This standard specifies the terms and definitions, classification, determination process and guidance, categories and warning labels, configuration of categories and label elements and general provisions for warning statements for self-igniting liquids. This standard applies to the hazard classification, warning labels and warning statements of self-igniting liquids according to the United Nations "Globally Harmonized System of Classification and Labeling of Chemicals". GB 20585-2006 Safety Specification for Chemical Classification, Warning Labels and Warning Statements Self-igniting Liquids GB20585-2006 Standard Download Unzip Password: www.bzxz.net
This standard specifies the terms and definitions, classification, determination process and guidance, categories and warning labels, configuration of categories and label elements and general provisions for warning statements for self-igniting liquids. This standard applies to the hazard classification, warning labels and warning statements of self-igniting liquids according to the United Nations "Globally Harmonized System of Classification and Labeling of Chemicals".

National Standard of the People's Republic of China
GB20585—2006
Safety rules for rlassificalion, precautionary labelling and precautionary statements of chemicals
Pyrophoric liquids
Safety rules for rlassificalion, precautionary labelling and precautionary statements of chemicalsPyrophorie: liguids2006-10-24Issued
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China
Standardization Administration of the People's Republic of China
2008-01-01Implementation
Chapter 4, Chapter 6, Chapter 7 and Chapter 8 of this standard are mandatory, and the rest are recommended. GR20585—2006
This standard is not equivalent to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS), and its relevant technical content is GHS This standard was proposed by the National Technical Committee for Standardization of Hazardous Chemicals (SAC/TC.25I) and drafted by China Chemical Standardization Research Institute. Participating drafters of this standard: Jiangsu Entry-Exit Inspection and Quarantine Bureau, Shandong Entry-Exit Inspection and Quarantine Bureau, Marine Chemical Research Institute, Anhui Exit-Exit Inspection and Quarantine Bureau. The drafters of this standard are: Mei Jian, Zhou Zhirong, Zhou Feizhou, Zhang Shaoyan, Xu Yan, Wang Wei. This standard will be implemented in the production field from January 1, 2008: in the circulation field from December 31, 2008, and the transition period from January 1 to December 31, 2008 is the implementation transition period. 1 Scope Classification, warning labels and warning statements of chemicals Safety specifications for spontaneous combustion liquids GB 20585-2006
and the standard stipulates the terms and definitions, classification, determination process and instructions, categories and labels, and general rules for the matching instructions of categories and labels for white flammable liquids.
This standard is used for the hazard classification, warning labels and some instructions of white flammable liquids in accordance with the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals".
2 Normative references
The clauses in the following documents become the clauses of this standard through reference in this standard. All! The contents or revisions of dated referenced documents (excluding dated errors) are not applicable to this standard. However, the latest version of this document shall apply according to the agreement reached between the parties in accordance with this standard. For undated referenced documents, the latest version shall apply. G136911-2C05 Classification and numbering of dangerous goods Joint Globally Harmonized System of Classification and Labelling of Chemicals (S) United Nations Protocol on the Transport of Dangerous Goods (Revised Edition) (TM) Joint Recommendations on the Transport of Dangerous Goods (Revised Edition) 3 Terms and definitions
Pyrophorie liquids
are liquids that can ignite within a few nanometers after coming into contact with air. 4 Classification
Pyrophorie liquids are classified according to the test standards of the United Nations Recommendations on the Transport of Dangerous Goods in accordance with 33.3.! .5 N.3 Test. Classification according to table
Classification of self-igniting liquids
Fluids added to air carriers burn within min, or come into contact with air, and ignite or carbonize within ma.
5 Judgment process and guidance
The judgment process is not part of the classification work, they are attached to the personnel responsible for classification in the judgment process. 5.1 Judgment process
The classification of flammable liquids should be based on the A. test method specified in 3.1.5 of the United Nations Recommendations on the Transport of Dangerous Goods. The procedure is divided into four steps and the classification is carried out according to the classification process in Figure 1. 1
GB 20585—2006
5.2 Guidance
The substance or mixture is a liquid
Will it catch fire within 5 minutes when poured into a cup containing pasting paint or brick glue?
Will it ignite or carbonize paper within 1 hour? Figure 1
Flowchart for the determination of spontaneous combustion liquids
Category
Category 1
Not classified
When experience in production or handling shows that the substance and mixture will not spontaneously ignite when in contact with air at normal temperature, that is, when it is known that the substance is stable for a long time (e.g. several hours) at room temperature, the classification procedure for flammable liquids does not need to be applied. Classification and warning labels
Classification and warning labels for flammable substances Table 2, Table 2 Category and warning labels of spontaneously igniting liquids
Hazard category
When the liquid is added to the carrier and exposed to the gas, it will ignite within 5 m, or it will cause the filter paper to ignite or carbonize when it comes into contact with the gas. Configuration of category and label elements
Graphic symbols
Hazard source
Alternative label elements
Spontaneous ignition when exposed to air
For the classification and warning labels of chemicals, each hazard category of the hazard type is listed in the order of designated graphic symbols, names and hazard statements. The United Nations Recommendations on the Transport of Dangerous Goods Model Regulations involve dangerous types. According to the requirements of the United Nations "Globally Harmonized System of Classification and Labeling of Chemicals (GIIS), the corresponding graphic signs designated for each type are engraved below. The configuration of white flames as categories and label elements is shown in Table 3.
Category 1
Such as explosive air
It will spontaneously ignite
8 Warning statement
Table 3 Configuration of liquid categories and label elements GB 20585-2006
In the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations
「1】Color of graphic signs
·Graphic symbols, numbers|black:
Upper half: white;
Lower half: red.
Number 4 in the figure is GB 6924-2:05
Category 4. The minimum size of the graphic sign for cargo transport is 100mm×100mm
This standard provides some commonly used warning instructions, which are instructions that can be suitable for labels provided for specific substances or mixtures. The warning instructions that are most suitable for the specific situation should be used. When using words in brackets in warning instructions, any word in the brackets can be used to supplement the core content contained in the sentence or replace the content. 8. 1 Physical hazard description
, General warning description
) Avoid fire sources:
Keep away from open flames (no smoking)
Keep away from heat sources, (sparks) (flames) No smoking) Keep away from heat and fire sources (no smoking). Keep away from fire sources, no smoking,
Avoid contact with heat and fire sources (oxidants) No smoking), no open flames, no fire and no smoking. Take precautionary measures to prevent static electricity.
Do not use Use tools that can produce sparks.
Avoid direct sunlight:
Keep away from open flames, sparks and hot surfaces.
Do not use or store near heat sources or open flames. b) Warnings about piercing devices:
Keep piercing devices closed,
Keep containers airtight
Keep containers airtight when not in use,
Store in sealed containers:
Can only be stored in original containers
GB 20585—2006
C) Storage of piercing devices or packaging:
Place in a cool place:
Keep at a temperature not exceeding
Decompose below the boiling point (
below the melting point in <
).
) "hours to relax.
Place the container/package in a well-ventilated place
Keep the container/package tightly closed in a cool and well-ventilated place. Only store coal in containers and packages in a well-ventilated place. Keep the container/package tightly closed and placed in a well-ventilated place. Store in a cool/low temperature, well-ventilated (dry) place (away from heat and fire sources). Store and transport according to the limits of the Dangerous Chemical Packaging List: Exposure to temperatures above 54.1(.13F) may cause combustion. Store away from incompatible materials: Do not store together with oxidants. Separate from oxidants, oxygen, explosives, halogens, compressed air, acids, alkalis and edible chemicals. Do not store and transport together with oxidants (acids and alkalis). Use carbon dihydrogen, dry powder or foam. If extinguished, use 8.1.1 Any additional instructions: 8. 1.2
Keep in [fill in the name of inert gas] Do not contact with target air.
Avoid exposure to sunlight, moisture and damage.
8.2 Instructions for preventing health effects caused by possible misuse and exposure 8.2.1 Ventilation control
Use only in areas with good headwind
Use only in close ventilation or closed system ventilation equipment. Before using the product, do not enter the windward area and the storage area. ! Use the product under conditions of adequate ventilation (or closed system ventilation) to keep the harmful substances (powder, smoke, steam, etc. in the air) below the recommended exposure limit. Use appropriate ventilation to remove steam (smoke, dust, etc.). Use ventilation and/or process control during high temperature work to avoid exposure to steam. Avoid gas accumulation by providing appropriate ventilation during operation and use. [When using, use ventilation equipment, local exhaust ventilation or take respiratory protection]. Do not use in a ventilated area without droplets. Do not inhale (powder or spray). 8. 2.2 Hygiene measures Do not inhale, eat, or drink during use. Do not inhale or drink during use. Wash hands before eating, talking, or smoking. Wash the operating parts thoroughly. Prevent all contact. Maintain good hygiene habits to prevent contact with skin and eyes. Prevent skin contact. Prevent contact with people. Wash thoroughly with soap and water after operation and before eating or smoking. Prevent contact with skin, eyes, and clothes. Prevent contact with skin (eyes or clothes). Prevent splashing into eyes (skin) or clothes.
8.2.3 Personal protective equipment
Wear appropriate protective clothing and goggles/masks. Wear protective clothing and goggles (specify the type of protective clothing and goggles). Wear eye protection (mouth guard, mask or safety goggles). Wear appropriate personal protective equipment and avoid direct contact. 8.3 Instructions for appropriate measures in case of an accident 8.3.1 Leakage
In case of leakage, stay away from the danger zone.
In case of leakage, consult an expert,
Clean up the ground and all objects contaminated by the material (pursuant to the manufacturer's instructions) with an absorbent or put into a container, collect and dispose of, cover the leakage with a cap.
Move the remaining objects to a safe place with an absorbent or absorbent.
Wash the remaining objects with plenty of water.
Do not flush them down the drain.
Avoid spillage into drains and sewers:
Remove spillage immediately.
Let product cool/solidify, pick up and clean immediately after solidification.
Handle flammable materials in non-dusty sparking appliances, remove all ignition sources and ensure proper ventilation to remove vapors, smoke, etc. Collect leaking liquid in a sealable (metal/plastic) container. Carefully neutralize leaking liquid.
Collect leakage and spillage as much as possible in a sealable (metal/plastic) container: Do not return spillage to the original container.
Use vacuum cleaner to remove spillage.
Put the treated material into
Put the leaked material into
container. If necessary, moisten the container to avoid dust and carefully neutralize the residue. Then rinse with plenty of water. Collect the residue:
Wipe off the residue, put it in
, and then move it to a safe place.
It is forbidden to absorb it with powder or other flammable absorbents. It is forbidden to spray water directly on the surface of the water
GB 20585-2006
G 20585-2006
8.3.2 Firefighting
In case of fire, use (specify the exact type of firefighting equipment) If water increases the risk - do not use water.
Use carbon dioxide, powder or foam.
Water may be used to cool or protect exposed materials, cut off the source: if this is not possible or there is a danger of death around, let the fire burn out; otherwise, use (if the surrounding area is on fire: all extinguishing agents can be used if the surrounding area is on fire: (use appropriate extinguishing agents). Firefighters should wear complete protective clothing, including self-contained breathing apparatus. 8.4 Rescue
Firefighting,
If an incident occurs Accident or physical discomfort. Seek medical help immediately (post medical labels where possible): Call the emergency station of the Central Control Center or the doctor for treatment. Carry the product container or label with you. 8.4.2 Accidents caused by inhalation
In case of a serious inhalation accident, move the patient to fresh air and keep quiet. If inhaled, seek medical treatment immediately.
Move the patient to fresh air and rest immediately. If symptoms or signs continue to appear, seek medical attention immediately. If breathing stops, provide human respiration.
If breathing is difficult, provide deaf air.
|Adopt supine position
Use human breathing if necessary.
Do not use mouth-to-mouth breathing.
If someone is inhaling, provide oxygen or perform artificial respiration and call a doctor. If someone is inhaling, use nitrite and call a doctor to take the person to fresh air.
Call 120 or call an ambulance, then perform artificial respiration. If possible, it is best to perform "1-6 mouth-to-mouth breathing" and call the emergency room or doctor for further treatment. 8.4.3 Accidents caused by ingestion
If ingested, seek medical treatment immediately.
If swallowed, do not swallow, seek medical advice immediately (medical ) and show the container or label. If swallowed, seek medical attention immediately and show the container or label. If swallowed, rinse mouth with water (applicable to patients who are conscious). If swallowed, if the patient is conscious and conscious, follow the recovery instructions to induce vomiting immediately. (Do not induce vomiting) (If the patient is conscious, give two glasses of water and get medical attention immediately) Ingestion (one glass) (two glasses) of water: Call a doctor (or call a poison control center immediately). Soften mouth.
Give activated charcoal slurry.
Induce vomiting (only for patients who are conscious) Do not induce vomiting.
Do not give anything to drink.
Drink plenty of water.
Rest,
Wear protective gloves when inducing vomiting.
If ingested, drink lukewarm water, induce vomiting, wash the stomach and call a doctor. If ingested, drink lukewarm (water) to induce vomiting, clean the intestines, call a doctor. If ingested, drink plants, induce vomiting, call a doctor. If ingested, rinse with water and drink milk or egg white. If ingested, wash the back with 5% sodium thiosulfate solution. If ingested, wash the stomach with 1% sodium thiosulfate solution. If ingested, vomit, use sodium bicarbonate solution to wash the stomach. If ingested, vomit, use plant saliva and wash. If ingested, immediately wash the stomach with 2 cups of copper sulfate solution. If ingested, vomit, wash the stomach with sodium sulfate solution, digest the stomach, if ingested, vomit, wash the stomach with potassium permanganate solution. If ingested, call a doctor for gastric lavage with milk or egg white. If ingested, call a poison control center or doctor for treatment advice. If the victim can swallow, let him swallow 1 cup of water at a time. Do not swallow, wash the mouth with water. If there are no symptoms, wash the mouth with 60mL of 1% iodine solution. Call a poison control center or doctor.
It is forbidden to feed anything to unconscious patients through the mountain. 8. 4. 4 Accidents caused by skin contact
GB20585—2006
After contact with the skin, immediately take off all contaminated clothing and wash immediately with plenty of (manufacturer specified) (if irritation develops and persists, give medical treatment)
If irritation develops and persists, seek medical treatment immediately. Immediately wash with soft soap and water, then wash with running water for 15nmin or rinse with plenty of water (if irritation develops and persists, seek medical treatment immediately).
Immediately rinse the skin with plenty of water and take off contaminated clothing: if irritation (redness, rash, blisters) deepens, seek medical treatment immediately before re-use, wash contaminated clothing
Take off clothes and wash thoroughly before use, take off contaminated clothes and wash again before use, rinse the contaminated part of the body with plenty of water. Wash the contaminated parts of the body with soap and fresh water. If it comes in contact with the body, seek medical attention immediately. If it comes in contact with the skin or eyes, rinse with fresh water. If frostbite occurs, seek medical attention immediately. If it comes in contact with the skin, apply 30% silver nitrate solution immediately. Remove contaminated clothing or rinse the skin with plenty of water. 4.5 Accidents caused by eye contact
Immediately flush eyes with a sufficient amount of (the solution specified by the manufacturer). Immediately flush for at least 15 minutes. Then seek medical treatment immediately: Wash eyes with water for at least 15 minutes. If eye irritation deepens or persists, then seek medical treatment immediately. 7
GB205852006
deciliter eye test-please flush with a large amount of water for at least 1 minute. Then seek medical treatment immediately. After opening the eyes, flush the eyes with water for at least 15 minutes. Those who wear contact lenses should put away their glasses and seek medical treatment immediately. First rinse with large amounts of water for 15 minutes (if it is too strong, remove the contact lenses), then seek medical treatment immediately. If there is contact and the eye is in a state of contact, rinse thoroughly with slowly running water. Keep the glasses open and rinse slowly and gently with water for 5 minutes or 2 minutes. Those who wear contact lenses should remove them after the first 5 minutes and then continue to rinse the glasses.
Instructions for environmental protection and appropriate disposal
Environmental protection
Use appropriate precautions to avoid environmental pollution. Avoid release into the environment. (Refer to the safety data sheet of this chemical) Prevent release in the surrounding environment
Use appropriate precautions.
Do not allow this chemical product to enter the surrounding environment. Do not allow it to be directly added to water or stored in surface water, or in the inner filter area below the mean water mark. Do not pollute the overall water quality when cleaning equipment or disposing of equipment washing water. Do not directly add it to the water.
This chemical has the properties and resistance to chemical-related noise that can be detected in groundwater. Use of this chemical in impermeable areas, especially in areas with shallow groundwater tables, can cause active groundwater pollution. This chemical is known to penetrate the soil into groundwater under certain conditions. In areas where the soil is highly permeable, especially in areas with shallow groundwater levels, this chemical may cause groundwater contamination. 8.5.2
The solution should be sent to a hazardous or special waste collection station for treatment. The solution and its container should be treated as hazardous waste. This material and its containers must be treated as hazardous waste. Do not dispose of with household garbage, war garbage or other solid waste. Dispose of in an approved waste disposal facility. Do not let it flow into large waterways. Do not let it flow into sewers. Dispose of it in a safe way. Do not let it flow into sewers. Take the material and its container to a hazardous or special waste collection station. The material and container must be disposed of in a safe way. Do not pollute water supplies, food or other materials during storage. Do not let it enter any land, drains or any water bodies. Please follow the manufacturer/supplier information for disposal. The most appropriate disposal plan is (select the appropriate one from the following sentences: Reuse. Collect and reuse or send to a recycling facility in a designated area, or to a municipal incinerator for disposal. Dispose of in a permitted landfill or call your local waste disposal station or (call toll free) for disposal information. Do not pour unused product into the sewer, indoors or outdoors. Special instructions for consumers. Prevent children from coming into contact with it. Lock and keep out of reach of children. Keep away from food, drink and animal feed. GB 20585-2006 20585-2006
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National Standards
Chemical Classification, Warning Labels and Warning Statements Safety Specification for Pyrophoric Liquids
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