This standard specifies the content and writing requirements of chemical safety labels. This standard applies to the writing of safety labels for explosives, compressed gases and liquefied gases, flammable liquids, flammable solids, self-igniting items and items that are flammable when wet, oxidants and organic peroxides, poisonous and corrosive substances, and other chemicals that are harmful to humans and the environment. GB 15258-1999 Chemical Safety Label Writing Regulations GB15258-1999 Standard Download Decompression Password: www.bzxz.net

GB152581999
This standard is formulated to regulate the expression and writing of chemical safety labels. Safety labels are the basic measures for preventing and controlling chemical hazards required by the International Convention for the Safe Use of Chemicals in Workplaces No. 170. It is mainly to label the chemicals circulating in the market, put forward safety precautions, and convey safety information to workers, so as to prevent and reduce chemical hazards and achieve the goal of ensuring safety and health. Chemical safety labels have been implemented in Europe and the United States and other industrial countries for many years. At present, my country has promulgated the first edition of this standard in 1994. According to the actual application situation over the past three years, the previous edition is now revised. The main revisions are: changing the original standard name "Guidelines for the Preparation of Dangerous Chemical Labels" to "Regulations for the Preparation of Chemical Safety Labels"; canceling the provisions on signs in the original standard, aligning the hazard signs with the signs specified in the United Nations Recommendations on the Transport of Dangerous Goods and GB136901092 Classification and Labeling of Commonly Used Hazardous Chemicals, canceling the protective measures graphic symbol, and the two-person leakage disposal item: merging the storage and transportation and first aid items into the safety measures item. In addition, safety disposal information is added to the safety measures, and the reminder "ask for safety data sheets from the production and sales companies" is added. and production batch number.
This standard replaces GH/T15258-1994 from the month of implementation. The appendix A, appendix 3 and appendix C in this standard are all indicative appendices. This standard is proposed by the Economic and Trade Commission of the People's Republic of China and drafted by the Occupational Safety and Health Research Institute of the Ministry of Chemical Industry. The drafters of this standard are Zhang Haifeng, Peng Xiangwei, Li Daohua, Li Xuancai and Zhang Qibo. ?u
1 Scope
National Standard of the People's Republic of China
General ruleg For preparation of precautionary labelfor iodustrial chemicals
This standard specifies the content and writing requirements of precautionary label for iodustrial chemicals GB 15258 --1999
G3/T15258—1994
This standard applies to the preparation of safety labels for explosives, compressed gases and liquid gases, flammable liquids, flammable bodies, inflammable articles and articles that are flammable when wet, oxidants and organic peroxides, poisonous and corrosive substances, and other chemicals that are harmful to the human body and the environment. 2 Referenced standards
The texts contained in the following standards constitute the provisions of this standard through reference in this standard. When this standard is published, the versions shown are valid. All standards will be revised, and the parties using this standard should explore the possibility of using the latest versions of the following standards. GR136901992 Classification and marking of commonly used hazardous chemicals GB6911··1986 Classification and name numbering of dangerous goods 3 Definitions
This standard adopts the following definitions.
3.1 Toxic substances
Acute toxicity is: intraoral LD5 mg/kg: 24 h LDn40 mg/kg; Chemicals with LC%≤0.5mg/L in 1h.
3.2 Recommended products
Acute impact: 15mg/kg≤LDm≤: 50mg/kg, 40mg/kg in skin contact for 24hand the symbols specified in GB13690. Each chemical can use up to two signs. The signs and symbols are placed on the label. Note: The United Nations "Recommendations on the Transport of Dangerous Goods" can be obtained from the National Chemical Equipment Registration Center. 4.2.2 Warning words
According to the degree of danger and category of the chemical, use the words "danger", "warning" and "caution" to warn of the degree of hazard respectively. Specific regulations are shown in Table 1. When a chemical has two or more hazards, use the warning word with the greatest danger. The warning word is located below the name of the chemical and must be eye-catching and clear. Table 1 Correspondence between warning words and chemical hazard categories Warning word
Chemical hazard category
Naked explosives Flammable gas Toxic gas Low flash point gas Peroxide hydride Brushless poison Level 1 Aldehyde corrosive Non-flammable gas Medium flash point liquid
Level 1 Spontaneous combustion items Level 1 Flammable items when wet
Level 1 oxidizer
Level 3 Flammable solids Level 3 Flammable items
Level 1 Acidic corrosive products Level 1 Alkaline corrosive products
Level 1 Flammable items Level 2 oxidizers Toxic gas High flash point liquid Level 1 flammable solids Hazardous products Level 2 Alkaline corrosive products Other corrosive products 4.2.3 Hazard overview
Briefly summarize the combustion and explosion hazard characteristics, health hazards and environmental hazards of chemicals, and place them below the warning word. 4.2.4 Safety measures
Describe the matters that must be paid attention to in the handling, removal, storage and use of chemicals, as well as the simple and effective rescue measures in case of accidents, etc. The content should be concise and the key points should be highlighted.
4. 2. 5 Fire extinguishing
Chemicals are flammable or combustion-supporting substances. Effective fire extinguishing agents and prohibited fire extinguishing agents as well as fire extinguishing precautions should be indicated. 4.2.6 Batch number
Indicate the production date and production shift. The production month is indicated by ×××× year × month × month, and the shift is indicated by ×. 4.2.7 Prompt to contact the production and sales company for the safety technical manual 4.2.8 Name, address, zip code and telephone number of the production company 4.2.9 Emergency consultation telephone number
Fill in the emergency consultation telephone number of the chemical production company and the national chemical accident emergency consultation telephone number. 5.1 The text of the label should be concise, clear and easy to understand. It should be expressed in standardized Chinese characters. It can also use minority languages ​​or foreign languages. However, the meaning must correspond to the Chinese characters. The font size should be smaller than Chinese characters. The same meaning should be expressed with the same Chinese characters and graphics. The text should be edited with reference to the phrases provided in Appendix A and Appendix B. When new information is found about a certain chemical, the label should be revised and changed in time. 5.2 Color The color of the mark in the label shall be implemented in accordance with GB13690. The text should use a color that has a clear contrast with the background color, generally black and white. 181
5.3
G15258—1999
The edge of the label should be marked clearly, and a blank of 3n1m should be left outside the edge. The printing of the label should be clear. The printing materials and adhesive materials used should be durable and waterproof. The safety label can be printed alone or combined with other labels. For examples, see Appendix C. 6 Use
6-1 Method of use
The label should be pasted, hung, or printed in a conspicuous position on the chemical packaging or container. In principle, for multi-layer packaging transportation, both the inner and outer packaging should be affixed (hung) with safety labels. However, if the outer packaging has been affixed with a safety label, and the inner packaging is the outer packaging, the inner packaging can be exempted from the safety label: the outer packaging is a clear object, and the safety label of the inner packaging can be clearly seen through the outer packaging, so the outer packaging can be exempted from the label. 6-2 Position
The position of the label is specified as follows:
Barrel and bottle packaging: better than barrel and bottle sideways! Box packaging: located at an obvious place on the end or side of the packaging; Bag, bundle packaging: located at an obvious place on the packaging; Container, grouped goods: located at the four sides below. 6.3 Precautions for use
6.3.1 The label should be firmly pasted, hung, and printed to ensure that it will not fall off or be damaged during transportation and storage. 6.3.2 The label should be pasted, hung, and printed by the manufacturer before the goods leave the factory. If the packaging needs to be changed, the label should be re-pasted and re-printed by the packaging unit.
6.3.3 The label of the container or package containing dangerous chemicals can only be torn off after it has been processed and confirmed that its danger has been completely eliminated. Otherwise, the corresponding label cannot be torn off.
Avoid heat, open flame, vibration and explosive
Explosive, highly toxic, highly irritating
Explosive, highly toxic, harmful to the environment
Explosive, toxic, irritating to the skin
Explosive, toxic and harmful
Flammable and explosive, toxic and harmful
Flammable and explosive, highly irritating
Easily heated and explosive, irritating
Flammable and flammable, corrosive
Flammable and explosive, highly corrosive
Flammable and explosive. Harmful to the human body
GB 15258 1999
Appendix A
(Notes)
Common phrases for the hazard overview of chemical safety labels A60
Flammable and explosive, irritating and anesthetic
Flammable and explosive, irritating and sensitizing
Flammable and explosive, toxic and irritating
Extremely flammable, toxic and harmful
Extremely flammable, highly irritating
Flammable and irritating||t t||Garbage is flammable and highly corrosive
Extremely flammable and harmful to human body
Extremely flammable and corrosive
Extremely flammable, highly toxic and irritating
Extremely flammable, toxic and irritating
Highly flammable, toxic and highly corrosive
Extremely flammable, irritating and anesthetic
Extremely flammable, irritating and sensitizing
Highly flammable, toxic and harmful
Highly flammable. Strong Irritant
Commonly flammable, smoky
Highly flammable, corrosive
Highly flammable, harmful to human body
Highly flammable, corrosive and irritating
Highly flammable, highly toxic, irritating
Highly flammable, toxic, irritating
Highly flammable, toxic, corrosive
Commonly flammable, irritating and anesthetic Use:
Highly flammable, irritating and sensitizing
Flammable, toxic and harmful
Flammable, highly irritating
Flammable, irritating
Flammable, corrosive
Flammable, highly corrosive
Flammable, harmful to human body
Flammable, highly toxic, irritating
Flammable, toxic, irritating
Flammable, toxic, corrosive||tt ||Flammable, irritating and anesthetic
Flammable, irritating and sensitizing
Flammable, spontaneous combustion, toxic
Flammable, spontaneous combustion and irritating
Flammable, low toxicity
Spontaneous combustion, irritating
Spontaneous combustion, commercially toxic, irritating
Spontaneous combustion, toxic, irritating
Spontaneous combustion, flammable when wet, highly toxic
Spontaneous combustion, flammable when wet, toxic||t t||Spontaneous combustion, flammable when avoiding moisture, highly corrosive
Spontaneous combustion, flammable when wet, irritating
White flame, highly toxic, harmful to the environment
Flammable when wet, highly corrosive and irritating
Flammable when wet, corrosive and piercing
Flammable when wet, spontaneous combustion, toxic
Flammable when wet, spontaneous combustion, highly corrosive
Flammable when wet, spontaneous combustion, corrosive
Flammable when wet, irritating|| tt||Decomposes with moisture to release toxic and self-igniting gases
Strong oxidizing, flammable, toxic
Strong oxidizing, flammable, corrosive
Strong oxidizing, toxic, irritating
A113Strong ferritic, toxic, corrosive AI11
Strong oxidizing, strongly corrosive, toxic
Strong oxidizing, strongly corrosive and irritating
Strong oxidizing, corrosive and irritating
|Strong ammoniation. Irritating
Strong hydrogenation, flammable and dry
Strong oxidizing, flammable and explosive, toxic
Strong oxidizing, flammable and explosive, corrosive Strong oxidizing, harmful to human body
True oxidizing, flammable, both
Oxidizing and corrosive, flammable
Other oxidizing. Toxic
A133 is oxidizing and toxic. Corrosive
Oxidizing and toxic.Strongly corrosive
A135 is oxidizing, highly corrosive and highly irritatingA13G is chemical, corrosive and irritating
is chemical and irritating
is oxidizing, flammable and explosive
A139 has an oxidizing smell, is flammable and explosive, and is toxic
is chemical and corrosive, flammable and explosive
Strongly oxidizing, the device may explode when heated, and the whole device may explode when heated
is oxidizing, the container may explode when heated, and the container may explode when heated, and its chemical properties
Strongly irritating and diluting
toxic, harmful to the environment
scratch, flammable, highly corrosive
highly toxic, flammable, harmful to the environment
highly toxic, flammable, corrosive and irritating
highly toxic, highly corrosive
highly toxic, corrosive and irritating
highly oxidizing
highly toxic, oxidizing, highly irritating
highly static, harmful to the environment
toxic, flammable, highly corrosive,
highly flammable, irritating
highly flammable, harmful to the environment
GB 15258 -1999
High alkali, flammable, corrosive
Highly toxic, flammable and irritating
Highly oxidizing, strong irritating
Highly toxic, oxidizing, strong irritating
Toxic, volatile, combustion-supporting
Highly toxic, harmful to the environment
Toxic, flammable, highly corrosive
Toxic, flammable, irritating
Toxic, flammable
Toxic, flammable, harmful to the environment
Toxic, flammable, corrosive and irritating
Toxic, flammable, irritating
Have a toxic and corrosive nature
Have red, its corrosive and irritating nature
Have a toxic and corrosive nature
Have red, its corrosive and irritating nature
Have a toxic and strong Oxidizing, strong irritation
toxic, ammoniation, strong irritation
toxic, volatile, combustion-supporting
toxic, harmful to the environment
strongly corrosive, flammable and high-noise
strongly dripping, flammable and highly toxic
strongly corrosive, highly toxic
strongly corrosive, toxic and harmful
strongly corrosive, toxic and flammable
strongly corrosive, toxic and flammable
strongly corrosive, toxic and flammable
strongly corrosive, toxic and flammable
strongly corrosive, toxic and fully wetted
strongly magical, toxic, strongly oxidizing
strongly corrosive, toxic, oxidizing
strongly corrosive, toxic, oxidizing
strongly corrosive, strong oxidizing
strongly corrosive, oxidizing, its oxidizing
strongly corrosive. Flammable||t t||Highly corrosive, flammable
Strongly abrasive and irritating
Highly corrosive, harmful to the environment
Corrosive, flammable
Corrosive, highly toxic
Eliminating, toxic and harmful
Corrosive, toxic and flammable
A235Corrosive, toxic and flammable
A236Corrosive, toxic, humidifying reactionA237Corrosive, toxic. Strong oxidizing
Corrosive, toxic, oxidizing
Corrosive, highly toxic, oxidizing
Corrosive, strong oxidizing
GB15258—1999
Corrosive, oxidizing
Irritating, flammable and low toxic
A2 43 Corrosive, flammable and low toxic
A244 Corrosive and irritating
A215 Corrosive, harmful to the environment
Appendix B
(Reminder Appendix)
Common safety measures phrases on chemical safety labels Keep away from heat sources and fire, avoid impact and friction Keep away from heat sources and fire, and avoid impact and friction Keep away from fire and heat sources, and prevent direct sunlight B03
Keep away from heat sources and fire, and store in a cool and ventilated place E374
Avoid contact with fire, heat sources, and oxidants
Avoid contact with fire and high heat, and avoid direct sunlight Keep in a low temperature and ventilated place, keep away from fire and heat sources Keep in a low temperature and ventilated place Keep away from fire and heat sources
Keep in a cool, ventilated and dry place
Store and air dry quickly Explosive place, avoid moisture
Sealed packaging, dry and ventilated place
Sealed packaging, and keep in a cool and ventilated place
Container is sealed to avoid vibration and impact
Sealed packaging, not easy to store in large quantities or for a long time
Sealed packaging, avoid moisture to prevent damage Sealed packaging, keep away from light, avoid moisture Sealed packaging, cannot contact with air
Keep away from light, avoid moisture to prevent damage Pay attention to adding wetting agentbZxz.net
Wear cylinder safety and shockproof rubber ring during transportation Handle in nitrogen, avoid moisture
It is forbidden to use tools that are easy to produce sparks
Classify and divide storage and transportation according to the dangerous goods loading table. Avoid storage and mixing with fluorinated agents, etc.
It should be stored with oxygen, compressed air, etc. Chemicals should be stored separately from oxygen, halogens, oxidants, etc. 1343
Do not store or transport them together with flammables, etc. Should be stored and transported separately with oxidants, alkalis, etc.
Do not store or transport them together with oxidants, acids, etc. 1346
Store and transport them together with oxidants, reducing agents, flammables, etc. B48
Should store chemical agents, edible chemicals separately
B50 Should store chemical agents, acids, edible chemicals separately Should store oxidants, alkalis, edible chemicals separately B51
Should store and transport oxidants, explosives, etc. 1352
Should be stored and transported separately with foaming agents, flammables, etc. B53
Do not store or transport them together with halogens, acids, etc.
Should be stored and transported together with oxidants Agents, window elements, etc. should be stored and transported separately.
They should be stored and transported separately from reducing agents, gold powder, etc. Pay attention to personal protection, and direct contact with the body is strictly prohibited. If inhaled (ingested), seek medical attention immediately.
Rinse the contacted parts with water.
Rinse the contacted parts with soap and water. If the body is directly in contact, seek medical attention immediately.
If it comes into contact with the skin or eyes, rinse with clean water. If injured, seek medical attention immediately.
Eye contact·Rinse with running clean water. Inhale, give oxygen or artificial respiration, seek medical attention. Inhale poisoning, inhale amyl nitrite, seek medical attention. Ingestion, drink warm water, induce vomiting, seek medical attention.
Ingestion, drink warm water. Induce vomiting·Gastric lavage, seek medical attention. Ingestion, drink water, induce vomiting, wash, induce diarrhea, seek medical attention. Ingestion, give plants·Induce vomiting, seek medical attention.
Ingestion, rinse mouth, drink Milk or egg white, ingestion + gastric lavage with 5 sodium thiosulfate. Ingestion. Use 1 thiosulfuric acid gastric lavage. Ingestion, induce vomiting, gastric lavage with titanium bicarbonate solution. Ingestion, induce vomiting, gastric lavage with vegetable oil and thin. Ingestion, immediately 2% sulfuric acid gastric lavage. Ingestion, gastric lavage with sodium sulfate solution, catharsis. B99 Ingestion, induce vomiting, gastric lavage with potassium permanganate solution. Ingestion, gastric lavage - drink milk or egg white, seek medical attention. 1392 Ingestion·Rinse mouth with water·No corrosion symptoms. Ingestion, induce vomiting. Use 1 potassium iodide 6Gml, perfusion. 1391 If skin contact, immediately apply 2 silver acid. B95 Jilin Chemical Co., Ltd.
Double power brand: 9%% (V/V)
Quantity: 160kg
No.: XXXXXXXXXX
GB 152581999
Appendix C
(Reminder Appendix)
Sample of Chemical Safety Label
Ethanol
Synthetic ethanol
CEECHOH
Highly flammable and harmful to human body
Safety measures:
. Keep in open source
, away from open flame, heat source, and chemical
·Rinse with clean water
to avoid accidental contact. Warm water male vomiting, medical treatment
Bubble ball, carbon dioxide, dry powder, sand
Please ask the manufacturer and seller for the safety technical test book Jilin Chemical Industry Co., Ltd. Organic Synthesis Guangfa City, Jilin Province, Dangtan District, Puyi Road, China Petrochemical Beijing Yan Petrochemical Company
Weight: 221.7 kg
: YYXNANXE
Zip code: 132022
Tel: 0432-3986257
Phenol
Highly toxic, corrosive to skin and mucous membranes
Safety broadcast city:
High and large species, heat source, suitable for the period of seeking legacy and should be used with chemical agents. Assimilated single products are stored and sorted. Avoid changes, storage,Cut objects into pieces. Prevent the risk of injury. Rinse exposed parts of the body with water. In case of accidental ingestion, seek medical attention immediately. Ice, distilled water, sand Please ask the manufacturer for the safety data sheet. Produced by Chemical Plant No. 2, Beijing Bishan Petroleum Engineering Company, Sinopec General Company, No. 1, Yanshan Xiangyang Road, Fangshan District, Beijing. Postal: 102501. Telephone: Flammable substances. UN No. 1170 CN No. 32061. Inquiry: 0432XXXXXX0532-3890 Highly toxic substances. UN No. 1671. 6106. Customer service: 010XXXXX052-389090
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