Rules for classification and labelling of chemicals—Part 7:Flammable liquids
Some standard content:
ICS 13.300
National Standard of the People's Republic of China
GB 30000.7—2013
Replaces GR20581--2006
Rules for classification and labelling of chemicals-Flammable liquids-Part 7:
Rules for classification and labelling of chemicals-Part 7:Flammable liquids
Issued on October 10, 2013
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China Administration of Standardization of the People's Republic of China
Implementation on November 1, 2014
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. The expected structure of the "B30000% Chemical Classification and Labeling Specification" and the national standards to be replaced are: - Part 1: General (replacing (G1313690-2009); Part 2: Explosives (replacing GB20576-2006); Part 3: Flammable gases (replacing GB20577-2006); Part 4: Aerosols (replacing GB20578-2006); Part 5: Oxidizing gases (replacing GB20579-2006); Part 6: Pressurized gases (replacing GB20580-2006); Part 7: Flammable liquids (replacing (G20581-2006); Part 8: Flammable solids ( Replace GB20582-2006); Part 9: Reactive substances and mixtures (replace (B20583-2006); Part 10: White flammable liquids (replace (GB20585-2006)); Part 11: Pyrophoric solids (replace (GB20586-2006)); Part 12: Self-heating substances and mixtures (replace (J320584-2006); Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replace GB20587-2006); Part 14: Oxidizing liquids (replace GB20589-2006); Part 15: Oxidizing solids (replace GB20590-2006); Part 16: Part: Peroxides (replace GB20591-2006): Part 17: Metal Corrosives (replace GB205882006); Part 18: Acute Toxicity (replace G20592-2006); Part 19: Skin Corrosion/Irritation (replace GT320593-2006); Part 20: Serious Eye Damage/Irritation (replace GB20594-2006): Part 21: Respiratory or Skin Sensitization (replace G120595-2006): Part 22: Germ Cell Mutagenicity (replace CR205962006): Part 23: Carcinogenicity (replace GB20597-2006) ): Part 24: Reproductive toxicity (replaces GB20598:2006); Part 25: Specific target organ toxicity - single exposure (replaces GB20599-2006); Part 26: Specific target organ toxicity - repeated exposure (replaces GB20601-2006): Part 27: Inhalation toxicity: Part 28: Hazards to the aquatic environment (replaces GB20602-2006): Part 29: Hazards to the odor layer; Part 30: Warning signs for chemical workplaces. This part is a part of (30000. This part is based on the rules given in CB/T1.12009. GB 30000.7—2013
This part replaces GB 20581-2006 Safety specification for classification, warning labels and warning statements of chemicals - Flammable materials. This part is consistent with the relevant technical contents of the United Nations Global Hermonized System for Chemicals Classification and Labelling (Globaly Hermonized System for Chemicals Classification and Labelling of Chemicals: GHS) (Fourth Revised Edition). Compared with GB 20581:2006, the main technical content changes of this part are as follows: GB 30000.7:2013-11 modified the name of the label, and the Chinese name was changed to "Rules for classification and labelling of chemicals Part seven: Flammable liruidts" in English. The content of Chapter 1 was modified, and "indicative label" was changed to "label" instead of "indicative instructions"; the introduction of Chapter 2 "Normative references" was modified, and "United Nations "Global Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" was added as a reference document; reference documents 1S01516, ISO1523 and [S3680] were deleted. - Added the introduction to Chapter 3 "Terms and Definitions"; - Added Figure 1 "Determination Map" and Guidance Notes in Chapter 5 as informative Appendix A; - Deleted the original Chapter 7, and modified Table 3 in the original Chapter 7 as normative Appendix B according to the United Nations Global Harmonized System of Classification and Labelling of Chemicals (4th revised edition);
According to the United Nations Global Harmonized System of Classification and Labelling of Chemicals (4th revised edition), the original Chapters 6, 7 and 8 were modified and integrated into Chapter 6; the original Table 2 was modified as a normative appendix; - Deleted the original Chapter 8, and added the relevant "Hazard Statements and Precautionary Statements" as informative Appendix D; Added informative Appendix E "Label Examples". This part is not officially approved by the National Technical Committee for the Administration of Hazardous Chemicals (SAC/TC 251) proposed and coordinated, this part of the regular units: Jiangsu Entry-Exit Inspection and Quarantine Bureau, China Chemical Information Center, Sichuan Provincial Dangerous Chemical Quality Supervision and Inspection Institute, Huafeng Group Co., Ltd.
This part of the main drafters: Xia Hongsong, Wang Mang, Shang Guiqin, Zhang, Zhang Junxi, Liang Jin, Li Xiaofeng, Ji Hongtao. The previous versions of the standards replaced by this part are: -GB205812006
1 Scope
Part 7:
Chemical Classification and Labeling Specification
Flammable Liquids
CB30000.7—2013
The water part of GB3000 specifies the terminology and definition, classification standards, judgment system and guidance, and labeling of flammable liquids. This part applies to flammable liquids in accordance with the United Nations Global Unified Classification and Labeling of Chemicals. 2 Normative references
The following documents are essential for the application of this document. For any dated reference, only the dated version is applicable to this document. For any undated applicable document, its latest version (including all amendments) is applicable to this document. GB6944:2012 Classification and name numbering of dangerous goods GB13690 General principles for classification and hazard communication of chemicals United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (4th revised edition) United Nations Recommendations on the Transport of Dangerous Goods Test and Standards Sub-book (5th revised edition) United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (7th revised edition) 3 Terms and definitions
The terms and definitions defined in GB13690 and the following terms and definitions apply to this document. 3.1
Flammable liquids
Liquids with a flash point not greater than 93°C.
4 Classification standards
4.1 General principles for classification and labeling of flammable liquids are shown in GR136%U. 4.2 Flammable liquids are divided into four categories, see Table 1. Table 1 Classification of flammable liquids
Flash point less than 23℃ and initial boiling point not greater than 35℃ Flash point less than 23℃ and initial boiling point greater than 35℃ Flash point less than ℃ and not greater than 60℃
Flash point less than 0℃ and not greater than 93℃
Note 1 is for some management, the flash point range can be between 55℃ and 75℃. ℃ fuel oil, diesel and civilian fuel are a specific range. Note 2: Liquids with a flash point higher than 35 but not more than 60℃ may be classified as flammable liquids for certain regulatory purposes (e.g. transport) if a negative result is obtained in the sustained burning test in Section 2, Part II, 1..2 of the United Nations Recommendations on the Transport of Dangerous Goods (hereinafter referred to as the Manual of Tests and Criteria). Note 3: For some regulatory purposes (e.g. transport), certain viscous flammable liquids such as paints, enamels, spray paints, cleaners, adhesives and polishes may be considered as a group, these liquids may be classified as non-flammable liquids or the decision to classify these liquids as non-flammable liquids may be made according to relevant regulations or local regulatory authorities. Note 4: Gas absorption is not a flammable liquid. 1
GB 30000.7—2013
5 Decision logic and guidance
Decision logic and guidance are for reference only. Decision logic and guidance are provided in Appendix A. It is particularly recommended that the person responsible for classification study Chapter 4 before and during the use of decision logic.
6 Labelling
6.1 General
6.1.1 For the labelling of flammable liquids, the hazard classes are listed in the order of the designated pictograms, signal words and hazard statements. The hazard classes or categories covered by the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (hereinafter referred to as the Model Regulations) shall be listed on the label with the corresponding pictograms designated for each category. The allocation of label elements for flammable liquids is shown in Appendix 13. 6.1.2 For the classification criteria and label elements for flammable liquids, see Appendix C. 6.1.3 The information required on the label includes hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and supplier identification. Note: For other labels that have not yet been standardized, precautionary statements also need to be included on the label. The competent authority may also require additional information. Suppliers may also add additional information.
6.2 Hazard pictograms
Hazard pictograms shall be black symbols with a white background. The red frame shall be wide enough to make them stand out. See Appendix 1 for hazard pictograms, pictorial symbol colours, numbers and minimum sizes. 6.3 Signal words
Signal words are words used on labels to indicate the severity of the hazard and to alert the reader to potential hazards. For hazard class 1 and hazard category 2 flammable liquids, the signal word "Danger" is used. For hazard class 3 and hazard category 4 flammable liquids, the signal word "Warning" is used. 6.4 Hazard statements
Hazard statements are phrases assigned to a hazard class and category that describe the hazardous nature of a hazardous product and, where appropriate, its degree of hazard. Hazard statements for flammable liquids are given in Appendix 1. 6.5 Precautionary statements
A precautionary statement is a phrase (and/or pictogram) describing recommended measures to minimize or prevent adverse effects of exposure to the hazardous product or improper storage or handling of the hazardous product. For the purpose of delivery, there are 5 types of precautionary statements: general, prevention, emergency, storage and disposal. For precautionary statements for flammable liquids, see Appendix 1). 6.6 Product identifier
6.6.1 The product identifier should be used on the label and should be consistent with the product identifier used in the chemical safety data sheet. If a substance or mixture is listed in the regulatory model, the correct UN shipping name should also be used on the packaging: 6.6.2 The label should include the chemical name of the substance. For mixtures or alloys, when acute irritation, skin or respiratory sensitization or specific target organ group irritation appear on the label, the label should include the chemical composition of all ingredients or alloying elements that may cause these hazards. The competent authority may require that the chemical names of all ingredients or alloying elements that may cause the hazard of the mixture or alloy be listed on the label. 6.7 Supplier identification
The name of the manufacturer or supplier of the substance or mixture, the email address and telephone number should be provided on the label. 6.8 Example of flammable liquid label
See Appendix E for an example of flammable liquid label. 2
Decision logic for flammable liquids
Appendix A
(Informative Appendix)
Decision logic and guidance
30000.72013
The classification of flammable liquids requires the flash point and initial boiling point data of the liquid. The classification should be carried out according to the decision logic of A.1: Is the liquid substance or liquid temperature substance
its internal point not greater than 93℃?
its internal point greater than 60℃?
its flash point is not small?
its initial boiling point greater than 35℃?
Non-flammable substances
No graphic number
Category 1
For some regulatory purposes, fuel oil, diesel and light heating oil with a flash point range of 55~75% may be classified as a specific group because these hydrocarbon sources have different flash points in this humidity range. Therefore, these products may be classified as category 3 or category 4 according to relevant regulations or by the competent authorities.
Non-flammable substances with a flash point higher than 3: but not exceeding 1:1 may be considered non-flammable substances for certain regulatory purposes (e.g. transport) if a negative result is obtained in the 1. Sustained flammability test in Section 32, Part 1I1 of the United Nations Manual of Test Standards. Determination logic for flammable liquids
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GB 30000.7—2013
A.2 Guidance
A.2.1 In order to classify flammable liquids, it is necessary to know the flash point and initial boiling point data of the flammable liquid. These data can be determined through experiments, or can be found in the literature or calculated. 4.2.2 If the mixture contains flammable liquids in known concentrations, although they may contain non-volatile components, such as polymers, additives, the flash point does not need to be determined experimentally, provided that the flash point of the mixture calculated by the method specified in A.2.1 is at least 5 °C higher than the corresponding classification criteria (23 °C and 60 °C, respectively) and the following conditions are met: a) the exact composition of the mixture is known (if the substance has a specified composition range, the component with the lowest calculated flash point should be selected for evaluation); b) the lower explosion limit of each component is known (when these data are extrapolated to temperatures other than the test conditions, appropriate corrections are applied), and the method for calculating the lower explosion limit of the mixture is known; c) the saturated vapour pressure and humidity dependence of the activity coefficient of each component in the mixture are known; d) the liquid phase is homogeneous. NOTE 1: So far, this calculation method is valid for mixtures containing up to six volatile components. These may be flammable liquids, such as liquid hydrocarbons, ethanol, alcohols, esters (except ethanol) and water. However, it has not been confirmed to be valid for mixtures of oxidized substances, sulfur, carbon and/or phosphides.
Note 2: If the calculated flash point deviates from the corresponding classification criterion by less than 5 °C, the calculation method cannot be used. The flash point should be determined experimentally. A.2.3 Gschlin and Rasnussen (Industrial Engineering Chemistry, 21, 186, (1982)) introduced a suitable method: For compounds containing non-volatile components, such as volatile components or additives, the flash point is calculated using the volatile components. The non-volatile components can slightly reduce the partial pressure of the solvent, so that the calculated flash point is only slightly lower than the measured value. A.2.4 If there are no relevant data, the flash point and initial boiling point should be determined experimentally. The flash point should be determined by closed cup test. The open cup test is acceptable only in special circumstances
A.2.5 The flash point of flammable liquids can be determined by the following methods: GB/T261GE/T21792.GB/T21775, GB/T21789GB/T 5208.GB/T 21790.1S0 2719.ASTM I G450.AS7M D 7094,ASTM D 3828-07a,ASTM 1) 56 05.ASTMD3278-96(2004)el,ASTMD93-08,NFM07-019.NFM07-011.NFM07-036 and DIN51755. A.2.6 The initial boiling point of flammable liquids is determined by the following methods: ISO 3924, IS (46261, ISO 3465, ASTM D86-07, ASTM D1078-05. Method A.2 as described in Part A of Annex to EU Council Regulation (EC) No 440/2008. The allocation of label elements is shown in Table 3.1.
Category 1
Extremely flammable liquids and vapors
Category 2
Highly flammable liquids and vapors
Appendix B
(Normative Appendix)
Allocation of label elements
Allocation of label elements for flammable liquids
Category 3
Flammable liquids and vapors
Category 4
Special pictograms
Flammable substances
Not included in the "Stamp Template"
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GB 30000.7—2013
In the current chapter template
Color of graphic label:
Symbols, mathematics and borders can be
displayed in black instead of white
Background color is maintained in both cases
The number 3 in the figure is 86944-
2012. The minimum size of the third category
cargo transport graphic label is 100mmx10cu
G1 30000.7-2013
Appendix C
(Normative Appendix)
Classification standards and label elements for flammable liquids
Classification standards and label elements for flammable liquids are shown in Table C.1. Classification standards and label elements for flammable liquids
Hazard category
Flash point less than 23℃ and boiling point
not less than 5℃
Flash point less than 23℃ and boiling point
greater than 35℃
Flash point not less than 2℃ and not
greater than 0
Flash point greater than 60℃ and
not more than 93℃
Graphic symbol
Signal
Hazard statement
Graphic symbol
Hazard statement
Graphic symbol
Hazard statement
Graphic symbol
Signal
Hazard statement
Signal element
Extremely flammable liquids and vapors
Highly flammable liquids and hot gases
Flammable waves and gases
No graphic symbol
Can be used
D.1 Overview
【Informative Appendix】
Hazard statements and precautionary statements for flammable liquids GB 30000.7—2013
D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for flammable liquids. It lists the recommended hazard statements and precautionary statements for each hazard type and hazard category of flammable liquids, see GI31690. D.1.2 Coding of hazard statements D.1.2.1 For the coding of hazard statements, see (HS Annex 3.D.1.2.2), each hazard statement is assigned a specific alphanumeric code consisting of one letter and three digits, as follows: (a) "H" (stands for "hazard statement"): b) The first digit represents the type of hazard referred to by the hazard statement with different part numbers, as follows: -2 for physical hazard; -3 for health hazard; -4 for environmental hazard; c) The last two digits correspond to the serial number of the hazard caused by the specific properties of the substance or mixture, such as; explosiveness (codes 200 to 210), flammability (codes 220 to 230), etc. D.1.2.3 Unless otherwise specified, all specified hazard statements shall appear on the label. The competent authority may specify the order in which hazard statements appear on the label. In addition, when a combination hazard statement is provided with two or more hazard statements, the competent authority may specify whether the combined hazard statement or the corresponding individual statement should be included in the label or whether it should be determined by the manufacturer/supplier. D.1.3 Precautionary statements should be marked together with the standard hazard communication elements (pictograms, signal words and hazard statements) on the label that meets the requirements. Additional supplementary information, such as instructions for use, may also be supplemented at the discretion of the manufacturer/supplier and/or the competent authority. D.1.3.1 Precautionary statement codes are shown in Annex 3 of the GHS. D.1.3.2 Coding of precautionary statements
D.1.3.2.1 Each precautionary statement is assigned a special alphanumeric code, consisting of 1 to 3 digits, as follows:
) "\P" (stands for "precautionary statement"): h) The first digit represents the type of precautionary statement, as follows: "1\ represents general precautionary statement;
; "2\ represents item precautionary statement;
—;
; "3\ represents emergency precautionary statement;
——;
; 4\ represents storage precautionary statement;
; 5\ represents disposal precautionary statement;
; c) The last two digits (corresponding to the serial number of the standard statement). D.1.3.2.2 Precautionary statement codes are for reference only. Precautionary statement codes are not part of the precautionary statement text and should not be used to replace the precautionary statement text: General precautionary statements General precautions should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels under given conditions (see Table ID), 1). 1
TKAoNKAca
GR 30000.7—2013
…·Generally speaking
Production workers
Supplementary information
Table D, 1 General precautionary statements
Bad pedicle, Supplementary label information
Label prohibition, Supplementary label information, Safety instructions, Workplace marking.
D.3 Precautionary statements for flammable liquids
D.3. 1 Precautionary statements for flammable liquids categories 1, 2 and 3 are shown in Table D. 2Pl?
General precautionary statements
If medical attention is required: Keep product container or label with you and within easy reach of children
Read the label before use
Table D.2 Precautionary statements for flammable liquids categories 1, 2 and 3 Graphic symbols
Hazard category
Signal word
Hazard statement
H22-1 Extremely flammable body and vapor
H225 Flammable gas and vapour
11225 Flammable gas and gas
Precautionary statements
303+P361+P353
Keep away from heat/extinguisher/open flame/hot surface
No smoking.
Manufacturer, supplier or competent authority to specify applicable ignition sources, P233
Keep container sealed. wwW.bzxz.Net
Grounding/bonding container and receiving equipment: If static sensitive materials are not used for refilling. If product is highly volatile, avoid hazardous atmosphere. P241
Use explosion proof electrical/ventilation/lighting/.··/equipment. Manufacturer/supplier or the competent authority to specify other equipment. P242
Use only non-sparking tools.
Take precautions against static discharge.
Wear protective gloves/protective clothing/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment8
If skin (or hair) gets
on, take off immediately all contaminated clothing. Wash skin/slippery with Yongqing
P370+P378
When extinguishing; use appropriate media listed by the manufacturer, supplier or competent authority.
P4D3+P235
Store in a well-ventilated
place. Keep cool
Dispose of contents/contents
In accordance with local
city/national/international regulations
(to be specified)
Precautionary statements for flammable liquids Category 1 See Table I), 3 Table I.3 Precautionary statements for flammable liquids Category 4 Hazard category
Signal room
Keep away from open flames and hot surfaces.
Hazard statements
H227 Flammable
1370 +1378
No smoking.
Wear protective gloves/protective clothing/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. In case of fire, use fire extinguisher
. Manufacturer/supplier or the competent authority to specify appropriate media.
May be hazardous in contact with water
P403+P235
Store in a well-ventilated
place. Isothermal
TKANTKAca-
GB 30000.7—2013
Graphical symbols
No graphic embossing
Disposal of contents/contents
According to local
city/national/international regulations
(may be specified)2 Each hazard statement is assigned a specific alphanumeric code consisting of one letter and three digits as follows: (a) the letter "H" (for "hazard statement"): (b) the first digit represents the type of hazard to which the hazard statement refers in the different parts of the hazard statement number as follows: -2 for physical hazards; -3 for health hazards; -4 for environmental hazards; (c) the last two digits correspond to the sequence number of the hazard caused by the specific properties of the substance or mixture, such as explosiveness (codes 200 to 210), flammability (codes 220 to 230), etc.: D.1.2.3 Unless otherwise specified, all specified hazard statements shall appear on the label. The competent authority may specify the order in which the hazard statements shall appear on the label. In addition, when two or more hazard statements are provided in combination, the competent authority may specify whether the combined hazard statement or the corresponding individual statement shall be included in the label or shall be determined by the manufacturer or supplier. D.1.3 Precautionary statements should be included on the label together with the standard hazard communication elements (pictograms, signal words and hazard statements) in compliance with the requirements. Additional supplementary information, such as instructions for use, may also be supplemented at the discretion of the manufacturer/supplier and/or the competent authority. D.1.3.1 Precautionary statement codes are listed in Annex 3 of the GHS. D.1.3.2 Coding of precautionary statements
D.1.3.2.1 Each precautionary statement is assigned a special alphanumeric code, consisting of 1 to 3 digits, as follows:
) "\P" (stands for "precautionary statement"): h) The first digit represents the type of precautionary statement, as follows: "1\ represents general precautionary statement;
; "2\ represents item precautionary statement;
—;
; "3\ represents emergency precautionary statement;
——;
; 4\ represents storage precautionary statement;
; 5\ represents disposal precautionary statement;
; c) The last two digits (corresponding to the serial number of the standard statement). D.1.3.2.2 Precautionary statement codes are for reference only. Precautionary statement codes are not part of the precautionary statement text and should not be used to replace the precautionary statement text: General precautionary statements General precautions should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels under given conditions (see Table ID), 1). 1
TKAoNKAca
GR 30000.7—2013
…·Generally speaking
Production workers
Supplementary information
Table D, 1 General precautionary statements
Bad pedicle, Supplementary label information
Label prohibition, Supplementary label information, Safety instructions, Workplace marking.
D.3 Precautionary statements for flammable liquids
D.3. 1 Precautionary statements for flammable liquids categories 1, 2 and 3 are shown in Table D. 2Pl?
General precautionary statements
If medical attention is required: Keep product container or label with you and within easy reach of children
Read the label before use
Table D.2 Precautionary statements for flammable liquids categories 1, 2 and 3 Graphic symbols
Hazard category
Signal word
Hazard statement
H22-1 Extremely flammable body and vapor
H225 Flammable gas and vapour
11225 Flammable gas and gas
Precautionary statements
303+P361+P353
Keep away from heat/extinguisher/open flame/hot surface
No smoking.
Manufacturer, supplier or competent authority to specify applicable ignition sources, P233
Keep container sealed.
Grounding/bonding container and receiving equipment: If static sensitive materials are not used for refilling. If product is highly volatile, avoid hazardous atmosphere. P241
Use explosion proof electrical/ventilation/lighting/.··/equipment. Manufacturer/supplier or the competent authority to specify other equipment. P242
Use only non-sparking tools.
Take precautions against static discharge.
Wear protective gloves/protective clothing/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment8
If skin (or hair) gets
on, take off immediately all contaminated clothing. Wash skin/slippery with Yongqing
P370+P378
When expelling; use appropriate media listed by the manufacturer, supplier or competent authority.
Water may occur
P4D3+P235
Store in a well-ventilated
place. Keep cool
Dispose of contents/contents
In accordance with local
city/national/international regulations
(to be specified)
Precautionary statements for flammable liquids Category 1 See Table I), 3 Table I.3 Precautionary statements for flammable liquids Category 4 Hazard Category
Signal Room
Keep away from open flames and hot surfaces.
Hazard statements
H227 Flammable
1370 +1378
No smoking.
Wear protective gloves/protective clothing/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. In case of fire, use fire extinguisher
. Manufacturer/supplier or the competent authority to specify appropriate media.
May be hazardous in contact with water
P403+P235
Store in a well-ventilated
place. Isothermal
TKANTKAca-
GB 30000.7—2013
Graphical symbols
No graphic embossing
Disposal of contents/contents
According to local
city/national/international regulations
(may be specified)2 Each hazard statement is assigned a specific alphanumeric code consisting of one letter and three digits as follows: (a) the letter "H" (for "hazard statement"): (b) the first digit represents the type of hazard to which the hazard statement refers in the different part numbers as follows: -2 for physical hazards; -3 for health hazards; -4 for environmental hazards; (c) the last two digits correspond to the sequence number of the hazard caused by the specific properties of the substance or mixture, such as explosiveness (codes 200 to 210), flammability (codes 220 to 230), etc.: D.1.2.3 Unless otherwise specified, all specified hazard statements shall appear on the label. The competent authority may specify the order in which the hazard statements shall appear on the label. In addition, when two or more hazard statements are provided in a combined hazard statement, the competent authority may specify whether the combined hazard statement or the corresponding individual statement shall be included in the label or shall be determined by the manufacturer or supplier. D.1.3 Precautionary statements should be included on the label together with the standard hazard communication elements (pictograms, signal words and hazard statements) in compliance with the requirements. Additional supplementary information, such as instructions for use, may also be supplemented at the discretion of the manufacturer/supplier and/or the competent authority. D.1.3.1 Precautionary statement codes are listed in Annex 3 of the GHS. D.1.3.2 Coding of precautionary statements
D.1.3.2.1 Each precautionary statement is assigned a special alphanumeric code, consisting of 1 to 3 digits, as follows:
) "\P" (stands for "precautionary statement"): h) The first digit represents the type of precautionary statement, as follows: "1\ represents general precautionary statement;
; "2\ represents item precautionary statement;
—;
; "3\ represents emergency precautionary statement;
——;
; 4\ represents storage precautionary statement;
; 5\ represents disposal precautionary statement;
; c) The last two digits (corresponding to the serial number of the standard statement). D.1.3.2.2 Precautionary statement codes are for reference only. Precautionary statement codes are not part of the precautionary statement text and should not be used to replace the precautionary statement text: General precautionary statements General precautions should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels under given conditions (see Table ID), 1). 1
TKAoNKAca
GR 30000.7—2013
…·Generally speaking
Production workers
Supplementary information
Table D, 1 General precautionary statements
Bad pedicle, Supplementary label information
Label prohibition, Supplementary label information, Safety instructions, Workplace marking.
D.3 Precautionary statements for flammable liquids
D.3. 1 Precautionary statements for flammable liquids categories 1, 2 and 3 are shown in Table D. 2Pl?
General precautionary statements
If medical attention is required: Keep product container or label with you and within easy reach of children
Read the label before use
Table D.2 Precautionary statements for flammable liquids categories 1, 2 and 3 Graphic symbols
Hazard category
Signal word
Hazard statement
H22-1 Extremely flammable body and vapor
H225 Flammable gas and vapour
11225 Flammable gas and gas
Precautionary statements
303+P361+P353
Keep away from heat/extinguisher/open flame/hot surface
No smoking.
Manufacturer, supplier or competent authority to specify applicable ignition sources, P233
Keep container sealed.
Grounding/bonding container and receiving equipment: If static sensitive materials are not used for refilling. If product is highly volatile, avoid hazardous atmosphere. P241
Use explosion proof electrical/ventilation/lighting/.··/equipment. Manufacturer/supplier or the competent authority to specify other equipment. P242
Use only non-sparking tools.
Take precautions against static discharge.
Wear protective gloves/protective clothing/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment8
If skin (or hair) gets
on, take off immediately all contaminated clothing. Wash skin/slippery with Yongqing
P370+P378
When extinguishing; use appropriate media listed by the manufacturer, supplier or competent authority.
P4D3+P235
Store in a well-ventilated
place. Keep cool
Dispose of contents/contents
In accordance with local
city/national/international regulations
(to be specified)
Precautionary statements for flammable liquids Category 1 See Table I), 3 Table I.3 Precautionary statements for flammable liquids Category 4 Hazard category
Signal room
Keep away from open flames and hot surfaces.
Hazard statements
H227 Flammable
1370 +1378
No smoking.
Wear protective gloves/protective clothing/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. In case of fire, use fire extinguisher
. Manufacturer/supplier or the competent authority to specify appropriate media.
May be hazardous in contact with water
P403+P235
Store in a well-ventilated
place. Isothermal
TKANTKAca-
GB 30000.7—2013
Graphical symbols
No graphic embossing
Disposal of contents/contents
According to local
city/national/international regulations
(may be specified)1 General precautionary statements
Bad, supplementary label information
Label prohibition, supplementary label information, safe disposal instructions, workplace marking
D.3 Precautionary statements for flammable liquids
D.3.1 Precautionary statements for flammable liquids categories 1, 2 and 3 are shown in Table D.2.2 General precautionary statements
If medical attention is required: Keep product container or label with you and within easy reach of children
Read the label before use
Table D.2 Precautionary statements for flammable liquids categories 1, 2 and 3 Graphic symbols
Hazard category
Signal word
Hazard statement
H22-1 Extremely flammable
H225 Keep away from flammable gases and vapours
11225 Flammable gases and vapours
Precautionary statements
303+P361+P353
Keep away from heat/spark extinguisher/open flame/hot surfaces
No smoking.
Manufacturer, supplier or the competent authority to specify applicable ignition sources, P233
Keep container airtight.
Grounding/equipotential bonding of container and receiving equipment: if static sensitive materials are not used for refilling. If product is highly volatile, avoid hazardous atmosphere. P241
Use explosion proof electrical/ventilation/lighting/.··/equipment. Manufacturer, supplier or the competent authority to specify other equipment. P242
Use only non-sparking tools,
Take measures to prevent static discharge.
Wear protective gloves/protective clothing/eye protection/protective mask. Manufacturer/supplier or the competent authority to specify equipment type 8
If skin (or hair) comes into contact with
Take off immediately all contaminated clothing. Wash skin/fat slippers with Yongqing
P370+P378
When discharging disaster; use appropriate media specified by the manufacturer/supplier
or the competent authority to specify
.
Plan for possible water exposure
P4D3+P235
Store in a well-ventilated
place. Keep cool
Dispose of contents/contents
In accordance with local
city/national/international regulations
(to be specified)
Precautionary statements for flammable liquids Category 1 See Table I), 3 Table I.3 Precautionary statements for flammable liquids Category 4 Hazard category
Signal room
Keep away from open flames and hot surfaces.
Hazard statement
H227 Flammable
1370 +1378
No smoking.
Wear protective gloves/protective clothing/face protection. Manufacturer/supplier or the competent authority to specify equipment type In case of fire Use fire extinguisher
. Manufacturer/supplier or the competent authority to specify appropriate media.
Contact with water may increase the risk
P403+P235
Store in a well-ventilated
place. Keep isothermal
TKANTKAca-
GB 30000.7—2013
Graphical symbols
No graphic projection
Dispose of contents/contents
In accordance with local
city/national/international regulations
(may be specified)1 General precautionary statements
Bad, supplementary label information
Label prohibition, supplementary label information, safe disposal instructions, workplace marking
D.3 Precautionary statements for flammable liquids
D.3.1 Precautionary statements for flammable liquids categories 1, 2 and 3 are shown in Table D.2.2 General precautionary statements
If medical attention is required: Keep product container or label with you and within easy reach of children
Read the label before use
Table D.2 Precautionary statements for flammable liquids categories 1, 2 and 3 Graphic symbols
Hazard category
Signal word
Hazard statement
H22-1 Extremely flammable
H225 Keep away from flammable gases and vapours
11225 Flammable gases and vapours
Precautionary statements
303+P361+P353
Keep away from heat/spark extinguisher/open flame/hot surfaces
No smoking.
Manufacturer, supplier or the competent authority to specify applicable ignition sources, P233
Keep container airtight.
Grounding/equipotential bonding of container and receiving equipment: if static sensitive materials are not used for refilling. If product is highly volatile, avoid hazardous atmosphere. P241
Use explosion proof electrical/ventilation/lighting/.··/equipment. Manufacturer, supplier or the competent authority to specify other equipment. P242
Use only non-sparking tools,
Take measures to prevent static discharge.
Wear protective gloves/protective clothing/eye protection/protective mask. Manufacturer/supplier or the competent authority to specify equipment type 8
If skin (or hair) comes into contact with
Take off immediately all contaminated clothing. Wash skin/fat slippers with Yongqing
P370+P378
When discharging disaster; use appropriate media specified by the manufacturer/supplier
or the competent authority to specify
.
Plan for possible water exposure
P4D3+P235
Store in a well-ventilated
place. Keep cool
Dispose of contents/contents
In accordance with local
city/national/international regulations
(to be specified)
Precautionary statements for flammable liquids Category 1 See Table I), 3 Table I.3 Precautionary statements for flammable liquids Category 4 Hazard category
Signal room
Keep away from open flames and hot surfaces.
Hazard statement
H227 Flammable
1370 +1378
No smoking.
Wear protective gloves/protective clothing/face protection. Manufacturer/supplier or the competent authority to specify equipment type In case of fire Use fire extinguisher
. Manufacturer/supplier or the competent authority to specify appropriate media.
Contact with water may increase the risk
P403+P235
Store in a well-ventilated
place. Keep isothermal
TKANTKAca-
GB 30000.7—2013
Graphical symbols
No graphic projection
Dispose of contents/contents
In accordance with local
city/national/international regulations
(may be specified)
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