Thermal spraying—Wires,rods and cords for flame and arc spraying—Classification and technical supply condition
Some standard content:
GB/T12608--2003
This standard is modified to adopt the English version of ISO14919:2001 "Wires for thermal spraying flame and arc spraying. Classification and supply technical conditions for powders and core materials".
According to my country's national conditions, the part of TS014919:2001 that quotes the European standard EV10204:1991 "Types of inspection documents for metal products" is modified to quote the national standard GB/T14436-1993 "General Principles of Industrial Product Assurance Documents": core materials with a diameter of 2.0 mm are added. The foreword of the international standard is deleted. This standard and GB/T19356-2003 "Thermal spraying powder: 2 Classification and supply technical conditions" replace GB/T12608-990 "Nomenclature of thermal spraying materials". Compared with GB/112608-1990, this standard has the following changes: 1. The material classification method has been changed, and the classification method of international standards has been fully adopted; 2. The material marking method has been changed, and the marking method of international standards has been fully adopted; 3. The content of Chapter 4 "Material Classification and Nomenclature Preparation and Management" in the original standard has been deleted; 4. The technical conditions for material supply have been added, and some technical conditions common to various materials have been specified. This standard is managed by the China Machinery Industry Federation. This standard is under the jurisdiction of the Technical Committee for Standardization of Metallic and Non-metallic Coatings. The drafting units of this standard are Wuhan Institute of Material Protection and Shanghai Ruifa Spraying Machinery Co., Ltd. The main drafters of this standard are Jiang Hongsheng, Chen Huiguo, Zuo Danjiang, Liu Zishan, 1 Scope
Wires for flame and arc spraying,
Rods and core materials for thermal spraying
Classification and technical supply conditions
GB/T 12608--2003
This standard specifies the classification requirements for metallic and non-metallic thick wires (solid and cored), rods and core materials used for thermal spraying, especially for arc and flame spraying.
Normative references
The clauses in the following documents have become clauses of this standard through reference in this standard. For any dated referenced document, all subsequent amendments (excluding errata) or revisions are not applicable to this standard. However, the parties to the agreement based on this standard are encouraged to study whether the latest version of this document can be used. For any undated referenced document, the latest version applies to this standard. GB/T14436-1993 General Principles of Industrial Product Warranty Documents 3 Classification
Classification based on manufacturing method and product structure
The classification of thermal spraying materials based on manufacturing method and product structure is shown in Table 1. Table 1 Classification number of thermal conductivity materials and product structure
Solid wire/rod
Solid wire/rod
Core wire (shaped wire)
Core wire (folded wire)
Ceramic material
Classification according to material type and chemical composition
Manufacturing method
Manufacturing and forming by powder metallurgy
Filling in metal tube and compacting during forming
Filling the metal shell with powder, bonding and compacting the powder, binder and organic material shell at the same time extrusion forming Ceramic material pressing and sintering forming
Material type is exempt from Table 2, and the chemical composition should be as shown in Tables 3 to 10. Table 2 Classification by material type
Tin and copper alloys
Zinc and zinc alloys
Aluminum and aluminum alloys
Steel and copper alloys
Iron and iron alloys
Gold and gold alloys
Oxide ceramics
Composition uniformity
Composition uniformity
Powder filled in solderless metal
Powder filled between metal shells
Powder filled in plastic shells
Material made of ceramic particles bonded together
GB/T 12608—2003
Gold and gold-containing
SnSbCu64
Zinc and zinc alloys
Table 3 Tin and tin alloys
Alloying elements
Mass fraction (%)
Table 4 Zinc and zinc alloys
Alloying elements
Mass fraction (%)
84--86
Other elements
Mass fraction/(%)
Al-cd-2n
Other elements
Mass fraction (%)
Others:
Other elements:
.0.006
e55,0. 12
Manufacturing method
Manufacturing method
3.2.3 Aluminum and aluminum alloys
Table 5 Aluminum and aluminum alloys
Alloying elements
Mass fraction (%)
4. 6~5. 3
0. 10 ~-0. 25
4. 5~5. 5
Other elements
GB/T126082003
Manufacturing method
Mass fraction/%>
≤.0.006
Others:
Others:
Others:
Others:
.0, 03
GB/T 12608—2003
Copper and alloys
CuZn37
Ca7n 3§
CuSn f
CuSn12
CLiAIB
CuAl 10
Table 6 Copper and copper alloys
Alloying element
Mass fraction/(%)
0. 5 ~-1. 5
11.0-~13.0
9. (-~11. (
Other elements
Mass fraction/(%)
Others:
Others:
Others:
Others:
Others:
0.01~~0. 4
0.01-0. 4
Preparation method
3.2.5 Iron and iron alloys
l0 MnSi 4
80 MnSi
150Cr4
110Cr3
110 MnCrTi5 5
X 45 Cr 13
）With copper bond layer
）Without plating layer
X 20 CrM 13 1
X 6 CrAl 22 4
Table 7 Iron and iron alloys
Alloy elements
Mass fraction/(%)
0.04-0.12
0. 42~0. 68
0.07--0.14
0.07--0, 14
1. 3~ 1. 6
0. 15-0, 35
0.50--0.70
1. 4 ~-1. 6
0. 15 ~0. 30
0, 50~0.70
1. 3 -- 1. 5
0. 9--1,2
0.20~0.40
0. 20 -~0, 40
0, 9--1. 1
0. 97--1. 23
0. 12-0. 38
1. 76 -~-2. 27
1. 65 -~ 1. 95
0, 3-~~0. 50
0., 17 ~ 0. 22
12--14
0. 9 1. 5
3. 5~-5. 5
Others
CB/T 12608--2003
Manufacturing method
Mass fraction/%)
.0. 15
0.13~-0.35
.0.025
.0,040
GB/T12608—2003
X 6 CrNi 19 9
X 5 CrNiMo 17 12 2
X 12 CrNiMn 18 8 6
X 12 Ni 25 20
X 25 CrCuB 26 3 3
X 25 MnAISi7 5
Table (continued)
Alloy elements
Mass fraction/(%)
18--20
8.5--10. 5
16. 5-~ 18, 5
10, 5-13, 5
5. 5~8. 0
7. 5 ~9. 5
1. 5 ~~3. 5
Other elements
Mass fraction/(%)
.0.045
≤.0.040
.0.020
Manufacturing method
3.2. 6 Nickel and chrome alloys
NiCu30
NiCrFe 15 2℃
Ni CT 20
NiAl 20
NiAIMu55
NiCrAI20 6
NiFeAICr 20 14 3
NiCrBSi
Filled with solid wire
Table nickel and nickel alloy
Taiwan gold element
Mass fraction "as)
27.0---35. 0)
1.0~-4, 0
1. 0-2. 5
18:-21
18~-22
4.5~-5. 5
14 --i5
17--- 23
Other elements
GB/T12608—2003
Manufacturing method
Mass fraction/(both)
s22, 5 | | tt | tt||Ak0T087/13
AO/T0,60/40
AlO./SiO,70/30
Al,(./Mg0 70/30
Table 9 Copper
Alloy elements
Mass fraction/(%》
Capsule 1D oxide ceramics
Alloy element scheme
With amount fraction%）
28--31
85~-87
76 ~82
Other elements
Mass fraction/(%)
Fe: O,
Manufacturing method
Manufacturing method
4 Dimensions and tolerances
GB/T12608—2003
The standard dimensions and tolerances of the diameters of wires, slugs and core materials for thermal spraying are shown in Tables 11, 12 and 13. If necessary, the user can negotiate with the manufacturer or supplier to determine a smaller tolerance range. The straightness of the material must be good so that the material will not break when it is fed. Wire diameter
Dimensions/mm
Inch/mm
Dimensions/mm
5 Properties
5.1 Mechanical properties
Wire diameter
10,05;
Core diameter
Tolerance/mm
—0,07
Tolerance/mm
Tolerance/mm
±0,05
The mechanical properties of the wire should be such that there are no problems with the wire during feeding and spraying. If necessary, the mechanical properties of the wire should be agreed upon by the manufacturer, supplier and user.
Note that the tempering treatment of the hot spray wire should be such that the wire is suitable for continuous feeding on the hot spray equipment. Inadequately tempered, too hard thermal spray wire is difficult to handle, difficult to straighten, and can cause important parts of the spray gun, such as feeding wheels, guides, conductive tubes or excessive spraying to wear out. On the other hand, too soft thermal spray wire (such as lead, pot, zinc, etc.) can cause feeding difficulties. 5.2 Surface properties
The surface of the thermal spray wire must be smooth and free from corrosion products, burrs and cracks, shrinkage cavities, overlaps and scales, as well as defects such as necking, welds and curling. In addition, foreign matter that affects the properties of the thermal spray material or the properties of the thermal spray coating should be removed. Martensitic and ferritic steel wires used for arc spraying should be bonded to prevent corrosion during storage. The coating should cover all surfaces of the wire without obvious defects.
Alloy wires numbered 5.7 (see Table 7) are of two types: 5.7a) are wires with copper coatings, and 5.7h) are wires with other suitable coatings. Without degrading the spray coating, a very small amount of lubricant may be applied to such thermal spray wires to allow the wires to be smoothly and low-frictioned through the thermal spray equipment. Note that cored wires manufactured according to the method in Table 1 of Chapter 3 cannot be lubricated or treated with any other agent. The core surface must be smooth and free of necking. The rod surface must be free of necking and scratching. The head of the rod should be free of twisting and head-to-head warping, which will affect the feeding of the rod. GB/T12608—2003 5.3 Workability: Wire winding Wires should be wound in wires, on reels, or in coils or in barrels. Twists or sharp bends should be avoided. The head of the wire should be tied tightly to prevent unraveling. The beginning of the wire should be marked for easy retrieval. The outermost layer of the wire on the spool should be at least 3 Ⅱm away from the reverse edge of the spool flange. The diameter of any loose single wire should not be greater than 1.2 times the outer diameter of the spool, and should not be less than the inner diameter of the spool. The wire should not be twisted. The loose and bottomed velvet rolls should be kept flat on the runner. The unwinding of the wire rolls does not affect normal use. 6 Sampling and testing
Any test of thermal spraying materials should be sampled at the beginning of the thermal spraying material packaging. In order to evaluate a thermal spraying material, a spraying performance test can be arranged between the supplier and the user. All types of analytical methods are applicable to the determination of the composition of thermal spraying materials, only within their proven test range: 7 Marking
Marking should be carried out according to the principles given in the following example.
The ferroalloy thermal spraying material containing 18%Ct, 85Ni, 6%Mn and 0.15%C, with a diameter of 1.6mm and manufactured and formed by metallurgical method (see Table 1. No. 1) and conforming to No. 5.10 in Table 7 is marked as: Thermal spraying material GB/T12608-5.[0-1,6-18 Technical requirements for supply
8.1 Form of supply
The material is supplied in the form of wire drum, wire coil, wire spool or barrel. The size is shown in Table 14. The material is supplied in bundles of 50 or 100. 8.2 Labeling
Wire in spools, baskets, reels, coils and drums and each package of ceramic rods shall have a durable label providing the following information:
Marking required by Section 7
- Name and trademark of the manufacturer/supplier # Label number:
- Net weight:
... Spools and baskets shall have a label containing the above information securely affixed to the inside surface of the spool or to a conspicuous location on the outside of at least one flange:
A reel shall have a label containing the above information securely affixed to the inside surface of the reel A coil shall have a label containing the above information securely affixed to a conspicuous location on the package Drums shall have a label containing the above information securely affixed to a conspicuous location on the top, and the side of the drum shall also have a label; - Ceramic rods shall have a label containing the above information securely affixed to a conspicuous location on the outside of the package: If the thermal spray material has an outer package, the above information shall also be marked on the outer package. 8.3 Packaging and storage
If there is no other cooperation, the thermal spray materials are supplied in packaging, which is to protect the materials from damage, contamination and corrosion. Ceramic rods should be packaged in impact-resistant tubular containers to prevent damage during transportation. Packaged thermal spray materials should be stored in a dry room at room temperature. 9 Certificates
9.1 Product Quality Assurance
A product quality assurance certificate that meets the requirements of 4.2 of GB/T14436-1993 is provided with the thermal spray materials. 10
9.2 Product Certificate
GB/T1260B-2003
If there is an agreement between the user and the supplier/manufacturer, a product certificate that meets the requirements of 4 of GB/T14436-1993 should also be provided.
According to the agreement between the customer and the supplier/manufacturer, in addition to the chemical analysis and mechanical performance test results, the product certificate should also indicate the supplier's product mark and batch number. Table 14 Spools, reels, reels,Size marking of barrelWww.bzxZ.net
Spool (S)
Spool (S)
Warp spool (BS)
Reel (R)
Reel (R)
Special C
Barrel (D)
Burning shaft (S)
Abbreviation marking
S 300 -- 180
S300--210
C (a,)e
Outer diameter di/mm
a00±5
300±5
30a±5
392·±5
500--800
Basket spool (RS)
The abbreviation marking of the coil should include the outer diameter of the coil. Inner diameter 4/mm
iao ±3
210±3
190±3
300+15
300+15
300-550
Reel (R)
When supplying barreled hot spray wire, the size and weight shall be negotiated between the user and the supplier, hole diameter da/mm
Outer width b/mm
Reel (C)
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