Specifications for storage and preservation of combustible and explosive goods
Some standard content:
GB179141999
This standard is formulated to regulate the storage management of flammable and explosive items in hazardous chemicals and ensure the safety of flammable and explosive items during storage.
This standard is based on the "Regulations on the Management of Hazardous Chemicals" issued by the State Council and the "Technical Specifications for Commodity Storage and Maintenance" Volume 7 formulated by the State Bureau of Domestic Trade, and combines more than 40 years of practical experience and experimental research results in the storage of such commodities to make specific provisions for the reasonable and safe storage of flammable and explosive items.
Appendix A and Appendix B of this standard are both recommended appendices. This standard was proposed by the State Bureau of Domestic Trade. Drafting unit of this standard: Beijing Commercial Storage and Transportation Company. The main drafters of this standard are Meng Hao, Gong Xiufen, Wu Fengqin, Yu Yuhong, and Zhang Guirong. 1 Scope
National Standard of the People's Republic of China
Specifications for storage and preservation of combustible and explostve goods This standard specifies the technical requirements for storage conditions, maintenance techniques and storage period of combustible and explostve goods. GB 179141999
This standard applies to explosives, compressed gases and liquefied gases, flammable liquids, flammable solids, spontaneous combustion articles, ignition-proof articles, oxidants and organic peroxides (excluding military hazardous materials) in GB 12268. 2 Referenced standards
The provisions contained in the following standards constitute the provisions of this standard by reference in this standard. When this standard was published, the versions shown were valid. All standards will be revised. All parties using this standard should explore the possibility of using the latest versions of the following standards: GB190--1990 Dangerous Goods Packaging Marking
GB191-1990 Packaging Storage and Transportation Pictorial Marking
GB12268-1990 Dangerous Goods Name List
GB12463-1990 General Technical Conditions for Dangerous Goods Transport Packaging GBJ16-1987 Code for Fire Protection Design of Buildings
3 Fins and spines
3.1 Building conditions
It should meet the requirements of Article 4.2.1 of GBJ16-~1987, and the fire resistance level of the warehouse should not be lower than level 3. 3.2 Warehouse conditions
Warehouses for storing flammable and explosive goods should be warm in winter and cool in summer, dry, easy to ventilate, sealed and light-proof. 3.2.1 According to the different properties of various commodities, warehouse conditions, fire extinguishing methods, etc., the products should be divided and classified, and stored in different warehouses. 3.2.1.1 Explosives should be stored in warehouses with light-duty fire-resistant buildings. 3.2.1.2 Low and medium flash point liquids, first-class flammable solids, self-igniting materials, compressed gases and liquefied gases should be stored in warehouses with first-class fire-resistant buildings.
3.2.1.3 Wet flammable materials, oxidants and organic peroxides can be stored in warehouses with first-class and second-class fire-resistant buildings. 3.2.1.4 Second-class flammable solids and high flash point liquids can be stored in warehouses with a fire level of not less than third class. 33 Safety conditions
3.3.1 Goods should be kept away from direct sunlight, fire sources, heat sources, power sources, and spark-free conditions. 3.3.2 In addition to the classified storage specified in Appendix A (Standard Appendix), the following varieties should be stored in special warehouses. 3.3.2.1 Explosives, black powders, and desiccant compounds should be stored in special warehouses. 3.3.2.2 Compressed gas and liquefied gas: flammable gas, non-flammable gas and toxic gas shall be stored in separate warehouses. 3.3.2.3 All flammable liquids can be stored in the same warehouse; but methanol, ethanol, thiocyanate, etc. shall be stored in separate warehouses. Approved by the State Administration of Quality and Technical Supervision on November 29, 1999 and implemented on April 1, 2000
GE17914-1999
Flammable solids can be stored in the same warehouse; but emulsions H and acids or acidic items shall be stored separately; nitrocellulose, safety matches, red phosphorus 3.312.4
and metal powders such as phosphorus sulfide and aluminum sulfide shall be stored separately; self-igniting items: yellow phosphorus, hydrocarbon metal compounds, animal and vegetable oil products shall be stored in separate warehouses. 3.3.2.5
3.3.2.6
Store flammable items that are easily flammable when wet in a special warehouse.
3.3.2.7 Oxidizers and organic peroxides Inorganic oxidizers and organic oxidizers must be stored separately, but ammonium nitrate, salts of oxygen, permanganate, nitrate, sodium peroxide, hydrogen peroxide, etc. must be stored separately in special warehouses. 3.4 Environmental and sanitation conditions
3.4.1 There are no weeds and flammable materials around the warehouse. 3.4.2 The warehouse is cleaned regularly, and there is no leakage of goods on the floor. Keep the floor and the shelves clean and hygienic. 3.5 Temperature and humidity conditions
3.5.1 The temperature and humidity suitable for the storage of various commodities are shown in Table 1. Table 1 Temperature and humidity conditions
Explosives
Compressed gas and liquefied gas
Flammable liquids
Flammable solids
Self-igniting items
Humidified flammable items
Oxidizers and
Organic peroxides
4 Warehouse acceptance
4.1 Acceptance principles
Black powder, compounds
Water as stabilizer
Flammable, non-combustible, with re-|tt||Low flash point
Medium and high medical points
Flammable solids
Cellulose nitrate
Safety matches
Red Phosphorus, phosphorus sulfide, aluminum powder
Hydrocarbon metal compounds
Oil-containing products
Commodities that are easily flammable when wet
Oxidants and organic peroxides
Sodium peroxide, magnesium, calcium, etc.
Zinc nitrate, calcium, etc.
Ammonium nitrate, sodium nitrite
Aqueous solution of salts
Crystalline manganese nitrate
Benzoyl peroxide
Organic oxidants such as butanone peroxide
Relative concentration, %
Contains stabilizer
4.1.1 Goods entering the warehouse must meet the product standards and be accompanied by a production license and a product inspection certificate. Imported products should also have a Chinese safety technical manual or other instructions.
GB17914-1999
4.1.2 The custodian shall inspect the internal and external markings, containers, packaging, cushions, etc. of the goods. Make an acceptance record after inspection. 4.1.3 Acceptance should be conducted at the safety pool point outside the warehouse or the acceptance room. 4.1.4 Unpack and inspect 2~5 boxes of each commodity (except for exempted commodities). If problems are found, expand the acceptance ratio. After inspection, restore the commodity packaging and mark it.
4.2 Acceptance items
4.2.1 Acceptance of internal and external markings
a) Product name;
b) Specifications:
c) Grade,
Number and weight:
e) Production date (batch number);
f) Production process F,
) Dangerous goods signs shall comply with the provisions of GB190 and GB191. 4.2.2. Acceptance of packaging
The containers and packaging of various commodities shall comply with the provisions of GB12463, shall be tightly closed, intact, and the containers and outer packaging shall not be stained with the internal commodities and other items, and shall not be damp or wet. The inner and outer packaging and cushioning of various commodities are shown in Table 2. Table 2 Inner and outer packaging and cushioning of various commodities
Explosives
Compressed gas
and liquefied gas
Flammable liquids
Flammable solids
Self-igniting articles
Hot and wet ignition articles
Oxidizers and organic peroxides
Black powder
Firecrackers, flower
Compounds
Blue nitrophenol, etc.
Compressed gas and
Liquid gas
Easy liquid area
Flammable solids
Hao Zhanluo sheet and
Safety matches|| |tt||Hydrocarbon-based metal oxides
Oil-containing products
Alkali metals and oxides
Oxidants
Sodium peroxide (potassium), high
Inner packaging
Plastic, restore weight
Wrap tightly
Glass bottles
Glass bottles
Steel cylinders (with caps)
Metal barrels and glass bottles
《Airtight》
Material paper. Glass bottles
Boxes (no exposed wood heads)
Bottles. Metal barrels
Bottles, barrels
Barrels. Bottles. Bags
Zinc manganate, potassium chlorate bottles,Pain
【(Sodium)
Benzyl peroxide
Bottle, pry
Outer packaging
Plastic sleeve
Safety rubber enclosure
Metal barrel, wooden barrel, wooden
bag, cardboard box
Cage-proof wooden box
Soft material
Non-combustible material
Loose material
Soft material
Non-combustible materials
Non-tender materials
Non-combustible materials
Loose materials
Non-combustible materials
Non-combustible trees
Three-layer packaging
Non-combustible trees Stabilizer
Stabilizer
Non-combustible pressure
Stabilizer
Stabilizer
4.2.3 Acceptance of product quality (sensory)
GB 17914 -1999
4.2.3.1 The surface has no deliquescence, no melting (dissolution), no discoloration and weathering. 4.2.32 The color of the liquid is normal, there is no loose seal, no volatilization and overflow. 4.2.3.3 The spiral of the gas cylinder is tight and there is no leakage. 4.3 Acceptance result processing
4.3.1 Any incomplete external markings and packaging that does not comply with the provisions of 4.2 shall not be accepted into the warehouse or temporarily stored in the observation room. If the packaging is broken or leaking, it must be repaired before entering the warehouse.
4.3.2 After the acceptance is completed, the qualified ones shall be put into the warehouse for acceptance and transferred to the storage party. 5 Stacking
5.1 Stacking method
According to the warehouse conditions, the nature of the goods and the packaging form, appropriate stacking and padding methods shall be adopted. 5.1.1 Various goods are not allowed to be stored directly on the ground. According to the height of the warehouse, the padding should generally be more than 15cm. In case of flammable items, goods that are easy to absorb moisture and dissolve, and goods that absorb moisture and decompose, the padding height should be increased according to the situation. 5.1-2 Various goods should be stacked in a row and pressed to ensure firmness, neatness, beauty, and convenience in entering and leaving the warehouse. Generally, the stacking height shall not exceed 3Ⅱ. 5. 1-3 Stacking distance,
a) Main channel is greater than or equal to 180cm
b) Branch channel is greater than or equal to 80emi
c) Wall distance is greater than or equal to 30cm
d) Column distance is greater than 10cms
e) Stack distance is greater than or equal to 10cm
f) Top distance is greater than or equal to 50cm.
6 Protection technology
6 1 Temperature and humidity management
6 1.1 A temperature and humidity meter is set up in the warehouse (a self-recording temperature and humidity meter can be set up in key warehouses), and observation and recording are carried out at the specified time. 6.1.2 According to the different properties of the goods, a humidity management method combining sealing, ventilation and moisture absorption in the warehouse is adopted to strictly control and maintain the temperature in the warehouse to meet the requirements of Table 1. 6.2 Inspection in warehouse
6.2.1 Safety inspection
Carry out safety inspection inside and outside the warehouse every day, check whether flammable materials are cleaned, the firmness of the goods stack and abnormal phenomena, etc. 6.2.2 Quality inspection
According to the nature of the goods, regular inspection of quality in warehouse mainly based on sensory perception is carried out, and 1-2 pieces of each product are randomly inspected, mainly to check the changes of the goods themselves, the changes of the commodity containers, seals, packaging and pads during the storage period. 6.2-2.1 Explosives: Generally, it is not suitable to unpack for inspection + mainly check the outer packaging. Explosive chemicals can be unpacked for inspection. 6.2.2.2 Compressed gas liquefied gas: Use a weighing scale to check its weight. Check whether the cylinder is leaking. Use a balloon to tie the bottle mouth tightly; you can also use a cotton ball to apply dilute hydrochloric acid solution (for nitrogen) or dilute nitrogen water (for nitrogen and chlorine) to the bottle mouth. If there is a lot of smoke, it will immediately produce gas. 6.2.2.3 For flammable liquids, check whether the seal is tight, whether there is volatilization or leakage, and whether there is discoloration, deterioration and precipitation. 6.2.2.4 For flammable solids: check whether there is dissolution (melting), sublimation, discoloration and deterioration. 6.2.2.5 Self-igniting articles and flammable articles that are easily ignited when wet: check whether there is volatilization, condensation, moisture absorption and dissolution. The stabilizer containing stabilizer should be sufficient, otherwise it should be replenished immediately.
6-2.2.6 Oxidizers and organic peroxides: check whether the package seal is tight, whether there is moisture absorption and dissolution, discoloration and deterioration; organic peroxides and stabilizers containing stabilizers should be sufficient, and the seal is tight and effective. GB 17914 —1999
6.2.2.7 Commodities measured by weight should be sampled for weight inspection to control the storage consumption of commodities. 6-2.2.8 After each quality inspection, obvious marks should be made on the outer packaging and records should be kept. 6.2.3 Problem handling of inspection results
6.2.3.1 Record the inspection results item by item and mark them on the outer packaging of the goods. 6.2.3.2 For problems found during the inspection, fill out the notification form for problematic goods in time to notify the stockholder. If the problem is serious or endangers safety, report and notify the stockholder immediately and take emergency measures. 6.2.3.3 For goods with expiration dates, the stockholder should be notified one month before the expiration date. 6.2.3.4 For goods that have exceeded the storage period or have not been shipped out for a long time, a reminder form for goods in stock should be filled out and transferred to the stockholder. 7 Safe operation
7.1 Operators should wear work clothes, gloves, masks and other necessary protective equipment. During operation, they should be handled with care to prevent friction and impact. 7.2 Tools that can produce sparks shall not be used in any operation. The operation site shall be kept away from heat and fire sources. 7.3 Anti-static work clothes shall be worn when handling flammable liquids, and spiked shoes are prohibited. Large barrels shall not flow directly on cement floors. Vehicles entering and leaving the warehouse must wear protective shields, and exhaust gas should not be directly aimed at the warehouse door. 7.4 Barrels of various oxidants must not roll on the cement floor. 7.5 No sorting or modification is allowed in the warehouse. Unpacking, barreling, acceptance and quality inspection must be carried out outside the warehouse. B Storage period
Determined according to the production date and validity period of various commodities. 9 Out of the warehouse
First in first out in the order of production date and batch number. 10 Emergency handling
10.1 See Appendix B (Standard Appendix) for fire extinguishing methods. 10.2 Various items will produce different degrees of toxic gases and toxic smoke during the combustion process. When extinguishing fires and rescuing, you should stand in the upwind direction and wear a gas mask or self-rescue respirator. 10.3 If you find symptoms of poisoning such as hooding, vomiting, breathing difficulties, blue face, etc., leave the scene immediately, move to a place with fresh air or give artificial respiration, and send to hospital for treatment in serious cases.
Chemical hazardous materials classification
ExplosivewwW.bzxz.Net
Oxidizer
Pressurized gas
Chemical hazardous materials classification
Ignition equipment
Super explosive equipment
Explosive and explosive drugs
Other explosives
First-level organic
First-level organic
Second-level inorganic
Second-level organic
Dragon group (liquid ammonia and liquid chlorine||t t||and liquefied gas
inflammable items
water-proof combustible
combustible items
flammable solids
sounding items
corrosive acidic
radioactive items
highly toxic inorganic
highly thin organic
toxic inorganic
toxic organic
Note, \C\ symbol indicates that they can be mixed + "\×\ symbol indicates that they cannot be mixed: GB 17914-1999
Appendix A
(Standard Appendix)
Chemical Hazardous Materials Mixed Storage Performance Compensation Table
Compressed Gas
Explosive Materials
Oxidizers
Body and Liquid
Liquid Solid! Articles
Article Door
Chemical Gas
Corrosive
Drama Has
Every No ... Level 1 weaving level 1 ... Machine
District area ... XIxIXIx
Min District District District District District District District District District District District District District District District District District District District District District District "Classification" refers to the storage of hazardous chemicals in different areas according to their classification. If there are not many items or the warehouse is insufficient, they can be stored separately because their properties do not conflict with each other; "Disinfection" refers to the storage of two items that do not conflict with each other but are stored in different ways if conditions permit: peroxides such as sodium nitrite should not be stored together with non-oxidizing agents; nitric acid materials such as sodium nitrite with reducing properties should not be stored together with other inorganic oxidizing agents. Where mixed goods are stored, a distance of more than 1m must be left between the stacks and the cargo handles, and the packaging containers must be intact to prevent the two items from coming into contact. Category
Explosives
Compounds
Compressed gases and reduced gasesCompressed wax gases and liquefied gasesFlammable liquids
Combustible solids
Self-igniting items
Wet flammable items
Oxidants and
Organic peroxides
Medium, low and high flash points
Methanol, ethanol, acetone
Flammable materials
Emulsifiers
Phosphorus
Self-igniting items
Hydrocarbon metal compounds
Dehumidifying items
Sodium, potassium
GB 17914—1999
(Appendix to the standard)
Fire extinguishing methods for inflammable and explosive articles
Fire extinguishing methods
Moldy water
Misty water, water
A lot of water
Dry powder
Anti-falling foam
Water, foam
Water, dry powder
Water, foam
Oxidants and organic peroxides
Sodium peroxide, potassium, magnesium, calcium, etc.
Thin water
Bottle making
Prohibited amine alkali foam
Water for recruitment
Prohibited water
Prohibited water
Prohibited water, dihydrogen fluoride, tetrachloride
Medicinal water
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