.3 Signal words
Signal words are words used on labels to indicate the relative severity of a hazard and to alert the reader to potential hazards. For inhalation hazard category 1, use the signal word "Danger". For aspiration hazard category 2, use the signal word "Warning"3
GB30000.27—2013
6.4 Hazard statements
Hazard statements are phrases assigned to a hazard class and category that describe the hazardous nature of a hazardous product and, where appropriate, its degree of hazard. Hazard statements for inhalation toxicity are shown in Table D.1 and in Appendix E6.5 Precautionary statements
A precautionary statement is a word (and/or pictogram) that describes a recommended measure to minimize or prevent adverse effects resulting from exposure to the hazardous product or from improper storage or handling of the hazardous product. To meet the requirements, there are five categories of precautionary statements: general, prevention, emergency, storage and disposal. See Appendix E for precautionary statements for inhalation hazards. 6.6 Product identifier
6.6.1 The product identifier should be used on the label and should be consistent with the product identifier used on the material safety data sheet. If a substance or mixture is listed in the Model Regulations, the correct UN shipping name should also be used on the packaging. 6.6.2 The label should include the chemical name of the substance. The competent authority may also require that the chemical names of all components or alloying elements that may contribute to the hazard of the mixture or alloy be listed on the label. 6.7 Supplier identification
The name, address and telephone number of the manufacturer or supplier of the substance or mixture should be provided on the label. 6.8 Label examples
For examples of inhalation hazard labels, see Appendix F. rkAoNrkAca
A.1 General precautions
Appendix A
(Normative Appendix)
General and specific precautions on aspiration hazards GB30000.272013
A.1.1 The purpose of this section is to provide a method for classifying substances or mixtures that may pose an aspiration toxicity hazard to humans.
A, 1.2 Aspiration toxicity includes a variety of severe acute effects, such as chemical pneumonia, varying degrees of lung damage and death by inhalation. A.1.3 Inhalation begins at the moment of inhalation, when the substance causing the effect stays at the junction of the upper respiratory tract and upper digestive tract in the throat area during the time required to inhale a breath.
A.1.4 Inhalation of substances and mixtures may occur when vomiting occurs after swallowing. This may affect labeling, especially due to acute toxicity, and it may be necessary to consider recommending inducing vomiting after swallowing. However, if substances and mixtures also present an aspiration toxicity hazard, the recommendation to induce vomiting may need to be modified.
A.2 Specific precautions
A.2.1 After reviewing the medical literature on chemical inhalation, it was found that some hydrocarbons (petroleum distillates) and certain hydrocarbon chlorides have been shown to be inhalation hazards to humans. Primary alcohols and ketones have only presented inhalation hazards in animal studies. A.2.2 Although a method for determining animal inhalation hazard is in use, it has not been standardized and positive results from animal test evidence can only be used as a guide to possible human inhalation hazard. Caution should be exercised when evaluating animal inhalation toxicity data. A.2.3 The classification criteria are based on kinematic viscosity. Formula (A.1) is used for the conversion between dynamic viscosity and kinematic viscosity: dynamic viscosity/(mPa·s)
2 = kinematic viscosity/(mm2/s)
density/(g/em)
.....(A.1)
A.2.4 Although the definition of "inhalation" in 3.1 includes solids entering the respiratory system, the classification of Category 1 or Category 2 in accordance with b) in Table 1 will only apply to liquid substances and mixtures. A.2.5 Aerosol and mist products are usually distributed in containers such as sealed containers, trigger and push-button sprayers. The key to the classification of these products is whether a cloud of liquid is formed in the nozzle and can then be inhaled. If the aerosol product sprayed from a sealed container is fine, then a cloud of liquid may not be formed. On the other hand, if the closed container sprays the product in the form of an airflow, then a cloud of liquid may be formed and then inhaled. Generally speaking, the aerosol sprayed from trigger-type and push-button sprayers is coarse, so a cloud of liquid may be formed and then inhaled. If the push-button device may be removed and the contents may be swallowed, then the product should be classified. GB30000.27—2013
Appendix B
(Informative Appendix)
Decision logic for inhalation hazard
Figures B.1 and B.2 respectively give the decision logic for inhalation hazard. Substance: Does the substance have inhalation toxicity data? Mixture: Does the mixture as a whole or its components have inhalation toxicity data? Yes
Mixture: Based on reliable high-quality evidence obtained from actual human experience, does the product rely on evidence that the product is not suitable for inhalation?
Is there necessary high-quality evidence obtained from actual human experience, such as certain types of evidence?
The reliable
substances for rosin and pine oil are hydrocarbons with a kinematic viscosity no greater than 20.55 measured at 40°C?
Based on animal studies and expert judgement, there is insufficient evidence and the substance has a kinematic viscosity no greater than 14 m2/s measured at 40°C?
Figure B.1 Decision logic for aspiration hazard
TrKAoNiKAca-
Cannot be classified
Cannot be classified
See the decision logic for ingredients used (Figure 2)
Category 2
Not of this category
Is the bridging test applicable? (See 4.4.2.1~4.4.2.5) Does the mixture contain not less than 10% of one or more ingredients classified as Category 1, and the kinematic viscosity measured at 40C is not greater than 20.5mm2/s? (See 4.4.3.1) Does the mixture contain not less than 10% of one or more ingredients classified as Category 1, and the kinematic viscosity measured at 40C is not greater than 14mm2/s? (Meta 4.3.2) Not classified
Decision logic for inhalation hazard of components used
GB30000.27—2013
Classify into appropriate category
Category 1
Category 2
GB30000.27-—2013
Appendix C
(Normative Appendix)
Label element configuration table for inhalation hazard
Table C.1 gives the label element configuration for inhalation hazard. Table of label elements for aspiration hazard
Category 1
Swallow and enter respiratory tract
May be fatal
Category 2
Swallow and enter respiratory tract
May be harmful
Not required in the "Recommendations on the Transport of Dangerous Goods Model Regulations" TKANTKAca
Appendix D
(Normative Appendix)
Classification and labeling of aspiration hazard
Table D.1 lists the classification and labeling of aspiration hazard Table D.1 Classification and labeling of aspiration hazard
Hazard category
1. Substances and tested mixtures
Reliable, high-quality human evidence obtained from practical experience shows that they have human8
inhalation toxicity, including chemical pneumonitis, varying degrees of lung damage, or are fatal if inhaled:
b) Hydrocarbons with a kinematic viscosity not greater than 20.5 mm/s measured at 40C. 2. If data for the mixture as a whole are not available, use the bridging principle (see 4.4.2). 3. If the bridging principle is not applicable, the mixture is classified as Category 1 if it contains at least one ingredient classified as Category 1 at a concentration of not less than 10% and a kinematic viscosity of not more than 20.5 mm/s measured at 40°C; or b) a mixture separated into two or more layers, at least one of which contains an ingredient classified as Category 1 at a concentration of not less than 10% and a kinematic viscosity of not more than 20.5 mm/s measured at 40°C. 1. Substances and tested mixtures: In addition to substances and mixtures classified as Category 1, substances and mixtures that are considered to be toxic to humans by inhalation based on animal studies and expert judgement, have a kinematic viscosity of not more than 14 mm/s measured at 40°C. 2. If data for the mixture as a whole are not available, use the bridging principle (see 4.4.2). 3. If the bridging principle does not apply, the mixture is classified as Category 2 if: a) it contains at least one ingredient classified as Category 2 with a concentration of not less than 10% and a kinematic viscosity measured at 40°C not greater than 14 mm/s; or b) it is a mixture divided into two or more layers, at least one of which contains a ingredient classified as Category 2 with a concentration of not less than 10% and a kinematic viscosity measured at 40% not greater than 14 mm/s. |Hazard statements
If swallowed and enters
Respiratory tract
May be fatal
If swallowed and enters
Respiratory tract
May be harmful
GB30000.27—2013
E.1 Overview
Appendix E
(Informative Appendix)
Hazard statements and precautionary statements for aspiration hazard E.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for chemicals with aspiration hazard. It lists the recommended precautionary statements for each hazard class and hazard category of chemicals with aspiration hazard. See GB13690. E.1.2 Coding of hazard statements: E.1.2.1 Coding of hazard statements See GHS Annex E.1.2.2 Each hazard statement is assigned a specific alphanumeric code consisting of letters and three numbers, specifically (standing for "hazard statement"). The letter "H" b) The first digit corresponds to the type of hazard referred to by the hazard statement assigned to the different parts of the code, specifically such as physical hazard, health hazard, 4\ environmental hazard, and the last two digits corresponding to the ordinal number of the hazard of the substance or mixture, 210 flammability (codes 226 to 280), etc. Unless otherwise specified, all specified hazard statements should appear on the label.
For example: Explosive (codes 200 to
The competent authority
may specify the order in which the hazard statement appears on the label
In addition, when two or more hazard statements are provided in combination, the competent authority may specify whether the order in which the hazard statement appears in the group.
Or a single statement of the same nature shall appear on the label, or the manufacturer/supplier may decide at his/her discretion whether to combine the hazard statement or
The hazard communication plan (pictogram, letter and hazard statement) E.1.3 Precautionary statements shall be marked on the label together with the required symbols, such as instructions for use, which may be added by the manufacturer/supplier and/or the competent authority at his/her discretion.
Additional supplementary information
E.1.3.1 Coding of precautionary statements See Annex 3 of GHS. E.1.3.2 Coding of precautionary statements
E.1.3.2.1 Each precautionary statement is assigned a unique alphanumeric code consisting of letters and 3 numbers, as follows:
The letter "P\ (stands for "Precautionary Statement"
The first number represents the type of precautionary statement as follows b)
"1" represents general precautionary statement;
"2\ represents prevention precautionary statement:
"3\ represents emergency precautionary statement:
4\ represents storage precautionary statement;
"5" represents disposal precautionary statement.
c) The last 2 numbers (corresponding to the serial number of the precautionary statement). E.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used to replace the precautionary statement text.
TKANTKAca-Substances and tested mixtures
Reliable, good quality human evidence from practical experience showing human 8
inhalation toxicity, including chemical pneumonitis, varying degrees of lung damage, or lethality by inhalation:
b) Hydrocarbons with a kinematic viscosity not greater than 20.5 mm/s measured at 40°C. 2. If data are not available for the mixture as a whole, use the bridging principle (see 4.4.2). 3. If the bridging principle does not apply, a mixture is classified as Category 1 if it: contains at least one ingredient classified as Category 1 at a concentration of not less than 10% and a kinematic viscosity measured at 40°C not greater than 20.5 mm/s; or b) is a mixture partitioned into two or more layers, at least one of which contains an ingredient classified as Category 1 at a concentration of not less than 10% and a kinematic viscosity measured at 40°C not greater than 20.5 mm/s. 1. Substances and tested mixtures: In addition to substances and mixtures classified as Category 1, substances and mixtures that are considered to be toxic to humans by inhalation based on animal studies and expert judgement have a kinematic viscosity measured at 40°C not greater than 14 mm/s. 2. If data for the mixture as a whole are not available, use the bridging principle (see 4.4.2). 3. If the bridging principle does not apply, the mixture is classified as Category 2 if: a) it contains at least one ingredient classified as Category 2 with a concentration of not less than 10% and a kinematic viscosity measured at 40°C not greater than 14 mm/s; or b) it is a mixture divided into two or more layers, at least one of which contains a ingredient classified as Category 2 with a concentration of not less than 10% and a kinematic viscosity measured at 40% not greater than 14 mm/s. |Hazard statements
If swallowed and enters
Respiratory tract
May be fatal
If swallowed and enters
Respiratory tract
May be harmful
GB30000.27—2013
E.1 Overview
Appendix E
(Informative Appendix)
Hazard statements and precautionary statements for aspiration hazard E.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for chemicals with aspiration hazard. It lists the recommended precautionary statements for each hazard class and hazard category of chemicals with aspiration hazard. See GB13690. E.1.2 Coding of hazard statements: E.1.2.1 Coding of hazard statements See GHS Annex E.1.2.2 Each hazard statement is assigned a specific alphanumeric code consisting of letters and three numbers, specifically (standing for "hazard statement"). The letter "H" b) The first digit corresponds to the type of hazard referred to by the hazard statement assigned to the different parts of the code, specifically such as physical hazard, health hazard, 4\ environmental hazard, and the last two digits corresponding to the ordinal number of the hazard of the substance or mixture, 210 flammability (codes 226 to 280), etc. Unless otherwise specified, all specified hazard statements should appear on the label.
For example: Explosive (codes 200 to
The competent authority
may specify the order in which the hazard statement appears on the label
In addition, when two or more hazard statements are provided in combination, the competent authority may specify whether the order in which the hazard statement appears in the group.
Or a single statement of the same nature shall appear on the label, or the manufacturer/supplier may decide at his/her discretion whether to combine the hazard statement or
The hazard communication plan (pictogram, letter and hazard statement) E.1.3 Precautionary statements shall be marked on the label together with the required symbols, such as instructions for use, which may be added by the manufacturer/supplier and/or the competent authority at his/her discretion.
Additional supplementary information
E.1.3.1 Coding of precautionary statements See Annex 3 of GHS. E.1.3.2 Coding of precautionary statements
E.1.3.2.1 Each precautionary statement is assigned a unique alphanumeric code consisting of letters and 3 numbers, as follows:
The letter "P\ (stands for "Precautionary Statement"
The first number represents the type of precautionary statement as follows b)
"1" represents general precautionary statement;
"2\ represents prevention precautionary statement:
"3\ represents emergency precautionary statement:
4\ represents storage precautionary statement;
"5" represents disposal precautionary statement.
c) The last 2 numbers (corresponding to the serial number of the precautionary statement). E.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used to replace the precautionary statement text.
TKANTKAca-Substances and tested mixtures
Reliable, good quality human evidence from practical experience showing human 8
inhalation toxicity, including chemical pneumonitis, varying degrees of lung damage, or lethality by inhalation:
b) Hydrocarbons with a kinematic viscosity not greater than 20.5 mm/s measured at 40°C. 2. If data are not available for the mixture as a whole, use the bridging principle (see 4.4.2). 3. If the bridging principle does not apply, a mixture is classified as Category 1 if it: contains at least one ingredient classified as Category 1 at a concentration of not less than 10% and a kinematic viscosity measured at 40°C not greater than 20.5 mm/s; or b) is a mixture partitioned into two or more layers, at least one of which contains an ingredient classified as Category 1 at a concentration of not less than 10% and a kinematic viscosity measured at 40°C not greater than 20.5 mm/s. 1. Substances and tested mixtures: In addition to substances and mixtures classified as Category 1, substances and mixtures that are considered to be toxic to humans by inhalation based on animal studies and expert judgement have a kinematic viscosity measured at 40°C not greater than 14 mm/s. 2. If data for the mixture as a whole are not available, use the bridging principle (see 4.4.2). 3. If the bridging principle does not apply, the mixture is classified as Category 2 if: a) it contains at least one ingredient classified as Category 2 with a concentration of not less than 10% and a kinematic viscosity measured at 40°C not greater than 14 mm/s; or b) it is a mixture divided into two or more layers, at least one of which contains a ingredient classified as Category 2 with a concentration of not less than 10% and a kinematic viscosity measured at 40% not greater than 14 mm/s. |Hazard statements
If swallowed and enters
Respiratory tract
May be fatal
If swallowed and enters
Respiratory tract
May be harmfulbZxz.net
GB30000.27—2013
E.1 Overview
Appendix E
(Informative Appendix)
Hazard statements and precautionary statements for aspiration hazard E.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for chemicals with aspiration hazard. It lists the recommended precautionary statements for each hazard class and hazard category of chemicals with aspiration hazard. See GB13690. E.1.2 Coding of hazard statements: E.1.2.1 Coding of hazard statements See GHS Annex E.1.2.2 Each hazard statement is assigned a specific alphanumeric code consisting of letters and three numbers, specifically (standing for "hazard statement"). The letter "H" b) The first digit corresponds to the type of hazard referred to by the hazard statement assigned to the different parts of the code, specifically such as physical hazard, health hazard, 4\ environmental hazard, and the last two digits corresponding to the ordinal number of the hazard of the substance or mixture, 210 flammability (codes 226 to 280), etc. Unless otherwise specified, all specified hazard statements should appear on the label.
For example: Explosive (codes 200 to
The competent authority
may specify the order in which the hazard statement appears on the label
In addition, when two or more hazard statements are provided in combination, the competent authority may specify whether the order in which the hazard statement appears in the group.
Or a single statement of the same nature shall appear on the label, or the manufacturer/supplier may decide at his/her discretion whether to combine the hazard statement or
The hazard communication plan (pictogram, letter and hazard statement) E.1.3 Precautionary statements shall be marked on the label together with the required symbols, such as instructions for use, which may be added by the manufacturer/supplier and/or the competent authority at his/her discretion.
Additional supplementary information
E.1.3.1 Coding of precautionary statements See Annex 3 of GHS. E.1.3.2 Coding of precautionary statements
E.1.3.2.1 Each precautionary statement is assigned a unique alphanumeric code consisting of letters and 3 numbers, as follows:
The letter "P\ (stands for "Precautionary Statement"
The first number represents the type of precautionary statement as follows b)
"1" represents general precautionary statement;
"2\ represents prevention precautionary statement:
"3\ represents emergency precautionary statement:
4\ represents storage precautionary statement;
"5" represents disposal precautionary statement.
c) The last 2 numbers (corresponding to the serial number of the precautionary statement). E.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used to replace the precautionary statement text.
TKANTKAca-3 Precautionary statements should be included in the label required by the GHS, such as instructions for use, which may be supplemented by the manufacturer/supplier and/or the competent authority at their discretion. Additional supplementary information E, 1.3.1 Precautionary statement codes are listed in Annex 3 of the GHS. E.1.3.2 Coding of precautionary statements
E.1.3.2.1 Each precautionary statement is assigned a unique alphanumeric code consisting of letters and three numbers, as follows:
The letter "P\ (stands for "Precautionary Statement"
The first number represents the type of precautionary statement as follows b)
"1" represents a general precautionary statement;
"2\ represents a prevention precautionary statement:
"3\ represents an emergency precautionary statement:
4\ represents a storage precautionary statement;
"5" represents a disposal precautionary statement.
c) The last two numbers (corresponding to the serial number of the precautionary statement). E.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement and should not be used to replace the precautionary statement.
TKANTKAca-3 Precautionary statements should be included in the label required by the GHS, such as instructions for use, which may be supplemented by the manufacturer/supplier and/or the competent authority at their discretion. Additional supplementary information E, 1.3.1 Precautionary statement codes are listed in Annex 3 of the GHS. E.1.3.2 Coding of precautionary statements
E.1.3.2.1 Each precautionary statement is assigned a unique alphanumeric code consisting of letters and three numbers, as follows:
The letter "P\ (stands for "Precautionary Statement"
The first number represents the type of precautionary statement as follows b)
"1" represents a general precautionary statement;
"2\ represents a prevention precautionary statement:
"3\ represents an emergency precautionary statement:
4\ represents a storage precautionary statement;
"5" represents a disposal precautionary statement.
c) The last two numbers (corresponding to the serial number of the precautionary statement). E.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement and should not be used to replace the precautionary statement.
TKANTKAca-
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