Some standard content:
1CS 65.100. 01
Agricultural Industry Standard of the People's Republic of China
NY/T 788-2004
Guideline on pesticide residue trials2004-04-16Issued
2004-06-01Implemented
Ministry of Agriculture of the People's Republic of China
NY/T 788—2004
Pesticide residue trials are an important component of pesticide management. Pesticide registration, formulation of the maximum residue limit (MRL) standard for pesticides in agricultural products, formulation of pesticide management guidelines and other relevant regulations are based on sufficient residue test data as a scientific basis, which is of great significance to the protection of agricultural product hygiene and food safety. In order to standardize pesticide residue tests and obtain complete and reliable residue evaluation data, this standard is formulated. This standard is proposed by the Ministry of Agriculture of the People's Republic of China: Drafting units of this standard: Pesticide Control Institute of the Ministry of Agriculture, Shanxi Provincial Pesticide Key Laboratory Main drafters of this standard: Liu Guangxue, Qiao Xiongwu, Tao Chuanjiang, He Zhibing, Gong Ren, Qin Dongyi, Zhu Guangyan, Qin Shu, Li Youshun, Song Wencheng 1 Scope
Criteria for pesticide residue test
VY/T 788—2004
This standard specifies the terms and definitions of pesticide residue tests, basic requirements, including the design and implementation of in-house tests, sampling and analysis, residue analysis, test records and reporting requirements. This standard is applicable to the registration of pesticide residue tests, the establishment of maximum residue limits and the formulation of guidelines for the rational use of pesticides. 2 Terms and Definitions
The following terms and definitions apply to this standard: 2.1
Pesticide residues
Refers to the metabolic (or degradation, transformation) products of pesticide active ingredients that have toxicological significance in terms of mass and quantity in agricultural products and the environment after the use of pesticides.
Supervised residue tests Trial refers to the test conducted under good agricultural practices (GAP) and good laboratory practices (P) or similar conditions to obtain the possible maximum commercial residue of the recommended pesticide in edible (or feed) primary agricultural products and soil, as well as the consumption dynamics of these pesticides in surface products, soil (or water).
Recommended dosage
refers to the dosage (in terms of concentration) of a pesticide product proposed for the prevention and control of a certain crop disease or weed after field efficacy test. 2.4
Harvest interval refers to the number of days between the last application of pesticide to the harvest group. 2.5
Preharvest interval interval
safety interval
refers to the number of days between the actual use of the test pesticide confirmed by the residue test and the last application of the pesticide. 2.6
field samplericldsamplc
refers to the sample collected in the field according to the prescribed method. 2.7
laboratory samplelahoratarysample
refers to the sample reduced according to the sample reduction principle, frozen and tested. 2.8
analytical sampleanalytical sample
refers to the sample directly analyzed according to the requirements of the analytical method. 2.9
minimum detection limitlinit nf deleclin, D refers to the mass of the analyte required to produce a signal three times the noise of the detection system (expressed in units of enough) 1
NY/T788—2004
Minimum detection concentration limit of quantificatian, Q refers to the minimum content of the analyte in the sample that can be detected by the method (expressed in units of m pieces) 3 Basic requirements
3.1 Pesticide residue test unit
The experimental space of the pesticide residue test unit should have the following conditions: (1) Instruments, equipment and environmental facilities that meet the technical requirements of residue analysis; (2) Residue analysis should be carried out in accordance with the operating procedures. 3.2 Pesticide residue test personnel
Pesticide residue test requires professional and technical personnel, with professional knowledge and experience in pesticide residue test, master the relevant regulations and skills of pesticide residue test:
3.3 Background information of residue test
The background information of the test includes: the physical and chemical properties of registered pesticide active ingredients and their dosage forms, the crops and control targets used, the appropriate period and frequency of use, the recommended safe interval, the residue analysis method and the existing residue environmental evaluation data, etc., and the common name of the pesticide (in Chinese and English) on the pesticide product label shall be recorded. Name (Chinese, English meaning), precautions and manufacturer (public), product batch number, etc. 3.4 Design principles of residue test
3.4.1 According to the method of use of the pesticide product, it is expected to obtain the maximum residue under the standard conditions. 3.4.2 Unlike the efficacy test, the existence or non-existence of the control target does not affect the implementation of the residue test plan: 4 Design of field test
4.1 Number of repetitions of field test
Determine the number of repetitions of field test according to the quality of the residue test material and the requirements of pesticide registration information. 4.2 Test site
4.2.1 Representative sites should be selected to cover the main planting areas. 4.2.2 The number of test sites depends on the application of registered pesticides, crop characteristics and farming methods. It is not necessary to set up a test site for the same ecological and climatic planting area. However, attention should be paid to the fact that the test data is representative enough and the test site should comply with the requirements of the "Registration Requirements". There should be no less than two planting areas with different ecological and climatic conditions. 4.2.3 Before the test, the soil type, crop, pesticide application industry, climate and other conditions of the test site should be carefully measured. The plots with uniform crop growth and flat terrain should be selected. Before and during the test site planning, the company's pesticides should not be neglected to avoid interference with the analysis and testing of the test pesticides. 4.3 Test Crops
Determine the test crops in accordance with the "Requirements for Pesticide Registration Information". - Use: Pesticides for multiple crops. ...: Select from crops! 1. Carry out residue test on the main varieties of 2 or more major crops: When the dosage and method of use are similar, the residue data on the major crops in the group can be considered to be used for other crops at the same time. 4.4 Experimental plot
Grain crops shall not be less than 30m, leafy vegetables shall not be less than 15㎡, and trees shall not be less than 2 carbon. More than 3 complex plots shall be set up in each plot, and protected rows or fields shall be set up between the plots: The experimental plots can be arranged from low to high according to the dosage of the pesticide. Avoid cross contamination: Pay attention to the water flow and wind when irrigating. Do not irrigate during watering: The test must have a control plot, and set up an effective isolation zone with the treatment area to avoid drift, volatilization and leaching pollution: When doing fumigation, fog and smoke tests in protected areas (warm slaughter, shed, warehouse), different dosage treatments shall be selected separately: 4.5 Application methods and equipment
VY/T 788—2004
The pesticide application method and equipment for the residue test should adopt the standard pesticide application method and equipment. Before application, the pesticide application equipment should be thoroughly cleaned. The application time should be averaged every ten minutes and the amount of liquid should be strictly controlled
4.6 Use of other pesticides
When other pesticides must be applied to ensure the normal growth of the test crops, the amount of pesticides should be selected and the treatment and control plots should be treated uniformly. The pesticides used, time, dosage, etc. should be recorded in detail. 5 Final residue test
5.1 Application dosage
Set more than two application dosages. Under the premise that no complete failure occurs, the highest recommended dosage of the registration H shall be used as the low dosage of the residue test, and 1.5 to 2 times of the low dosage shall be used as the high dosage of the residue test. The unit of application amount is consistent with the unit of dosage on the pesticide label. For example, the application amount for agroforestry, small vegetables and other crops is expressed as "effective ingredient", and the application amount for fruit trees, tea and other crops is expressed as "effective ingredient". 5.2 Application frequency and time || tt || The maximum number of control times deduced at the time of registration and the number of times increased by 1 are the number of applications for residue test: for treatment agents such as seed treatment agents (seed dressing agents), herbicides or plant growth regulators, the number of applications for residue test may not be increased: - generally 5.3 Harvest interval
According to the actual situation of pest control for root crops, weeds, and clothing products, the appropriate harvest period and the estimated harvest interval for the test products to be picked during the spraying period are as follows: cucumber, tea, etc. The test harvest interval should be shorter, such as 2-3-5-1 or 7-1 days for other crops, such as watermelon, citrus, oranges, etc.The interval can be appropriately extended, usually 7d14(..12h). Each residue test is set with more than two harvest intervals, and the second year is a test: 6. Dynamic degradation test
6.1 Expression of degradation dynamics and half-life
The degradation of pesticides is expressed as the time required for the half-time of degradation of pesticide residues, that is, half-life. It can be expressed by graphical method: Plot the degradation curve with the residues of pesticide active ingredients or metabolites and degradation products as the ordinate and time as the abscissa. 3: 2 (linear regression) The half-life is calculated. The residual amount of pesticides in crops and the environment after application generally changes with time in a law of decreasing logarithm. It is calculated using the reaction dynamic equation formula: Gt-Gne K?
(—time (d into) pesticide line residue, unit gram, kilogram (k): one original deposition amount after application, unit gram kilogram (tr): K—dissipation coefficient;
T—time after application, unit day or hour (chengh) 6.2 Dissipation dynamic test type
single crop should be done on the edible part of the crop (plant or fruit), the dynamic "action" in the soil also needs to do the pesticide in the daily water meter dissipation station test: in order to avoid too much cattle length dilution as a knife, do sticky plants or fruits! Choose sticky plants when expressing Or when the fruit is about one square meter in size, start applying the pesticide: 6.3 Dosage for dynamic dissolution test
Use the high dose of the final residue test as the chain drug card for the dynamic dissolution test. When the residue is very low (low 10 times the minimum detection concentration), increase the application of pesticide according to the minimum detection concentration of the analytical method: When spraying plants cannot ensure uniform coverage of the soil and affects soil rolling sampling, spray the pesticide in a special area or another special area of equal size: herbicides and other soil treatment pesticides are carried out according to the application requirements. NY/T 788—2004
6.4 Sampling interval and frequency
The test was conducted by applying pesticides multiple times and taking samples multiple times in the same plot. Samples were taken at 0:00, 1d, 3d, 7d, 14d, 21d, 30d and 45d, respectively, within 2h of the basic temperature of the pesticide solution (i.e. the original sedimentation). For pesticides that degrade quickly, the sampling interval in the early stage should be calculated in hours. The sampling frequency should be no less than 6 times. The minimum residual amount in the last sample should be such that the degradation rate is more than 90%. 6.5 Dynamic degradation test of soil treatment agents and seed dressing agents For soil application of granular agents, seed dressing agents (coating agents), pre-emergence soil treatment agents, etc., samples can be taken at different intervals starting from the time of seedlings to study their degradation trend (the half-life can be ignored). period, or calculate the half-life based on the peak release event as the original deposition scene): 7. Collection, transportation and storage of samples for residue tests 7.1 Sampling methods
7.1.1 Random method: Determine the plants to be collected in the plot by pulling random numbers 7.1.2 Diagonal method: Collect samples at fixed points in the plot in an X-ray shape, 7.1.3 Method: A special case of the diagonal method, or sample at fixed points in the middle and four corners of the plot: 7.1.2 Selectively sample at the selected sampling points, and avoid sampling diseased, too small or immature samples: When collecting fruit tree samples, samples should be collected from all parts of the plant: top, bottom, inside, outside, sunny and shady sides), and more samples should be collected from parts with dense fruits. 7.1.5 Avoid sampling at the edge of the field or the side of the pond (leave a 0.5m edge). Collect all edible parts as required, and pay attention to as much as possible 7.1.6 First collect samples from the control area, and then collect samples from other plots in the order of small to large doses. Collect a representative sample from each plot. 7.2 Sampling volume and sampling location. 7.2.1 Determine the sampling location and sampling volume according to the crop classification, sampling location and recommended sampling volume. 7.2.2 Take 15cm2 soil samples from ten soil products as 1cm2/15cm2 layers. Set 5-10 sampling points in each plot. The sampling volume is not less than 1kg. For the soil decomposition dynamic test, take 1000ml of soil samples from multiple points. After mixing, take 1000ml-2000ml. 7.3 Sample disposal. 7.3.1 Avoid residual agricultural products on the surface of the sample during the collection, loading and preparation of the sample. 7.3.2 Avoid damage and deterioration of samples during sample collection and transportation to avoid affecting the residual amount. 7.3.3 Soil and other debris adhering to the sample can be brushed off with a soft brush or wiped off with a cloth, but avoid cross contamination. 7.4 Sample reduction
7.4.1 Reduce the sample into laboratory samples and 7.4.2 For smaller samples, such as wheat grains and small fruits, use the quartering method to further divide the sample into the actual experimental samples. 7.4.3 The sample cannot be blown, pass through a 1mm aperture sieve, and finally take about 250g-500g of sample and save it for testing. The test can be 1 yuan, +, and the upper residual amount can be corrected with dryness. For samples that cannot pass the soil sieve, remove plant branches and gravel and save them for testing. 7.4.4 For samples of medium-sized individuals, such as tangerine peel, the sample reduction may lead to loss of representativeness. Sufficient test samples can be collected from the fully mixed samples. 7.4.5 For samples of larger individuals, such as cabbage, watermelon and other vegetable and fruit samples, sufficiently representative samples should be collected. 7.5 Sample packaging and storage 7.5.1 Each sample collected should be labeled. The label should be rotatable and should be placed inside and outside the sample packaging. After the samples arrive at the laboratory, each sample should be assigned a number and accompanied by the sample analysis at each stage. The product information (sample name, sampling time, location and precautions, etc.) should be delivered to the laboratory within 24 hours. After the sample is received, the personnel shall check and record the sample information, check and record the sample status and whether it is consistent with the product information and the sample records are complete and accurate. If necessary, they shall be supplemented by checking with the test organizer.
7.5.2 The samples shall be packed in containers that do not contain analytical interfering substances and are not easily damaged. They shall be stored in a freezer or refrigerator as soon as possible. 7.5.3 Fresh samples arriving at the laboratory shall be stored at 1-5°C (maximum 3-5°C) and tested as soon as possible. If they need to be stored for a long time or are frozen samples, the samples must be stored at -20°C and tested after thawing. Some pesticides may degrade during storage and need to be verified by adding yield tests under the same conditions. For products that are tested separately for peel and pulp, they should be separated and packaged separately before freezing. Generally, samples shall not be frozen after pulping unless it is proven that this will not cause loss of pesticide residues. However, the samples can be extracted and the solvent removed before being stored at -20°C. Water samples shall be stored above freezing point to prevent freezing and cracking. When taking frozen samples for testing, the water samples shall not be separated from the samples and the pulp shall be reversed when necessary. The tested samples shall be stored for at least 1 year for re-testing.
8 Field test records
See Appendix 13. Field test record table for pesticide residue test 9 Residue analysis
9.1 Detection method
9.1.1 Selection of detection method
All established detection methods must be validated to prove that the selected method meets the analysis requirements and is feasible. The performance test of the method should be measured by the sensitivity, accuracy and precision of the method. Usually, sensitivity is expressed by the lowest detection concentration of the method; accuracy is expressed by the method addition recovery rate; precision is expressed by the relative standard deviation. 9.1.2 The minimum detection concentration (LO0) must be lower than or equal to the recommended MRI value. 9.1.3 Recovery rate
In principle, the addition concentration should be close to the pesticide content of the sample to be tested. However, the pesticide residue in the sample to be tested is unknown. Therefore, the maximum residue limit (MRI) of the sample and the minimum detection concentration of the method are generally used as the required concentrations, that is, at least 2 addition concentrations must be selected for the addition recovery test: If there is no recommended MRI, the minimum detection concentration and a concentration 10 times the minimum detection concentration are used as the addition recovery rate: The required recovery rates for different addition concentrations are shown in Table 1. Table 1 The required recovery rates for different addition concentrations
Additive concentration
reg-kg
>0.01-- *0.1
>0.m1 --30.01
9.1.4Relative standard deviation (RSI))
Average recovery
70)--110
70-110
0·-120
501 --120
When conducting the recovery test, the recovery test of the concentration must be repeated at least 5 times. The relative standard deviations required for the recovery test of different concentrations are shown in Table 2. Table 2 Relative standard deviations required for the recovery test of different concentrations of addition
>0.1.....0.1
>0.( --001
.0.001
Standard deviation (RS[))
NY/T788—2004
9.1.5 Preparation of standard curve
.-Generally, the external standard method is used for quantification. The standard curve is prepared with the absolute amount of the test pesticide (1g) as the horizontal axis and the response value (such as peak height or peak area) as the vertical axis. The linear response range is determined, and the regression equation and correlation coefficient are calculated. The number of test points for drawing the standard curve shall be no less than 5. 9.2 Confirmation of pesticide detection (confirmatinn test) 9.2.1 Conditions of confirmation test
In the case of qualitative uncertainty in the test results, a confirmation experiment is still required before reporting the test results to avoid making wrong conclusions: Usually, the test pesticide is confirmed by changing the extraction, purification, separation and detection techniques according to the physicochemical properties of the pesticide and the characteristics of the medium. Usually one of the following methods can be selected for confirmation: 9.2.2 Chromatographic column change
That is, use another chromatographic column with different polarity and test conditions for detection. At this time, the relative retention index of the analyte often changes significantly and confirmation can be achieved.
9.2.3 Detector changes
Change the detector, especially the selective detection test 9.2.4 Gas-mass spectrometry or liquid-mass spectrometry technology
First, the retention time, peak shape and response value of the pesticide to be tested in the total ion current chromatogram (T) should be consistent with the standard. Since the H ionization method cannot provide enough molecular structure information, the electron beam method (EI) is generally used: the composition should be referenced to the mass spectrum of the standard substance under the same conditions or the mass spectrum established under similar conditions. When the full scan mode (Scan) is not flexible enough, you need to select the separation mode (SIM). At least 2 special ions with a mass unit of more than 200 or 3 special ions with a mass unit of more than 100 should be selected. The ion ratio of each ion should be consistent with the standard spectrum at a rate of 70% to 130%. In qualitative testing, special attention should be paid to the isotope ion, which can provide reliable qualitative information. Before comparing the spectra, the instrument and sample should be carefully selected to ensure that the sample is consistent with the standard spectrum. 9.2.5 Change of detection method
In certain cases, changing the detection system is also a good choice, such as changing gas chromatography to high-performance liquid chromatography or changing thin-layer chromatography to spectroscopy.
9.3 Calculation and presentation of results
The results are calculated and data statistics are performed based on the detection method adopted. The most commonly used calculation methods for chromatography are external standard method and internal standard method: The residue should be the sum of the pesticide itself and its toxic metabolites and degradation products, which can be expressed as: When the measured value is lower than the lowest measured concentration, "<set lower detection concentration value" should be written. The actual test results should be recorded truthfully, and the repeated test values and average values of each sample should be listed separately, and the recovery rate cannot be corrected.
The results are expressed in two significant figures (such as 0.11.1.1, 11 and 1.1×10, etc.). When the residual concentration is lower than 0.01 mg/kg, the relative standard deviation is even greater. At this time, the results can be expressed in 10 significant figures: For statistical purposes, one significant figure can be added respectively. The recovery rate can be expressed in integer percentages: For soil products, it is calculated based on fresh weight for weeds, and for plant samples. 10 Writing of test report
Appendix (. Format of pesticide residue test report: Appendix A
(Normative Appendix]
Crop classification and sampling location and recommended sampling quantity table NYT 788—2004
This standard is formulated in accordance with the "Requirements for Pesticide Registration Information". Unless otherwise stated, the parts of primary agricultural products for which the MRL should be applied are equivalent to the parts sampled and analyzed. bzxZ.net
Rare cereals
Wheat and wheat
Early grains
Roots and tubers
Small grains
Square vegetables
Green leafy vegetables
Commodity categories
Starch species of this family. Edible hulled rice, early rice, etc.
Most of the genus, starch species of different genus, hulled before consumption, including wheat, small wheat Starchy foods include sweet rice, corn, millet, etc., and are mainly composed of tubers, etc. Most of the lower parts of many species are edible, including potatoes, yam, potatoes, etc. Small grains include red beans, mung beans, peas, etc. The whole part is called edible leaves, etc. Foods composed of cabbage, green vegetables, small mountain vegetables, small rapeseed, etc. Including foods formed by the whole edible white leaf stems and inflorescences of cabbage, green cabbage, tea, etc. Primary agricultural products that should be evaluated and analyzed for high residue limits Seeds: fresh rice including rice grains and axis, block, ring and withered parts; stems and leaves; and purple leaves of sugarcane: cauliflower and cauliflower (rice indigo), outer indigo, spore indigo, ball indigo, leaf indigo, flower tea, steamed flower, kale, etc. Green leafy vegetables are mainly leaf-forming vegetables, the whole leaf is edible, excluding leafy vegetables of the genus Sedum. Including: spinach, cabbage, fennel, moss, cabbage, cabbage, pea seedlings, some radish leaves, sugar cane leaves, wild, chrysanthemum, etc. Root vegetables have many swollen roots, tubers, root tea, etc., and the underground parts of multiple species are the whole vegetable vegetables. Vegetable vegetables include: radish, cabbage, mustard, mustard, sweet potato, celery, parsley, etc. Legumes include legumes, fresh and even inflammatory species, such as peas and peas include: silkworms, sweet peas, scallions, etc. Vegetables are composed of the food pads of real plants, tender and fragrant foods such as orchids, beans, kidney beans, lima beans, greens, etc.
Vegetarian vegetables are composed of the food pads of real plants, tender and fragrant foods such as bamboo shoots, vegetables, grass vegetables, purple steamed vegetables, artichokes, meat mangosteens, edible rhubarb, etc.
The ripening tactics of the mature or painful woody plants are composed of real plants: pumpkin, melon, winter melon, silk pie, zucchini, bitter melon, etc.
Remove the small sweet vegetable sprouts Remove the swollen part of the stem with obvious rot ring and the end, and rinse with running cold water. If necessary, gently brush away the attached mud and residue. After ripening, use clean water paper to absorb the bean or seed powder. Each sample is collected 12 12 points, at least
pick 12 points, pick 12 points sincerely, less
pick 2kz
at least 4 tea: 12
each sample is not less than
+ but not less than
at least 4·13
individuals, not less than
62
individuals, not
at least 6 12
individuals, not less
fresh (roasted), not
less than 2 kg
at least 12
too much edible leaves and tender shoots of Asian and Australian bad and water chestnut department: rhubarb:! Taste, not less than 2kg instrument sample for analysis
whole fruit after removing the fruit
dust less 4 to 6
NY/T 783 -2004
Table A.1 (continued)
Commodity classification
The whole fruit is edible, including: tomatoes, peppers, green peppers, sunflowers, etc. Blue vegetables are mostly edible, and the general mountain vegetables
Vegetables
H-type vegetables
The whole skin of the plants of the family Leucaceae can be eaten after it is peeled off: non-vegetable vegetables such as radish, garlic, ginger, radish, etc. The whole body of the fungi can be eaten
Withholding: Agaricus bisporus, big fat sticky, fragrant stickers, straw mushrooms, 1. Mushrooms, mushrooms,Bamboo shoots are a kind of fruit, which is called pome fruit and belongs to the genus Microbiology of the family Microbiology. The fruit can be eaten directly except for the core. Fruits: berry fruits, tangerine fruits, melon fruits, and other various economic crops, including peach, sour cherry, and peach. The whole fruit is edible in Sichuan. Various fruits of the family Aromaticaceae: sticky, kiwi, field plum, black plum, Yuetie, Boxianchen, sour fruit, blackberry, blackberry, etc., with a peel that has a strong flavor and a juicy fruit inside. The fruit can be eaten directly or used to make beverages. It includes: tangerine, orange, lemon and other winter fruits of this woody or shrub tree, with a hard inedible shell, and a variety of woody or hot rice fruits including: walnut, chestnut, stick, sweet potato, American pecan, etc., which are different kinds of tropical fruits such as melon, white melon, etc., which are mature or unripe fruits of this plant. Generally, the whole fruit can be eaten fresh, including: jujube, peach, olive, red date, persimmon, and other tropical fruits of various tropical industries, and mature or hot or hot fruits of shrub plants. The edible part of the fruit is covered by the peel or outer layer. The whole inedible part is not edible
Package: banana, pineapple, lychee, kiwi, lotus, melon, etc. are each a category
Floral, flower, cattle, stalk, big bean, tobacco, sense, vegetable, note box color to mouth, hemp, flax seed, candy, coffee, single berry, etc. are each a category
Chinese herbal medicines are mostly plant seeds, roots, roots, leaves, fruits and fruits, and are generally processed with multiple flavors of medicine. Various Chinese grapes: Class
Maximum aunt limit company application primary
agricultural products and analysis parts
Except for the fruit stems and green onions: Cloud source and
Root whole part: No sampling of each product
and 12
six bodies, not less
at least 12. 24
Each one depends on, uneasy
T12 kg
Onion or large: Remove the root and can
After the skin is removed, the whole part
contains the entity
The whole collection or edible part!
Asparagus: the whole fruit after the fruit is thinned is analyzed, and the whole fruit is removed, and the rotten edible part is removed.
Fruit: the whole fruit after the stalk is removed is the fruit.
Jujube: the whole fruit is removed, and the remaining part is calculated. Fig:
The whole fruit
unless otherwise specified, the whole fruit
is distinguished, the whole seed or edible part
and the medicinal part
not less than 12 individuals
frequently less than 6-1
individually, not less than 12 individuals, not less than 2
or less than 2 individuals
individually! k
At least 6 2
personal book, less people "
At least 4
slightly soft sand
.1 n: 0.5 4()
table kg-2 kg (fresh)
It's not a small amount
0.$ kg: +)1 ks
Food
Gramineae
Forage crops
Herbs
Condiments
Table A.1 (continued)
Commodity categories
Leguminous materials Made from different crops (with or without seeds)Fresh feed
Including: beans, peanuts, reeds, grass, peas, soybeans, etc., belonging to various genera of Gramineae, fresh feed, silage or hay; Animal materials
Including: sorghum, barley, grass, three-meter straw, high-yield straw, etc. Leaves, stems and roots of many herbs, small, add flavor to food, usually fresh or added to other foods after processing
Seasonings with aromatic seeds, roots, fruits and kernels, used in small amounts, add flavor to other foods, used in other foods
Usually added after processing
Maximum residue limit in the state
Agricultural product parts and sub-parts
Whole plant
Whole →plant sample
Whole edible part
Whole edible part
IY/T 788—2004
I ky,Teu.sx?.
At least one harvest
Not less than 2kg
More than 1 kg () or
0.2kg (fresh)
More than 0.2 (ten or
0.5kg ()
NY/T 788—2004
Test unit
Station
Responsible person (including signature
Sex classification
(fish name]
Species name
Concentrated crop classification
Target of control
Crop planting information
Plot size
Number of treated plants (weight)
Number of plots
Pesticides used in the previous year
Other pesticides used in the plots during the trial period
(application time and frequency)
Crop measures
such as irrigation and fertilization, etc.
Climatic conditions, such as temperature
Rainfall, sunshine, etc. (if possible||t t||Detailed information)
Appendix R
[Informative Appendix
Field Test Record Sheet for Pesticide Residue Test
Test Name
Test Designer
Trade Name
Pesticide Classification
Or Code
Province (Region)
Model Point or Return
Questionnaire
(Including allowance)
Test State
Test Period
Test Period
Such as: Production Orchard or Greenhouse: Planting Period: Long Term: Row: Ten Seasoning (Soil Type, PH. Composition, etc.)
Number of Crops in Each Plot
Number of Rows in Each Plot
1-Before Application (96 h)
2. When taking medicine
3. After taking medicine (before taking medicine)Big melon, etc. are each a category
ground flower, flower cattle, stalk, big bean, tobacco, sense, out of vegetables, injection box color to the mouth, hemp, flax seed, can, coffee, single berry, etc. are each a category
Chinese herbal medicine is mostly plant seeds, roots, cultivation, leaves and fruits, Kaicheng, generally processed after multiple flavors of medicine used in combination. Various Chinese grapes: Class
Maximum aunt limit company application primary
agricultural products obstetrics and scallion: Cloud source and
root whole part: forbidden
Each rotten product
sampling things
and 12
six bodies, not less than
at least 12. 24
Each one is dependent and uneasy
T12 kg
Onion or large scale: remove the root and
can remove the skin and then load the whole part
carry the entity
the whole set or edible part!
Asparagus: the whole fruit after the fruit is thinned is analyzed, and the whole fruit is removed, and the rotten edible part is removed.
Fruit: the whole fruit after the stalk is removed is the fruit.
Jujube: the whole fruit is removed, and the remaining part is calculated. Fig:
The whole fruit
unless otherwise specified, the whole fruit
is distinguished, the whole seed or edible part
and the medicinal part
not less than 12 individuals
frequently less than 6-1
individually, not less than 12 individuals, not less than 2
or less than 2 individuals
individually! k
At least 6 2
personal book, less people "
At least 4
slightly soft sand
.1 n: 0.5 4()
table kg-2 kg (fresh)
It's not a small amount
0.$ kg: +)1 ks
Food
Gramineae
Forage crops
Herbs
Condiments
Table A.1 (continued)
Commodity categories
Leguminous materials Made from different crops (with or without seeds)Fresh feed
Including: beans, peanuts, reeds, grass, peas, soybeans, etc., belonging to various genera of Gramineae, fresh feed, silage or hay; Animal materials
Including: sorghum, barley, grass, three-meter straw, high-yield straw, etc. Leaves, stems and roots of many herbs, small, add flavor to food, usually fresh or added to other foods after processing
Seasonings with aromatic seeds, roots, fruits and kernels, used in small amounts, add flavor to other foods, used in other foods
Usually added after processing
Maximum residue limit in the state
Agricultural product parts and sub-parts
Whole plant
Whole →plant sample
Whole edible part
Whole edible part
IY/T 788—2004
I ky,Teu.sx?.
At least one harvest
Not less than 2kg
More than 1 kg () or
0.2kg (fresh)
More than 0.2 (ten or
0.5kg ()
NY/T 788—2004
Test unit
Station
Responsible person (including signature
Sex classification
(fish name]
Species name
Concentrated crop classification
Target of control
Crop planting information
Plot size
Number of treated plants (weight)
Number of plots
Pesticides used in the previous year
Other pesticides used in the plots during the trial period
(application time and frequency)
Crop measures
such as irrigation and fertilization, etc.
Climatic conditions, such as temperature
Rainfall, sunshine, etc. (if possible||t t||Detailed information)
Appendix R
[Informative Appendix
Field Test Record Sheet for Pesticide Residue Test
Test Name
Test Designer
Trade Name
Pesticide Classification
Or Code
Province (Region)
Model Point or Return
Questionnaire
(Including allowance)
Test State
Test Period
Test Period
Such as: Production Orchard or Greenhouse: Planting Period: Long Term: Row: Ten Seasoning (Soil Type, PH. Composition, etc.)
Number of Crops in Each Plot
Number of Rows in Each Plot
1-Before Application (96 h)
2. When taking medicine
3. After taking medicine (before taking medicine)Big melon, etc. are each a category
ground flower, flower cattle, stalk, big bean, tobacco, sense, out of vegetables, injection box color to the mouth, hemp, flax seed, can, coffee, single berry, etc. are each a category
Chinese herbal medicine is mostly plant seeds, roots, cultivation, leaves and fruits, Kaicheng, generally processed after multiple flavors of medicine used in combination. Various Chinese grapes: Class
Maximum aunt limit company application primary
agricultural products obstetrics and scallion: Cloud source and
root whole part: forbidden
Each rotten product
sampling things
and 12
six bodies, not less than
at least 12. 24
Each one is dependent and uneasy
T12 kg
Onion or large scale: remove the root and
can remove the skin and then load the whole part
carry the entity
the whole set or edible part!
Asparagus: the whole fruit after the fruit is thinned is analyzed, and the whole fruit is removed, and the rotten edible part is removed.
Fruit: the whole fruit after the stalk is removed is the fruit.
Jujube: the whole fruit is removed, and the remaining part is calculated. Fig:
The whole fruit
unless otherwise specified, the whole fruit
is distinguished, the whole seed or edible part
and the medicinal part
not less than 12 individuals
frequently less than 6-1
individually, not less than 12 individuals, not less than 2
or less than 2 individuals
individually! k
At least 6 2
personal book, less people "
At least 4
slightly soft sand
.1 n: 0.5 4()
table kg-2 kg (fresh)
It's not a small amount
0.$ kg: +)1 ks
Food
Gramineae
Forage crops
Herbs
Condiments
Table A.1 (continued)
Commodity categories
Leguminous materials Made from different crops (with or without seeds)Fresh feed
Including: beans, peanuts, reeds, grass, peas, soybeans, etc., belonging to various genera of Gramineae, fresh feed, silage or hay; Animal materials
Including: sorghum, barley, grass, three-meter straw, high-yield straw, etc. Leaves, stems and roots of many herbs, small, add flavor to food, usually fresh or added to other foods after processing
Seasonings with aromatic seeds, roots, fruits and kernels, used in small amounts, add flavor to other foods, used in other foods
Usually added after processing
Maximum residue limit in the state
Agricultural product parts and sub-parts
Whole plant
Whole →plant sample
Whole edible part
Whole edible part
IY/T 788—2004
I ky,Teu.sx?.
At least one harvest
Not less than 2kg
More than 1 kg () or
0.2kg (fresh)
More than 0.2 (ten or
0.5kg ()
NY/T 788—2004
Test unit
Station
Responsible person (including signature
Sex classification
(fish name]
Species name
Concentrated crop classification
Target of control
Crop planting information
Plot size
Number of treated plants (weight)
Number of plots
Pesticides used in the previous year
Other pesticides used in the plots during the trial period
(application time and frequency)
Crop measures
such as irrigation and fertilization, etc.
Climatic conditions, such as temperature
Rainfall, sunshine, etc. (if possible||t t||Detailed information)
Appendix R
[Informative Appendix
Field Test Record Sheet for Pesticide Residue Test
Test Name
Test Designer
Trade Name
Pesticide Classification
Or Code
Province (Region)
Model Point or Return
Questionnaire
(Including allowance)
Test State
Test Period
Test Period
Such as: Production Orchard or Greenhouse: Planting Period: Long Term: Row: Ten Seasoning (Soil Type, PH. Composition, etc.)
Number of Crops in Each Plot
Number of Rows in Each Plot
1-Before Application (96 h)
2. When taking medicine
3. After taking medicine (before taking medicine)5k（）
NY/T 788—2004
Test unit
Station
Responsible person (including signature
Sex classification
(fish name】
Species name
Concentrated crop classification
Target of control
Crop planting information
Plot size
Long treatment quantity (weight)
Number of plots
Pesticides used in the previous year
Other pesticides used in the plot during the trial period
(application time and time)
Crop measures
Such as irrigation and fertilization, etc.
Climate conditions, such as temperature
Rainfall, sunshine, etc. (if possible||t t||Detailed information)
Appendix R
[Informative Appendix
Field Test Record Sheet for Pesticide Residue Test
Test Name
Test Designer
Trade Name
Pesticide Classification
Or Code
Province (Region)
Model Point or Return
Questionnaire
(Including allowance)
Test State
Test Period
Test Period
Such as: Production Orchard or Greenhouse: Planting Period: Long Term: Row: Ten Seasoning (Soil Type, PH. Composition, etc.)
Number of Crops in Each Plot
Number of Rows in Each Plot
1-Before Application (96 h)
2. When taking medicine
3. After taking medicine (before taking medicine)5k（）
NY/T 788—2004
Test unit
Station
Responsible person (including signature
Sex classification
(fish name】
Species name
Concentrated crop classification
Target of control
Crop planting information
Plot size
Long treatment quantity (weight)
Number of plots
Pesticides used in the previous year
Other pesticides used in the plot during the trial period
(application time and time)
Crop measures
Such as irrigation and fertilization, etc.
Climate conditions, such as temperature
Rainfall, sunshine, etc. (if possible||t t||Detailed information)
Appendix R
[Informative Appendix
Field Test Record Sheet for Pesticide Residue Test
Test Name
Test Designer
Trade Name
Pesticide Classification
Or Code
Province (Region)
Model Point or Return
Questionnaire
(Including allowance)
Test State
Test Period
Test Period
Such as: Production Orchard or Greenhouse: Planting Period: Long Term: Row: Ten Seasoning (Soil Type, PH. Composition, etc.)
Number of Crops in Each Plot
Number of Rows in Each Plot
1-Before Application (96 h)
2. When taking medicine
3. After taking medicine (before taking medicine)
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