GB 30000.9-2013 Chemical Classification and Labelling Specification Part 9: Self-reactive substances and mixtures GB30000.9-2013 Standard compression package decompression password: www.bzxz.net
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of self-reactive substances and mixtures. This part applies to the classification and labeling of self-reactive substances and mixtures in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals. ||
tt|| Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended.
The expected structure of GB30000.9 "Specifications for Classification and Labelling of Chemicals" and the national standards to be replaced are:
———Part 1: General (replaces GB13690-2009);
———Part 2: Explosives (replaces GB20576-2006);
———Part 3: Flammable gases (replaces GB20577-2006);
———Part 4: Aerosols (replaces GB20578-2006);
———Part 5: Oxidizing gases (replaces GB20579-2006);
———Part 6: Gases under pressure (replaces GB20580-2006);
———Part 7: Flammable liquids (replaces GB20581-2006);
———Part 8: Flammable solids (replaces GB 20582-2006);
———Part 9: Self-reactive substances and mixtures (replaces GB 20583-2006);
———Part 10: Pyrophoric liquids (replaces GB 20585-2006);
———Part 11: Pyrophoric solids (replaces GB 20586-2006);
———Part 12: Self-heating substances and mixtures (replaces GB 20584-2006);
———Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB 20587-2006);
———Part 14: Oxidizing liquids (replaces GB 20589-2006);
——Part 15: Oxidizing solids (replaces GB 20590-2006);
——Part 16: Organic peroxides (replaces GB 20591-2006);
——Part 17: Corrosive to metals (replaces GB 20588-2006);
——Part 18: Acute toxicity (replaces GB 20592-2006);
——Part 19: Skin corrosion/irritation (replaces GB 20593-2006);
——Part 20: Serious eye damage/eye irritation (replaces GB 20594-2006);
——Part 21: Respiratory or skin sensitization (replaces GB 20595-2006);
———Part 22: Germ cell mutagenicity (replaces GB 20596-2006);
———Part 23: Carcinogenicity (replaces GB 20597-2006);
———Part 24: Reproductive toxicity (replaces GB 20598-2006);
———Part 25: Specific target organ toxicity single exposure (replaces GB 20599-2006);
———Part 26: Specific target organ toxicity repeated exposure (replaces GB 20601-2006);
———Part 27: Aspiration hazard;
———Part 28: Hazard to the aquatic environment (replaces GB 20602-2006);
———Part 29: Hazard to the ozone layer;
———Part 30: Warning signs for chemical workplaces.
This part is Part 9 of GB 30000.
This part was drafted in accordance with the rules given in GB/T 1.1-2009.
This part replaces GB 20583-2006 "Safety Specification for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Self-reactive Substances".
This part is consistent with the relevant technical content of the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition).
Compared with GB 20583-2006, the main technical content changes of this part are as follows:
———The name of the standard has been modified. The Chinese name has been modified to "Rules for classification and labelling of chemicals—Part 9:—Self-reactive substances and mixtures", and the English name is "Rules for classification and labelling of chemicals—Part 9:—Self-reactive substances and mixtures";
———The scope of Chapter 1 has been modified, "Warning label" has been changed to "label", and "Warning statement" has been deleted;
———The introductory words of Chapter 2 "Normative references" have been modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" has been added as a reference document;
———The introductory words of Chapter 3 "Terms and Definitions" have been added;
———Figure 1 "Decision Logic Diagram" and "Guidance" in Chapter 5 have been made informative Appendix A;
———Deleted the original Chapter 7, and revised Table 3 of the original Chapter 7 as normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition);
———In accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition), revised and integrated the original Chapters 6, 7 and 8 into Chapter 6; revised Table 2 as normative Appendix C;
———Deleted the original Chapter 8, and added the relevant "Hazard Statements" and "Precautionary Statements" as informative Appendix D; ———
Added informative Appendix E "Label Examples".
This part was proposed and coordinated by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251).
Drafting units of this part: China Chemical Economic and Technological Development Center, Shanghai Research Institute of Chemical Industry, China Chemical Information Center, Pony Testing Technology Co., Ltd., Huafeng Group Co., Ltd.
The main drafters of this part of the standard are: Wang Xiaobing, Fan Bin, Liang Jin, Zhu Tao, Song Wei, Yang Ting, Guan Shitai, Xiang Chaoli, Cao Mengran, Gao Shuxia, Wen Tao. The
previous versions of the standards replaced by this part are:
——GB20583-2006.
The following documents are indispensable for the application of this document. For all dated referenced documents, only the dated version applies to this document. For all undated referenced documents, the latest version (including all amendments) applies to this document.
GB13690 General Rules for Classification and Hazard Communication of Chemicals
GB30000.2 Specification for Classification and Labelling of Chemicals Part 2: Explosives
GB30000.14 Specification for Classification and Labelling of Chemicals Part 14: Oxidizing Liquids
GB30000.15 Specification for Classification and Labelling of Chemicals Part 15: Oxidizing Solids
GB30000.16 Specification for Classification and Labelling of Chemicals Part 16: Organic Peroxides
GB/T21613 Test Method for Self-Accelerating Decomposition Temperature of Dangerous Goods
United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (Fourth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition)
United Nations Manual of Tests and Criteria for Recommendations on the Transport of Dangerous Goods (Fifth Revised Edition)

ICS13.300
National Standard of the People's Republic of China
GB30000.9—2013
Replaces GB205832006
Rules for classification and labelling of chemicals-Part 9:Self-reactive substances and mixtures mixtures2013-10-10 Issued
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China
Standardization Administration of the People's Republic of China
2014-11-01 Implementation
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended: GB30000.9 "Chemical Classification and Labeling Specification" is expected to be structured and replaced by the national standards: Part 1: General (replaces GB136902009): Part 2: Explosives (replaces GB20576-2006); Part 3: Flammable gases (replaces GB205772006): Part 4: Aerosols (replaces GB20578-2006); Part 5: Oxidizing gases (replaces GB20579-2006); 06); Part 6: Gases under pressure (replaces GB20580-2006); Part 7: Flammable liquids (replaces GB20581-2006); Part 8: Flammable solids (replaces GB20582-2006); Part 9: Self-reactive substances and mixtures (replaces GB20583-2006); Part 10: Pyrophoric liquids (replaces GB20585-2006); Part 11: Pyrophoric solids (replaces GB20586-2006); Part 12: Incandescent substances and mixtures (replaces GB20584-2006); Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB20587-2006); Part 14: Oxidizing liquids (replaces GB20589-2006); Part 15: Oxidizing solids Part 16: Organic peroxides (replaces GB20591-2006); Part 17: Metal corrosion (replaces GB20588-2006); Part 18: Acute toxicity (replaces GB20592-2006); Part 19: Skin corrosion/irritation (replaces GB20593-2006); Part 20: Serious eye damage/eye irritation (replaces GB20594-2006); Part 21: Respiratory or skin sensitization (replaces GB20595-2006); Part 22: Germ cell mutagenicity (replaces GB20596-2006); Part 23: Carcinogenicity (replaces GB20597-2006); Part 24: Reproductive toxicity (replaces GB20598-2 006): Part 25: Specific target organ toxicity single exposure (replaces GB20599-2006): Part 26: Specific target organ toxicity repeated exposure (replaces GB206012006); Part 27: Inhalation hazard:
Part 28: Hazards to the aquatic environment (replaces GB20602-2006); Part 29: Hazards to the ozone layer:
Part 30: Warning signs in chemical workplaces This part is Part 9 of GB30000
This part is drafted according to the rules given in GB/T1.12009, GB30000.9-—2013
This part replaces GB205832006 "Safety Specifications for Classification, Warning Labels and Warning Statements of Chemicals Self-reactive Substances". This part is consistent with the technical content of the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (4th revised edition). Compared with GB20583-2006, the main technical content changes of this part are as follows: T
GB30000.9-2013
The standard name has been modified. The Chinese name has been changed to "Chemical Classification and Labelling Rules Part 9: Self-reactive substances and mixtures", and the English name is "Rules for classification and labelling of chemicals—Part 9:—Self-reactive substances and mixtures" mixtures\,
Modified the scope of Chapter 1, changed "warning label" to "label", deleted "warning statement"; modified the introduction of Chapter 2 "normative references", and added "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" as a reference document: added the introduction of Chapter 3 "Terms and Definitions"; added Figure 1 "Decision Logic Diagram" and "Guide" in Chapter 5 as informative Appendix A: deleted the original Chapter 7, and followed the United Nations Globally Harmonized System of Classification and Labelling of Chemicals ( The fourth revised edition) revised the original Table 3 of Chapter 7 as normative Appendix B;
According to the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (fourth revised edition), the original Chapter 6, Chapter 7 and Chapter 8 were revised and integrated into the original Table 2 of Chapter 6 as normative Appendix C; the original Chapter 8 was deleted, and the relevant "Hazard Statements" and "Precautionary Statements" were included as informative Appendix D; and the informative Appendix E "Label Examples" was added. This part was proposed and managed by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251). The drafting units of this part are: China Chemical Economic and Technological Development Center, Shanghai Research Institute of Chemical Industry, China Chemical Information Center, PONY Testing Technology Co., Ltd., Huafeng Group Co., Ltd. The main drafters of this part of the standard are: Wang Xiaobing, Fan Bin, Liang Jin, Zhu Tao, Song Wei, Yang Ting, Guan Shitai, Xiang Chaoli, Cao Mengran, Gao Shuxia, Wen Tao.
The previous versions of the standards replaced by this part are: GB20583-2006.
1 Scope
Chemical Classification and Labelling Specification
Part 9: Self-reactive substances and mixtures
GB30000.9—2013
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of self-reactive substances and mixtures. This part applies to the classification and labeling of self-reactive substances and mixtures in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (hereinafter referred to as GHS)
2 Normative References
The following documents are indispensable for the application of this document. For all dated references, the dated version applies to this document. All undated references - the latest version GB136 GB/T21618 Chemical Classification and Hazard Communication Specification for Classification and Labelling of Chemicals Specification for Classification and Labelling of Chemicals Part 2: Explosives Oxidizing Liquids Oxidizing Solids Specification for Sub-Classification and Labelling of Chemicals Part 16 Organic Peroxides Test Method for Self-Accelerating Decomposition Temperature Dangerous Goods United Nations Global Chemical Product Classification and Labelling System (HS) (4th revised edition) United Nations Recommendations on the Transport of Dangerous Goods Regulations (Main revised edition) United Nations Recommendations on the Transport of Dangerous Goods (Test Standards) (5th revised edition) 3 Terms and Definitions (GB13690) The terms and definitions defined in GB13690 and the following terms and definitions apply to this document 3.1 Self-reactive substances or mixtures Self-reactive substances or mixtures are thermally unstable liquid or solid substances or mixtures that are liable to undergo violent exothermic decomposition even in the absence of oxygen (air). This definition does not include substances and mixtures classified as explosives, organic peroxides or oxidizing substances according to GHS. Self-reactive substances or mixtures should be considered to have explosive properties if their components are easy to detonate, deflagrate rapidly or show violent effects when heated under confinement in laboratory tests. 4 Classification criteria
4.1 General principles for classification and labelling of self-reactive substances and mixtures are as follows: GB136904.2 Classification criteria
4.2.1 Any self-reactive substance or mixture should be classified in this category unless: a) it is classified as an explosive according to GB30000.2; GB30000.9-2013
according to GB30000.14 or GB30000.15 classified as an oxidizing liquid or oxidizing solid, but a mixture of oxidizing substances, such as containing 5% or more combustible organic substances, should be classified as a self-reactive substance in accordance with the procedure defined in 4.2.2: classified as an organic peroxide in accordance with GB30000.16; the decomposition heat is less than 300J/g; or the self-accelerating decomposition temperature (SADT) of
50kg package is greater than 75°C Note 1: A mixture of oxidizing substances that meets the criteria for classification as an oxidizing substance, such as containing 5% or more combustible organic substances and does not meet the conditions described in a), c), d) or e) above, should be subject to the self-reactive substance classification procedure; such a mixture should be classified as a self-reactive substance if it exhibits the characteristics of self-reactive substances of types B to F (see 4.2.2).
Self-reactive substances and mixtures are classified in one of the seven categories "Type A" and "Type G" in this class according to the following principles: a)
Any self-reactive substance or mixture which may detonate or deflagrate rapidly in the package shall be classified as white-reactive substance Type A; any self-reactive substance or mixture with explosive properties which will not detonate or deflagrate rapidly in the package but may undergo a thermal explosion in the package shall be classified as self-reactive substance Type B: any self-reactive substance or mixture with explosive properties which is unlikely to detonate or deflagrate rapidly or may undergo a thermal explosion in the package shall be classified as self-reactive substance Type C; any white-reactive substance or mixture which, in laboratory tests: 1) detonates partially, does not deflagrate rapidly and does not exhibit any violent effect when heated under confinement; 2) does not detonate at all, deflagrates slowly and does not exhibit any violent effect when heated under confinement, or 3) does not detonate or deflagrate at all and undergoes thermal explosion under confinement Moderate effect when heated: It will be defined as Type D self-reactive substance; Any self-reactive substance or mixture that does not detonate or deflagrate at all in laboratory tests, and shows a weak effect or no effect when heated under closed conditions, will be defined as Type E white-reactive substance: Any self-reactive substance or mixture that does not detonate or deflagrate at all in a cavitation state in laboratory tests, and shows only a weak effect or no effect when heated under closed conditions, and has a weak or no explosive power, will be defined as Type F self-reactive substance: Any self-reactive substance or mixture that neither detonates nor deflagrates at all in a cavitation state in laboratory tests, and shows no effect when heated under closed conditions, and has no explosive power, will be defined as Type G self-reactive substance, but the substance or mixture should be thermally stable (the self-accelerating decomposition temperature of a 50kg package is 60C~75C). For liquid mixtures, the boiling point of the desensitizing diluent used is greater than or equal to 150C. If the mixture is not thermally stable or the boiling point of the desensitizing diluent used is below 150°C, the mixture should be classified as a self-reactive substance type F. NOTE 2: Type G has no corresponding hazard communication requirement, but properties belonging to other hazard classes should be considered. NOTE 3: Types A to G may not be suitable for all systems. 4.2.3 Temperature control criteria
Self-reactive substances require temperature control if their self-accelerating decomposition temperature is less than or equal to 55°C. The test method for determining the self-accelerating decomposition temperature and the calculation of the control temperature and the critical temperature are shown in GB/T 21613. The selected test should be conducted in a manner that is representative of the size and material of the package.
5 Decision logic and guidance
The decision logic and guidance are for reference only. See Appendix A for the decision logic and guidance. It is particularly recommended that the person responsible for classification study Chapter 4 before and during the use of the decision logic.
6 Labels
6.1 Overview
6.1.1 For labels of self-reactive substances and mixtures, the hazard categories are listed in the order of the designated pictograms, signal words and hazard statements. 2
GB30000.9-—2013
The United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" (Seventeenth Revised Edition) (hereinafter referred to as the "Model Regulations") The hazard classes or categories covered should be listed in the label with the designated corresponding graphic symbols for each item. The allocation of label elements for self-reactive substances and mixtures is shown in Appendix B.
6.1.2 For the classification criteria and label elements for self-reactive substances and mixtures, see Appendix C. 6.1.3 The information required on the label includes hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and supplier identification. Note: For other label elements that have not yet been standardized, such as precautionary statements that need to be included on the label, the competent authority may also require additional information, and the supplier may also add supplementary information.
6.2 Hazard pictograms
Hazard pictograms shall be black symbols with a white background, and the red background shall be wide enough to be eye-catching. The hazard pictograms, graphic symbol colors, numbers and minimum sizes specified in the Model Regulations are shown in Appendix B6.3 Signal words
Signal words are words used on labels to indicate the relative severity of the hazard and to alert the reader to potential hazards. The signal word "Danger" is used for Type A, Type B, Type C and Type D self-reactive substances and mixtures, and the signal word "Warning" is used for Type E and Type F self-reactive substances and mixtures; no signal word is used for Type G self-reactive substances and mixtures. 6.4 Hazard statements
Hazard statements are phrases assigned to a hazard class and category that describe the hazardous properties of a hazardous product and, where appropriate, its degree of hazard. Hazard statements for white reactive substances and mixtures are shown in Appendix D6.5 Precautionary statements
Precautionary statements are words (and/or pictograms) used to describe measures recommended to minimize or prevent adverse effects of exposure to a hazardous product or improper storage or handling of a hazardous product. For this purpose, there are five categories of precautionary statements: general, prevention, emergency, storage and disposal. Precautionary statements for self-reactive substances and mixtures are given in Annex D. 6.6 Product identifiers
6.6.1 The product identifier should be used on the label and should be consistent with the product identifier used on the Material Safety Data Sheet. If a substance or mixture is listed in the Model Regulations, the correct UN shipping name should also be used on the packaging. 6.6.2 The label should include the chemical name of the substance. For mixtures or alloys, when acute toxicity, skin or respiratory sensitization or specific target organ toxicity appear on the label, the label should include the chemical composition of all ingredients or alloying elements that may cause these hazards. The competent authority may require that the chemical names of all ingredients or alloying elements that may contribute to the hazards of the mixture or alloy be listed on the label. 6.7 Supplier identification
The name, address and telephone number of the manufacturer or supplier of the substance or mixture should be provided on the label. 6.8 Examples of labels for self-reactive substances and mixtures Examples of labels for self-reactive substances and mixtures are given in Annex E. KAoNiKAca
GB30000.9—2013
A.1 Decision logic
Appendix A
(Informative Appendix)
Decision logic and guidance
A.1.1 For the classification of self-reactive substances or mixtures, test series A to test series H of the Manual of Tests and Criteria, Part II should be used. Classification is carried out in accordance with decision logic diagram A, 1. A.1.2 The properties that are decisive for the classification of self-reactive substances or mixtures shall be determined by application of tests. Test methods with relevant evaluation criteria are given in Part II of the Manual of Tests and Criteria (Test Series A to Test Series H). 2.1 Yes
Test B
Can it detonate in the package?
Yes, rapidly
Test D
Can it detonate rapidly in the package
Please?
Test G
Substance/Mixture
Test A
Does it conduct explosion?
Part 1.2
Test C
Can it conduct deflagration?
4.1 Yes, rapidly
Can it not conduct?
4.2 Yes, very slowly
What is the effect of heating under closed conditions
7.3 Can the micropackage detonate in the package
What is the effect of heating under closed conditions
Test C
5.1 Yes, rapidly
GB30000.9—2013
Can it conduct deflagration?
5.2 Yes, very slow
In the closed strip heating
effect as you?
9.2 Medium
8.2 Medium
Installed at more than 400km
4501.tt|| Is it safe to use the classification procedure for self-reactive substances and mixtures?
Decision logic for self-reactive substances and mixtures
TTKAONTKAca-
Test F
What is its explosive power?
Test E
What is the effect of heating under confinement? www.bzxz.net
GB30000.9-2013
A.2 Guidance
The classification procedure for self-reactive substances and mixtures need not be used if: there are no radicals in the molecule associated with explosive or reactive properties; examples of these radicals are given in Tables A.6.1 and a) of Appendix 6 of the Manual of Tests and Criteria
A.6.2, or the estimated self-accelerating decomposition temperature of a single organic substance or homogeneous mixture of organic substances is greater than 75°C or the heat of decomposition is less than b
300 J/g. Appropriate calorimetric methods may be used to determine the onset temperature and decomposition heat, see Part 2, 20.3.3.3 of the Manual of Tests and Criteria. The allocation of label elements is shown in Table B.1.
Appendix B
(Normative Appendix)
Allocation of label elements
Table B.1 Allocation of label elements for self-reactive substances and mixtures Self-reactive substances and mixtures
Heating may explode
Same as explosives
(Use the same
graphic symbol selection process)
Heating may cause fire
Or explosion
Type C and D
Heating may cause fire
Type E and F
Heating may cause fire
GB3 0000.9—2013
This hazard category
No label element is assigned
In the Model Regulations
No requirement
Note 1: For Type B, special provision 181 of the Model Regulations may apply (explosive labels may be exempted with approval by the competent authority. See Chapter 3.3 of the Model Regulations for details)
Note 2: Pictograms and symbols in the Model Regulations Colors of self-reactive substances Pictograms: Graphic symbol (flame): black; Background: self-colored with seven vertical red stripes: Number "4\ in the lower corner: black. Graphic symbol for explosives: Graphic symbol (exploding bomb): black; Background color: Color: Number "1\ located in the lower corner, black rKAoNTKAca
GB30000.9-2013
Appendix C
(Normative Appendix)
Classification standards and labels for self-reactive substances and mixtures Classification standards and labels for self-reactive substances and mixtures See Table C.1. Table C.1 Classification standards and label elements for self-reactive substances and mixtures Hazard category
Type C and Type D
Type E and Type F
Based on the test results of Part 1 of the Model Regulations and the application of the judgment logic of the Appendix.
Based on the test results of Part 2 of the Model Regulations
Select and identify according to the test
of Part 2 of the Model Regulations.
Based on the test results of Part II of the Model Regulations and applying the decision logic of Appendix A
Based on the test results of Part II of the Model Regulations and applying the decision logic of Appendix A.
Based on the test results of Part II of the Model Regulations and applying the decision logic of Appendix A.
Graphic No.
Signal Word
Hazard Statement
Encai No.
Signal Word
Emergency Statement
Graphic Symbol
Hazard Statement
Graphic Symbol
Signal Word
Hazard Statement
Graphic Symbol
Signal Word
Hazard Statement
Graphic Symbol
Signal Word
Hazard Statement
Label Elements
Heat May Explode
Heating May Explode Can explode or catch fire
Heating may catch fire
Heating may catch fire
This hazard category has no
allocated label elements
D.1 Overview
Appendix D
(Informative Appendix)
Hazard statements and precautionary statements for self-reactive substances and mixtures GB30000.9—2013
D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for self-reactive substances and mixtures, and lists the hazard statements and precautionary statements for each hazard class and hazard category of self-reactive substances and mixtures, see GB13690. D.1.2 Coding of hazard statements
D.1.2.1 For the coding of hazard statements, see GHS Annex 3 Special letters The digital mixed code consists of 1 letter and 3 numbers, as follows: D.1.2.2 Each hazard statement is assigned the letter "H" (standing for "hazard statement"); a
the first digit represents the hazard type referred to by the hazard statement set by the same part number below, as follows; b
"2" represents physical hazard;
represents health hazard;
represents environmental hazard); the last 2 digits are as follows: D.1.2.3 Except for the sequence codes corresponding to hazards caused by the inherent properties of substances or compounds, such as: explosive code 200~flammable (code 22
, all specified hazard statements shall be marked unless otherwise indicated.
It may be specified that the hazard statement should appear on the label
When two or more hazard statements are provided during the combination of hazard statements, the competent authority may specify whether the combination statement should appear in the order
, or the manufacturer or supplier may determine the order of the combined hazard statement or the corresponding individual statement
D.1.3 Precautionary statements shall be accompanied by uniform risk elements (pictures, signal words and hazard statements) on the label that meets the requirements. The manufacturer or the competent authority may decide on the supplementary information. For additional supplementary information, such as instructions for use, the manufacturer may provide D.1.3.1 Coding of precautionary statements See IS Annex
D.1.3.2 Coding of precautionary statements
1 Each precautionary statement is assigned a special alphanumeric code consisting of 1 letter and 1 number, as follows: D. 1.3.2. 1
a) The letter \P\ (standing for "Precautionary Statements\): The first digit represents the type of precautionary statement, as follows: b)
"1\ represents general precautionary statements;
"2\ represents prevention precautionary statements;
\3\ represents emergency precautionary statements;
"4\ represents storage precautionary statements;
"5" represents disposal precautionary statements;
c) The last two digits (corresponding to the sequential number of the precautionary statements). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used in place of the precautionary statement text.
General precautionary statements
General precautionary measures should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements are applicable to GHS labels under the given conditions (see Table D.1). 9
TTTKANTKAcaChapter 3)
Note 2: Pictograms and symbols in the Model Regulations Pictogram of self-reactive substances: Graphic symbol (flame): black; background color: self-colored with seven vertical red stripes: number "4\ located in the lower corner: black. Graphic symbol for explosives: Graphic symbol (exploding bomb): black; background color: color: number "1\ located in the lower corner, black rKAoNTKAca
GB30000.9—2013
Appendix C
(Normative Appendix)
Classification criteria and labeling of self-reactive substances and mixtures See Table C.1 for the classification criteria and labeling of self-reactive substances and mixtures. Table C.1 Classification criteria and labeling elements for self-reactive substances and mixtures Hazard category
Type C and Type D
Type E and Type F
Based on the test results of Part 1 of the Model Regulations and application of the decision logic of the appendix.
Based on the test results in Part II of the Model Regulations and the application of the decision logic in Appendix A.
Based on the test results in Part II of the Model Regulations and the application of the decision logic in Appendix A.
Based on the test results in Part II of the Model Regulations and the application of the decision logic in Appendix A.
Graphic number
Signal word
Hazard statement
Encai number
Signal
Emergency statement
Graphic symbol
Hazard statement
Graphic symbol
Signal word
Hazard statement
Graphic symbol
Signal word
Hazard statement
Label elements
Heat may explode
Heating may cause explosion or fire
Heating may cause fire
Heating May catch fire
This hazard category has no
assigned label elements
D.1 Overview
Appendix D
(Informative)
Hazard statements and precautionary statements for self-reactive substances and mixtures GB30000.9—2013
D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for self-reactive substances and mixtures. It lists the hazard statements and precautionary statements for each hazard class and hazard category of self-reactive substances and mixtures. See GB13690. D.1.2 Coding of hazard statements D.1.2.1 The coding of hazard statements is specified in Annex 3 of the GHS, which contains a special alphanumeric code consisting of 2 letters and 3 digits, as follows: D.1.2.2 Each hazard statement is assigned a letter (H) (standing for "hazard statement"); a) the first digit represents the type of hazard referred to by the hazard statement numbered in the same section below, as follows; b) "2" represents a physical hazard; 3 represents a health hazard; 4 represents an environmental hazard; 5 represents a chemical hazard; 6 represents a health hazard; 7 represents an environmental hazard; 8 represents an environmental hazard; 9 represents a chemical hazard; 10 represents a chemical hazard; 11 represents a chemical hazard; 12 represents a chemical hazard; 13 represents a chemical hazard; 14 represents a chemical hazard; 15 represents a chemical hazard; 16 represents a chemical hazard; 17 represents a chemical hazard; 18 represents a chemical hazard; 19 represents a chemical hazard. D.1.2.3 Except for the sequence codes corresponding to hazards caused by the inherent properties of substances or humidities, such as: explosive code 200~flammable (code 22), all specified hazard statements shall be used unless otherwise specified. t|| Appearance place
On the label.
It may be specified that the hazard statement should appear on the label
When two or more hazard statements are provided during the combination of hazard statements, the competent authority may specify whether the combination statement should appear
In addition, the manufacturer or supplier may determine the order of the combined hazard statement or the corresponding individual statement
D.1.3 Precautionary statements shall be accompanied by uniform risk elements (pictures, signal words and hazard statements) on the label that meets the requirements. The manufacturer or the competent authority may decide on the supplementary information. For additional supplementary information, such as instructions for use, the manufacturer may provide D.1.3.1 Coding of precautionary statements See IS Annex
D.1.3.2 Coding of precautionary statements
1 Each precautionary statement is assigned a special alphanumeric code, consisting of 1 letter and 1 number, as follows: D. 1.3.2. 1
a) The letter \P\ (standing for "Precautionary Statements\): The first digit represents the type of precautionary statement, as follows: b)
"1\ represents general precautionary statements;
"2\ represents prevention precautionary statements;
|\3\ represents emergency precautionary statements;
"4\ represents storage precautionary statements;
"5" represents disposal precautionary statements;
c) The last two digits (corresponding to the sequential number of the precautionary statements). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used in place of the precautionary statement text.
General precautionary statements
General precautionary measures should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements are applicable to GHS labels under the given conditions (see Table D.1). 9
TTTKANTKAcaChapter 3)
Note 2: Pictograms and symbols in the Model Regulations Pictogram of self-reactive substances: Graphic symbol (flame): black; background color: self-colored with seven vertical red stripes: number "4\ located in the lower corner: black. Graphic symbol for explosives: Graphic symbol (exploding bomb): black; background color: color: number "1\ located in the lower corner, black rKAoNTKAca
GB30000.9—2013
Appendix C
(Normative Appendix)
Classification criteria and labeling of self-reactive substances and mixtures See Table C.1 for the classification criteria and labeling of self-reactive substances and mixtures. Table C.1 Classification criteria and labeling elements for self-reactive substances and mixtures Hazard category
Type C and Type D
Type E and Type F
Based on the test results of Part 1 of the Model Regulations and application of the decision logic of the appendix.
Based on the test results in Part II of the Model Regulations and the application of the decision logic in Appendix A.
Based on the test results in Part II of the Model Regulations and the application of the decision logic in Appendix A.
Based on the test results in Part II of the Model Regulations and the application of the decision logic in Appendix A.
Graphic number
Signal word
Hazard statement
Encai number
Signal
Emergency statement
Graphic symbol
Hazard statement
Graphic symbol
Signal word
Hazard statement
Graphic symbol
Signal word
Hazard statement
Label elements
Heat may explode
Heating may cause explosion or fire
Heating may cause fire
Heating May catch fire
This hazard category has no
assigned label elements
D.1 Overview
Appendix D
(Informative)
Hazard statements and precautionary statements for self-reactive substances and mixtures GB30000.9—2013
D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for self-reactive substances and mixtures. It lists the hazard statements and precautionary statements for each hazard class and hazard category of self-reactive substances and mixtures, see GB13690. D.1.2 Coding of hazard statements D.1.2.1 The coding of hazard statements is specified in Annex 3 of the GHS, which contains a special alphanumeric code consisting of 2 letters and 3 digits, as follows: D.1.2.2 Each hazard statement is assigned a letter (H) (standing for "hazard statement"); a) the first digit represents the type of hazard referred to by the hazard statement numbered in the same section below, as follows; b) "2" represents a physical hazard; 3 represents a health hazard; 4 represents an environmental hazard; 5 represents a chemical hazard; 6 represents a health hazard; 7 represents an environmental hazard; 8 represents an environmental hazard; 9 represents a chemical hazard; 10 represents a chemical hazard; 11 represents a chemical hazard; 12 represents a chemical hazard; 13 represents a chemical hazard; 14 represents a chemical hazard; 15 represents a chemical hazard; 16 represents a chemical hazard; 17 represents a chemical hazard; 18 represents a chemical hazard; 19 represents a chemical hazard. D.1.2.3 Except for the sequence codes corresponding to hazards caused by the inherent properties of substances or humidities, such as: explosive code 200~flammable (code 22), all specified hazard statements shall be used unless otherwise specified. t|| Appearance place
On the label.
It may be specified that the hazard statement should appear on the label
When two or more hazard statements are provided during the combination of hazard statements, the competent authority may specify whether the combination statement should appear
In addition, the manufacturer or supplier may determine the order of the combined hazard statement or the corresponding individual statement
D.1.3 Precautionary statements shall be accompanied by uniform risk elements (pictures, signal words and hazard statements) on the label that meets the requirements. The manufacturer or the competent authority may decide on the supplementary information. For additional supplementary information, such as instructions for use, the manufacturer may provide D.1.3.1 Coding of precautionary statements See IS Annex
D.1.3.2 Coding of precautionary statements
1 Each precautionary statement is assigned a special alphanumeric code, consisting of 1 letter and 1 number, as follows: D. 1.3.2. 1
a) The letter \P\ (standing for "Precautionary Statements\): The first digit represents the type of precautionary statement, as follows: b)
"1\ represents general precautionary statements;
"2\ represents prevention precautionary statements;
|\3\ represents emergency precautionary statements;
"4\ represents storage precautionary statements;
"5" represents disposal precautionary statements;
c) The last two digits (corresponding to the sequential number of the precautionary statements). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement text and should not be used in place of the precautionary statement text.
General precautionary statements
General precautionary measures should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements are applicable to GHS labels under the given conditions (see Table D.1). 9
TTTKANTKAca1 Coding of precautionary statements See IS Annex
D.1.3.2 Coding of precautionary statements
1 Each precautionary statement is assigned a special alphanumeric code, consisting of 1 letter and, as follows: D. 1.3.2. 1
a) Letter \P\ (standing for "precautionary statement\): The first digit represents the type of precautionary statement, as follows: b)
"1\ represents general precautionary statement;
"2\ represents prevention precautionary statement;
\3\ represents emergency precautionary statement;
"4\ represents storage precautionary statement;
"5" represents disposal precautionary statement;
c) The last 2 digits (corresponding to the serial number of the precautionary statement). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement and should not be used to replace the precautionary statement.
General precautionary statements
General precautionary measures should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels under the given conditions (see Table D.1). 9
TTTKANTKAca1 Coding of precautionary statements See IS Annex
D.1.3.2 Coding of precautionary statements
1 Each precautionary statement is assigned a special alphanumeric code, consisting of 1 letter and, as follows: D. 1.3.2. 1
a) Letter \P\ (standing for "precautionary statement\): The first digit represents the type of precautionary statement, as follows: b)
"1\ represents general precautionary statement;
"2\ represents prevention precautionary statement;
\3\ represents emergency precautionary statement;
"4\ represents storage precautionary statement;
"5" represents disposal precautionary statement;
c) The last 2 digits (corresponding to the serial number of the precautionary statement). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code is not part of the precautionary statement and should not be used to replace the precautionary statement.
General precautionary statements
General precautions should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels under the given conditions (see Table D.1). 9
TTTKANTKAca
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