Directives for the work of reference materials (5) Technologic rules for reference materials of chemical composition
Some standard content:
URC CCG.3
National Standard of the People's Republic of China
CB/T 15000. 1---15000. 5--94 Directives for the work of reference materials
Promulgated on March 11, 1994
State Technical Supervision Bureau
Implementation on April 1, 1994
National Standard of the People's Republic of China
Directives for the work of reference materials (5)
Technical rules for reference materials of chemical composition
Directives for the work of reference materials (5)Technical rules for referehce materials pf chemical rompositian1Subject content and applicable scope
tH/T15000.5-94
This standard specifies the technical requirements for the preparation, evaluation and packaging of chemical composition standard samples of body, relative humidity and gas. This standard is applicable to the analysis of the chemical composition of solid, liquid and gaseous standard samples. 2 Referenced standards GB/T8171 Rules for rounding off values GB/T5274 Preparation of mixed gases for calibration of gas analysis GB/T5275 Preparation of mixed gases for calibration of gas analysis GB/T10245 Preparation of mixed gases for calibration of gas analysis Static emulsion method GB/T15003.2 Working guide for standard samples (2) Definition of common terms for standard samples GB/T15001.3 Working guide for standard samples (3) General rules and statistical methods for determining the value of standard samples GR/T15000.4 Working guide for standard samples (4) Provisions on the contents of the certificate for standard samples Part I Technical general introduction to standard samples for chemical composition of solids 3 Preparation 3.1 Selection of materials 3.1.1 The quality and properties of the standard samples should meet the expected requirements of the standard samples. For example, geological standard samples should be representative, and the materials used in the standard samples should not contain pores, cracks, and light defects.
3.1.2 When preparing standard samples for the basic products, the content of the main components should comply with the technical specifications of the product, and the impurity content should be higher than 30% of the upper limit.
3.1.3 The series of standard samples should reasonably arrange the gradient change of the performance coefficient values, so that the core standard samples can cover more product types. If necessary, the matrix or residual composition of each standard product should be as close as possible. 3.1.4 The selected materials must have enough quantity to ensure that they can meet the needs of use. 3.2 Material preparation 3.2.1 The process and preparation technology of the finished product should ensure the homogeneity of the finished product: avoid contamination of the container and the environment to the finished product, prevent direct contact with the particles, and pay attention to the loss of volatile components. State Technical Supervision Bureau 1994-D3-11 approved 1994-04-01 implementation CB/T15000.5--54 3.2.2 Process materials, especially those that are easy to be averaged, should be processed and averaged before processing, and the finished product should be recorded. In addition, the finished product should be physically inspected to ensure that there is no deficiency in the standard sample. 3.2.3 The sample composition and processing technology of the standard instrument such as photoelectric spectroscopy, photoelectric reading, X-ray fluorescence spectroscopy should be described. If other process conditions are also applied, experimental data should be attached. 3.2.4 Application characteristics of standard products: The properties of the selected materials should be selected. The material preparation should be in a suitable form, such as powder, crumbs, etc.
3.3 Separation of sodium materials
3.3.1 For the material used to prepare the standard product, several representative sampling points should be determined at its easily segregated parts, and samples should be selected for segregation test.
3.3.2 Add 1 powdered tablet of the standard sample to the material and divide it into four parts to make a suitable weight (for example, about 3.5 kg). 3.3.3 Segregation test 4.1 All samples must be subjected to uniformity test after preparation or after product preparation. 4.2 The purpose of the uniformity test is to determine whether the product is uniform or not. The method used for the uniformity test should be a method with high precision and should be at least equivalent to the specified method.
4.3 Representative and easy-to-analyze instruments should be selected for uniformity test. For standard products, the uniformity test should be carried out on all parts of the product and the method and quantity should be specified. 4.4 Randomly select a number of inspected products to reflect the overall characteristics of the samples. Under the condition that the conclusion is credible, a number of samples can be reduced, but not less than 15 (sets). When the total number of units is less than 1000, 1520 (sets) shall be selected; when it is greater than or equal to 10H, the number of samples selected shall be 2×10 (N is the total number of units).
Note: For samples with uneven quality (such as fast-moving products), increase the number of samples according to the actual situation, and conduct risk inspections one by one if necessary. 4.5 After the number of samples is confirmed, randomly select the samples to be inspected (see Appendix A or Appendix B): 4.E Use the following test method or the range test method for statistical inspection (see Appendix B for the critical value table of the F test method and Appendix C for the range test value table)
4.7 The series of standard samples should be inspected, and the standard products of the instrument should be randomly selected according to the variation of the standard samples. Take 5-10 sets at random, use the best analysis conditions, and draw the working curve. The effective point should fall on the working curve or close to the working curve. If there are individual points that are far from the working curve, the reason should be explained.
5 Value determination
-5..1 Only samples that have passed the uniformity test can be valued. Value determination can be carried out in one of the following ways. 5.1.1 Absolute measurement method,
5.1.2 Two or more accurate and reliable methods with the same principle are used to obtain collaborative values. These methods have been carefully studied and have a high degree of reliability.
5.1.3 More than 100 experimental results are collaboratively determined using accurate and reliable measurement methods with different principles. 5.1.3.1 The collaborative inspection room must be recognized by the state or department. If necessary, the inspection room must also be quality controlled and clear guidelines must be formulated.
5.1.3.2 The minimum number of independent measurement results obtained by the collaborative laboratory for several days or according to the specified method is generally not less than 8 groups, and each group reports independent data.
52 Processing of fixed value data
5.2.1 The fixed measurement data are processed according to the laboratory and the measurement method. After technically eliminating the suspicious values of the pulse cause, the Grubbs test method (see Appendix D for the critical value table) or the Jackson test method (see Appendix E for the critical value table) are used to statistically eliminate the suspicious values. If necessary, the original laboratory may be required to recheck the values. When the data are relatively sensitive or the range of possible values is large, the inspection should include the measurement method used by each laboratory, the measurement conditions and the operation process. When the source is confirmed, 5.2.2 All data shall be tested for normality. Under the condition that they obey the normal distribution or are approximately normal distribution, the mean value of the data obtained by each test and each flow determination method shall be regarded as a single measurement value to form a new set of measurement data. Calculate the mean value and standard deviation. 5.2.3 When determining that the accuracy and precision of the measurement data of one or more laboratories are comparable to those of several other laboratories, the unequal distribution method may also be adopted, using the weighted mean value and the corresponding standard deviation as the standard value and standard deviation. 5.3 Representation of measurement results
5.3.1 Rounding off of numerical values It shall be carried out in accordance with the provisions of GH/T8170 standard. The measured deviation shall be approximated according to the lower limit, and its digits shall be aligned with the digits of the standard value. 1 to 2 valid mathematical values shall be retained. 5.3.2 The result of the fixed value shall be expressed as standard value and uncertainty. 6 Stability test
6.1 The marked product shall be regularly tested for stability under the specified conditions. When there are multiple performance indicators, the performance parameters with variable characteristics can be selected for inspection and adjustment:
6.2 Qualitative test can be carried out according to the determination method of fixed value. 6.3 When the deviation of the measured results in different time intervals and the standard value does not tend When the precision of the test method is passed, the stability of the standard sample is considered to meet the requirements.
6.4 Standard products should have a clear validity period. ? Packaging
7.1 Standard products should have a specified qualified packaging format to facilitate transportation and long-term storage. 7.2 Each packaging unit should have a standard product label and a standard sample certificate. 7.3 For products that require special storage conditions to ensure stability, indicate and use the standard seal.
Technical Specifications for Standard Samples of Liquid Chemical Components B Preparation
8.1. Material Preparation
B.1.1. The materials for preparing standard samples can be directly collected from representative natural materials. After processing, their properties should meet the expected requirements of standard samples.
Pure substances with standards or criteria should be selected and prepared according to the specified characteristics and technical conditions. The standard samples should have representativeness and compatibility, and their properties and compatibility should also meet the expected requirements of standard samples. 8.1.2 The selected material group (or sample system) should meet the technical requirements specified in the reference standard and standard analysis method. 8.1.3 The basic composition property values of the selected material group should be representative and comparable. The number of standard samples cut should be sufficient to ensure that the actual needs are met.
8.2 Material processing
8.2.1 For the natural materials collected, the appropriate processing technology and appropriate storage conditions should be selected according to the properties of the selected materials to maintain the homogeneity and stability of the standard samples. When using the reference or standard pure substances as materials, the appropriate processing technology and appropriate storage conditions should also be selected according to the properties of the materials and the basic composition and performance value of the prepared standard samples to maintain the expected homogeneity and stability of the standard samples.
B.2.2 No foreign matter should be mixed into the material during the material processing. 8.2.3 For the particles that are difficult to be homogeneous, the homogeneity should be initially checked during the processing. 8.2.4 After the material is processed, it should be divided into the smallest packaging. 21
9 Homogeneity test
GB/T15000.5-94
9.1 For the samples that have been prepared and initially homogenized, after being divided into small packaging units, the F test method (for the table of threshold values, see Appendix B) and the T test method (see Appendix F>) shall be used for homogeneity test. 9.2 The unit efficiency of the product and the number of repeated measurements of each sample shall meet the requirements of statistical test. When the number of samples is 15~25 or more than 1000 packaging units, the number of samples shall not be less than 31. After the number of samples is determined, the samples shall be randomly selected.
9.3 The components with representativeness and difficulty in uniformity shall be selected for uniformity test. The minimum number of repeated measurements for each sample shall be not less than 13 times. 9. 4. The quality test should be carried out by a high-precision determination method: The determination of the same performance value should be carried out by the same operator and the test equipment and instrument status should be checked to ensure consistency. 10 Determination of value
10.1 Determination method The sample that is used for the quality test can be determined in the following ways. 10.1.1 Absolute measurement method
10.1.2 Accurate and reliable methods based on two or more different principles. 10.1.3 Collaborative determination by multiple laboratories using accurate and reliable methods. 10.1.3.1 The collaborative laboratory selected by the product development unit must have a high level of testing. When necessary, it shall conduct a joint control of the operating laboratory and formulate clear guidelines. 10.1.3.2 The minimum number of independent test results reported by the participating laboratories on a daily basis or according to the test method shall generally not be less than 8 Groups, each group reports no less than 6 drug data, 10.2 Processing of fixed value data
10.2.1 For each laboratory or each test method, 6 independent data are batched out. After technically eliminating the suspicious values with clear reasons, use the Glass test method (Glass critical value table Appendix D) or the Johnson test method (Glass test method critical value table Appendix E) to statistically eliminate the suspicious values. If necessary, it is required to conduct a test on the suspicious values. When the data are relatively complete or there are many suspicious values, the test methods, measurement conditions and operating procedures used in each laboratory should be carefully checked. 102.2 All data should be tested for normality of distribution. If the results are abnormal, it can be judged by observing the histogram or using the GB4882 normality test method, or collecting relevant test experience to determine whether it is abnormal. Normal distribution. If the data are relatively scattered and the distribution is multi-peaked, the laboratory should carefully check the laboratory's determination conditions, measurement conditions and operation process. Find out the reasons and make improvements, and then re-measure. 10.2.3 Under the condition that the data obeys normal distribution or approximate normal distribution, the average value of each test data of each test method of each experiment is defined as a single determination value, forming a new set of data, and calculating its mean value and standard deviation. 10.2.4 When the stability is poor and there are many test batches, the median value and the uncertainty of the median value can also be used as the standard value and uncertainty. 10.3 Presentation of determination results 10.3.1 The numerical value is determined in accordance with the provisions of GB/8171; the standard deviation is determined by the standard deviation, and its digits are aligned with the standard elimination number: generally 1 to 2 significant figures are guaranteed. 10.3.2 The determination results are presented as standard values and uncertainties. 11.1 The stability test of the standard sample should be carried out regularly under the specified storage conditions. When the standard sample has multiple performance values, the variable and representative performance values can be selected for testing. 11.2 The stability test method can be carried out according to the fixed value determination method. 22
GB/T 15000.5—94
11.3 When the accuracy of the results of the determination does not exceed the precision of the test method, the sample is considered to be accurate within the test time. The standard sample is effective. 12 Packaging, storage and transportation
12.1 The non-standard product should be placed in a container with different properties: the standard sample with corrosion resistance should be packed in a strict packaging,
12.2 The packaging container should have the standard sample mark, etc., and the standard sample certificate should be provided. 12.3 For the convenience of use, standard samples can be packaged in different units according to different varieties and requirements: 12.4 The marked samples should meet the requirements of the products and storage methods. For the storage, analysis and transportation with special requirements, clear regulations should be made. Part III
Technical Specifications for Standard Samples of Gas Chemical Composition 13 Names of Standard Samples of Gas Chemical Composition
The names of standard samples of gas chemical composition should be in the following format. 8. The name format of the specified component is "*×× Standard Sample of Gas Chemical Composition", such as: "Gas Chemical Composition Standard Sample of Carbon Dioxide".
1. The name format indicating the purpose is "gas chemical composition standard sample for ××", for example, "gas chemical composition standard sample for carbon dioxide analyzer",
; the name format indicating the preparation method is "×> gas chemical composition standard sample, for example: "high temperature hydrogen peroxide gas chemical composition standard sample",
14 Expression of component quantity
14.1 The component quantity of the gas chemical composition standard sample is generally expressed in degrees. The concentration unit should preferably be one of the following three: molar ratio, liquid concentration, ×× million (mal/mol>, ×× mole/mal, mass concentration, ××% (m/m), ××g/g
volume of liquid 14.2 The amount of the components of the standard sample is expressed in terms of permeability, and the unit is min. 14.3 The concentration of the gas chemical composition standard product is called the gas chemical composition standard sample with a concentration of 1% (V/V); it is called the trace gas chemical composition standard sample when it is below 0.1% (V/V). 15 Technical requirements
The technical requirements for gas chemical composition standard samples should include the following contents. Standard value (or range)
Uncertainty
Specified period;
High filling pressure (for commercial pressure standard samples): Minimum usable pressure (for high pressure standard samples) ): Use temperature (do not penetrate into the standard sample). 16.1 Raw materials 4 16.1.1 The raw gas used to prepare the standard sample of gas chemical composition must have a quality certificate or analysis report. 23 16.1.2 When preparing the standard sample of gas chemical composition, the raw gas must have a quality certificate or analysis report. 23 16.1.3 When preparing the standard sample of gas chemical composition by weight method, the analysis of various impurities in the raw gas must meet the requirements of the determination, and the analysis report with high accuracy should be used. Method. 16.2 Containers
162.1 The containers for gas chemical composition standard samples can be made of aluminum, steel, and other materials. The latter two are made of aluminum, and the chemical composition standard products of micro-organisms or chemically active micro-organisms must be contained in aluminum bottles. 16.2.2 Steel bottles, alloy bottles, glass bottles, and calcium bottles: they must be inspected in accordance with relevant regulations! Appearance inspection. 16.2.3 The outer surface of the high-pressure container should have a mark showing different types of gases. Different gases and high-pressure containers are not allowed to be mixed. 16.2.4 The high-pressure container should be heated and air-conditioned before use. The residual moisture in the container of the gas chemical composition standard product should be less than 1rL/1..5.16.3 Preparation of gas chemical composition standard samples 16.3.1 Gas chemical composition standard samples are prepared individually. 16.3.2 When using the cupping method, the method should be carried out in accordance with GB/5274. The weighing method is currently the most accurate method, and its uncertainty in the value can reach 0.1% to 1%. Therefore, the most accurate method should be selected first to prepare gas chemical composition standard samples. 16.3.3 When using the permeation method, GB3/T527: should be followed. 16.3.4 When using the state volume method, GB/T10245 should be followed. 16.3.5 When using the pressure method, flow method, and method, etc., the relevant specifications should be consulted. 17 Homogenization treatment After preparation, the container containing the gas chemical filtration standard sample must be subjected to a frequency of more than 30mil (or rotation) treatment. 18 Determination
18.1 The determination of gas chemical composition standard samples is generally completed by one laboratory. When the determination is jointly carried out by several laboratories, the numerical processing shall be carried out in accordance with GB/15000,3.
18.2 The gas chemical composition standard samples prepared by the weighing method shall be preferably used as the basis for the determination of gas chemical composition standard samples prepared by other methods.
183 The determination of difficult samples shall be carried out by gas analysis of equivalent quality. 18.4 When determining the value, the uncertainty of various factors affecting the accuracy of the determination shall be calculated one by one and all shall meet the technical requirements. 19 Comparative analysis
19.1 After the determination of the gas chemical composition standard samples, one or more methods shall be used to make comparative analysis. The data obtained by the comparative method shall not be less than four.
19.2 When the uncertainty of the comparative analysis method is significantly better than the uncertainty of the fixed value, the comparative error limit is equal to the uncertainty of the fixed value. When the uncertainty of the inverse analysis method is equivalent to or slightly different from the uncertainty of the fixed value, the comparative error limit should be equal to the sum of the two. If multiple methods are used for comparative analysis, the uncertainty of different methods should be obtained and the comparative difference should be calculated separately. 19.3 When the difference between the comparative analysis value and the standard value is within the range of the comparative error tree, the test fixed value result is valid and the value should be re-determined. 20 Accuracy report
Each gas chemical component standard sample should provide more than 11 fixed value data. When the nominal value of the gas chemical component standard sample reported is a base, there should be at least two standards in the accuracy report that are respectively at the upper and lower limits of the range. 24
GI/T150D0.5:94
The gas chemical composition standard sample in the production report must be prepared by a certain method, but the original gas used may not be the same as the original gas used. The operator may also be a different person in the laboratory. 21 Stability test
21.1 Time stability test
When the gas chemical composition standard sample is developed or the process is changed, it must be tested and adjusted to determine the overall quality of its chemical composition. 21.1.1 Test method
Use the same method to analyze the chemical composition standard sample of the same unit regularly. The analysis method should have good reproducibility. The analysis time should be greater than 1/5 of the predetermined validity period. 21.1.2 Result judgment
The standard value is taken as the standard. When the difference between the analysis value and the standard value each time is not greater than the current uncertainty, the predetermined validity period is considered to be correct.
If the phenomenon of overpressure occurs, find out the reason. When it is confirmed that the error is not accidental, the predetermined validity period should be shortened. 21.2 Stability
When the standard sample of high-pressure gas chemical composition is developed or the process is changed, it must be subjected to a decompression test to determine the influence of pressure change on chemical composition.
21.2.1 Test method
Use the same supply: a standard sample of gas chemical composition, and analyze it under different pressures. The analysis method should have good reproducibility:
The change of pressure of the standard sample of gas chemical composition should be 1/10~1/5 of the difference between the given maximum filling pressure and the predetermined minimum usable pressure.
21.2.2 Result judgment
If the difference between the standard value and the standard value each time is not greater than the specified tolerance, it is considered that the predetermined amount is correct.
If the deviation is caused by pressure drop, the minimum available pressure should be increased. 21.3 The amount of the gas chemical composition standard sample put into the stability test should be no less than 2/3 of the prepared amount. 21.4 The above two tests can be combined. 22 Packaging, transportation and storage
22.1 The packaging container of the gas chemical composition standard sample should be labeled and certified. 22.2 The transportation of gas cylinders is recommended to comply with relevant regulations. 22.3 Gas chemical composition standard samples should be stored in an environment with an ambient temperature of 5-40°C, a relative humidity not exceeding 85°C, no sunlight, good ventilation, and a certain degree of safety protection. 25
33 4745 7 B6
5774256763
Jh 76 E2 27 h
12E6859926
55 +9 5h 35 64
16 2 77 94 39
84 2 17 53 1
53 63 78 55
33 21 12 34 8
57 0 8332 14
18 18 07 92 45 | | tt | 50472
1 92 32 43
68 34 3hearts 13 7:5
75 57256576
27 42878658
039652961
20 04 98 04 24
16 90 92 56 9
11 2775 6
35 24 10 16 20
3X 23J |tt||20 40 78 73 90
61 19 58 67 79
36 56 47 3C 61
42 21 14 57 20
06 15 6 71 07
5 8 6 X2
49 54 43 54 K3 | |tt | 97 61
93 39 08 33
40 33 30 28 26
95 B3 5C 67 75
3321424
5U 27 25 97 69 60
48 55 9G 85 72
60 7 3223 30
68 55 69 15 82
63 52 64 11 12
06 6 19 7 66
3330526 3 3 | | tt | | 42 38 57 G150 | 2G
GB/7 15000.5 -94
Appendix A
Random number table
46 $8 63 T1 62
42 53 32 37 32
32 9U 79 TX A3
0S3 15
31 63 43 40
17 3:05 23 78
77 62 74 47 67
9810507175
E2 42 Dr 44 36
49 17 46 09 62
7983861962
11 4624
07 45 32 14 0B
5 55 76 31 38
42 34 37 96 89
1381037
97 =2 25 93 47| |tt||1661 3616 63
45 59 34 66 49
20 15 37 U0 49
44 3 78 K 25
71 91386751
5657593610
77 84 57 (3 29
53 TE 91 53 3)
615 00 71 4
02 04 87 0:
79 76 45 C+91
RF 7 F6 1 41||tt| |34 G 62 5J 91
11 05 65 09 68
52 2? 1 14 R6
075629355
M02331
33 26 .6 96 15
27 01 36 7 5.
13 55 5 59
# 12101421
R 13 +4 37 53
$7 33 26 16 43
2: 79 33 56 25
12 75 807
1551:132| |tt||SD52817T27
CG 75 5C 03 10
2D =4 35 XK 43
32 98 94 07 72
822025353
54426798
17 7E 37 13 04
70 33 24 03 54
C 4s 18 66 73||tt| |1$ 72 07 24 45
S? RE 66 D 44
0433CA52
13 5E 18 24 76
9666224245
lu1565c126||tt| |342520 5727
60 47 21 29 G6
T67CD B8
16 92 53 55 16
n; 7 91 62
0052 43 48 B5
76832337C
2298122208
59 33 82 13 W
39 E416 45 36
16 78 78 69 52
24 51 79 89 73
88 97 54 14 16
E5 26 45 8_ 75
23 83 1 sn 25
E: 25 34 9: 6:
3 92 12 06 75
41 39 52 38 79
9: 66 02 79 54
502734323
55 23 6+ 05 05
1932B71
9385751075
866042 053
3a B: 29 45 3Y
U7 71 2: 1 3U
97 7 464 R0
94 7 34 21 90
99 27 72 95 14
38 F: XX 11
88 07 07 09 57
16 54 55 85 52
976091
1 U4 66 67 24
40 4873 51 92||tt ||0202170331
38455-303F
02755D939E
51 808 32
27 55 25 89 2
57[G[ 66
07 52 74 9 80
4978 4
4795931330
02 741783
n526937960
0F710 B 23
63 71 86 85 85
6: 53
14 65 52 B 75
J 2F 59 1 14
41 2352 55 93
69 20 5G 51 69
268590
31 7 7
85 22 4 39 43||tt| |4 T9 1 7T 48
6B T5 8C 16 1-
83 74 22 99 μ7
6338068655
35305E2146
63 43 3E 82 69
$B 25 37 55 26
02 63 21 17 69
64 5 221 62
85 67 26 13 89
58 54 16 24 15
34 85' 27 84 67
03 93 =8 27 46
62 53 3n 27 59
08 45 93 15 22
078551840
0J 65 39 95 66
724711435
76291684
45 17 75 65 57
9676251254
50 44 ±6 44 21
2266821586
96 24 4D 14 51
78 60 73 99 B4
22 85 81:13
09 5B 42 95 64
54 87 65 47 4
59 37 7a B0 7C
8759352341
71 4! 61 50 72
23 1:2 23 33 12
71 04 49 69 83
31 99 74 3 58
245623 41 6
7360175
73 82 67 22 1|| tt||22 95 75 42 45
00 06
51X22K69K4
9500652694
D672171094
G5 J1 1B 37 BE
91 62 81 4RbZxz.net
71809956
18 22 28 G6 00
01 1C 07E2 04
51 41 $2 0t
61 48 64 56 25
57 95 16 $6 56
377547664
6021754591
45 44 75 14 90
511019488
19584925
185253ed53
2840621
22 01 11 94 25
BR 05 5K 05 2
2663754199
33 22 D 88 57
6020729348
4389945645
CB/T 15000:5
2 63 51 59 77
61 71 62 99 15
73 $2 0X 11 12
4215505742
26.7%63 0W5
1241 20
9663021689|| tt||1047484588
5 3 6
45 37 59 23 09
0977 9315 82
3362455828
05 03 27 24 83
35 32 82 23 49.
5 85 98 38 36||tt ||94626/8621
32 82 90 23 07
25 3 1 75 96
61 38 4 13 45
74 77 12 94 7
35 15 75 :1 49
G154134391
5063898558
615015
9018481326
30 93 72 85 22
86 97 $0 61 41
98 77 27 85 42
24 94 15 61 D2
15 4 97 19 76
5011171776
75 4559 35 96
25 12 74 75 67
71 96 16 16 83
1882366602
68 15 4 35 03
55 42 36 72 24
5 89 47 07 41
59 56 78 06 83||tt ||06 51 29 16 53
49 63 16
221758574
13 8 22 01 59
4495759
016218 36 07
1341438930
24 30 124860
90 35 57 29 12
74 94 80 04 04
D 3) 54 42 81
72 99 44 05 60
2487087
94,37 30 69 38
79 62 67 86 60
49 28 24 (K 49
3 92 6588 65
24 Heart 2 T1 7 07
8278±22329| |tt||38B6E97
3770154857
84 6d 38 56 98
8 3 DI 3
28 $B 61 08 84
4 t:b 8 15
1276334378
8631572018
7389 657031
G0 40 60 311S
63 54 36 74 45
69 36 6 25 39
12 35 48 9 32
5887521851
659539 6958||tt| |90 2 9 0712
52 91 05 7D 74
55 05 77 09 51
29 56 24 29 18
0 4d 07 16 94
15 2939$9 43
D29674 O 83
2599327023||tt ||57 17 14 49 17
IB9910723
82 62 54 65 69
45 07 31 66 49
5 94 1 8K 47
75 80 JS948J
1804616787
SO 89 0C 76 33
47 553 33 9
75 91 12 81 10
BI 667678C?
4 34 B1 85 35
03 53 16 66 75|| tt||DD 83 26 9: C
06 6624 12 27
13 29 54 1923
85 72 13 49 21
65 65 B 39 c7||tt ||99 01 30 93 64
45 96 06 64 27
69 62 03 42 73
73 43 37: 61
64 63 91 03 25
95 63 73 46 75
9 17 6
24 6201 61 62|| tt||1000382
4803451512
14 52 41 52 43
033783911
18163678.86
56 80 301544
78 $5 4 72
B4 37 90 61 56
#6 62 1U 36 23
07 28 59 07 46| |tt||10 15 83 |37 71 67 96 13
3 613 83 27
132 95 DX 45 65
49 83 43 48 35
54 60 71 82 46
117301
79 6910 51 78
75 93 36 57 83||tt| | 0 92 26 U3
51 29 50 10 34
311 4
29 0123 87 88
25 33 9 28 0
9 84 60 79 86
1610 629882
20 31 29 03 43
71 59 73 UI: 5C
791023 035
89 64 58 69 75
79 24 166
03 73 52 16 56
35 21 20 71 34| |tt||33 92 74 65 94
80 53 54 7 27
20) 03 44 95 4
93 79 64 6472
82 B8 33 69 95| |tt||4 0 8: 30 27
44 9114 66 47
7132765562
5520148211
28 1 9
3157159580
37 79 81 b3 74
58 02 39 37 67||tt ||1B 74 72 00 1B
24 35 59 87 8
5497205655
2B 45 82 58 72
OB 22 23 71 T7
GR/ T 15000.5-94
F513 car 78
$9 29 76 39 81
83 85 52 27 99
21 48 94 06 $3
60 55 55 00 27
62 33 74 62 14
40 14 71 4 53
95 94 78 32 65
64 B5 4 135 72
29 54 96 5384
93 075472 59
7236041975
3 39 3 05 33
89 23 3 63 15
#7 0 22 5X 40
7 21 90 5
2 25 6 84 63
5107927477
73 21 16 10 33
42 10 14 20 $2||tt| |38 79 56 69 32
K2 07 5$ 89 35
1574B00832
8 14 8 99 70
91 r:1 93 20 49
75 4k 45 4 6u
33 J4 91 5# 93
3014 78 56 27
91 96 94 65 49
3352293987
53 73 19 S
50 95 52 74 33
01 32 90 76 34||tt| |43 14 52 5 94
2145570977
4745151860
25 15 35 71 30
55 34 2447 89
92 b4 01 f6 2||tt ||9R 43 8 63 5
61 29 08 93 67
?615 4849 44
52 83 9c 94 76
16 55 23 42 45
B1 76 9 26 92
5535237918||tt| |16 45 70 50 83
KD 60 4718 7
82 95 55 26 5
63 14 2 32 52
86 53 E9 X 22
01 4759 38 D
565439 55
1 9817
133C55 6254
589 6041
56 (7 93 39 30
:9 48 56 27 44
11 0R 597
88125T21T7
99 B2 93 2 93
74 54 13 26 91
04 32 92 08 09
1 55 63 77 09
70 47 14 54 36
54 96 09 11 06
82 B0 84 25 39
05 98 90 07 35
6772164279
49 1 30
66 39 67 98 69
292 919- 0
94 7 5
29- 0 -2 1
UR'ZLR'Z
1 FT2
Bys y' ly
S~9 2F*9 20\9 21*9 +h\| |tt||5 F8* 0P-5 EF'0 2F'6 15'6 C5'6 19'6 99'6 22*6 69*6 1'01 8'01 E GTt
1n' ' !a s' 'g'
2892197152482 33
2 292 8'92 N'02 6-08 1-68 7-28 8'48 9 23092
565 *66 966 366 5-66
9-66 563 565
9*66 #*6 1*66 P66 +*66 p*66 +*6 +'6*6
229129.6192191919
(100=)
contained* 99 -5 2
8 5 5
*9 88 95C
791023 035
89 64 58 69 75
79 24 166
03 73 52 16 56
35 21 20 71 34||tt| |33 92 74 65 94
80 53 54 7 27
20) 03 44 95 4
93 79 64 6472
82 B8 33 69 95||tt| |4 0 8: 30 27
44 9114 66 47
7132765562
5520148211
28 1 9
3157159580
37 79 81 b3 74
58 02 39 37 67||tt ||1B 74 72 00 1B
24 35 59 87 8
5497205655
2B 45 82 58 72
OB 22 23 71 T7
GR/ T 15000.5-94
F513 car 78
$9 29 76 39 81
83 85 52 27 99
21 48 94 06 $3
60 55 55 00 27
62 33 74 62 14
40 14 71 4 53
95 94 78 32 65
64 B5 4 135 72
29 54 96 5384
93 075472 59
7236041975
3 39 3 05 33
89 23 3 63 15
#7 0 22 5X 40
7 21 90 5
2 25 6 84 63
5107927477
73 21 16 10 33
42 10 14 20 $2||tt| |38 79 56 69 32
K2 07 5$ 89 35
1574B00832
8 14 8 99 70
91 r:1 93 20 49
75 4k 45 4 6u
33 J4 91 5# 93
3014 78 56 27
91 96 94 65 49
3352293987
53 73 19 S
50 95 52 74 33
01 32 90 76 34||tt| |43 14 52 5 94
2145570977
4745151860
25 15 35 71 30
55 34 2447 89
92 b4 01 f6 2||tt ||9R 43 8 63 5
61 29 08 93 67
?615 4849 44
52 83 9c 94 76
16 55 23 42 45
B1 76 9 26 92
5535237918||tt| |16 45 70 50 83
KD 60 4718 7
82 95 55 26 5
63 14 2 32 52
86 53 E9 X 22
01 4759 38 D
565439 55
1 9817
133C55 6254
589 6041
56 (7 93 39 30
:9 48 56 27 44
11 0R 597
88125T21T7
99 B2 93 2 93
74 54 13 26 91
04 32 92 08 09
1 55 63 77 09
70 47 14 54 36
54 96 09 11 06
82 B0 84 25 39
05 98 90 07 35
6772164279
49 1 30
66 39 67 98 69
292 919- 0
94 7 5
29- 0 -2 1
UR'ZLR'Z
1 FT2
Bys y' ly
S~9 2F*9 20\9 21*9 +h\| |tt||5 F8* 0P-5 EF'0 2F'6 15'6 C5'6 19'6 99'6 22*6 69*6 1'01 8'01 E GTt
1n' ' !a s' 'g'
2892197152482 33
2 292 8'92 N'02 6-08 1-68 7-28 8'48 9 23092
565 *66 966 366 5-66
9-66 563 565
9*66 #*6 1*66 P66 +*66 p*66 +*6 +'6*6
229129.6192191919
(100=)
contained* 99 -5 2
8 5 5
*9 88 95C
791023 035
89 64 58 69 75
79 24 166
03 73 52 16 56
35 21 20 71 34||tt| |33 92 74 65 94
80 53 54 7 27
20) 03 44 95 4
93 79 64 6472
82 B8 33 69 95||tt| |4 0 8: 30 27
44 9114 66 47
7132765562
5520148211
28 1 9
3157159580
37 79 81 b3 74
58 02 39 37 67||tt ||1B 74 72 00 1B
24 35 59 87 8
5497205655
2B 45 82 58 72
OB 22 23 71 T7
GR/ T 15000.5-94
F513 car 78
$9 29 76 39 81
83 85 52 27 99
21 48 94 06 $3
60 55 55 00 27
62 33 74 62 14
40 14 71 4 53
95 94 78 32 65
64 B5 4 135 72
29 54 96 5384
93 075472 59
7236041975
3 39 3 05 33
89 23 3 63 15
#7 0 22 5X 40
7 21 90 5
2 25 6 84 63
5107927477
73 21 16 10 33
42 10 14 20 $2||tt| |38 79 56 69 32
K2 07 5$ 89 35
1574B00832
8 14 8 99 70
91 r:1 93 20 49
75 4k 45 4 6u
33 J4 91 5# 93
3014 78 56 27
91 96 94 65 49
3352293987
53 73 19 S
50 95 52 74 33
01 32 90 76 34||tt| |43 14 52 5 94
2145570977
4745151860
25 15 35 71 30
55 34 2447 89
92 b4 01 f6 2||tt ||9R 43 8 63 5
61 29 08 93 67
?615 4849 44
52 83 9c 94 76
16 55 23 42 45
B1 76 9 26 92
5535237918||tt| |16 45 70 50 83
KD 60 4718 7
82 95 55 26 5
63 14 2 32 52
86 53 E9 X 22
01 4759 38 D
565439 55
1 9817
133C55 6254
589 6041
56 (7 93 39 30
:9 48 56 27 44
11 0R 597
88125T21T7
99 B2 93 2 93
74 54 13 26 91
04 32 92 08 09
1 55 63 77 09
70 47 14 54 36
54 96 09 11 06
82 B0 84 25 39
05 98 90 07 35
6772164279
49 1 30
66 39 67 98 69
292 919- 0
94 7 5
29- 0 -2 1
UR'ZLR'Z
1 FT2
Bys y' ly
S~9 2F*9 20\9 21*9 +h\| |tt||5 F8* 0P-5 EF'0 2F'6 15'6 C5'6 19'6 99'6 22*6 69*6 1'01 8'01 E GTt
1n' ' !a s' 'g'
2892197152482 33
2 292 8'92 N'02 6-08 1-68 7-28 8'48 9 23092
565 *66 966 366 5-66
9-66 563 565
9*66 #*6 1*66 P66 +*66 p*66 +*6 +'6*6
229129.6192191919
(100=)
contained* 99 -5 2
8 5 5
*9 88 95-94
F513 car 78
$9 29 76 39 81
83 85 52 27 99
21 48 94 06 $3
60 55 55 00 27
62 33 74 62 14
40 14 71 4 53
95 94 78 32 65
64 B5 4 135 72
29 54 96 5384
93 075472 59
7236041975
3 39 3 05 33
89 23 3 63 15
#7 0 22 5X 40
7 21 90 5
2 25 6 84 63
5107927477||tt ||73 21 16 10 33
42 10 14 20 $2
38 79 56 69 32
K2 07 5$ 89 35
1574B00832
8 14 8 99 70
91 r:1 93 20 49
75 4k 45 4 6u
33 J4 91 5# 93
3014 78 56 27
91 96 94 65 49
3352293987
53 73 19 S||tt| |50 95 52 74 33
01 32 90 76 34
43 14 52 5 94
2145570977
4745151860
25 15 35 71 30|| tt||55 34 2447 89
92 b4 01 f6 2
9R 43 8 63 5
61 29 08 93 67
?615 4849 44
52 83 9c 94 76
16 55 23 42 45
B1 76 9 26 92
5535237918
16 45 70 50 83
KD 60 4718 7
82 95 55 26 5
63 14 2 32 52
86 53 E9 X 22
01 4759 38 D
565439 55
1 9817
133C55 6254
589 6041
56 (7 93 39 30
:9 48 56 27 44
11 0R 597
88125T21T7
99 B2 93 2 93
74 54 13 26 91
04 32 92 08 09
1 55 63 77 09
70 47 14 54 36
54 96 09 11 06
82 B0 84 25 39
05 98 90 07 35
6772164279
49 1 30
66 39 67 98 69
292 919- 0
94 7 5
29- 0 -2 1
UR'ZLR'Z
1 FT2
Bys y' ly| |tt||S~9 2F*9 20\9 21*9 +h\
5 F8* 0P-5 EF'0 2F'6 15'6 C5'6 19'6 99'6 22*6 69*6 1'01 8'01 E GTt
1n' ' !a s' 'g'
2892197152482 33
2 292 8'92 N'02 6- 08 1-68 7-28 8'48 9 23092
565 *66 966 366 5-66
9-66 563 565
9*66 #*6 1*66 P66 +*66 p*66 +*6 +'6*6
229129.6192191919
(100=)
Set* 99 -5 2
8 5 5
*9 88 95-94
F513 car 78
$9 29 76 39 81
83 85 52 27 99
21 48 94 06 $3
60 55 55 00 27
62 33 74 62 14
40 14 71 4 53
95 94 78 32 65
64 B5 4 135 72
29 54 96 5384
93 075472 59
7236041975
3 39 3 05 33
89 23 3 63 15
#7 0 22 5X 40
7 21 90 5
2 25 6 84 63
5107927477||tt ||73 21 16 10 33
42 10 14 20 $2
38 79 56 69 32
K2 07 5$ 89 35
1574B00832
8 14 8 99 70
91 r:1 93 20 49
75 4k 45 4 6u
33 J4 91 5# 93
3014 78 56 27
91 96 94 65 49
3352293987
53 73 19 S||tt| |50 95 52 74 33
01 32 90 76 34
43 14 52 5 94
2145570977
4745151860
25 15 35 71 30|| tt||55 34 2447 89
92 b4 01 f6 2
9R 43 8 63 5
61 29 08 93 67
?615 4849 44
52 83 9c 94 76
16 55 23 42 45
B1 76 9 26 92
5535237918
16 45 70 50 83
KD 60 4718 7
82 95 55 26 5
63 14 2 32 52
86 53 E9 X 22
01 4759 38 D
565439 55
1 9817
133C55 6254
589 6041
56 (7 93 39 30
:9 48 56 27 44
11 0R 597
88125T21T7
99 B2 93 2 93
74 54 13 26 91
04 32 92 08 09
1 55 63 77 09
70 47 14 54 36
54 96 09 11 06
82 B0 84 25 39
05 98 90 07 35
6772164279
49 1 30
66 39 67 98 69
292 919- 0
94 7 5
29- 0 -2 1
UR'ZLR'Z
1 FT2
Bys y' ly| |tt||S~9 2F*9 20\9 21*9 +h\
5 F8* 0P-5 EF'0 2F'6 15'6 C5'6 19'6 99'6 22*6 69*6 1'01 8'01 E GTt
1n' ' !a s' 'g'
2892197152482 33
2 292 8'92 N'02 6- 08 1-68 7-28 8'48 9 23092
565 *66 966 366 5-66
9-66 563 565
9*66 #*6 1*66 P66 +*66 p*66 +*6 +'6*6
229129.6192191919
(100=)
Set* 99 -5 2
8 5 5
*9 88 9a s' 'g'
2892197152482 33
2 292 8'92 N'02 6-08 1-68 7-28 8'48 9 23092
565 *66 966 366 5 -66
9-66 563 565
9*66 #*6 1*66 P66 +*66 p*66 +*6 +'6*6
229129.6192191919||tt ||(100=)
contained* 99 -5 2
8 5 5
*9 88 9a s' 'g'
2892197152482 33
2 292 8'92 N'02 6-08 1-68 7-28 8'48 9 23092
565 *66 966 366 5 -66
9-66 563 565
9*66 #*6 1*66 P66 +*66 p*66 +*6 +'6*6
229129.6192191919||tt ||(100=)
contained* 99 -5 2
8 5 5
*9 88 9
Tip: This standard content only shows part of the intercepted content of the complete standard. If you need the complete standard, please go to the top to download the complete standard document for free.