GB 30000.4-2013 Chemical Classification and Labelling Specification Part 4: Aerosols GB30000.4-2013 Standard compression package decompression password: www.bzxz.net
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of aerosols. This part applies to the classification and labeling of aerosols in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals.
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended.
The expected structure of GB30000 "Specifications for Classification and Labelling of Chemicals" and the national standards to be replaced are:
———Part 1: General (replaces GB13690-2009);
———Part 2: Explosives (replaces GB20576-2006);
———Part 3: Flammable gases (replaces GB20577-2006);
———Part 4: Aerosols (replaces GB20578-2006);
———Part 5: Oxidizing gases (replaces GB20579-2006);
———Part 6: Gases under pressure (replaces GB20580-2006);
———Part 7: Flammable liquids (replaces GB20581-2006);
———Part 8: Flammable solids (replaces GB 20582-2006);
———Part 9: Self-reactive substances and mixtures (replaces GB 20583-2006);
———Part 10: Pyrophoric liquids (replaces GB 20585-2006);
———Part 11: Pyrophoric solids (replaces GB 20586-2006);
———Part 12: Self-heating substances and mixtures (replaces GB 20584-2006);
———Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB 20587-2006);
———Part 14: Oxidizing liquids (replaces GB 20589-2006);
——Part 15: Oxidizing solids (replaces GB 20590-2006);
——Part 16: Organic peroxides (replaces GB 20591-2006);
——Part 17: Corrosive to metals (replaces GB 20588-2006);
——Part 18: Acute toxicity (replaces GB 20592-2006);
——Part 19: Skin corrosion/irritation (replaces GB 20593-2006);
——Part 20: Serious eye damage/eye irritation (replaces GB 20594-2006);
——Part 21: Respiratory or skin sensitization (replaces GB 20595-2006);
———Part 22: Germ cell mutagenicity (replaces GB 20596-2006);
———Part 23: Carcinogenicity (replaces GB 20597-2006);
———Part 24: Reproductive toxicity (replaces GB 20598-2006);
———Part 25: Specific target organ toxicity single exposure (replaces GB 20599-2006);
———Part 26: Specific target organ toxicity repeated exposure (replaces GB 20601-2006);
———Part 27: Aspiration hazard;
———Part 28: Hazard to the aquatic environment (replaces GB 20602-2006);
———Part 29: Hazard to the ozone layer;
———Part 30: Warning signs for chemical workplaces.
This part is Part 4 of GB 30000.
This part was drafted in accordance with the rules given in GB/T 1.1-2009.
This part replaces GB 20578-2006 "Safety Specification for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Flammable Aerosols".
This part is consistent with the relevant technical content of the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition).
Compared with GB 20578-2006, the main technical content changes of this part are as follows:
———The name of the standard has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals—Part 4: Aerosols" and the English name is "Rules for classification and labelling of chemicals—Part 4: Aerosols";
———The scope of Chapter 1 has been modified, "Warning labels" has been changed to "labels", and "Warning statements" has been deleted; ||tt
|| ———The introductory words of Chapter 2 "Normative references" have been modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" has been added as a reference document;
———The introductory words of Chapter 3 "Terms and Definitions" have been added;
———Figure 1 "Decision Logic Diagram" and "Guidance" in Chapter 5 have been made informative Appendix A;
——Deleted the original Chapter 7, and revised Table 2 of the original Chapter 7 as normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition);
——In accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition), revised and integrated the original Chapters 6, 7 and 8 into Chapter 6; revised Table 1 as normative Appendix C;
——Deleted the original Chapter 8, and made the relevant "Hazard Statements" and "Precautionary Statements" as informative Appendix D;
——Added informative Appendix E "Label Examples".
This part was proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251).
Drafting units of this part: China Chemical Economic and Technological Development Center, Hangzhou Yangyi Technology Co., Ltd., China Chemical Information Center, Zhejiang Chemical Research Institute Co., Ltd., Huafeng Group Co., Ltd.
The main drafters of this part: Yang Ting, Ye Shuliang, Qiu Jian, Fang Lu, Liang Jin, Wang Xiaobing, Cao Mengran, Jiang Lin, Wen Wenxian, Guan Shitai, Gao Yang, Wen Tao.
The previous versions of the standards replaced by this part are:
———GB 20578—2006.
The following documents are indispensable for the application of this document. For any dated referenced document, only the dated version applies to this document. For any undated referenced document, the latest version (including all amendments) applies to this document.
GB6944—2012 Classification and Product Name Numbering of Dangerous Goods
GB13690 General Rules for Classification and Hazard Communication of Chemicals
GB30000.3 Specification for Classification and Labelling of Chemicals Part 3: Flammable Gases
GB30000.7 Specification for Classification and Labelling of Chemicals Part 7: Flammable Liquids
GB30000.8 Specification for Classification and Labelling of Chemicals Part 8: Flammable Solids
United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition)
United Nations Manual of Tests and Criteria for Recommendations on the Transport of Dangerous Goods (Fifth Revised Edition)

ICS13.300www.bzxz.net
National Standard of the People's Republic of China
GB30000.4-—2013
Replaces GB205782006
Rules for classification and labelling of chemicals-Part 4:Aerosols
Issued on October 10, 2013
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China Administration of Standardization of the People's Republic of China
Implementation on November 1, 2014
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. The expected structure of GB30000 "Chemical Classification and Labeling Specification" and the national standards to be replaced are: Part 1: General (replaces GB13690-2009); Part 2: Explosives (replaces GB20576-2006): Part 3: Flammable gases (replaces GB20577-2006); Part 4: Aerosols (replaces GB20578-2006): Part 5: Oxidizing gases (replaces GB20579-2006); Part 6: Pressurized gases (replaces GB20580-2006); Part 7: Flammable liquids (replaces GB20581-2006): Part 8 : Flammable solids (replacing GB20582-2006): Part 9: Self-reactive substances and mixtures (replacing GB20583-2006): Part 10: Pyrophoric liquids (replacing GB20585-2006): Part 11: Pyrophoric solids (replacing GB20586-2006): Part 12: Self-heating substances and mixtures (replacing GB20584-2006); Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replacing GB20587-2006); Part 14: Oxidizing liquids (replacing GB20589-2006); Part 15: Oxidizing solids ( Replace GB20590-2006); Part 16: Organic Peroxides (Replace GB20591-2006); Part 17: Metal Corrosives (Replace GB20588-2006); Part 18: Acute Toxicity (Replace GB20592-2006); Part 19: Skin Corrosion/Irritation (Replace GB20593-2006); Part 20: Serious Eye Damage Eye Irritation (Replace GB20594-2006); Part 21: Respiratory or Skin Sensitization (Replace GB20595-2006); Part 22: Germ Cell Mutagenicity (Replace GB20596-2006); Part 23: Acute Toxicity (Replace GB20597-2006); Part 24: Acute Toxicity (Replace GB20598-2006); Part 25: Acute Toxicity (Replace GB20599-2006); Part 26: Acute Toxicity (Replace GB20591-2006); Part 27: Acute Toxicity (Replace GB20598-2006); Part 28: Acute Toxicity (Replace GB20599-2006); Part 29: Acute Toxicity (Replace GB20591-2006); Part 30: Acute Toxicity (Replace GB20591-2006); Part 31: Acute Toxicity (Replace GB20591-2006); Part 32: Acute Toxicity (Replace GB20591-2006); Part 33: Acute Toxicity (Replace GB20591-2006); Part 34: Acute Toxicity (Replace GB20591-2006); Part 35: Acute Toxicity ( 2006); Part 23: Carcinogenicity (replaces GB20597-2006); Part 24: Reproductive toxicity (replaces GB20598-2006); Part 25: Specific target organ toxicity single exposure (replaces GB20599-2006); Part 26: Specific target organ toxicity repeated exposure (replaces GB20601-2006); Part 27: Aspiration hazard;
Part 28: Hazards to the aquatic environment (replaces GB20602-2006); Part 29: Hazards to the ozone layer;
Part 30: Warning signs for chemical workplaces. This part is Part 4 of GB30000.
This part was drafted in accordance with the rules given in GB/T1.1-2009. GB30000.4—2013
This part replaces GB20578-2006 "Safety Rules for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Flammable Aerosols". This part is consistent with the technical content related to the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals GHS) (Fourth Revised Edition). Compared with GB20578-2006, the main technical content changes of this part are as follows: 1
GB30000.4—2013
The standard name has been modified. The Chinese name has been changed to "Chemical Classification and Labelling Specifications Part 4: Aerosols", and the English name is "Rules for classificationand labelling of chemicalsPart4:Aerosols\; The scope of Chapter 1 was modified, "Warning Label" was changed to "Label", and "Warning Statement" was deleted; the introduction of Chapter 2 "Normative References" was modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" was added as a reference document; the introduction of Chapter 3 "Terms and Definitions" was added; Figure 1 "Decision Logic Diagram" and "Guidance" in Chapter 5 were made as informative Appendix A; the original Chapter 7 was deleted, and the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition) was added as a reference document; the introduction of Chapter 3 "Terms and Definitions" was added; the "Decision Logic Diagram" and "Guidance" in Figure 1 of Chapter 5 were made as informative Appendix A; the original Chapter 7 was deleted, and the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition) was added as a reference document; the introduction of Chapter 3 "Terms and Definitions" was added as a reference document; ... According to the United Nations Global Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition), the original Chapter 6, Chapter 7 and Chapter 8 were modified and integrated into Chapter 6. The original Table 1 was modified and became the normative Appendix C. The original Chapter 8 was deleted. The relevant hazard statements and precautionary statements were made as informative Appendix D. The informative Appendix E "Label Examples" was added. This part was proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251). The drafting units of this part are: China Chemical Economic and Technological Development Center, Hangzhou Yangyi Technology Co., Ltd., China Chemical Information Center, Zhejiang Chemical Research Institute Co., Ltd., Huafeng Group Co., Ltd. The main drafters of this part are: Yang Ting, Ye Shuliang, Qiu Jian, Fang Lu, Liang Jin, Wang Xiaobing, Cao Mengran, Jiang Lin, Wen Wenxian, Guan Shitai, Gao Yang, Wen Tao. The previous versions of the standards replaced by this part are: GB20578-2006.
1 Scope
Chemical Classification and Labeling Specification
Part 4: Aerosols
GB30000.4—2013
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of aerosols. This part applies to the classification and labeling of aerosols in accordance with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (hereinafter referred to as GHS). 2 Normative References
The following documents are indispensable for the application of this document. For all dated references, only the version with the date is applicable to this document. For any undated document, the latest version (including all amendments) shall apply to this document GB6944201
GB13690
GB30000
GB30000
Classification and product name numbering of dangerous goods
General rules for classification and hazard communication of chemicals
Specifications for classification and labelling of chemicals Part 3 Flammable gases Specifications for classification and labelling of chemicals
Part 7 Flammable liquids
GB30000
Chemical classification and labeling specifications
United Nations Global Chemicals Standards - Part 8: Flammable Solids
Classification and labeling system (fourth revised edition
United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (tenth revised edition
United Nations Recommendations on the Transport of Dangerous Goods 3 Terms and Definitions
GB13690 defines the following terms and
Aerosols
Manual of Tests and Criteria
( Fifth revised edition)
Aerosols (any non-refillable container made of metal, glass or plastic) contain compressed, liquefied or pressurized dissolved gas (with or without liquid, paste or powder) and are equipped with a release device to spray the contents to form suspended solid or liquid particles in the gas or to form foam, inoculant or powder or to appear in liquid or gaseous form. 4 Classification standards
For the general principles of aerosol classification and labeling, see GB13690. 4.1
4.2 If the aerosol contains If there is any component classified as flammable according to GHS, the aerosol should be classified as flammable, that is: 1) For flammable liquids, see GB30000.7;
For flammable gases, see GB30000.3;
For flammable solids, see GB30000.8.
Note 1: Flammable components do not include self-igniting substances, self-heating substances or water-reactive substances and mixtures, because these components are never used as the contents of sprayers. Note 2: Flammable aerosols no longer fall into the scope of flammable gases, pressurized gases, flammable liquids and flammable solids. 4.3 Aerosols are classified into one of three categories according to their composition, chemical heat of combustion and, as appropriate, the results of the foam test (for foam aerosols), the ignition distance test1
GB30000.4—2013
and the confined space test (for spray aerosols). See the decision logic in Chapter 5. Aerosols not classified in Category 1 or Category 2 (extremely flammable or flammable aerosols) should be classified in Category 3 (non-flammable aerosols) Note: Aerosols containing more than 1% flammable components or a heat of combustion of at least 20 kJ/g and not subject to the flammability classification procedure of this standard should be classified as aerosols Category 1. 5 Decision logic and guidance
The decision logic and guidance are for reference only. See Appendix A for decision logic and guidance. It is particularly recommended that the person responsible for classification study Chapter 4 before and during the use of the decision logic.
6 Labels
6.1 Overview
6.1.1 For labels of aerosols, hazard categories are listed in the order of designated pictograms, signal words and hazard statements. The hazard types or categories covered by the United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (Seventeenth Revised Edition) (hereinafter referred to as the "Model Regulations") should list the designated corresponding graphic signs for each category on the label. The allocation of aerosol label elements is shown in Appendix B. 6.1.2 See Appendix C for aerosol classification standards and label elements. 6.1.3 The information required on the label includes hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and supplier logos, etc. Note: For other label elements that have not yet been standardized, such as precautionary statements, they also need to be included on the label. The competent authority may also require additional information, and the supplier may also add supplementary information
6.2 Hazard pictograms
Hazard pictograms should use black symbols on a white background, with a red frame wide enough to be eye-catching. The colors, numbers and minimum sizes of hazard pictograms and graphic symbols specified in the "Model Regulations" are shown in Appendix B. 6.3 Signal words
Signal words are words used on labels to indicate the relative severity of hazards and to alert readers to potential hazards. For extremely flammable aerosols, use the signal word "Danger". For flammable aerosols, use the signal word "Warning". 6.4 Hazard statements
Hazard statements are phrases assigned to a hazard class and category that describe the hazardous properties of a hazardous product and, where appropriate, its degree of hazard. For aerosol hazard statements, see Appendix D6.5 Precautionary statements
Precautionary statements are words (and/or pictograms) used to describe recommended measures to minimize or prevent adverse effects of exposure to hazardous products or improper storage or handling of hazardous products. For this purpose, there are five categories of precautionary statements: general, prevention, emergency, storage and disposal. Aerosol precautionary statements are listed in Annex D. 6.6 Product identifiers
6.61 The product identifier should be used on the label and should be consistent with the product identifier used on the Material Safety Data Sheet. If a substance or mixture is listed in the Model Regulations, the correct UN shipping name should also be used on the packaging. 6.6.2 The label should include the chemical name of the substance. For mixtures or alloys, when acute toxicity, skin or respiratory sensitization or specific target organ toxicity appear on the label, the label should include the chemical composition of all ingredients or alloying elements that may cause these hazards. The regulatory authority may require that the chemical names of all ingredients or alloying elements that may cause the mixture or alloy to be listed on the label2
Supplier identification
The name, address and telephone number of the manufacturer or supplier of the substance or mixture should be provided on the label. 6.8
Examples of labels
See Annex E for examples of aerosol labels.
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GB 30000.4—2013
GB30000.4-2013
A.1 Decision logic
Appendix A
(Informative Appendix)
Decision logic and guidance
Classification of aerosols requires data on their flammable components, their chemical heat of combustion and, as appropriate, the results of the foam test (for foam aerosols), ignition distance test and enclosed space test or for spray aerosols). Classification should be carried out according to decision logic A.1.1, A.1.2 and A.1.3.
A.1.1 Decision logic for aerosols See Figure A1
Category 3
No graphic symbol
Contains no more than 1% of flammable components and has a direct combustion heat of less than 20kl/g
Does it contain no less than 85% of flammable components and has a combustion heat of no less than 30kJ/g? For spray aerosols, continue with decision logic A.1.2: For foam aerosols, continue with decision logic A.1.3. Yes
Decision logic for aerosols in Figure A.1
Category 1
A.1.2 Decision logic for spray aerosols See Figure A.2 Spray aerosols
In the ignition distance test, does the distance at which ignition occurs not less than 75cm? Is its combustion heat less than 20kJ/g?
In the ignition distance test, does the distance at which ignition occurs not less than 15cm? In the closed space ignition test,
a) the time equivalent is not greater than 300s/m: or
b) the deflagration density is not greater than 300g/m32
Figure A.2 Spray aerosol judgment logic
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GB30000.4—2013
Category 1
Category 2
Category 2
Category 3
No graphic symbol
GB30000.4-2013
A.1.3 Foam aerosol judgment logic See Figure A.3 Foam aerosol
In the foam test,
a) the flame height is not less than 20cm and the flame duration is not less than 2s: or b) the flame height is not less than 4cm and the flame duration is not less than 7s? In the foam test, is the flame height not less than 4 cm and the flame duration not less than 2 s?
Figure A.3 Foam aerosol decision logic
A.2 Guidance
Category 1
Category 2
Category 3
No graphic symbol
A.2.1 The chemical heat of combustion (AH.) expressed in kilojoules per gram (kJ/g) is the product of the theoretical heat of combustion (ΔHemb) and the combustion efficiency, which is usually less than 1.0 (typical combustion efficiencies are 0.95 or 95%). A.2.1.1 For composite aerosol preparations, the chemical heat of combustion is the sum of the weighted heats of combustion of each component, as shown in formula (A.1): AH(product)=
Wherein:
CwXAH]
Chemical heat of combustion, in kJ/g; mass fraction of the component in the product, expressed in %; specific heat of combustion of component i in the product, in kJ/g..(A.1)
GB30000.42013
A.2.1. 2 Chemical heat of combustion can be found in the literature, calculated or determined based on tests [see GB/T21631. GB/T21614, ASTM D240, IS0/FDIS13943:1999 (E/F) 86.186.3 and NFPA30B A.2.2 For ignition distance tests, closed space ignition tests and aerosol foam flammability tests, see Sections 31.4, 31.5 and 31.6 of the United Nations Manual of Tests and Criteria for the Transport of Dangerous Goods (Fifth Revised Edition). Recommendations for the transport of dangerous goods
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For the allocation of aerosol label elements, see Table B.1. Appendix B
(Normative Appendix)
Allocation of label elements
Table B.1 Allocation of aerosol label elements
Aerosol
Category 1
Extremely flammable aerosol
With pressure container: If heated
Category 2
Flammable aerosol
With pressure container: If heated
Category 3
No pictogram
With pressure container: If heated
In the Model Regulations:
Color of graphic symbols
·Graphic symbols, numbers and borders may
be black instead of white:
·The background color remains
red in both cases.
Number 2 in the figure refers to Category 2 in GB6944-2012
.
The minimum size of the transport pictogram is
100mm×100mm
Appendix C
(Normative Appendix)
Aerosol classification standards and label elements
Aerosol classification standards and label elements are shown in Table C.1. Table C.1 Classification criteria and labelling elements for aerosols Hazard category Based on the chemical heat of combustion of its ingredients and, as appropriate, the results of the foam test (for foam aerosols), the ignition distance test and the enclosed space test (for spray aerosols) (see A.1.1, A.1.2 and A.1.3) Based on the chemical heat of combustion of its ingredients and, as appropriate, the results of the foam test (for foam aerosols), the ignition distance test and the enclosed space test (for spray aerosols) Results (see A.1.1, A.1.2 and A.1.3) rKAoNrKAca
Graphic symbol
Hazard statement
Signal word
Hazard statement
Graphic symbol
Signal word
Test statement
GB30000.4—2013
Label elements
Extremely flammable aerosols
Pressure vessels: may burst if
heated
Flammable aerosols
Pressure vessels: may burst if
heated
No graphic symbol
Pressure vessels: may burst if
heated
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