This standard specifies the preparation methods of preparations, products, reagent solutions, buffer solutions, indicators and indicator solutions used in the test methods of inorganic chemical products. This standard is applicable to the preparation of preparations and products required in the test methods of inorganic chemical products, and can also be used for other chemical product standards. HG/T 3696.3-2002 Preparation of preparations and products for chemical analysis of inorganic chemical products HG/T3696.3-2002 Standard download decompression password: www.bzxz.net

1ICS 71. 060. 01:71. 060. 99G10
Registration No.: 1094110943—2002
Chemical Industry Standard of the People's Republic of China
HG/T3696.1-3696.3—2002
Inorganic Chemical Products
Preparation of Standard Titration Solutions, Standard Solutions for Impurities and Preparations and Crystallization for Chemical Analysis
Published on September 28, 2002
Implemented on June 1, 2003
Published by the State Economic and Trade Commission of the People's Republic of ChinaRegistration No.: 109432002
HG/T 3696. 3--2002
Narrow standard
General provisions
Preparation method·
Preparation·
Reagent box
Clearing agent and indicating liquid
Appendix A (Appendix of indication)
Chinese pinyin indexwww.bzxz.net
Multiplication sign: 10943-2002
I[G, 3696.3-2002
This paragraph is not equivalent to the use of national materials The standard A5TME200-1997 "Chemical Analysis and Calibration of Liquid Reagents - Preparation, Calibration and Preparation of Liquid Test Solution" is formulated based on the needs of chemical product analysis. Compared with ASTM F20 (1507), the standard has ten differences:
The "Required" in the short-circuit solution has been changed:
The indicator solution and indicator solution have been added with one additional item, nine items. The preparations and products to be classified into categories; preparations, products, reagent screening, differential screening, indicator solution, indicator device, and the product conditions are recorded in the Appendix A of this standard.
This standard was originally proposed by the State Administration of Chemical Industry and the Chemical Industry Policy and Regulations Department. This standard is under the technical jurisdiction of the National Chemical Standardization Technical Committee, especially the Inorganic Chemical Subcommittee. The maintenance unit of this standard is Tianjin Chemical Research and Design Institute. The main body of this standard is:
The second issue of this standard is:
This standard committee is responsible for the interpretation of the Inorganic Chemical Subcommittee of the Beijing Institute of Standardization Technical Committee. 41
Chemical Industry Standard of the People's Republic of China
Inorganic Chemical Products
Preparation of Preparations and Products for Chemical Analysis
Inoreanic chemical product
Preparaliuns af reagent solutions for chemical analysis1Standard
11G/T3696.3—2002
This standard specifies no new preparations, products, formulas, indicators and indicator methods for chemical product testing.
This standard is used for the preparation of preparations without preparation, and can also be used for other chemical product standards.2Referenced standards
The text contained in the following notes shall become the certification of this standard through citation in the standards, and the version required by the standard shall be long-lasting. All extremely common parts shall be considered, and the points of use shall be considered to be full of sensitivity. G/T—19: New Laboratory H Water Specification Experimental Method (5:D) T97331% Chemical Test: Benzene Compounds Determination Method 3 General Observation
3.1 The requirements used in this standard\1 are not specified when other requirements are not specified. (B/T62, Secondary Water Specification.3.2 The test standard is based on the purity of the three. 3.3\V,+V\ refers to the accumulated fire V, the specific case of the added liquid is V: the reagent! 3.4 The volume of the device is expressed as grams per liter) 3.5 When the product is mixed, eroded, and the width of the package changes beyond the specified limit, it should be re-prepared: 3.6 The coating has been mentioned outside the ring, and the buoyancy in this standard refers to water drop liquid, and dilution refers to water flushing with: 3.7 The alcohol not specified in the standard is ethanol with a score of 3 (report). 4 Preparation method
4 1 Preparation
4.1.1 Pour water into the flask without sodium dioxide, drain ain, and when the tube with sodium ash is full, cool it down. Make the moon phase one week. 4.1.2 Requirement of rate
Pour water into the flask, and use the rubber stopper of the tube with sodium ash to fill it. The tube is filled with 1 part of the sodium ash to collect the fat. The constant out period is 4.1.3 Rat-free water
or 1 part of the decomposable cross-linking resin and 1 part of the strong acidic high-ion exchange material, fill the exchange meter with the diameter of m: m, and keep the flow rate of 3--=m./an through the exchanger. Approved by the State Economic and Trade Commission of the People's Republic of China on September 2, 2002, and implemented on June 1, 2003
4.1.4 Non- or re-emulsified calcium solution
IIG/T3696.3-2002
Put the total oxygen content of the new liquid into a full bucket (with a volume of more than 30 hours of acid-free filter) (as shown in Figure 1), cool, and use the group to make up to the original volume. 1 oxygen 2 years me!
4.1.5 Take 50) ml of ammonia water, add 1000 ml of round-bottomed bottle, add 1 C. g of raw stone slurry obtained by digestion, mix well, and place the plate connected to the condenser for 18-20 hours. Remove the sodium tube (2), and then use a mole leather tube with about G of carbon dioxide to burn the water. Use ice cold outside. Use a tight limit of water to bathe the water, and guide the core out of the single system 5.9 product / ml. Ten, 1 plastic water and stone suburbs: 2:3 gas outlet 11, fishing stone report, burn the grain, and the water is 7-ice road
4.1.6 danger and: until the system solution
will be oxidized gas at room temperature 15-2 *. Pass water until saturated. Fu Run preparation. 4.1.7 Bubble and environment chemical Weng heart
shoot to make the gas into the no, public Chemical loading water, until the and is positive. Make the month preparation. 4.1.8 Aqua regia
Write 1 bath of nitric acid to 3 aldehydes in a solution, according to the combination of convenient month preparation, 4.1.9 No need to
Collect T monoalcohol, people 1 heat saturated micro, 1u2, 1 nitro molybdenum pressure and .5 alcohol. Water bath 2 on the second stream, training heat English who, Ben Dachu 0ml family increase wave. Change the collection of mountain liquid bar learning in the trace color only plug the bottle. 1
IIG/T3696.32002
Nuclear gas above the mouth of the core, according to (/TS?33 of the current determination, frequent inspection Kang not 5 people" C.314. 1. 10 Take 23ml of the tablets and add 15.02-1.1 hydrochloric acid and 4% water to reflux, heat and sell, collect the hot liquid in a brown color. Take 5ml of the above-mentioned alcohol without formaldehyde, add 1% water and heat until 2% red. The acid solution emits a red color. 4.2 Preparation No. 4.2.1 Lead acetate cotton. Use OT acetic acid to make cotton. Lead FC: H, the liquid delivery value is not much, surprise, ensure that the line.
4.2.2 Calcium-free oxidation
Mix one volume of the superior grade of North Zhong and solution with one volume of anhydrous ethanol, stir continuously without re-extracting, ten 101-.110 drying F service book,
4.2.3 Sediment - chemical test paper
1)r ". Newly prepared 111. Sediment, add 0.2u chemical Zhong, Put the drop into the liquid and set it aside, then put it in a place to dry for ten minutes. 4.2.4 Stimulation without test 1. Fluidize the powder, dissolve in 1% ethanol, and store it in a place where it can reach the effective rate. 4.3 Reagent concentration 4.3.1 Ethylenediaminetetraacetic acid-ammonium hydroxide solution 1 A mg-0.01 aol/ 2 m sodium tetrazolium chloride solution ETA 0.2 mol/l . Prepare a homogenous mixture of IMC32mA, 1H-HCl (pH 1> and a small amount of indicator. Add 0.2mnL/L of diethyl ether (ELTA) or 0.02mol/L of residual MgCa. The solution is blue in color. 4.3.2 Sieve a microcentrifuge. The concentration of the acetic acid is generally 1:1 mixture of 1:1 acetic acid solution (mass fraction 3C). Collect 295mL of icy acid and 7.1mL of water. 4.3.3 Use an acetaldehyde absorber (2R/min). Take 20mL of acetaldehyde, 1:1 ethanol, and selectivity for acetone (m/s:1.4).3.41 brand concentrated solution
Take 3.41 brand concentrated solution [Ph(CH0U): 3 and 15.0% hydroxyl radical in 0ml water, dilute to 4.3.5% sodium thiosulfate (18/1) sodium dithiocarbamide reagent dissolved in water, dilution rate 1, the shelf life is -4.3.5 g ethylenediaminetetraacetic acid solution, take 0. The base. Thio-nitrogen formaldehyde silver is called m diamine, this liquid is put into a brown bottle, put it in a cool place, and test it together.
4.3.7 ethylbenzene disubstituted 4:7. Base gum-oxymethane is called (with a small amount of ethylbenzene disubstituted 4:7. Base gum-oxymethane is dissolved in 1.B ethyl gum, use three carriers to select 10T, put it overnight, and store it in a color box 1, put it in a place where there is still a reduction in the quality of 4.3.8 diamine dialdehyde (1GR/1.7 nickel dihydrate) when the base is reduced. The dry weight is 0g/1.0g/1.0g. The base is used, and the gaseous liquid is 1001
H/13696.3 ..2002
4.3.94,-*H-].1m-phenanthrene chromium is relatively r[(Ci1,)CH,N-0,wu1mel/L I collected.033%R4,7-long base 1.10 non-7 grid no, dropped in ethanol, with ethanol olefins selected to: 00m.4.3.10 crazy Deng green solution (2g/1.)
transfer garbage 2.20x pore energy not green, Hu di water, release 1GC:ml. 3.11 double trace year burning (or carbon tetrachloride) two liquid ().) R.. East limit 1) double system compensation in two containing methyl system or carbon dioxide "with three amount system (or west carbon chloride grid whole 1m. glass and medium, constant use period is two weeks.||tt| |4.3.12 Add 50% H2O to 0.5% iodine and dilute with water. Add 100% iodine to 14.C iodine and 50% iodine to 200% water. Pour the solution into the sodium hydroxide solution and grind it. Take the upper layer and add 1mL of sodium hydroxide to the blank solution. Add 2 mL of sodium E reagent and stain it with the blank solution. 4.3.14 Red-containing solution. Add 0.25% aluminum reagent and 5 mL of sodium iodine. Add 25% sodium iodine. )mT water. Warm five sales, such as 7.0 ethylammonium, degradation weight, point fraction. % hydrochloric acid 1251 olefins released to 500m, must be full time, so that the knife is divided into months: 4.3.15 to o-effective wood H acid - alcohol fall school, 13 [. Transfer. 10 tea core good ammonia in the middle brand, ten, etc., ethanol with release to 1ml4.3.16 first in the year base model: 8/1.
said 2.3 to towel cool to the film hydroxy melt: try). Reduce to ethanol with 7. Sa rare light car: 00m1.4.3.17 winter when fluorescent rain Hui (6,1g/1) deep take 3.30 base fee and mix) reduce to appropriate temperature ethyl plus this fraction is 22% salt teaching full 1m1: use 2 alcohol Xi cited year 113 ml.,
4.3.1 Hydrogen oxidize-7-hydroxide solution
Weigh 30 ml of ethanol without aldehydes and add to 300 ml. Place in a microcentrifuge for 4 hours. Use overnight. 4.3.19 Hydrogen oxidize alcohol with activity
Add 1 g of hydrogen oxidize alcohol with a fineness of 1. ccm and mix. The reaction is continued for two weeks. 4.3.20 Ammonia solution
System liquid (double or fraction is 2.5%: volume C3L nitrogen water and m water promotion: water rate roll (mass fraction is 1) collect mt. point water in 6L water company 4.3.21 Hydrochloric acid solution
Acid tank (member volume fraction is 5%: gradient 11: m1. Salt film point 695 cement acid wave (mass fraction fire 1) volume section 240m1. Salt night: 77G. Mix and add the mass fraction of the acid to 15 ml. 1m unmixed acid concentration (mass fraction is 20%): Take 501mL salt sugar: 1eml. Water filter. 4.3.22 Prepare 10g as required except 1g less, dilute to 1l with water for use. 4.3.23 Iron mixed with concentrated iron: weigh 1 tt|| iron and add 1 tt|| acid to make the concentration of 20% liquid. Dilute to 1 tt|| 4.3.24 Zinc iodide bath batch: JIG/T 3696.32002
Select liquid 1: Take 2.3 yuan armor flow horse 21mT. Water temperature, inject into 200m1. Add 13.) Chemical penetration: Drop: weigh 2.50 is gold quality lead powder and 0.5 of its, 10m. This. Hold until it turns yellow, add the refrigerant
and inject the cooling liquid 1, 53ml, need to be stored in the color version for one week. The precipitation powder prepared by the above method is zinc dye reduction, 15:1uL water, 1+5% acid drop, very uniform, drop liquid bottom To obtain a white color: add 1 drop of slightly acidic acid (/K10).0.(1/:.1). The color should immediately appear. 4.3.25 Mix the mixture with 100/1.0 volume of hydrogen peroxide and 1.30 volume of anhydrous sodium. 4.3.26 1.1 U-nonacid (2g/ 10):10 nonacid (2g/ 10):10:1 (nonacid (1g/ 10):10:1 (nonacid (1g/ 10):10:1 (nonacid (1g/ 10):10:1 (nonacid (1g/ 10):10:1 (nonacid (1g/ 10):10:1 (nonacid (1g/ 10):10:1 (nonacid (1g/ 10):10:1 (nonacid (1g/ 10):10:1 (nonacid (1g/ 10):10:1 (nonacid (1g/ 10):10:1 (nonacid (1g/ 10):10:1 (nonacid (1g/ 10):10 , H) or 1,1-dichlorobenzene salt. H·HCl·H(). Soak in a gel-acetic acid buffer solution, use F-sodium acetate to dilute the solution to 100mL.
4.3.27 Synthesis of sodium hydroxide solution 1 Weigh 1 hexadecyl trimethylol radical and dilute it to 100mL in water. Solution T: Add 9.04g of 5.1% ethanol to the solution and dilute to 100mL. Take 10mL of the solution and 50mL of ethanol to make 100mL of solution. 4.3.23 Copper acid solution (10VR/1.)
Weigh 100.0g of monoxide, add 35% sulfuric acid solution to make it dilute to 1% by weight, and add 20ml of cold water to make it dilute to 1%, and add 4.3.30 Weigh 50ml of 4/1 ClH2O (4:4): place in a dry place and heat at 10℃ for 2 weeks. Prepare a solution of tantalum hydride (2 ml): add 2.0% tantalum hydride (C·21I·), place in olefin combustion, dissolve with a small amount of salt (heat if necessary) and dilute to 1:1: use a precipitate with a relatively high content of tantalum hydride (/[): weigh 3.30% tantalum hydride (mtl, 2H)), place in a dry beaker and add 100mL of the mixture (heat if necessary). The use period is one week, tin chloride-ascorbic acid wave: weigh 0.5V each tin oxide ntl2E.0) and dry ten coal as the standard medium flow to 8mT. Salt silk to 5m, m (, 7g ascorbic acid carrier. When out of use: the oxide liquid (432/pulse) collected 13.0g tin oxide (3rC, ·210. Place in a vortex beaker and release to 100m in 4ml hydrochloric acid. The use period is one week
4.3.31 Three sieve liquids (10m&/T.) weigh 0.0g-chloride (FeL1.iE0), dissolved in 1+ HCl solution, with 1+ HCl glassware 30m...4.3.32 Acid dye
Make sure the acid solution mass fraction is 13:, take 151. and 863m water, carbonate solution (mass fraction is 2)): see Table 24UT Acid and 780m. Water Lu sentence. (fraction): 1 nitric acid 7 water energy
4.3.33 Eye mask solution (17R/1.) ||tt| |Weigh 1.70% ion, add water, need 1.3 ml) of ethylene. This is stored in a brown preparation bottle, protected from light, 49
4.3.34 System correction liquid
EIC/13696.3—2002
Material: 100 ml of hydrogen water without divalent catalyst: pass hydrogen gas until the liquid turns into white. 4.3.35 Acid drop
Acid solution (mass ratio is .%> Take 2.1% acid and put it in 978 ml of water according to the test, Cool, mix. The system should have a decomposed liquid (volume fraction is 5%), take 23% sulfuric acid, add it into 6ml water, cool, and mix well. Sulfuric acid solution (volume fraction is 2%): take 28ml of acid, add it into 869ml water, cool, and mix well. Take 2g of acid (volume fraction is 2%), slowly add it into 7ml water, cool, and mix well. 3.36% acid reduction (2) 2/[.
Weigh 2g of copper sulfate (CmS), ·5IT), add it to water, add two sulfur brands, and sieve it to 100ml.4.3.37 Iron sulfate (50 g/L)
F.3R dissolve Fe in water or add 11 ml. Total solution, dilute to 1 ml 4.3.3 Iron sulfate (10)/L) 1 ml. Ferrous sulfate (VTI::Teg pin single pack Letc.: In 0mT. water and 3ml, propylene glycol mixed condensation ten through, method:: take sodium hydride: only 30I. water and SCm ten oil in the mixture of lead solution will be half of the flow through the hydrogen saturated body to make it, then the result will be the car mud under the rate of light into the car in the color: after preparation within a month, 4.3.55 horse into liquid: 5 +/-1.1
weigh ig horse money city, ice acetic acid cavity cattle, ice (waist potassium single 14.4 line flushing liquid
4.4.1 ethyl acetic acid grade wave H3
weigh sodium sulfate CN + 3 flow in 5 ice acid flow to 14.4.22 acid-acetic acid bag! H=4
weigh. +II.O flow in x ice acid to
4.4.3 ethyl-acetic acid pseudo 4.4.7.7.4 h. 4h. Weigh 1.5g acetic acid (CN-1. Dissolve in 1L glacial Z acid, 130ml. 4.4.5 Acetic acid-sodium acetate buffer (nTT=> Weigh 10g acetic acid (Na·3H> 5.m glacial acetic acid, dilute to 1.4.4.6 Acid buffer solution (1~5)
Weigh 5.5g acetic acid, dilute to 28.6ml water, dilute to 0.01L 4.4.7 Acetic acid-ethyl acetate buffer solution (pH~6.5) Weigh 1.87g water, dilute to 2M. 4.4.8 Chemical I[
EG/T 3696.3—2002
You take. Add 35UL water to 100ml..4.4.9 Natural sensitization shock (T210)
Weigh 2G.7R ammonium oxide, add 36nI nitrogen water to reduce to: 000ml.4.4.10 Carbonic acid-sodium citrate strong shock dissolvem[. Make the H value =.~-5., cool down the temperature in 00ml., and adjust the solution rate scale
4.5 Tips and indicators
4.5.1 Middle age indicator solution (/1.1
Weigh 0.20g of a portion, add water, dilute to 30ml. The use period is 11 days. 4.5.2-Recovery acid solution (5R/1) Weigh the product sodium sulfonate, float in water, and dilute to 100ml..4.5.3 Related phenylcarbazide indicator solution (0.25k/1,) Weigh 0.2: phenyl ethanol, add acetaldehyde to 100mT..4. 5. 44-(2-pyridine) effective index (1 g/1.) Weigh 0.1℃ 1 (2-chloro-2-nitropropene)-1,2-dichlorobenzene (PAR) in ethanol, add 30ml of ethanol, and mix with 1C.4.5.6 red indicator, weigh 0.1g/ml, and add 1g/ml of red indicator. The blue ethanol solution is mixed with the 1/10% red ethyl solution. 4.5.8 Toluene indicator solution (12/1.)
Weigh 0.10% orange and dissolve in 70% sodium chloride to 10 ml 4.5.9 Toluene indicator solution (n.5 g/1.)
Weigh 0.1% purple in water and dissolve to 10 ml 4.5.10× red ethyl solution (1 g/1.)
Weigh more than 10% red ethyl solution and crush in ethyl 4.5.11 Weigh the most aromatic alcohol and dilute it with ethanol to 1g/1.4.5.12 Weigh 1g aromatic alcohol and dilute it with ethanol to 7g/1.4.5.13 Weigh 0.4GP with ethanol as an indicator and dilute it with ethanol to 1g/1.4.5.14 1.5.15 chlorinated trichloride indicator (1/4) || tt || weigh 3.3 g chlorinated trichloride, add 12 ml of sodium chloride and a small amount of water to dissolve, and dilute to 0.00 ml. 4.5.16 active 2.4 dibasic indicator solution || tt || 2,-tribasic trichloride solution saturated with water
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