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Test method of classification for import and export dangerous goods-Part 13:Flammable liquid
Basic Information
Standard ID:
SN/T 1828.13-2013
Standard Name:Test method of classification for import and export dangerous goods-Part 13:Flammable liquid
drafter:Liu Shaocong, Li Xueyang, Gao Jian, Lü Gang, Wang Na, Zhang Ling
Drafting unit:Tianjin Entry-Exit Inspection and Quarantine Bureau of the People's Republic of China, Hubei Entry-Exit Inspection and Quarantine Bureau of the People's Republic of China
Focal point unit:Certification and Accreditation Administration of the People's Republic of China
Publishing department:General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China
SN/T 1828.13-2013. Test method of classification for import and export dangerous goods-Part 13: Flammable liquid.
1 Scope
SN/T 1828.13 specifies the test and classification of flammable liquid dangerous goods for import and export.
SN/T 1828.13 is applicable to the test of hazardous characteristics of flammable liquid dangerous goods for import and export
2 Normative references
The following documents are indispensable for the application of this document. For all dated references, only the dated version applies to this document. For all undated references, the latest version (including all amendments) applies to this document.
GB/T 616 General method for determination of boiling point of chemical reagents
ASTM D93-11 Standard method for determination of flash point by Pensky-Martin spherical apparatus
ASTM D6450-5(2010) Standard method for determination of flash point by continuous spherical cup
Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria (United Nations, 5th revised edition).
3 Terms and definitions
The terms and definitions defined in the "Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria" (5th revised edition) and the following terms and definitions apply to this document.
3.1 Flammable liquids
This category of chemicals refers to flammable liquids, liquid mixtures or liquids containing solid substances, but does not include liquids that have been included in other categories due to their hazardous properties, and whose closed cup flash point test flash point is equal to or lower than 60°C.
3.2 Flash point
The lowest temperature at which the sample is heated to a mixture of its vapor and air under specified conditions and flashes when it contacts a flame.
4 Tests
4.1 Closed cup flash point test
4.1.1 Test equipment
Closed cup flash point tester.
4.1.2 Test procedures
Determine the flash point of the liquid according to the method of ASTM D93-11 or ASTM D6450-5 (2010).
Some standard content:
SN/T1828.13—2013, the entry-exit inspection and quarantine industry standard of the People's Republic of China, replaces SN/T1828.13—2006, Test method of classification for import and export dangerous goods-Part 13: Flammable liquids 13: Flammable liquid 2013-11-06 Issued People's Republic of China General Administration of Quality Supervision, Inspection and Quarantine 2014-06-01 Implementation SN/T1828 "Classification and Test Methods for Import and Export Dangerous Goods" is divided into 17 parts: Part 1: General: Part 2: Civilian explosives; Part 3: Oxidizers: bZxz.net -Part 4: Corrosive substances; Part 5: Gas mixtures; ||t t||Part 6: Substances that emit flammable gases in contact with water: Part 7: Compressed gases; Part 8: Organic peroxides: Part 9: Toxic substances: Part 10: Toxic gases: Part 11: Flammable solids Part 12: Flammable gases: Part 13: Flammable liquids: Part 14: Lithium batteries: Part 15: Self-heating solids; Part 16: Nitrates: Part 17: Marine pollutants. This part is Part 13 of SN/T1828. This standard was drafted in accordance with the rules given in GB/T1.1-2009. SN/T1828.13—2013 Go to Part 13: Flammable liquids". This part replaces SN/T1828.13-2006 "Classification and Test Methods for Import and Export Dangerous Goods". Compared with SN/T1828.13-2006, the main technical changes are as follows: the definition of flammable liquids has been modified (see 3.1, 3.1 of the 2006 edition); the determination of hazard categories has been modified (see 5.1, 5.1 of the 2006 edition); the closed cup flash point and viscosity test results have been modified (see 5.2.2 Table 2, 5.2.2 Table 2 of the 2006 edition): - Added that viscous substances with the following properties should be included in the Class III packaging (see 5.2.4): Added that if the flash point is between 23℃ and 60℃ and meets the following conditions, it can be classified as a non-flammable liquid (see 5.2.5). This part adopts the United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (17th revised edition), and its relevant technical content is completely consistent with the above regulations. This part is proposed and managed by the Certification and Accreditation Administration of the People's Republic of China. This part was drafted by: Tianjin Entry-Exit Inspection and Quarantine Bureau of the People's Republic of China, Hubei Entry-Exit Inspection and Quarantine Bureau of the People's Republic of China. The main drafters of this part are: Liu Shaocong, Li Xueyang, Gao Jian, Lv Gang, Wang Na, Zhang Ling. The previous versions of the standard replaced by this part are: SN/T1828.13-2006. Test methods for classification of dangerous goods for import and export Part 13: Flammable liquids SN/T 1828.13-2013 Warning-Due to the inherent danger, the testing laboratory should pay special attention to the health and safety requirements required by regulations 1 Scope This part of SN/T1828 specifies This part applies to the test of dangerous properties of flammable liquids for import and export. Normative reference documents The following documents are indispensable for the application of this document. All social For any undated referenced document, its latest version (including the two general methods for determining the boiling point of chemical reagents. For referenced documents with a date, only the dated version applies to the amendment of this document) applies to this document. ASTM D93-11 Pensky-Martin flash point standard ASTM D6450-5 (2010) Standard method for determination of interior point of the conical cup Recommendations on the transport of dangerous goods Terms and definitions Recommendations on the transport of dangerous goods This document. Flammable liquidsflammableliqu This category of chemicals refers to flammable liquids and the terms and definitions specified in the Standard Manual and the following terms and definitions apply to liquid mixtures or liquids containing solids but not including liquids that have been listed as hostages due to their hazardous properties with an internal point equal to or lower than other categories of liquids, and its closed cup flash point test 3.2 flashpoint so℃. The sample is heated to the lowest temperature at which the mixture of its vapor and air contacts the flame and flashes under specified conditions. 4 Test Closed cup flash point test Test equipment Closed cup flash point tester. 4.1.2 Test steps The flash point of the liquid shall be determined according to the method of ASTMD93-11 or ASTMD6450-5 (2010). SN/T1828.13—2013 Continued combustion test 4.2.1 Test equipment Continued combustion test instrument. 4.2.2 Test steps The test shall be conducted in accordance with the method in Chapter 32 of the Manual of Tests and Criteria (5th revised edition) of the Recommendations on the Transport of Dangerous Goods. 3 Liquid initial boiling point determination test Test equipment Instruments specified in GB/T616. 4.3.2 Test steps Determine in accordance with the method in GB/T616. 4 Solvent separation test Test equipment 100mL measuring cylinder (total height is about 25cm, and the inner diameter of the scale segments is consistent, about 3cm). 4.4.2 Test procedure 4.4.2.1 Stir the viscous liquid (e.g. paint, varnish, adhesive and polish) with a flash point below 23℃ until it is evenly mixed. 4.4.2.2 Pour the stirred liquid into the 100mL mark of the measuring cylinder. After plugging the stopper, let the measuring cylinder stand for 24 hours. After 24 hours, measure the height of the upper separation layer. The test result is expressed as the percentage of the height of the upper separation layer of the falling liquid in the measuring cylinder to the total height of the sample. 4.5 Viscosity test Test equipment Viscosity tester (nozzle diameter: 4mm and 6mm), timing device. 4.5.2 Test procedure 4.5.2.1 Stir the viscous liquid (e.g. paint, varnish, adhesive and polish) with a flash point below 23℃ until it is evenly mixed. 4.5.2.2 Carefully inject the stirred liquid into the 4mm diameter nozzle of the viscosity tester, start timing immediately, and record the time taken for the entire sample to flow through the viscosity tester. If the flow time exceeds 100s, carefully inject the sample into the 6mm diameter nozzle of the viscosity tester and start timing. Record the time taken for the entire sample to flow through the viscosity tester. 5 Category determination 5.1 Determination of hazard category Liquids or liquid mixtures with a flash point equal to or lower than 60°C determined by the closed cup flash point test belong to Class 3 flammable liquids. However, if the flash point is higher than 35°C, liquids that do not continue to burn do not belong to Class 3 flammable liquids. 2 Determination of applicable packaging category The packaging category determination of flammable liquids is shown in Table 1. Danger categories according to flammability Flash point (closed cup) <23℃ >23℃≤60℃ Initial boiling point >35℃ >35℃ Note: For the determination of packing categories of viscous flammable liquids with a flash point below 23℃, see 5.2.2. SN/T1828.13—2013 Packing category Viscous flammable liquids with a flash point below 23℃ (e.g. paints, varnishes, adhesives and polishes) are classified into 5.2.2 Group III packaging if they meet the following conditions: In the solvent separation test, the height of the clear solvent upper separation layer is less than 3% of the total height; a) The mixture does not contain any primary hazard or subsidiary hazard belonging to 6.b) Substances of 1 poisonous substance or 8th class corrosive substances; Test results meet Table 2: The capacity of the container used shall not exceed 450L. Table 2 Nozzle diameter/mm Closed cup flash point and viscosity test results Flow time/s Substances classified as flammable liquids due to transportation at high temperature (≥55℃) are listed in Group III packaging. Viscous substances with the following properties are included in packing group III: a) flash point between 23℃~60℃; non-toxic, corrosive or environmentally hazardous; flash point/℃ >17℃ >10℃ >-1℃ >-5℃ contains no more than 20% nitrocellulose, and the dry matter mass of nitrogen contained in nitrocellulose does not exceed 12.6%; the capacity of the storage container used does not exceed 450L. d) If the flash point is between 23℃ and 60℃ and meets the following conditions, it can be classified as a non-flammable liquid: 5.2.5 In the solvent separation test in 4.4, the height of the solvent separation layer is less than 3% of the total height; b) In the viscosity test in 4.5 using a nozzle with a diameter of 6mm, the flow time is greater than or equal to: 60s; 40S, and the viscous material content does not exceed 60% of Class 3 substances. SN/T1828.13-2013 Industry Standard of the People's Republic of China for Entry-Exit Inspection and Quarantine Classification and Test Methods for Import and Export Dangerous Goods Part 13: Flammable Liquids SN/T1828.13—2013 Published by China Standards Press No. 2, Hepingli West Street, Chaoyang District, Beijing (100029) No. 16, Sanlihe North Street, Xicheng District, Beijing (100045) Editorial Office: (010) 64275323 Website: spc.net.cn Printed by China Standard Press, King of Fighters Island Printing Factory* Format: 880×12301/16 Printing Sheet: 0.5 Word Count: 8,000 First Edition: June 2014 First Printing: June 2014 Print Quantity: 1-1600 Book Number: 155066·2-26991 Tip: This standard content only shows part of the intercepted content of the complete standard. If you need the complete standard, please go to the top to download the complete standard document for free.