GB 30000.16-2013 Chemical Classification and Labelling Specification Part 16: Organic Peroxides GB30000.16-2013 Standard compression package decompression password: www.bzxz.net
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of organic peroxides. This part applies to the classification and labeling of organic peroxides in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals.
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended.
The expected structure of GB30000 "Specifications for Classification and Labelling of Chemicals" and the national standards to be replaced are:
———Part 1: General (replaces GB13690-2009);
———Part 2: Explosives (replaces GB20576-2006);
———Part 3: Flammable gases (replaces GB20577-2006);
———Part 4: Aerosols (replaces GB20578-2006);
———Part 5: Oxidizing gases (replaces GB20579-2006);
———Part 6: Gases under pressure (replaces GB20580-2006);
———Part 7: Flammable liquids (replaces GB20581-2006);
———Part 8: Flammable solids (replaces GB 20582-2006);
———Part 9: Self-reactive substances and mixtures (replaces GB 20583-2006);
———Part 10: Pyrophoric liquids (replaces GB 20585-2006);
———Part 11: Pyrophoric solids (replaces GB 20586-2006);
———Part 12: Self-heating substances and mixtures (replaces GB 20584-2006);
———Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB 20587-2006);
———Part 14: Oxidizing liquids (replaces GB 20589-2006);
——Part 15: Oxidizing solids (replaces GB 20590-2006);
——Part 16: Organic peroxides (replaces GB 20591-2006);
——Part 17: Corrosive to metals (replaces GB 20588-2006);
——Part 18: Acute toxicity (replaces GB 20592-2006);
——Part 19: Skin corrosion/irritation (replaces GB 20593-2006);
——Part 20: Serious eye damage/eye irritation (replaces GB 20594-2006);
——Part 21: Respiratory or skin sensitization (replaces GB 20595-2006);
———Part 22: Germ cell mutagenicity (replaces GB 20596-2006);
———Part 23: Carcinogenicity (replaces GB 20597-2006);
———Part 24: Reproductive toxicity (replaces GB 20598-2006);
———Part 25: Specific target organ toxicity single exposure (replaces GB 20599-2006);
———Part 26: Specific target organ toxicity repeated exposure (replaces GB 20601-2006);
———Part 27: Aspiration hazard;
———Part 28: Hazard to the aquatic environment (replaces GB 20602-2006);
———Part 29: Hazard to the ozone layer;
———Part 30: Warning signs for chemical workplaces.
This part is part 16 of GB 30000.
This part was drafted in accordance with the rules given in GB/T 1.1-2009.
This part is consistent with the technical content of the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (Fourth Revised Edition).
This part replaces GB 20591-2006 "Safety Specification for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Organic Peroxides".
Compared with GB 20591-2006, the main technical content changes of this part are as follows:
———The name of the standard has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals—Part 16: Organic peroxides" and the English name is "Rules for classification and labelling of chemicals—Part 16: Organic peroxides";
———The scope of Chapter 1 has been modified, "Warning label" has been changed to "Label", and "Warning statement" has been deleted; ||tt
|| ———The introductory words of Chapter 2 "Normative references" have been modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" has been added as a reference document;
———The introductory words of Chapter 3 "Terms and Definitions" have been added;
———Figure 1 "Decision Logic Diagram" and "Guidance" in Chapter 5 have been made informative Appendix A;
——Deleted the original Chapter 7, and modified Table 3 of the original Chapter 7 as normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition);
——In accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition), modified and integrated the original Chapters 6, 7 and 8 into Chapter 6; the original Table 2 was modified as normative Appendix C;
——Deleted the original Chapter 8, and added the relevant "Hazard Statements" and "Precautionary Statements" as informative Appendix D;
——Added informative Appendix E "Examples of Labels".
This part was proposed and managed by the National Technical Committee for Standardization of Dangerous Chemicals Management (SAC/TC251).
Drafting units of this part: China Chemical Economic and Technical Development Center, Beihai Entry-Exit Inspection and Quarantine Bureau, Shanghai Entry-Exit Inspection and Quarantine Bureau, Huafeng Group Co., Ltd.
The main drafters of this part are Wang Xiaobing, Wu Junyi, Shang Jie, Wang Jingmin, Jiang Wei, Ji Ruwu, Wen Tao, Ma Congyue, Xiang Chaoli, Dai Sheng, Cao Mengran, An Chao, and Yang Ting.
The previous versions of the standards replaced by this part are:
———GB20591—2006.
The following documents are indispensable for the application of this document. For any dated referenced document, only the dated version applies to this document. For any undated referenced document, the latest version (including all amendments) applies to this document.
GB13690 General Principles of Classification and Hazard Communication of Chemicals
United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria (Fifth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition)

ICS13.300
National Standard of the People's Republic of China
GB30000.16—2013
Replaces GB20591-—2006
Rules for classification and labelling of chemicals-Part 16:Organic peroxides
Promulgated on October 10, 2013
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China
Administrative Committee of Standardization of the People's Republic of China
Implementation on November 1, 2014
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. The expected structure of GB30000 "Chemical Classification and Labeling Specification" and the national standards to be replaced are: Part 1: General (replaces GB136902009); Part 2: Explosives (replaces GB205762006): Part 3: Flammable gases (replaces GB20577-2006): Part 4: Aerosols (replaces GB20578-2006); Part 5: Oxidizing gases (replaces GB205792006); Part 6: Pressurized gases (replaces GB20580-2006); Part 7: Flammable liquids (replaces GB20581-2006): Part 8: Flammable solids (replacing GB20582-2006): Part 9: Self-reactive substances and mixtures (replacing GB20583-2006): Part 10: White flammable liquids (replacing GB20585-2006): Part 11: Self-igniting solids (replacing GB20586-2006); Part 12: Self-heating substances and mixtures (replacing GB20584-2006): Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replacing GB20587-2006): Part 14: Oxidizing liquids (replacing GB20589-2006): Part 15: Oxidizing solids (replacing GB 20590-2006): Part 16: Organic peroxides (replaces GB20591-2006): Part 17: Metal corrosion (replaces GB205882006): Part 18: Acute toxicity (replaces GB205922006): Part 19: Skin corrosion/irritation (replaces GB20593-2006); Part 20: Serious eye damage/eye irritation (replaces GB205942006); Part 21: Respiratory or skin sensitization (replaces GB20595-2006); Part 22: Germ cell mutagenicity (replaces GB20596-2006) ：Part 23: Carcinogenicity (replaces GB20597-2006): Part 24: Reproductive toxicity (replaces GB20598-2006): Primary single exposure (replaces GB20599-2006): Part 25: Specific target organ toxicity
Part 26: Specific target organ toxicity repeated exposure (replaces GB20601-2006); Part 27: Inhalation hazard;Www.bzxZ.net
Part 28: Hazards to the aquatic environment (replaces GB20602-2006); Part 29: Hazards to the ozone layer;
Part 30: Warning signs for chemical workplaces. This part is Part 16 of GB30000.
This part was drafted in accordance with the rules given in GB/T 1.1-2009. GB30000.16-2013
This part is consistent with the technical content related to the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (Fourth Revised Edition). This part replaces GB20591-2006 "Safety Specification for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Organic Peroxides".
Compared with GB20591-2006, the main technical content changes of this part are as follows: GB30000.16-—2013
The standard name has been modified. The Chinese name has been changed to "Chemical Classification and Labelling Specifications Part 16: Organic Peroxides", and the English name is "Rules for classification and labelling of chemicals Part 16: Organic peroxides". ofchemicals-Part 16: Organic peroxides"; modified the scope of Chapter 1, changed "warning label" to "label", deleted "warning statements", modified the introductory words of Chapter 2 "normative references", and added "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" as a reference document; added the introductory words of Chapter 3 "Terms and Definitions"; added Figure 1 "Decision Logic Diagram" and "Guide" in Chapter 5 as informative Appendix A; deleted the original Chapter 7, and modified Table 3 of the original Chapter 7 as normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition);
According to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition), the original Chapters 6, 7 and 8 were modified and integrated into Chapter 6; the original Table 2 was modified as normative Appendix C; deleted the original Chapter 8, and added the relevant "hazard statements" and "precautionary statements" as informative Appendix D; added informative Appendix E "Label Examples". This part is proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251). Drafting units of this part: China Chemical Economic and Technical Development Center, Beihai Exit-Entry Inspection and Quarantine Bureau, Shanghai Exit-Entry Inspection and Quarantine Bureau, Huafeng Group Co., Ltd.
Main drafters of this part: Wang Xiaobing, Wu Junyi, Shang Jie, Wang Jingmin, Jiang Wei, Ji Ruwu, Wen Tao, Ma Congyue, Xiang Chaoli, Dai Sheng, Cao Mengran, An Chao, Yang Ting.
The previous versions of the standards replaced by this part are: GB205912006.
1 Scope
Chemical Classification and Labeling Specifications
Part 16: Organic Peroxides
GB30000.16—2013
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of organic peroxides. This part applies to the classification and labeling of organic peroxides according to the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (hereinafter referred to as GHS).
2 Normative references
The following documents are essential for the application of this document. For any dated referenced document, only the dated version applies to this document. For undated references, the latest version (including all amendments) applies to this document GB 13690 General Rules for Classification and Hazard Communication of Chemicals Global System for Classification and Labelling of Chemicals (4th revision) United Nations Manual of Construction, Test and Standardization for the Transport of Dangerous Goods (5th revision) United Nations Recommended Model Regulations for the Transport of Dangerous Goods (17th revision) 3 Terms and Definitions GB 13690 defines and defines the following terms and definitions: Organic peroxides Liquid or divalent solid organic compounds having a 0-0 structure and one or two carrier atoms that can be regarded as peroxides and in which organic groups have replaced them. This definition also includes organic peroxide preparations (mixtures). Organic peroxides are thermally unstable substances or compounds which undergo exothermic self-accelerating decomposition. In addition, they may have one or more of the following properties: prone to explosive decomposition; rapid combustion; sensitive to impact or friction; d) react dangerously with other substances. Organic peroxides are considered to have explosive properties if their preparations in laboratory tests are prone to explosion, deflagrate rapidly or show violent effects when heated under confinement.
4 Classification criteria
4.1 General principles
For the general principles of classification and labeling of organic peroxides, see GB13690. 4.2 Classification criteria
4.2.1 Any organic peroxide should be considered for classification into this category unless the organic peroxide mixture: 1
GB30000.16——2013
a) The available oxygen content of its organic peroxide does not exceed 1.0%, and the hydrogen peroxide content does not exceed 1.0%; or b) The available oxygen content of its organic peroxide does not exceed 0.5%, and the hydrogen peroxide content exceeds 1.0% but does not exceed 7.0% The effective oxygen content (%) of the organic peroxide mixture is calculated according to formula 1: 16x
Wherein:
Number of peroxide groups per molecule of organic peroxide; Concentration of organic peroxide (mass percentage, %); Molecular weight of organic peroxide.
According to the following principles, organic peroxides can be classified into the following seven categories 4.2.2
Any organic peroxide that may detonate or deflagrate rapidly in the package will be classified as Type A organic peroxide;...( 1) Any organic peroxide with explosive properties, which neither explodes nor deflagrates rapidly in the package, but may undergo thermal explosion in the package, shall be defined as Type B organic peroxide; Any organic peroxide with explosive properties, which is unlikely to detonate or deflagrate rapidly or undergo thermal explosion in the package, shall be defined as Type C organic peroxide; Any organic peroxide, if in laboratory tests: d) partially detonates, does not deflagrate rapidly, and does not exhibit any violent effect when heated under closed conditions; or 2) does not detonate at all, deflagrates slowly, and does not exhibit any violent effect when heated under closed conditions; or does not detonate or deflagrate at all, and exhibits moderate effect when heated under closed conditions; 3) shall be defined as Type D organic peroxide; Any organic peroxide Any organic peroxide that, in laboratory tests, neither detonates nor deflagrates at all, and shows only a weak effect or no effect when heated under closed conditions, will be defined as an E-type organic peroxide; any organic peroxide that, in laboratory tests, neither detonates nor deflagrates at all in a cavitation state, and shows only a weak effect or no effect when heated under closed conditions, and has a weak or no explosive power, will be defined as an F-type organic peroxide; any organic peroxide that, in laboratory tests, neither detonates nor deflagrates at all in a cavitation state, and shows no effect when heated under closed conditions, and has no explosive power, will be defined as a G-type organic peroxide. However, the substance or mixture should be thermally stable (the self-accelerating decomposition temperature of a 50 kg package is 60°C or higher), and for liquid mixtures: the boiling point of the desensitizing diluent used is not less than 150°C. If the organic peroxide is not thermally stable, or the boiling point of the desensitizing diluent used is less than 150°C, it will be defined as an F-type organic peroxide.
Note 1: Type G peroxides do not have assigned hazard communication elements, but properties belonging to other hazard categories need to be considered. Note 2: Type A~G organic peroxides may not be suitable for all systems. 4.3 Temperature control standards
The following organic peroxides require temperature control: Type B and Type C organic peroxides with SADT (self-accelerating decomposition temperature) 50°C: a
Type D organic peroxides that show a moderate effect when heated under confinement and SADT ≤ 50°C or that show a weak or b)
no effect when heated under confinement and SADT ≤ 45°C; and Note: Type E and Type F organic peroxides C with SADT ≤ 45°C are determined by test series E specified in Part 2 of the United Nations Manual of Tests and Criteria (Fifth Revised Edition) (hereinafter referred to as the Manual of Tests and Criteria)
4.3.2 The test method for determining SADT and the calculation of control temperature and critical temperature are shown in Chapter 28 of Part 2 of the Manual of Tests and Criteria. The chosen test should be conducted in a manner that is representative of the size and material of the package. 5 Decision logic and guidance
The decision logic and guidance are for reference only. See Appendix A for decision logic and guidance. It is particularly recommended that the person responsible for classification study Chapter 4 before and during the use of decision logic. 6 Labelling
6.1 Overview
GB30000.16—2013
6.1.1 For the labelling of organic peroxides, the hazard categories are listed in the order of the designated pictograms, signal words and hazard statements. The hazard types or categories covered by the United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (Seventeenth Revised Edition) (hereinafter referred to as the "Model Regulations") should list the designated corresponding graphic signs for each category on the label. The allocation of label elements for organic peroxides is shown in Appendix B. 6.1.2 See Appendix C for the classification criteria and label elements for organic peroxides. 6.1.3 The information required on the label includes hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and supplier logos, etc. Note: For other label elements that have not yet been standardized, such as precautionary statements, they also need to be included on the label. The competent authorities may also require additional information, and suppliers may also add supplementary information.
6.2 Hazard pictograms
Hazard pictograms should use black symbols with white backgrounds, and the red frame should be wide enough so that Eye-catching The colours, numbers and minimum sizes of hazard pictograms, graphic symbols specified in the Model Regulations are shown in Appendix B. 6.3 Signal words
Signal words are words used on labels to indicate the relative severity of hazards and to alert readers to potential hazards. The signal word "Danger" is used for Type A organic peroxides, Type B organic peroxides, Type C organic peroxides and Type D organic peroxides. The signal word "Warning" is used for Type E organic peroxides and Type F organic peroxides. 6.4 Hazard statements
Hazard statements are phrases assigned to a hazard class and category that describe the hazardous properties of a hazardous product and, where appropriate, its degree of hazard. Hazard statements for organic peroxides are shown in Table C, 1 and in Appendix D. 6.5 Precautionary statements
A precautionary statement is a word (and/ or pictogram) is used to describe recommended measures to minimize or prevent adverse effects that may result from exposure to, or improper storage or handling of, hazardous products. For this purpose, there are five categories of precautionary statements: general, prevention, emergency, storage and disposal. See Appendix D for precautionary statements for organic peroxides. 6.6 Product identifiers
6.6.1 The product identifier should be used on the label and should be consistent with the product identifier used on the Material Safety Data Sheet. If a substance or mixture is listed in the Model Regulations, the correct UN shipping name should also be used on the packaging. 6.6.2 The label should include the chemical name of the substance. For mixtures or alloys, when acute toxicity, skin or respiratory sensitization or specific target organ toxicity appear on the label, the label should include all ingredients that may cause these hazards. The competent authority may also require that the chemical names of all ingredients or alloying elements that may contribute to the hazard of the mixture or alloy be listed on the label. 6.7 Supplier identification
The name, address and telephone number of the manufacturer or supplier of the substance or mixture should be provided on the label. 6.8 Label examples
For examples of organic peroxide labels, see Appendix E3
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GB30000.16—2013
A.1 Decision logic
Appendix A
(Informative Appendix)
Decision logic and guidance
For the classification of organic peroxides, the test series A to H described in the second part of the Manual of Tests and Criteria should be used, and the classification shall be carried out according to the decision logic diagram A.1.
Test B
Can it be detonated in the package?
Yes, rapidly
Substance/mixture
Test A
Can it conduct a deflagration
Part 1.2
Test C
Can it conduct a deflagration
3.2Yes, very slowly
Test D
Can it conduct a deflagration rapidly in the packaged product?
4.1Yes, rapidly
Can it conduct a deflagration?
4.2Yes, very slowly
In the packaged product
! What is the effect of the highest heat?
What is the effect of heating
in confinement?
Test G
Can it dehumidify in the packaged product?
Test C
GB30000.16-—2013
Test C
Can it conduct deflagration
V2 is very sensitive
Test store
Heated under closed conditions
9.2 Medium,
8.2 Medium
Packed in packages larger than 400kg
450L or
with containers?
Not too low
Decision logic for organic peroxides
rKANTKAca
Test F
What is its explosive power?
Test E
What is the effect of heating under closed conditions?
GB30000.16-2013
A.2 Guidance
A, 2.1 Organic peroxides are classified according to their chemical structure and the definition of the effective oxygen and hydrogen peroxide content of the mixture (see 4.2.1)
A.2.2 The properties of organic peroxides that are decisive for classification should be determined by tests. Test methods with relevant evaluation criteria are given in the Manual of Tests and Criteria, Part 2, Test Series A to H). A.2.3 Mixtures of organic peroxides may be classified as the same type of organic peroxide as the most dangerous ingredient. However, since two stable ingredients may form a mixture with a lower thermal stability, the self-accelerating decomposition temperature (SADT) of the mixture should be determined. For the allocation of label elements, see Table B.1. Heating may cause an explosion and explosives (using the same graphic symbol selection process) Appendix B (Normative Appendix) Allocation of label elements Allocation of label elements for organic peroxides Organic peroxides Heating may cause combustion or explosion Type C and Type D Heating may cause Type E and Type F Heating may cause GB30000.16-2013 No label element is allocated to this hazard category Not used in the Model Regulations Note 1: For Type B, in the Model Regulations, 181 Special provisions may apply (explosive labels may be exempted with approval from the competent authority. See Chapter 3.3 of the Model Regulations.
Note 2: Color of graphic signs in the Model Regulations: Organic peroxide pictogram: Symbol (flame): black or self-color: Background color: red in the upper half, yellow in the lower half: Number "5.2\ in the lower corner: black:
Explosive pictogram: Symbol (exploding bomb): black: Background color: orange: Number\1\ in the lower corner: blackTrKAONTKAca
GB30000.16-—2013
Appendix C
(Normative Appendix)
Classification standards and label elements for organic peroxides See Table C.1 for the classification standards and label elements for organic peroxides. Table C.1 Classification standards and label elements for organic peroxides Hazard category
Type C and D type
Type E and F
Test results and application according to Part II series A to H of the Manual of Tests and Criteria Appendix A
Test results and application according to Part II series H of the Manual of Tests and Criteria Appendix A
Test results and application according to Part II series A to H of the Manual of Tests and Criteria Appendix A
Test results and application according to Part II series A to H of the Manual of Tests and Criteria Appendix A
Graphic symbols
Signal word
Hazard statement
Graphic symbols
Signal word
Hazard statement
Graphic symbols
Signal word
Hazard statement
Graphic symbols
t||Signal word
Hazard statement
Graphic symbol
Signal word
Hazard statement
Label elements
Heat may cause explosion
Heating may cause
Burn or explosion
Heating may cause
Heating may cause
This hazard category
No label element is assigned
D.1 Overview
Appendix D
(Informative)
Hazard statements and precautionary statements for organic peroxides GB30000.16—2013
D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with HS for self-heating substances and mixtures. It lists the recommended hazard statements and precautionary statements for each hazard class and hazard category of organic peroxides. See G13690. D.1.2 Coding of hazard statements:
D.1.2.1 The coding of hazard statements is shown in Annex 3 of CHS. D.1.2.2 Each hazard statement is assigned a special alphanumeric code, consisting of a letter and three numbers, as follows:
a) Letters
b) The first digit (representing "hazard warning") represents the type of hazard referred to by the different parts of the hazard statement, as follows:
represents physical hazard
3 represents health hazard
represents environmental hazard
c) The last digit corresponds to the number of hazards caused by the proper properties of the substance or mixture, such as: Explosiveness code 200 to 210 Flammability (code
220 all 2
D.1.2.3 Unless otherwise specified, all specified hazard statements shall appear on the label. The competent authority may specify the order in which the hazard statements appear on the label. In addition, when two or more hazard statements are provided in combination, the competent authority may specify whether the combined hazard statement or the corresponding single statement appears on the label, or leave it to the manufacturer/supplier’s discretion. D.1.3 Precautionary statements shall appear on the label together with the combined hazard communication elements (pictogram, signal word and hazard statement). Supplementary information may also be provided at the discretion of the manufacturer/supplier and/or the competent authority. D.1.3. 1 The codes of precautionary statements are shown in Annex 3 of GHIS. D.1.3.2 Coding of precautionary statements:
D.1.3.2.1 Each precautionary statement is assigned a special alphanumeric code consisting of 1 letter and 3 numbers, as follows:
The letter "P" (standing for "precautionary statement"); the first number represents the type of precautionary statement, as follows, "1\ represents general precautionary statement:
"2\ represents prevention precautionary statement;
"3\ represents emergency precautionary statement;
\4\ represents storage precautionary statement:
"5\ represents disposal precautionary statement;
c) The last 2 numbers (corresponding to the serial number of the precautionary statement). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used to replace the precautionary statement text.
TKAONTKAca-1 Classification criteria and labelling elements for organic peroxides Hazard class
Type C and Type D
Type E and Type F
Test results and application according to Part II, Series A to H of the Manual of Tests and Criteria Appendix A
Test results and application according to Part II, Series H of the Manual of Tests and Criteria Appendix A
Test results and application according to Part II, Series A to H of the Manual of Tests and Criteria Appendix A
Test results and application according to Part II, Series A to H of the Manual of Tests and Criteria Appendix A
Graphic symbol
Signal word
Hazard statement
Graphic symbol
Signal word
Hazard statement
Graphic symbol
Signal word
Hazard statement
Graphic symbol
Signal word
Hazard statement
Graphic symbol
Signal word
Hazard statement
Label elements
Heat may cause explosion
Heating may cause
Burn or explosion
Heating may cause
Heating may cause
This hazard category
No label element is assigned
D.1 Overview
Appendix D
(Informative Appendix)
Hazard statements and precautionary statements for organic peroxides GB3000 0.16—2013
D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with HS for self-heating substances and mixtures, and lists the recommended hazard statements and precautionary statements for each hazard class and hazard category of organic peroxides, see G13690. D.1.2 Coding of hazard statements:
D.1.2.1 The coding of hazard statements can be found in Annex 3 of CHS. D.1.2.2 A special alphanumeric code is set for each hazard statement, consisting of 1 letter and 3 numbers, as follows:
a) Letters
b) The
(representing "hazard warning")
number, representing the hazard type referred to by the hazard statement set in different parts of the code. The details are as follows: 2" represents physical hazard, 3 represents health hazard, and 4 represents environmental hazard (c) followed by a number corresponding to the number of hazards caused by the appropriate properties of the substance or mixture, such as: Explosiveness code 200 to 210 Flammability (code 220 in total) D.1.2.3 Unless otherwise specified, all specified hazard statements shall appear on the label. The competent authority may further specify the order in which the hazard statements appear on the label. In addition, when two or more hazard statements are provided in combination, the competent authority may specify whether the combined hazard statement or the corresponding single statement should appear on the label, or leave it to the manufacturer/supplier to decide. D.1.3 Precautionary statements shall appear on the label together with the unified hazard communication elements (pictogram, signal word and hazard statement). Supplementary statements may also be added at the discretion of the manufacturer/supplier and/or the competent authority. Additional information, such as instructions for use
D.1.3. 1 The codes for precautionary statements are shown in Annex 3 of GHIS. D.1.3.2 Coding of precautionary statements:
D.1.3.2.1 Each precautionary statement is assigned a unique alphanumeric code consisting of 1 letter and 3 digits, as follows:
The letter "P" (standing for "precautionary statement"); the first digit represents the type of precautionary statement, as follows, "1\ represents general precautionary statement:
"2\ represents prevention precautionary statement;
"3\ represents emergency precautionary statement;
\4\ represents storage precautionary statement:
"5\ represents disposal precautionary statement;
c) The last 2 digits (corresponding to the serial number of the precautionary statement). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used to replace the precautionary statement text.
TKAONTKAca-1 Classification criteria and label elements for organic peroxides Hazard class
Type C and Type D
Type E and Type F
Test results and application according to Part II, Series A to H of the Manual of Tests and Criteria Appendix A
Test results and application according to Part II, Series H of the Manual of Tests and Criteria Appendix A
Test results and application according to Part II, Series A to H of the Manual of Tests and Criteria Appendix A
Test results and application according to Part II, Series A to H of the Manual of Tests and Criteria Appendix A
Graphic symbol
Signal word
Hazard statement
Graphic symbol
Signal word
Hazard statement
Graphic symbol
Signal word
Hazard statement
Graphic symbol
Signal word
Hazard statement
Graphic symbol
Signal word
Hazard statement
Label elements
Heat may cause explosion
Heating may cause
Burn or explosion
Heating may cause
Heating may cause
This hazard category
No label element is assigned
D.1 Overview
Appendix D
(Informative Appendix)
Hazard statements and precautionary statements for organic peroxides GB3000 0.16—2013
D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with HS for self-heating substances and mixtures, and lists the recommended hazard statements and precautionary statements for each hazard class and hazard category of organic peroxides, see G13690. D.1.2 Coding of hazard statements:
D.1.2.1 The coding of hazard statements can be found in Annex 3 of CHS. D.1.2.2 A special alphanumeric code is set for each hazard statement, consisting of 1 letter and 3 numbers, as follows:
a) Letters
b) The
(representing "hazard warning")
number, representing the hazard type referred to by the hazard statement set in different parts of the code. The details are as follows: 2" represents physical hazard, 3 represents health hazard, and 4 represents environmental hazard (c) followed by a number corresponding to the number of hazards caused by the appropriate properties of the substance or mixture, such as: Explosiveness code 200 to 210 Flammability (code 220 in total) D.1.2.3 Unless otherwise specified, all specified hazard statements shall appear on the label. The competent authority may further specify the order in which the hazard statements appear on the label. In addition, when two or more hazard statements are provided in combination, the competent authority may specify whether the combined hazard statement or the corresponding single statement should appear on the label, or leave it to the manufacturer/supplier to decide. D.1.3 Precautionary statements shall appear on the label together with the unified hazard communication elements (pictogram, signal word and hazard statement). Supplementary statements may also be added at the discretion of the manufacturer/supplier and/or the competent authority. Additional information, such as instructions for use
D.1.3. 1 The codes for precautionary statements are shown in Annex 3 of GHIS. D.1.3.2 Coding of precautionary statements:
D.1.3.2.1 Each precautionary statement is assigned a unique alphanumeric code consisting of 1 letter and 3 digits, as follows:
The letter "P" (standing for "precautionary statement\); the first digit represents the type of precautionary statement, as follows, "1\ represents general precautionary statement:
"2\ represents prevention precautionary statement;
"3\ represents emergency precautionary statement;
\4\ represents storage precautionary statement:
"5\ represents disposal precautionary statement;
c) The last 2 digits (corresponding to the serial number of the precautionary statement). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used to replace the precautionary statement text.
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