GB 30000.11-2013 Chemical Classification and Labelling Specification Part 11: Self-igniting solids GB30000.11-2013 Standard compression package decompression password: www.bzxz.net
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of self-igniting solids. This part applies to the classification and labeling of self-igniting solids in accordance with the United Nations Globally Harmonized System of Classification and Labelling of Chemicals.
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended.
The expected structure of GB30000 "Specifications for Classification and Labelling of Chemicals" and the national standards to be replaced are:
———Part 1: General (replaces GB13690-2009);
———Part 2: Explosives (replaces GB20576-2006);
———Part 3: Flammable gases (replaces GB20577-2006);
———Part 4: Aerosols (replaces GB20578-2006);
———Part 5: Oxidizing gases (replaces GB20579-2006);
———Part 6: Gases under pressure (replaces GB20580-2006);
———Part 7: Flammable liquids (replaces GB20581-2006);
———Part 8: Flammable solids (replaces GB 20582-2006);
———Part 9: Self-reactive substances and mixtures (replaces GB 20583-2006);
———Part 10: Pyrophoric liquids (replaces GB 20585-2006);
———Part 11: Pyrophoric solids (replaces GB 20586-2006);
———Part 12: Self-heating substances and mixtures (replaces GB 20584-2006);
———Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replaces GB 20587-2006);
———Part 14: Oxidizing liquids (replaces GB 20589-2006);
——Part 15: Oxidizing solids (replaces GB 20590-2006);
——Part 16: Organic peroxides (replaces GB 20591-2006);
——Part 17: Corrosive to metals (replaces GB 20588-2006);
——Part 18: Acute toxicity (replaces GB 20592-2006);
——Part 19: Skin corrosion/irritation (replaces GB 20593-2006);
——Part 20: Serious eye damage/eye irritation (replaces GB 20594-2006);
——Part 21: Respiratory or skin sensitization (replaces GB 20595-2006);
———Part 22: Germ cell mutagenicity (replaces GB 20596-2006);
———Part 23: Carcinogenicity (replaces GB 20597-2006);
———Part 24: Reproductive toxicity (replaces GB 20598-2006);
———Part 25: Specific target organ toxicity single exposure (replaces GB 20599-2006);
———Part 26: Specific target organ toxicity repeated exposure (replaces GB 20601-2006);
———Part 27: Aspiration hazard;
———Part 28: Hazard to the aquatic environment (replaces GB 20602-2006);
———Part 29: Hazard to the ozone layer;
———Part 30: Warning signs for chemical workplaces.
This part is Part 11 of GB 30000.
This part was drafted in accordance with the rules given in GB/T 1.1-2009.
This part replaces GB 20586-2006 "Safety Specification for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Pyrophoric Solids".
This part is consistent with the relevant technical content of the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition).
Compared with GB 20586-2006, the main technical content changes of this part are as follows:
———The name of the standard has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals—Part 11: Pyrophoric solids" and the English name is "Rules for classification and labelling of chemicals—Part 11: Pyrophoric solids";
———The scope of Chapter 1 has been modified, "Warning label" has been changed to "label", and "Warning statement" has been deleted; ||tt
|| ———The introductory words of Chapter 2 "Normative references" have been modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" has been added as a reference document;
———The introductory words of Chapter 3 "Terms and Definitions" have been added;
———Figure 1 "Decision Logic Diagram" and "Guidance" in Chapter 5 have been made informative Appendix A;
———Deleted the original Chapter 7, and revised Table 3 of the original Chapter 7 as normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition);
———Revised and integrated the original Chapters 6, 7 and 8 into Chapter 6 according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (4th revised edition); revised Table 2 as normative Appendix C;
———Deleted the original Chapter 8, and added the relevant "Hazard Statements" and "Precautionary Statements" as informative Appendix D;
———Added informative Appendix E "Label Examples".
This part was proposed and coordinated by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251).
Drafting units of this part: China Chemical Economic and Technological Development Center, Hangzhou Yangyi Technology Co., Ltd., Zhejiang Chemical Research Institute Co., Ltd., China Chemical Information Center, Huafeng Group Co., Ltd.
The main drafters of this part are: Wang Xiaobing, Ye Shuliang, Li Kunyuan, Wang Gaosheng, Ma Ning, Wang Jingmin, Zhang Chunli, Zhang Qibin, Cao Mengran, Zhao Yongquan, Wen Tao. The
previous versions of the standards replaced by this part are:
———GB 20586—2006.
The following documents are indispensable for the application of this document. For all dated referenced documents, only the dated versions apply to this document. For all undated referenced documents, the latest versions (including all amendments) apply to this document.
GB6944—2012 Classification and Product Name Numbering of Dangerous Goods
GB13690 General Rules for Classification and Hazard Communication of Chemicals
United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS) (Fourth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria (Fifth Revised Edition)
United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition)

ICS13.300
National Standard of the People's Republic of China
GB30000.11—2013
Replaces GB20586-2006
Rules for classification and labelling of chemicals-Part 11: Pyrophoric solids
Issued on October 10, 2013
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China Administration of Standardization of the People's Republic of China
Implementation on November 1, 2014
Chapter 4 and Chapter 6 of this part are mandatory, and the rest are recommended. The expected structure of GB30000 "Chemical Classification and Labeling Specification" and the national standards to be replaced are: Part 1: General (replaces GB13690-2009); Part 2: Explosives (replaces GB20576-2006); Part 3: Flammable gases (replaces GB20577-2006); Part 4: Aerosols (replaces GB20578-2006); Part 5: Oxidizing gases (replaces GB20579-2006): Part 6: Pressurized gases (replaces GB20580-2006) Part 7: Flammable liquids (replaces GB20581-2006): Part 8 : Flammable solids (replacing GB20582-2006): Part 9: Self-reactive substances and mixtures (replacing GB20583-2006); Part 10: Pyrophoric liquids (replacing GB20585-2006); Part 11: Pyrophoric solids (replacing GB20586-2006): Part 12: Self-heating substances and mixtures (replacing GB20584-2006); Part 13: Substances and mixtures which, in contact with water, emit flammable gases (replacing GB20587-2006): Part 14: Oxidizing liquids (replacing GB20589-2006); Part 15: Oxidizing solids ( Replace GB20590-2006); Part 16: Organic Peroxides (Replace GB20591-2006); Part 17: Metal Corrosives (Replace GB20588-2006); Part 18: Acute Toxicity (Replace GB20592-2006); Part 19: Skin Corrosion/Irritation (Replace GB20593-2006); Part 20: Serious Eye Damage/Eye Irritation (Replace GB20594-2006); Part 21: Respiratory or Skin Sensitization (Replace GB20595-2006); Part 22: Germ Cell Mutagenicity (Replace GB20596-2006); Part 23: Acute Toxicity (Replace GB20597-2006); Part 24: Acute Toxicity (Replace GB20598-2006); Part 25: Acute Toxicity (Replace GB20599-2006); Part 26: Acute Toxicity (Replace GB20598-2006); Part 27: Acute Toxicity (Replace GB20599-2006); Part 28: Acute Toxicity (Replace GB20599-2006); Part 29: Acute Toxicity (Replace GB20591-2006); Part 30: Acute Toxicity (Replace GB20591-2006); Part 31: Acute Toxicity (Replace GB20591-2006); Part 32: Acute Toxicity (Replace GB20591-2006); Part 33: Acute Toxicity (Replace GB20591-2006); Part 34: Acute Toxicity (Replace GB20591-2006); Part 35: Acute Toxi —2006); Part 23: Carcinogenicity (replaces GB20597-2006); Part 24: Reproductive toxicity (replaces GB205982006); Part 25: Specific target organ toxicity single exposure (replaces GB20599-2006); Part 26: Specific target organ toxicity repeated exposure (replaces GB20601-2006); Part 27: Inhalation hazard;
Part 28: Hazards to the aquatic environment (replaces GB20602-2006); Part 29: Hazards to the ozone layer:
Part 30: Warning signs for chemical workplaces. This part is Part 11 of GB30000.
This part was drafted in accordance with the rules given in GB/T1.1-2009. GB30000.11—2013
This part replaces GB20586-2006 "Safety Rules for Classification, Precautionary Labelling and Precautionary Statements of Chemicals - Pyrophoric Solids". This part is consistent with the relevant technical content of the United Nations "Globally Harmonized System of Classification and Labelling of Chemicals" (Globally Harmonized System of Classification and Labelling of Chemicals, GHS) (Fourth Revised Edition). Compared with GB20586-2006, the main technical content changes of this part are as follows: 1
GB30000.11—2013
The standard name has been modified. The Chinese name has been changed to "Rules for classification and labelling of chemicals-Part 11: Pyrophoric Solids", and the English name is \Rules for classification and labelling of chemicals-Part ll: Pyrophoric solids\; The scope of Chapter 1 was modified, "Warning Label" was changed to "Label", and "Warning Statement" was deleted; the introductory words of Chapter 2 "Normative References" were modified, and "United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)" was added as a reference document; the introductory words of Chapter 3 "Terms and Definitions" were added; Figure 1 "Decision Logic Diagram" and "Guide" in Chapter 5 were used as informative Appendix A; the original Chapter 7 was deleted, and Table 3 of the original Chapter 7 was modified as Normative Appendix B according to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition)
According to the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (Fourth Revised Edition), the original Chapters 6, 7, and 8 were modified and integrated into Chapter 6: the original Table 2 was modified as Normative Appendix C; the original Chapter 8 was deleted, and the corresponding The relevant "hazard statements" and "precautionary statements" are included as informative appendix D: informative appendix E "label examples" is added. This part is proposed and coordinated by the National Technical Committee for Standardization of Hazardous Chemicals Management (SAC/TC251). Drafting units of this part: China Chemical Economic and Technological Development Center, Hangzhou Yangyi Technology Co., Ltd., Zhejiang Chemical Research Institute Co., Ltd., China Chemical Information Center, Huafeng Group Co., Ltd. The main drafters of this part: Wang Xiaobing, Ye Shuliang, Li Kunyuan, Wang Gaosheng, Ma Ning, Wang Jingmin, Zhang Chunli, Zhang Qibin, Cao Mengran, Zhao Yongquan, Wen Tao.
The previous versions of the standard replaced by this part are: GB205862006.
1 Scope
Chemical classification and labeling specifications
Part 11: Self-igniting solids
GB 30000.11—2013
This part of GB30000 specifies the terms and definitions, classification criteria, decision logic and guidance, and labeling of self-igniting solids. This part applies to the classification and labeling of self-igniting solids in accordance with the United Nations Global Harmonized System of Classification and Labeling of Chemicals (hereinafter referred to as GHS). Normative references
The application of this document is indispensable. For any dated referenced document, only the dated version applies to this document. For the following documents, for this
part. For any undated reference and part, the latest version (including all amendments) applies to this document GB6944-202
GB13690
Classification and product name numbering of hazardous goods
General rules for chemical quantity classification and hazard communication
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS (Part I) United Nations "Recommendations on the Transport of Dangerous Goods" (Fifth revised edition) United Nations "Recommendations on the Transport of Dangerous Goods" Terms and Definitions
Regulations (GB 13690 as defined and the following terms and definitions apply) 3.1
Pyrophoric solids
Solids which can ignite within 5 minutes of contact with air even in small quantities 4 Classification criteria
For the general principles of classification and labelling of pyrophoric solids, see GB 196904.1
Fifth revised edition)
4.2 Pyrophoric solids are classified according to the N.2 test in 33.3.1.4 of Part 3 of the United Nations "Recommendations on the Transport of Dangerous Goods: Manual of Tests and Criteria" (Fifth revised edition) (hereinafter referred to as the "Manual of Tests and Criteria"), see Table 1. Table 1
Classification of spontaneously igniting solids
Solids that ignite within 5 min of coming into contact with air Standard
For classification tests on solid substances or mixtures, the tests should be conducted using the substance or mixture in the form in which it is supplied. For example, if, for the purpose of supply or transport, the same chemical is supplied in a physical form different from that in a previous test and it is considered likely that this form will materially change its performance in the classification test, then the substance or mixture should also be tested in the new form GB30000.11—2013
5 Decision logic and guidance
Decision logic and guidance are for reference only. See Appendix A for decision logic and guidance. It is particularly recommended that those responsible for classification study Chapter 4 before and during the use of decision logics.
6 Labelling
6.1 Overview
6.1.1 For the labels of self-igniting solids, hazard categories are listed in the order of designated pictograms, signal words and hazard statements. The hazard types or categories covered by the United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations (Seventeenth Revised Edition)" (hereinafter referred to as the "Model Regulations") should list the designated corresponding graphic signs for each category on the label. The allocation of label elements for self-igniting solids is shown in Appendix B. 6.1.2 For the classification criteria and label elements for self-igniting solids, see Appendix C6.1.3 The information required on the label includes hazard pictograms, signal words, hazard statements, precautionary statements, product identifiers and supplier logos. Note: For other label elements that have not yet been standardized, such as precautionary statements, they also need to be included on the label. The competent authorities may also require additional information, and suppliers may also add supplementary information
6.2 Hazard pictograms
Hazard pictograms should use black symbols with white backgrounds and red frames. Be wide enough to be eye-catching. The hazard pictograms, graphic symbol colors, numbers and minimum sizes specified in the Model Regulations are shown in Appendix B. 6.3 Signal words
Signal words are words used on labels to indicate the relative severity of the hazard and to alert readers to potential hazards. The signal word "Danger" is used for pyrophoric solids.
6.4 Hazard statements
Hazard statements are phrases assigned to a hazard class and category that describe the hazardous properties of a hazardous product and, where appropriate, its degree of hazard. For pyrophoric solid hazard statements, see Appendix D. 6.5 Precautionary statements
A precautionary statement is a word (and/or pictogram) used to describe measures to minimize or prevent the risk of exposure to hazardous products or improper storage or handling of hazardous products. Adverse effects Recommended measures to be taken. For the purpose of this requirement, there are 5 categories of precautionary statements: general, prevention, emergency, storage and disposal. Precautionary statements for pyrophoric solids are given in Appendix D. 6.6 Product identifiers
6.6.1 The product identifier should be used on the label and should be consistent with the product identifier used on the material safety data sheet. If a substance or mixture is listed in the Model Regulations, the correct UN shipping name should also be used on the packaging. 6.6.2 The label should include the chemical name of the substance. For mixtures or alloys, when acute toxicity, skin or respiratory sensitization or specific target organ toxicity appear on the label, the label should include the chemical composition of all ingredients or alloying elements that may cause these hazards. The competent authority may also require that the substances that may cause the mixture be listed on the label. or alloy hazard. 2
Supplier identification
The name, address and telephone number of the manufacturer or supplier of the substance or mixture shall be provided on the label. Example of a label for a pyrophoric solid
For an example of a label for a pyrophoric solid, see Appendix E. TKAONKAca-
GB30000.11—2013
GB30000.11—2013
A.1 Decision logic
Appendix A
(Informative Appendix)
Decision logic and guidance
For the classification of pyrophoric solids, the decision logic of Figure A. 1 shall be used according to the test method N.2 described in Section 33.3.1.4 of the Manual of Tests and Criteria, Part III. Substance/mixture back to the body
Category 1
It is exposed to air
Category
A.2 Guidance
Decision logic for pyrophoric solids
If production or handling experience shows that the substance or mixture will not ignite spontaneously when exposed to air at normal temperature (i.e. the substance is known to be stable for long periods of time (several days) at room temperature), the classification procedure for pyrophoric solids is not applicable. The allocation of label elements is shown in Table B.1.
Category 1
Spontaneous combustion when exposed to air
Appendix B
(Normative Appendix)
Allocation of label elements
Table B.1 Allocation of label elements for spontaneously igniting solids
Natural solids
rKAoNTKAca
GB30000.11—2013
In the "Model Regulations":
Color of graphic symbols
Graphic symbol (flame): black;
Background, upper half white, lower half
red:
Number "4\ in the lower corner: black.
Number 4 in the figure is GB6944
2012 Class 4.
The minimum size of the graphic sign for cargo transport is 100mmX100mm
GB30000.11—2013
Appendix C
(Normative Appendix)
Classification standards and label elements for spontaneous combustion solids
Classification standards and label elements for spontaneous combustion solids are shown in Table C.1. Table C.1
Classification standards and label elements for spontaneous combustion solids
Hazard category
Graphic symbol
This solid will burn within 5 minutes when in contact with air
Signal word
Hazard statement
Label element| |tt||Spontaneous combustion when exposed to air
D.1 Overview
Appendix D
(Informative Appendix)
Hazard statements and precautionary statements for spontaneously igniting solids
GB30000.11—2013
D.1.1 This appendix provides guidance on how to use hazard statements and precautionary statements that comply with GHS for spontaneously igniting solids, and lists the recommended hazard statements and precautionary statements for each hazard class and hazard category of spontaneously igniting solids, see GB13690. D.1.2 Coding of hazard statements
D.1.2.1 For the coding of hazard statements, see Annex 3 of GHS. D.1.2.2 Each hazard statement is assigned a specific alphanumeric character. A mixed code consisting of 1 letter and 3 digits, as follows: wwW.bzxz.Net
The letter "H\ (standing for "Hazard Statement") a)
b) The first digit represents the type of hazard referred to by the hazard statement set by the different part numbers, as follows: "2" represents physical hazard;
"3" represents health hazard:
-"4" represents environmental hazard:
C) The last 2 digits correspond to the sequential number of the hazard caused by the inherent properties of the substance or mixture, such as: explosiveness (codes 200 to 210), flammability (codes 220 to 230), etc. D.1.2.3 Unless otherwise specified, all specified hazard statements shall appear on the label. The competent authority may specify the order in which the hazard statements appear on the label. In addition, when a combined hazard statement provides two or more hazard statements, the competent authority may specify whether the combined hazard statement or the corresponding individual statement shall be included on the label, or whether it is left to the manufacturer/supplier to decide. D.1.3 Precautionary statements should be included on the label together with the harmonized hazard communication elements (pictograms, signal words and hazard statements). Additional supplementary information, such as instructions for use, may also be provided at the discretion of the manufacturer/supplier and/or competent authority. D.1.3.1 Precautionary statement codes are listed in Annex 3 of the GHS. D.1.3.2 Coding of precautionary statements
D.1.3.2.1 Each precautionary statement is assigned a special alphanumeric code consisting of 1 letter and 3 numbers, as follows:
The letter "P\ (standing for "precautionary statement\"); the first number represents the type of precautionary statement, as follows:b)
"1\ represents general precautionary statement;
\2" represents prevention precautionary statement;
"3\ represents emergency precautionary statement:
*4\ represents storage precautionary statement;
"5\ represents disposal precautionary statement;
c) the last 2 numbers (corresponding to the serial number of the precautionary statement). D.1.3.2.2 The precautionary statement code is for reference only. The precautionary statement code The code is not part of the precautionary statement and should not be used in place of the precautionary statement.
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GB30000.11—2013
D.2 General precautionary statements
General precautions should be taken for all substances and mixtures classified as hazardous to human health or the environment. The following general precautionary statements apply to GHS labels under the given conditions (see Table D.1). Table D.1
General public
Production workers
Supplementary information
Label, supplementary label information
Label, supplementary label information, safety data sheet, workplace labeling
D.3 Precautionary statements for spontaneously igniting solids
D.3.1Precautionary statements for pyrophoric solidsSee Table 102
Hazard category
Hazard statement
General precautionary statements
General precautionary statements
If medical attention is required: Keep product container or label with you. Keep out of reach of children.
Read label before use.
Precautionary statements for pyrophoric solids
Graphic symbol
H250 May ignite spontaneously if exposed to air
Precautionary statements
P335P334
Keep away from heat/sparks/open flames/hot surfaces. No smokingIgnition sources specified by manufacturer/supplier or the competent authority as applicable.
Do not allow contact with air.
Wear protective gloves/protective clothing/eye protection/face protection.
Manufacturer/supplier or the competent authority to specify type of equipment. Shake off fine particles from skin
Wash in cool water/wrap with wet bandage
.
P370+P378
In case of fire·Use·to extinguish.
.Manufacturer/supplier or the competent authority to specify appropriate media.
Contact with water may increase the hazard.
Store contents in
.Manufacturer/supplier or the competent authority to specify appropriate liquid
or inert gas.
GB30000.11—2013
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